skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

This content will become publicly available on November 19, 2020

Title: Aerobijels: Ultralight Carbon Monoliths from Cocontinuous Emulsions

Authors:
 [1];  [2];  [3];  [4];  [5];  [4];  [4];  [3];  [2];  [2];  [6]; ORCiD logo [4]
  1. Weapon Systems Surveillance (W‐9)Weapon Systems Engineering DivisionLos Alamos National Laboratory Los Alamos NM 87545 USA
  2. Materials Synthesis and Integrated Devices (MPA‐11)Materials Physics and Applications DivisionLos Alamos National Laboratory Los Alamos NM 87545 USA
  3. Physical Chemistry and Applied Spectroscopy (C‐PCS)Chemistry DivisionLos Alamos National Laboratory Los Alamos NM 87545 USA
  4. Engineered Materials (MST‐7)Materials Science and Technology DivisionLos Alamos National Laboratory Los Alamos NM 87545 USA
  5. Physics of Condensed Matter and Complex Systems (T‐4)Theoretical DivisionLos Alamos National Laboratory Los Alamos NM 87545 USA
  6. Inorganic, Isotope and Actinide Chemistry (C‐IIAC)Chemistry DivisionLos Alamos National Laboratory Los Alamos NM 87545 USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1597560
Grant/Contract Number:  
20160519ER; LDRD 20160519ER
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Advanced Functional Materials
Additional Journal Information:
Journal Name: Advanced Functional Materials Journal Volume: 30 Journal Issue: 6; Journal ID: ISSN 1616-301X
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
Germany
Language:
English

Citation Formats

Santiago Cordoba, Miguel A., Spendelow, Jacob S., Parra‐Vasquez, Alario Nicholas G., Kuettner, Lindsey A., Welch, Paul M., Hamilton, Christopher E., Oertel, John A., Duque, Juan G., Meierdierks, Eric J., Semelsberger, Troy A., Gordon, John C., and Lee, Matthew N. Aerobijels: Ultralight Carbon Monoliths from Cocontinuous Emulsions. Germany: N. p., 2019. Web. doi:10.1002/adfm.201908383.
Santiago Cordoba, Miguel A., Spendelow, Jacob S., Parra‐Vasquez, Alario Nicholas G., Kuettner, Lindsey A., Welch, Paul M., Hamilton, Christopher E., Oertel, John A., Duque, Juan G., Meierdierks, Eric J., Semelsberger, Troy A., Gordon, John C., & Lee, Matthew N. Aerobijels: Ultralight Carbon Monoliths from Cocontinuous Emulsions. Germany. doi:10.1002/adfm.201908383.
Santiago Cordoba, Miguel A., Spendelow, Jacob S., Parra‐Vasquez, Alario Nicholas G., Kuettner, Lindsey A., Welch, Paul M., Hamilton, Christopher E., Oertel, John A., Duque, Juan G., Meierdierks, Eric J., Semelsberger, Troy A., Gordon, John C., and Lee, Matthew N. Wed . "Aerobijels: Ultralight Carbon Monoliths from Cocontinuous Emulsions". Germany. doi:10.1002/adfm.201908383.
@article{osti_1597560,
title = {Aerobijels: Ultralight Carbon Monoliths from Cocontinuous Emulsions},
author = {Santiago Cordoba, Miguel A. and Spendelow, Jacob S. and Parra‐Vasquez, Alario Nicholas G. and Kuettner, Lindsey A. and Welch, Paul M. and Hamilton, Christopher E. and Oertel, John A. and Duque, Juan G. and Meierdierks, Eric J. and Semelsberger, Troy A. and Gordon, John C. and Lee, Matthew N.},
abstractNote = {},
doi = {10.1002/adfm.201908383},
journal = {Advanced Functional Materials},
number = 6,
volume = 30,
place = {Germany},
year = {2019},
month = {11}
}

