One-Pot Aqueous and Template-Free Synthesis of Mesoporous Polymeric Resins

Nabavinia, Mahboubeh; Kanjilal, Baishali; Hesketh, Alexander; Wall, Philip; Shirazi Amin, Alireza; Kerns, Peter; Stanzione, Joseph; Suib, Steven; Liu, Fujian; Noshadi, Iman

doi:10.3390/catal9090782

Title: One-Pot Aqueous and Template-Free Synthesis of Mesoporous Polymeric Resins

Journal Article · 19 September 2019 · Catalysts

DOI: https://doi.org/10.3390/catal9090782 · OSTI ID:1598222

^[1]; Kanjilal, Baishali ^[1]; Hesketh, Alexander ^[1]; Wall, Philip ^[1]; Shirazi Amin, Alireza ^[2]; Kerns, Peter ^[2]; Stanzione, Joseph ^[1]; Suib, Steven ^[2]; Liu, Fujian ^[3]; Noshadi, Iman ^[1]

Rowan Univ., Glassboro, NJ (United States)
Univ. of Connecticut, Storrs, CT (United States)
Fuzhou Univ. (China)

This report explores the novel one-pot aqueous phase synthesis of mesoporous phenolic-hyperbranched polyethyleneimine resins without the use of a template, and their utility as heterogeneous catalysts in batch reactors and continuous microreactors. Catalyst surface areas of up to 432 m²/g were achieved with a uniform Pd distribution and an interconnected, highly porous, network structure, confirmed through Brunauer–Emmett–Teller (BET) surface area measurements, scanning electron microscopes (SEM), X-Ray Photoelectron Spectroscopy (XPS), Transmission Electron Microscopy (TEM), and Energy-dispersive X-ray spectroscopy (EDS). The heterogeneous catalysts achieved a maximum 98.98 ± 1% conversion in batch Suzuki couplings, with conversions being dependent upon reaction conditions, reactant chemistries, Pd loading and catalyst surface area. The catalysts were shown to be recyclable with only a marginal loss in conversion achieved after five runs. Up to 62 ± 5% and 46.5 ± 8% conversions at 0.2 mL/s and 0.4 mL/s flow rates, respectively, were achieved in a continuous microreactor. Understanding the mechanism of action of this mesoporous resin is a future research area, which could help expand the application vistas for this catalyst platform.

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Research Organization:: Univ. of Connecticut, Storrs, CT (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences, and Biosciences Division

Grant/Contract Number:: FG02-86ER13622

OSTI ID:: 1598222

Journal Information:: Catalysts, Vol. 9, Issue 9; ISSN 2073-4344

Publisher:: MDPICopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 1 work

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