Organothiol Monolayer Formation Directly on Muscovite Mica
Abstract
Organothiol monolayers on metal substrates (Au, Ag, Cu) and their use in a wide variety of applications have been extensively studied. Here, we demonstrate the growth of layers of organothiols directly onto muscovite mica using a simple protocol. Atomic force microscopy, surface X-ray diffraction and vibrational sum-frequency generation IR spectoscopy studies revealed that organothiols with various functional endgroups could be self-assembled into (water) stable and adaptable ultra-flat organothiol monolayers over homogenous areas as large as 1 cm2. We were able to tune the strength of the mica-organothiol interactions by exchanging the potassium surface ions for copper ions. Several of these organothiol monolayers were subsequently used as a template for calcite growth.
- Authors:
-
[1];
[1];
[1];
[1];
[1];
[2];
[2];
[2];
[4];
[4];
[1];
[1];
[1];
[1]
- Radboud UniversityInstitute for Molecules and Materials Heyendaalseweg 135 6525AJ Nijmegen The Netherlands
- ESRF, 71 Avenue des Martyrs Grenoble France
- Utrecht UniversityInstitute for Theoretical Physics Princetonplein 5 3584 CC Utrecht The Netherlands
- Physical Sciences DivisionPacific Northwest National Laboratory Richland WA 99352 USA
- Publication Date:
- Research Org.:
- Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Biological and Environmental Research (BER); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division
- OSTI Identifier:
- 1579766
- Alternate Identifier(s):
- OSTI ID: 1579767; OSTI ID: 1614999
- Report Number(s):
- PNNL-SA-149556
Journal ID: ISSN 0044-8249
- Grant/Contract Number:
- AC05-76RL01830
- Resource Type:
- Published Article
- Journal Name:
- Angewandte Chemie
- Additional Journal Information:
- Journal Name: Angewandte Chemie Journal Volume: 132 Journal Issue: 6; Journal ID: ISSN 0044-8249
- Publisher:
- German Chemical Society
- Country of Publication:
- Germany
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Kalzit; Monolagen; Muskovit; Oberflächenchemie; Organothiol-Verbindungen
Citation Formats
Poel, Wester, Brugman, Sander J. T., Ven, Kim H. A., Gasseling, Anouk, Lange, Jordi, Townsend, Eleanor R., Engwerda, Anthonius H. J., Jankowski, Maciej, Blijlevens, Melian A. R., Werkhoven, Ben L., Drnec, Jakub, Carlà, Francesco, Felici, Roberto, Tuladhar, Aashish, Adhikari, Narendra M., De Yoreo, James J., Elemans, Johannes A. A. W., Enckevort, Willem J. P., Rowan, Alan E., and Vlieg, Elias. Organothiol Monolayer Formation Directly on Muscovite Mica. Germany: N. p., 2019.
Web. doi:10.1002/ange.201913327.
Poel, Wester, Brugman, Sander J. T., Ven, Kim H. A., Gasseling, Anouk, Lange, Jordi, Townsend, Eleanor R., Engwerda, Anthonius H. J., Jankowski, Maciej, Blijlevens, Melian A. R., Werkhoven, Ben L., Drnec, Jakub, Carlà, Francesco, Felici, Roberto, Tuladhar, Aashish, Adhikari, Narendra M., De Yoreo, James J., Elemans, Johannes A. A. W., Enckevort, Willem J. P., Rowan, Alan E., & Vlieg, Elias. Organothiol Monolayer Formation Directly on Muscovite Mica. Germany. https://doi.org/10.1002/ange.201913327
Poel, Wester, Brugman, Sander J. T., Ven, Kim H. A., Gasseling, Anouk, Lange, Jordi, Townsend, Eleanor R., Engwerda, Anthonius H. J., Jankowski, Maciej, Blijlevens, Melian A. R., Werkhoven, Ben L., Drnec, Jakub, Carlà, Francesco, Felici, Roberto, Tuladhar, Aashish, Adhikari, Narendra M., De Yoreo, James J., Elemans, Johannes A. A. W., Enckevort, Willem J. P., Rowan, Alan E., and Vlieg, Elias. Wed .
"Organothiol Monolayer Formation Directly on Muscovite Mica". Germany. https://doi.org/10.1002/ange.201913327.