Journal Article:
Free Publicly Available Full Text
This content will become publicly available on November 19, 2020
Publisher's Version of Record

Save / Share:

Works referenced in this record:

Mass Transport to Nanoelectrode Arrays and Limitations of the Diffusion Domain Approach: Theory and Experiment
journal, June 2009

  • Godino, Neus; Borrisé, Xavier; Muñoz, Francesc Xavier
  • The Journal of Physical Chemistry C, Vol. 113, Issue 25
  • DOI: 10.1021/jp9031354

Time-Efficient Acid-Catalyzed Synthesis of Resorcinol−Formaldehyde Aerogels
journal, December 2007

  • Mulik, Sudhir; Sotiriou-Leventis, Chariklia; Leventis, Nicholas
  • Chemistry of Materials, Vol. 19, Issue 25, p. 6138-6144
  • DOI: 10.1021/cm071572m

Controlled growth of monodisperse silica spheres in the micron size range
journal, January 1968

  • Stöber, Werner; Fink, Arthur; Bohn, Ernst
  • Journal of Colloid and Interface Science, Vol. 26, Issue 1, p. 62-69
  • DOI: 10.1016/0021-9797(68)90272-5

Mesoporous TiO 2 Nanocrystals Grown in Situ on Graphene Aerogels for High Photocatalysis and Lithium-Ion Batteries
journal, April 2014

  • Qiu, Bocheng; Xing, Mingyang; Zhang, Jinlong
  • Journal of the American Chemical Society, Vol. 136, Issue 16
  • DOI: 10.1021/ja500873u

Synthesis and performance evaluation of the aerogel-filled PET nanofiber assemblies prepared by electro-spinning
journal, January 2015

  • Mazrouei-Sebdani, Z.; Khoddami, A.; Hadadzadeh, H.
  • RSC Advances, Vol. 5, Issue 17
  • DOI: 10.1039/C4RA15297B

Pristine Graphene Aerogels by Room-Temperature Freeze Gelation
journal, July 2016


Biomimetic Self-Templated Hierarchical Structures of Collagen-Like Peptide Amphiphiles
journal, September 2015


Chalcogen-Based Aerogels As Sorbents for Radionuclide Remediation
journal, June 2013

  • Riley, Brian J.; Chun, Jaehun; Um, Wooyong
  • Environmental Science & Technology, Vol. 47, Issue 13
  • DOI: 10.1021/es400595z

Multifunctional SiO 2 @Gd 2 O 3 :Yb/Tm Hollow Capsules: Controllable Synthesis and Drug Release Properties
journal, September 2014

  • Yang, Guixin; Lv, Ruichan; Gai, Shili
  • Inorganic Chemistry, Vol. 53, Issue 20
  • DOI: 10.1021/ic501121t

Hierarchically porous carbons with optimized nitrogen doping as highly active electrocatalysts for oxygen reduction
journal, September 2014

  • Liang, Hai-Wei; Zhuang, Xiaodong; Brüller, Sebastian
  • Nature Communications, Vol. 5, Issue 1
  • DOI: 10.1038/ncomms5973

Chemistry of Aerogels and Their Applications
journal, November 2002

  • Pierre, Alain C.; Pajonk, Gérard M.
  • Chemical Reviews, Vol. 102, Issue 11
  • DOI: 10.1021/cr0101306

Supercritical Drying of Alginate Beads for the Development of Aerogel Biomaterials: Optimization of Process Parameters and Exchange Solvents
journal, August 2013

  • Della Porta, Giovanna; Del Gaudio, Pasquale; De Cicco, Felicetta
  • Industrial & Engineering Chemistry Research, Vol. 52, Issue 34
  • DOI: 10.1021/ie401335c

Aerogel Templated ZnO Dye-Sensitized Solar Cells
journal, April 2008

  • Hamann, Thomas W.; Martinson, Alex B. F.; Elam, Jeffrey W.
  • Advanced Materials, Vol. 20, Issue 8, p. 1560-1564
  • DOI: 10.1002/adma.200702781

