Organothiol Monolayer Formation Directly on Muscovite Mica

de Poel, Wester; Brugman, Sander J. T.; van de Ven, Kim H. A.; Gasseling, Anouk; de Lange, Jordi; Townsend, Eleanor R.; Engwerda, Anthonius H. J.; Jankowski, Maciej; Blijlevens, Melian A. R.; Werkhoven, Ben L.; Drnec, Jakub; Carlà, Francesco; Felici, Roberto; Tuladhar, Aashish; Adhikari, Narendra M.; De Yoreo, James J.; Elemans, Johannes A. A. W.; van Enckevort, Willem J. P.; Rowan, Alan E.; Vlieg, Elias

doi:10.1002/anie.201913327

Title: Organothiol Monolayer Formation Directly on Muscovite Mica

Journal Article · 17 December 2019 · Angewandte Chemie (International Edition)

DOI: https://doi.org/10.1002/anie.201913327 · OSTI ID:1605475

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^[1]; van de Ven, Kim H. A. ^[1]; Gasseling, Anouk ^[1]; de Lange, Jordi ^[1];

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^[1]; Jankowski, Maciej ^[2];

^[1]; Werkhoven, Ben L. ^[3];

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^[4]; Adhikari, Narendra M. ^[4];

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Radboud University Institute for Molecules and Materials Heyendaalseweg 135 6525AJ Nijmegen The Netherlands
ESRF, 71 Avenue des Martyrs Grenoble France
Utrecht University Institute for Theoretical Physics Princetonplein 5 3584 CC Utrecht The Netherlands
Physical Sciences Division Pacific Northwest National Laboratory Richland WA 99352 USA

Abstract Organothiol monolayers on metal substrates (Au, Ag, Cu) and their use in a wide variety of applications have been extensively studied. Here, the growth of layers of organothiols directly onto muscovite mica is demonstrated using a simple procedure. Atomic force microscopy, surface X‐ray diffraction, and vibrational sum‐frequency generation IR spectroscopy studies revealed that organothiols with various functional endgroups could be self‐assembled into (water) stable and adaptable ultra‐flat organothiol monolayers over homogenous areas as large as 1 cm ² . The strength of the mica–organothiol interactions could be tuned by exchanging the potassium surface ions for copper ions. Several of these organothiol monolayers were subsequently used as a template for calcite growth.

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Sponsoring Organization:: USDOE

OSTI ID:: 1605475

Journal Information:: Angewandte Chemie (International Edition), Journal Name: Angewandte Chemie (International Edition) Journal Issue: 6 Vol. 59; ISSN 1433-7851

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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