Mesoporous cobalt/manganese oxide: a highly selective bifunctional catalyst for amine–imine transformations
Abstract
Here, we discuss a heterogeneous catalytic protocol using cobalt doped mesoporous manganese oxide for amine–alcohol cross-coupling to selectively produce symmetric or asymmetric imines. Thorough investigations on the surface chemistry and physical properties of the material revealed its outstanding oxidation–reduction properties and reaction mechanism which was supported by quantum mechanical calculations done by using density functional theory (DFT).
- Publication Date:
- Research Org.:
- Univ. of Connecticut, Storrs, CT (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division
- OSTI Identifier:
- 1598153
- Alternate Identifier(s):
- OSTI ID: 1454376
- Grant/Contract Number:
- FG02-86ER13622
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Green Chemistry
- Additional Journal Information:
- Journal Volume: 20; Journal Issue: 14; Journal ID: ISSN 1463-9262
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Dutta, Biswanath, March, Seth, Achola, Laura, Sahoo, Sanjubala, He, Junkai, Shirazi Amin, Alireza, Wu, Yang, Poges, Shannon, Pamir Alpay, S., and Suib, Steven L. Mesoporous cobalt/manganese oxide: a highly selective bifunctional catalyst for amine–imine transformations. United States: N. p., 2018.
Web. doi:10.1039/c8gc00862k.
Dutta, Biswanath, March, Seth, Achola, Laura, Sahoo, Sanjubala, He, Junkai, Shirazi Amin, Alireza, Wu, Yang, Poges, Shannon, Pamir Alpay, S., & Suib, Steven L. Mesoporous cobalt/manganese oxide: a highly selective bifunctional catalyst for amine–imine transformations. United States. https://doi.org/10.1039/c8gc00862k
Dutta, Biswanath, March, Seth, Achola, Laura, Sahoo, Sanjubala, He, Junkai, Shirazi Amin, Alireza, Wu, Yang, Poges, Shannon, Pamir Alpay, S., and Suib, Steven L. Mon .
"Mesoporous cobalt/manganese oxide: a highly selective bifunctional catalyst for amine–imine transformations". United States. https://doi.org/10.1039/c8gc00862k. https://www.osti.gov/servlets/purl/1598153.
@article{osti_1598153,
title = {Mesoporous cobalt/manganese oxide: a highly selective bifunctional catalyst for amine–imine transformations},
author = {Dutta, Biswanath and March, Seth and Achola, Laura and Sahoo, Sanjubala and He, Junkai and Shirazi Amin, Alireza and Wu, Yang and Poges, Shannon and Pamir Alpay, S. and Suib, Steven L.},
abstractNote = {Here, we discuss a heterogeneous catalytic protocol using cobalt doped mesoporous manganese oxide for amine–alcohol cross-coupling to selectively produce symmetric or asymmetric imines. Thorough investigations on the surface chemistry and physical properties of the material revealed its outstanding oxidation–reduction properties and reaction mechanism which was supported by quantum mechanical calculations done by using density functional theory (DFT).},
doi = {10.1039/c8gc00862k},
journal = {Green Chemistry},
number = 14,
volume = 20,
place = {United States},
year = {Mon Jan 01 00:00:00 EST 2018},
month = {Mon Jan 01 00:00:00 EST 2018}
}
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