Bijel reinforcement by droplet bridging: a route to bicontinuous materials with large domains
journal, January 2013

  • Witt, Jessica A.; Mumm, Daniel R.; Mohraz, Ali
  • Soft Matter, Vol. 9, Issue 29
  • DOI: 10.1039/c3sm00130j

Ordered Hierarchical Mesoporous/Macroporous Carbon: A High-Performance Catalyst for Rechargeable Li-O 2 Batteries
journal, August 2013


Hierarchical Nested-Network Nanostructure by Dealloying
journal, June 2013


Hydrogels and Aerogels from Noble Metal Nanoparticles
journal, November 2009

  • Bigall, Nadja C.; Herrmann, Anne-Kristin; Vogel, Maria
  • Angewandte Chemie International Edition, Vol. 48, Issue 51
  • DOI: 10.1002/anie.200902543

A dual-emitting core–shell carbon dot–silica–phosphor composite for white light emission
journal, January 2015

  • Chen, Yonghao; Lei, Bingfu; Zheng, Mingtao
  • Nanoscale, Vol. 7, Issue 47
  • DOI: 10.1039/C5NR05637C

Influence of freeze-drying conditions on the mesoporosity of organic gels as carbon precursors
journal, January 2000


Ultralight and Highly Compressible Graphene Aerogels
journal, February 2013


Nanoporous Metals with Structural Hierarchy: A Review
journal, August 2017

  • Juarez, Theresa; Biener, Juergen; Weissmüller, Jörg
  • Advanced Engineering Materials, Vol. 19, Issue 12
  • DOI: 10.1002/adem.201700389

Aerogels—Airy Materials: Chemistry, Structure, and Properties
journal, February 1998


Three dimensional graphene based materials: Synthesis and applications from energy storage and conversion to electrochemical sensor and environmental remediation
journal, July 2015

  • Wang, Hou; Yuan, Xingzhong; Zeng, Guangming
  • Advances in Colloid and Interface Science, Vol. 221
  • DOI: 10.1016/j.cis.2015.04.005

Electrospun nanofibrous materials: a versatile medium for effective oil/water separation
journal, September 2016


Water-Stable, Magnetic Silica-Cobalt/Cobalt Oxide-Silica Multishell Submicrometer Spheres
journal, June 2005

  • Salgueiriño-Maceira, V.; Spasova, M.; Farle, M.
  • Advanced Functional Materials, Vol. 15, Issue 6
  • DOI: 10.1002/adfm.200400469

Effects of Hierarchical Architecture on Electronic and Mechanical Properties of Nanocast Monolithic Porous Carbons and Carbon−Carbon Nanocomposites
journal, November 2006

  • Wang, Zhiyong; Li, Fan; Ergang, Nicholas S.
  • Chemistry of Materials, Vol. 18, Issue 23
  • DOI: 10.1021/cm062050u

Development of high-porosity resorcinol formaldehyde aerogels with enhanced mechanical properties through improved particle necking under CO 2 supercritical conditions
journal, January 2017

  • Alshrah, Mohammed; Tran, Minh-Phuong; Gong, Pengjian
  • Journal of Colloid and Interface Science, Vol. 485
  • DOI: 10.1016/j.jcis.2016.09.030

3D Printing of Graphene Aerogels
journal, February 2016

  • Zhang, Qiangqiang; Zhang, Feng; Medarametla, Sai Pradeep
  • Small, Vol. 12, Issue 13
  • DOI: 10.1002/smll.201503524

Colloidal Nanocrystal-Based Gels and Aerogels: Material Aspects and Application Perspectives
journal, December 2011

  • Gaponik, Nikolai; Herrmann, Anne-Kristin; Eychmüller, Alexander
  • The Journal of Physical Chemistry Letters, Vol. 3, Issue 1
  • DOI: 10.1021/jz201357r