@article{osti_1579766,
title = {Organothiol Monolayer Formation Directly on Muscovite Mica},
author = {Poel, Wester and Brugman, Sander J. T. and Ven, Kim H. A. and Gasseling, Anouk and Lange, Jordi and Townsend, Eleanor R. and Engwerda, Anthonius H. J. and Jankowski, Maciej and Blijlevens, Melian A. R. and Werkhoven, Ben L. and Drnec, Jakub and Carlà, Francesco and Felici, Roberto and Tuladhar, Aashish and Adhikari, Narendra M. and De Yoreo, James J. and Elemans, Johannes A. A. W. and Enckevort, Willem J. P. and Rowan, Alan E. and Vlieg, Elias},
abstractNote = {Organothiol monolayers on metal substrates (Au, Ag, Cu) and their use in a wide variety of applications have been extensively studied. Here, we demonstrate the growth of layers of organothiols directly onto muscovite mica using a simple protocol. Atomic force microscopy, surface X-ray diffraction and vibrational sum-frequency generation IR spectoscopy studies revealed that organothiols with various functional endgroups could be self-assembled into (water) stable and adaptable ultra-flat organothiol monolayers over homogenous areas as large as 1 cm2. We were able to tune the strength of the mica-organothiol interactions by exchanging the potassium surface ions for copper ions. Several of these organothiol monolayers were subsequently used as a template for calcite growth.},
doi = {10.1002/ange.201913327},
journal = {Angewandte Chemie},
number = 6,
volume = 132,
place = {Germany},
year = {Wed Dec 18 00:00:00 EST 2019},
month = {Wed Dec 18 00:00:00 EST 2019}
}
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1002/ange.201913327
https://doi.org/10.1002/ange.201913327
Other availability
Search WorldCat to find libraries that may hold this journal
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
A Brief Introduction to the Streptavidin-Biotin System and its Usage in Modern Surface Based Assays
journal, May 2008
- Grunwald, Christian
- Zeitschrift für Physikalische Chemie, Vol. 222, Issue 5-6
Noble metal surface degradation induced by organothiols
journal, August 2017
- de Poel, Wester; Gasseling, Anouk; Mulder, Peter
- Surface Science, Vol. 662
Quantitative determination of molecular structure in multilayered thin films of biaxial and lower symmetry from photon spectroscopies. I. Reflection infrared vibrational spectroscopy
journal, January 1992
- Parikh, Atul N.; Allara, David L.
- The Journal of Chemical Physics, Vol. 96, Issue 2
Fabrication of Molecular Nanotemplates in Self-Assembled Monolayers by Extreme-Ultraviolet-Induced Chemical Lithography
journal, December 2007
- Turchanin, Andrey; Schnietz, Mark; El-Desawy, Mohamed
- Small, Vol. 3, Issue 12
Freestanding Nanosheets from Crosslinked Biphenyl Self-Assembled Monolayers
journal, November 2005
- Eck, W.; Küller, A.; Grunze, M.
- Advanced Materials, Vol. 17, Issue 21
Self-assembled monolayers as a tunable platform for biosensor applications
journal, January 2002
- Chaki, Nirmalya K.; Vijayamohanan, K.
- Biosensors and Bioelectronics, Vol. 17, Issue 1-2
Oriented Growth of Calcite Controlled by Self-Assembled Monolayers of Functionalized Alkanethiols Supported on Gold and Silver
journal, May 1999
- Aizenberg, Joanna; Black, Andrew J.; Whitesides, George M.
- Journal of the American Chemical Society, Vol. 121, Issue 18
Sum-frequency vibrational spectroscopy of the solid/liquid interface
journal, January 1995
- Bain, Colin D.
- Journal of the Chemical Society, Faraday Transactions, Vol. 91, Issue 9
Structure and growth of self-assembling monolayers
journal, November 2000
- Schreiber, Frank
- Progress in Surface Science, Vol. 65, Issue 5-8
Formation of Holes in Alkanethiol Monolayers on Gold
journal, July 1994
- Sondag-Huethorst, J. A. M.; Schonenberger, C.; Fokkink, L. G. J.
- The Journal of Physical Chemistry, Vol. 98, Issue 27
Metal ion-exchange on the muscovite mica surface
journal, November 2017
- de Poel, Wester; Vaessen, Sarah L.; Drnec, Jakub
- Surface Science, Vol. 665
Muscovite mica: Flatter than a pancake
journal, January 2014
- de Poel, Wester; Pintea, Stelian; Drnec, Jakub
- Surface Science, Vol. 619
Non-chemisorbed gold–sulfur binding prevails in self-assembled monolayers
journal, March 2019
- Inkpen, Michael S.; Liu, Zhen–Fei; Li, Haixing
- Nature Chemistry, Vol. 11, Issue 4
One Nanometer Thin Carbon Nanosheets with Tunable Conductivity and Stiffness
journal, March 2009
- Turchanin, Andrey; Beyer, André; Nottbohm, Christoph T.
- Advanced Materials, Vol. 21, Issue 12
Formation and Structure of Self-Assembled Monolayers
journal, January 1996
- Ulman, Abraham
- Chemical Reviews, Vol. 96, Issue 4, p. 1533-1554
Comparison of the structures and wetting properties of self-assembled monolayers of n-alkanethiols on the coinage metal surfaces, copper, silver, and gold
journal, September 1991
- Laibinis, Paul E.; Whitesides, George M.; Allara, David L.
- Journal of the American Chemical Society, Vol. 113, Issue 19
Adsorption of bifunctional organic disulfides on gold surfaces
journal, June 1983
- Nuzzo, Ralph G.; Allara, David L.
- Journal of the American Chemical Society, Vol. 105, Issue 13
Self-assembled monolayers of thiols and dithiols on gold: new challenges for a well-known system
journal, January 2010
- Vericat, C.; Vela, M. E.; Benitez, G.
- Chemical Society Reviews, Vol. 39, Issue 5
Self-Assembled Monolayers of Thiolates on Metals as a Form of Nanotechnology
journal, April 2005
- Love, J. Christopher; Estroff, Lara A.; Kriebel, Jennah K.
- Chemical Reviews, Vol. 105, Issue 4
Epitaxy of Calcite on Mica
journal, February 2010
- Stephens, Christopher J.; Mouhamad, Youmna; Meldrum, Fiona C.
- Crystal Growth & Design, Vol. 10, Issue 2
Organic surfaces exposed by self-assembled organothiol monolayers: Preparation, characterization, and application
journal, July 2009
- Kind, Martin; Wöll, Christof
- Progress in Surface Science, Vol. 84, Issue 7-8