Organothiol Monolayer Formation Directly on Muscovite Mica
Abstract
Abstract Organothiol monolayers on metal substrates (Au, Ag, Cu) and their use in a wide variety of applications have been extensively studied. Here, the growth of layers of organothiols directly onto muscovite mica is demonstrated using a simple procedure. Atomic force microscopy, surface X‐ray diffraction, and vibrational sum‐frequency generation IR spectroscopy studies revealed that organothiols with various functional endgroups could be self‐assembled into (water) stable and adaptable ultra‐flat organothiol monolayers over homogenous areas as large as 1 cm 2 . The strength of the mica–organothiol interactions could be tuned by exchanging the potassium surface ions for copper ions. Several of these organothiol monolayers were subsequently used as a template for calcite growth.
- Authors:
-
- Radboud University Institute for Molecules and Materials Heyendaalseweg 135 6525AJ Nijmegen The Netherlands
- ESRF, 71 Avenue des Martyrs Grenoble France
- Utrecht University Institute for Theoretical Physics Princetonplein 5 3584 CC Utrecht The Netherlands
- Physical Sciences Division Pacific Northwest National Laboratory Richland WA 99352 USA
- Publication Date:
- Research Org.:
- Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Science (SC), Biological and Environmental Research (BER)
- OSTI Identifier:
- 1605475
- Alternate Identifier(s):
- OSTI ID: 1605476; OSTI ID: 1623492
- Grant/Contract Number:
- AC05-76RL01830
- Resource Type:
- Published Article
- Journal Name:
- Angewandte Chemie (International Edition)
- Additional Journal Information:
- Journal Name: Angewandte Chemie (International Edition) Journal Volume: 59 Journal Issue: 6; Journal ID: ISSN 1433-7851
- Publisher:
- Wiley Blackwell (John Wiley & Sons)
- Country of Publication:
- Germany
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; surface chemistry; organothiol; muscovite mica; monolayers; calcite
Citation Formats
de Poel, Wester, Brugman, Sander J. T., van de Ven, Kim H. A., Gasseling, Anouk, de Lange, Jordi, Townsend, Eleanor R., Engwerda, Anthonius H. J., Jankowski, Maciej, Blijlevens, Melian A. R., Werkhoven, Ben L., Drnec, Jakub, Carlà, Francesco, Felici, Roberto, Tuladhar, Aashish, Adhikari, Narendra M., De Yoreo, James J., Elemans, Johannes A. A. W., van Enckevort, Willem J. P., Rowan, Alan E., and Vlieg, Elias. Organothiol Monolayer Formation Directly on Muscovite Mica. Germany: N. p., 2019.
Web. doi:10.1002/anie.201913327.
de Poel, Wester, Brugman, Sander J. T., van de Ven, Kim H. A., Gasseling, Anouk, de Lange, Jordi, Townsend, Eleanor R., Engwerda, Anthonius H. J., Jankowski, Maciej, Blijlevens, Melian A. R., Werkhoven, Ben L., Drnec, Jakub, Carlà, Francesco, Felici, Roberto, Tuladhar, Aashish, Adhikari, Narendra M., De Yoreo, James J., Elemans, Johannes A. A. W., van Enckevort, Willem J. P., Rowan, Alan E., & Vlieg, Elias. Organothiol Monolayer Formation Directly on Muscovite Mica. Germany. https://doi.org/10.1002/anie.201913327
de Poel, Wester, Brugman, Sander J. T., van de Ven, Kim H. A., Gasseling, Anouk, de Lange, Jordi, Townsend, Eleanor R., Engwerda, Anthonius H. J., Jankowski, Maciej, Blijlevens, Melian A. R., Werkhoven, Ben L., Drnec, Jakub, Carlà, Francesco, Felici, Roberto, Tuladhar, Aashish, Adhikari, Narendra M., De Yoreo, James J., Elemans, Johannes A. A. W., van Enckevort, Willem J. P., Rowan, Alan E., and Vlieg, Elias. Wed .
"Organothiol Monolayer Formation Directly on Muscovite Mica". Germany. https://doi.org/10.1002/anie.201913327.
@article{osti_1605475,
title = {Organothiol Monolayer Formation Directly on Muscovite Mica},
author = {de Poel, Wester and Brugman, Sander J. T. and van de Ven, Kim H. A. and Gasseling, Anouk and de Lange, Jordi and Townsend, Eleanor R. and Engwerda, Anthonius H. J. and Jankowski, Maciej and Blijlevens, Melian A. R. and Werkhoven, Ben L. and Drnec, Jakub and Carlà, Francesco and Felici, Roberto and Tuladhar, Aashish and Adhikari, Narendra M. and De Yoreo, James J. and Elemans, Johannes A. A. W. and van Enckevort, Willem J. P. and Rowan, Alan E. and Vlieg, Elias},
abstractNote = {Abstract Organothiol monolayers on metal substrates (Au, Ag, Cu) and their use in a wide variety of applications have been extensively studied. Here, the growth of layers of organothiols directly onto muscovite mica is demonstrated using a simple procedure. Atomic force microscopy, surface X‐ray diffraction, and vibrational sum‐frequency generation IR spectroscopy studies revealed that organothiols with various functional endgroups could be self‐assembled into (water) stable and adaptable ultra‐flat organothiol monolayers over homogenous areas as large as 1 cm 2 . The strength of the mica–organothiol interactions could be tuned by exchanging the potassium surface ions for copper ions. Several of these organothiol monolayers were subsequently used as a template for calcite growth.},
doi = {10.1002/anie.201913327},
journal = {Angewandte Chemie (International Edition)},
number = 6,
volume = 59,
place = {Germany},
year = {Wed Dec 18 00:00:00 EST 2019},
month = {Wed Dec 18 00:00:00 EST 2019}
}
https://doi.org/10.1002/anie.201913327
Web of Science
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