Making a Robust Interfacial Scaffold: Bijel Rheology and its Link to Processability
journal, September 2012

  • Lee, Matthew N.; Thijssen, Job H. J.; Witt, Jessica A.
  • Advanced Functional Materials, Vol. 23, Issue 4
  • DOI: 10.1002/adfm.201201090

Synthesis of Contiguous Silica−Gold Core−Shell Structures:  Critical Parameters and Processes
journal, May 2008

  • Phonthammachai, Nopphawan; Kah, James C. Y.; Jun, Guo
  • Langmuir, Vol. 24, Issue 9
  • DOI: 10.1021/la703580r

One-step synthesis of silica@resorcinol–formaldehyde spheres and their application for the fabrication of polymer and carbon capsules
journal, January 2012

  • Fuertes, Antonio B.; Valle-Vigón, Patricia; Sevilla, Marta
  • Chemical Communications, Vol. 48, Issue 49
  • DOI: 10.1039/c2cc32552g

Hierarchical Network Architectures of Carbon Fiber Paper Supported Cobalt Oxide Nanonet for High-Capacity Pseudocapacitors
journal, December 2011

  • Yang, Lei; Cheng, Shuang; Ding, Yong
  • Nano Letters, Vol. 12, Issue 1
  • DOI: 10.1021/nl203600x

Boron nitride colloidal solutions, ultralight aerogels and freestanding membranes through one-step exfoliation and functionalization
journal, November 2015

  • Lei, Weiwei; Mochalin, Vadym N.; Liu, Dan
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms9849

Monodisperse Silica-Polymer Core-Shell Microspheres via Surface Grafting and Emulsion Polymerization
journal, April 2003

  • Zhang, Kai; Chen, Haitao; Chen, Xin
  • Macromolecular Materials and Engineering, Vol. 288, Issue 4
  • DOI: 10.1002/mame.200390031

Silica–metal core–shell nanostructures
journal, January 2012

  • Jankiewicz, B. J.; Jamiola, D.; Choma, J.
  • Advances in Colloid and Interface Science, Vol. 170, Issue 1-2
  • DOI: 10.1016/j.cis.2011.11.002

Ultralight nanofibre-assembled cellular aerogels with superelasticity and multifunctionality
journal, December 2014

  • Si, Yang; Yu, Jianyong; Tang, Xiaomin
  • Nature Communications, Vol. 5, Issue 1
  • DOI: 10.1038/ncomms6802

Accessible Graphene Aerogel for Efficiently Harvesting Solar Energy
journal, May 2017


Organic aerogels from the polycondensation of resorcinol with formaldehyde
journal, September 1989


Carbon aerogels for catalysis applications: An overview
journal, January 2005


Hierarchically Structured Sulfur/Carbon Nanocomposite Material for High-Energy Lithium Battery
journal, October 2009

  • Liang, Chengdu; Dudney, Nancy J.; Howe, Jane Y.
  • Chemistry of Materials, Vol. 21, Issue 19, p. 4724-4730
  • DOI: 10.1021/cm902050j

Porous Gold with a Nested-Network Architecture and Ultrafine Structure
journal, March 2015

  • Qi, Zhen; Vainio, Ulla; Kornowski, Andreas
  • Advanced Functional Materials, Vol. 25, Issue 17
  • DOI: 10.1002/adfm.201404544

Core/Shell Nanoparticles: Classes, Properties, Synthesis Mechanisms, Characterization, and Applications
journal, December 2011

  • Ghosh Chaudhuri, Rajib; Paria, Santanu
  • Chemical Reviews, Vol. 112, Issue 4
  • DOI: 10.1021/cr100449n

Structure and electrochemical properties of carbon aerogels synthesized at ambient temperatures as supercapacitors
journal, January 2008


Bicontinuous Macroporous Materials from Bijel Templates
journal, September 2010


3D Assembly of All-Inorganic Colloidal Nanocrystals into Gels and Aerogels
journal, April 2016

