Perovskite-related hybrid noble metal iodides: Formamidinium platinum iodide [(FA)2PtIVI6] and mixed-valence methylammonium gold iodide [(MA)2AuIAuIIII6]
Abstract
Noble metal halide compounds are an exciting class of materials which display unique crystal chemistry with temperature and pressure. In this paper, we report two new compounds, single-valence formamidinium platinum iodide [(FA)2PtIVI6] and mixed-valence methylammonium gold iodide [(MA)2AuIAuIIII6]. Structural changes between 300 K and 100 K have been monitored. The compounds crystallize in two different perovskite-related structure classes, with the added complexity of a disordered, “tumbling”, organic cation at 300 K. This tumbling is significantly reduced at 100 K. (FA)2PtIVI6 undergoes in-phase octahedral tilting similar to related vacancy-ordered perovskite materials. At 100 K, (MA)2AuIAuIIII6 undergoes a transition which facilitates stronger Au–I covalent bonding as made evident by a contraction of the unit cell and distances between Au and I atoms in the ab plane.
- Publication Date:
- Research Org.:
- Univ. of California, Santa Barbara, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF)
- OSTI Identifier:
- 1599742
- Alternate Identifier(s):
- OSTI ID: 1550518
- Grant/Contract Number:
- SC0012541; DMR-1121053
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Inorganica Chimica Acta
- Additional Journal Information:
- Journal Volume: 468; Journal Issue: C; Journal ID: ISSN 0020-1693
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 36 MATERIALS SCIENCE; Mixed-valence; Perovskite; Gold-iodide; Methylammonium; Formamidinium
Citation Formats
Evans, Hayden A., Schueller, Emily C., Smock, Sara R., Wu, Guang, Seshadri, Ram, and Wudl, Fred. Perovskite-related hybrid noble metal iodides: Formamidinium platinum iodide [(FA)2PtIVI6] and mixed-valence methylammonium gold iodide [(MA)2AuIAuIIII6]. United States: N. p., 2017.
Web. doi:10.1016/j.ica.2017.04.060.
Evans, Hayden A., Schueller, Emily C., Smock, Sara R., Wu, Guang, Seshadri, Ram, & Wudl, Fred. Perovskite-related hybrid noble metal iodides: Formamidinium platinum iodide [(FA)2PtIVI6] and mixed-valence methylammonium gold iodide [(MA)2AuIAuIIII6]. United States. https://doi.org/10.1016/j.ica.2017.04.060
Evans, Hayden A., Schueller, Emily C., Smock, Sara R., Wu, Guang, Seshadri, Ram, and Wudl, Fred. Thu .
"Perovskite-related hybrid noble metal iodides: Formamidinium platinum iodide [(FA)2PtIVI6] and mixed-valence methylammonium gold iodide [(MA)2AuIAuIIII6]". United States. https://doi.org/10.1016/j.ica.2017.04.060. https://www.osti.gov/servlets/purl/1599742.
@article{osti_1599742,
title = {Perovskite-related hybrid noble metal iodides: Formamidinium platinum iodide [(FA)2PtIVI6] and mixed-valence methylammonium gold iodide [(MA)2AuIAuIIII6]},
author = {Evans, Hayden A. and Schueller, Emily C. and Smock, Sara R. and Wu, Guang and Seshadri, Ram and Wudl, Fred},
abstractNote = {Noble metal halide compounds are an exciting class of materials which display unique crystal chemistry with temperature and pressure. In this paper, we report two new compounds, single-valence formamidinium platinum iodide [(FA)2PtIVI6] and mixed-valence methylammonium gold iodide [(MA)2AuIAuIIII6]. Structural changes between 300 K and 100 K have been monitored. The compounds crystallize in two different perovskite-related structure classes, with the added complexity of a disordered, “tumbling”, organic cation at 300 K. This tumbling is significantly reduced at 100 K. (FA)2PtIVI6 undergoes in-phase octahedral tilting similar to related vacancy-ordered perovskite materials. At 100 K, (MA)2AuIAuIIII6 undergoes a transition which facilitates stronger Au–I covalent bonding as made evident by a contraction of the unit cell and distances between Au and I atoms in the ab plane.},
doi = {10.1016/j.ica.2017.04.060},
journal = {Inorganica Chimica Acta},
number = C,
volume = 468,
place = {United States},
year = {Thu May 04 00:00:00 EDT 2017},
month = {Thu May 04 00:00:00 EDT 2017}
}
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