  • Sayevich, Vladimir; Cai, Bin; Benad, Albrecht
  • Angewandte Chemie International Edition, Vol. 55, Issue 21
  • DOI: 10.1002/anie.201600094

Controlled freezing and freeze drying: a versatile route for porous and micro-/nano-structured materials
journal, September 2010

  • Qian, Lei; Zhang, Haifei
  • Journal of Chemical Technology & Biotechnology, Vol. 86, Issue 2
  • DOI: 10.1002/jctb.2495

Depth-sensing indentation of low-density brittle nanoporous solids
journal, July 2009


Functionalized mesoporous silica materials for controlled drug delivery
journal, January 2012

  • Yang, Piaoping; Gai, Shili; Lin, Jun
  • Chemical Society Reviews, Vol. 41, Issue 9
  • DOI: 10.1039/c2cs15308d

Structural Design of Polymer-Derived SiOC Ceramic Aerogels for High-Rate Li Ion Storage Applications
journal, June 2016

  • Vallachira Warriam Sasikumar, Pradeep; Zera, Emanuele; Graczyk-Zajac, Magdalena
  • Journal of the American Ceramic Society, Vol. 99, Issue 9
  • DOI: 10.1111/jace.14323

High nitrogen-containing cotton derived 3D porous carbon frameworks for high-performance supercapacitors
journal, October 2015

  • Fan, Li-Zhen; Chen, Tian-Tian; Song, Wei-Li
  • Scientific Reports, Vol. 5, Issue 1
  • DOI: 10.1038/srep15388

Ceramics With Ultra-Low Density Fabricated by Gelcasting: An Unconventional View
journal, November 2007


Microstructural characteristics of bijel-templated porous materials
journal, September 2019


In Situ Mechanical Testing of Nanostructured Bijel Fibers
journal, May 2016


Nickel–Cobalt Hydroxide Nanosheets Coated on NiCo 2 O 4 Nanowires Grown on Carbon Fiber Paper for High-Performance Pseudocapacitors
journal, June 2013

  • Huang, Liang; Chen, Dongchang; Ding, Yong
  • Nano Letters, Vol. 13, Issue 7
  • DOI: 10.1021/nl401086t

Quantitative morphological characterization of bicontinuous Pickering emulsions via interfacial curvatures
journal, January 2016

  • Reeves, Matthew; Stratford, Kevin; Thijssen, Job H. J.
  • Soft Matter, Vol. 12, Issue 18
  • DOI: 10.1039/C5SM03102H

Synthesis of micro- and mesoporous carbon spheres for supercapacitor electrode
journal, May 2013

  • Ma, Xiaomei; Liu, Mingxian; Gan, Lihua
  • Journal of Solid State Electrochemistry, Vol. 17, Issue 8
  • DOI: 10.1007/s10008-013-2110-7

Highly compressible 3D periodic graphene aerogel microlattices
journal, April 2015

  • Zhu, Cheng; Han, T. Yong-Jin; Duoss, Eric B.
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms7962

Coherent Expanded Aerogels and Jellies
journal, May 1931


Modelling the elastic properties of bi-continuous composite microstructures captured with TriBeam serial-sectioning
journal, April 2017


Convenient Recycling of 3D AgX/Graphene Aerogels (X = Br, Cl) for Efficient Photocatalytic Degradation of Water Pollutants
journal, May 2015


Colloidal Jamming at Interfaces: A Route to Fluid-Bicontinuous Gels
journal, September 2005

  • Stratford, K.; Adhikari, R.; Pagonabarraga, I.
  • Science, Vol. 309, Issue 5744, p. 2198-2201
  • DOI: 10.1126/science.1116589

Dry-Machining of Aerogel Foams, CH Foams, and Specially Engineered Foams Using Turn-Milling Techniques
journal, November 2017