DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Managing hysteresis of Gd5Si2Ge2 by magnetic field cycling

Abstract

The influence of magnetic field cycling through the first-order magnetostructural transformation on the magnetic and magnetocaloric properties, as well as hysteresis of polycrystalline Gd5Si2Ge2, has been studied using magnetometry. Here, the cycling has a minimal effect on the magnetic field-induced entropy change and the phase transformation temperature of the material. On the other hand, magnetic hysteresis decreases by 30% after approximately ten cycles and remains low unless the sample is moved far into the paramagnetic regime. Factors playing a role in the history dependence of hysteresis have been discussed.

Authors:
ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [1]; ORCiD logo [1]
  1. Ames Lab., and Iowa State Univ., Ames, IA (United States)
  2. Ames Lab., and Iowa State Univ., Ames, IA (United States); SUNY Buffalo State, Buffalo, NY (United States)
Publication Date:
Research Org.:
Ames Laboratory (AMES), Ames, IA (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division
OSTI Identifier:
1580709
Alternate Identifier(s):
OSTI ID: 1580170
Report Number(s):
IS-J-10,100
Journal ID: ISSN 0021-8979; TRN: US2100785
Grant/Contract Number:  
AC02-07CH11358
Resource Type:
Accepted Manuscript
Journal Name:
Journal of Applied Physics
Additional Journal Information:
Journal Volume: 126; Journal Issue: 24; Journal ID: ISSN 0021-8979
Publisher:
American Institute of Physics (AIP)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE

Citation Formats

Biswas, Anis, Mudryk, Yaroslav, Pathak, Arjun K., Zhou, Lin, and Pecharsky, Vitalij K. Managing hysteresis of Gd5Si2Ge2 by magnetic field cycling. United States: N. p., 2019. Web. doi:10.1063/1.5129660.
Biswas, Anis, Mudryk, Yaroslav, Pathak, Arjun K., Zhou, Lin, & Pecharsky, Vitalij K. Managing hysteresis of Gd5Si2Ge2 by magnetic field cycling. United States. https://doi.org/10.1063/1.5129660
Biswas, Anis, Mudryk, Yaroslav, Pathak, Arjun K., Zhou, Lin, and Pecharsky, Vitalij K. Mon . "Managing hysteresis of Gd5Si2Ge2 by magnetic field cycling". United States. https://doi.org/10.1063/1.5129660. https://www.osti.gov/servlets/purl/1580709.
@article{osti_1580709,
title = {Managing hysteresis of Gd5Si2Ge2 by magnetic field cycling},
author = {Biswas, Anis and Mudryk, Yaroslav and Pathak, Arjun K. and Zhou, Lin and Pecharsky, Vitalij K.},
abstractNote = {The influence of magnetic field cycling through the first-order magnetostructural transformation on the magnetic and magnetocaloric properties, as well as hysteresis of polycrystalline Gd5Si2Ge2, has been studied using magnetometry. Here, the cycling has a minimal effect on the magnetic field-induced entropy change and the phase transformation temperature of the material. On the other hand, magnetic hysteresis decreases by 30% after approximately ten cycles and remains low unless the sample is moved far into the paramagnetic regime. Factors playing a role in the history dependence of hysteresis have been discussed.},
doi = {10.1063/1.5129660},
journal = {Journal of Applied Physics},
number = 24,
volume = 126,
place = {United States},
year = {Mon Dec 23 00:00:00 EST 2019},
month = {Mon Dec 23 00:00:00 EST 2019}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record

Citation Metrics:
Cited by: 10 works
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

A multicaloric cooling cycle that exploits thermal hysteresis
journal, September 2018

  • Gottschall, Tino; Gràcia-Condal, Adrià; Fries, Maximilian
  • Nature Materials, Vol. 17, Issue 10
  • DOI: 10.1038/s41563-018-0166-6

Reduction of hysteresis losses in the magnetic refrigerant Gd5Ge2Si2 by the addition of iron
journal, June 2004

  • Provenzano, Virgil; Shapiro, Alexander J.; Shull, Robert D.
  • Nature, Vol. 429, Issue 6994
  • DOI: 10.1038/nature02657

Caloric materials near ferroic phase transitions
journal, April 2014

  • Moya, X.; Kar-Narayan, S.; Mathur, N. D.
  • Nature Materials, Vol. 13, Issue 5
  • DOI: 10.1038/nmat3951

Crystal structure-magnetic property relationships of Gd 5 Ge 4 examined by in situ x-ray powder diffraction
journal, August 2005


Anomalous behavior of the electrical resistivity in the giant magnetocaloric compound Gd 5 ( Si 0.1 Ge 0.9 ) 4
journal, April 2003


Multi-energy conversion of Gd 5 (Si 2 Ge 2 )-poly (vinylidene fluoride), a hybrid material
journal, August 2014

  • Ozaydin, M. F.; Liang, H.
  • Applied Physics Letters, Vol. 105, Issue 6
  • DOI: 10.1063/1.4893296

Tunable magnetic regenerator alloys with a giant magnetocaloric effect for magnetic refrigeration from ∼20 to ∼290 K
journal, June 1997

  • Pecharsky, V. K.; Gschneidner, K. A.
  • Applied Physics Letters, Vol. 70, Issue 24
  • DOI: 10.1063/1.119206

Large magnetocaloric effect in La(FexSi1−x)13 itinerant-electron metamagnetic compounds
journal, August 2002

  • Fujieda, S.; Fujita, A.; Fukamichi, K.
  • Applied Physics Letters, Vol. 81, Issue 7
  • DOI: 10.1063/1.1498148

Transition-metal-based magnetic refrigerants for room-temperature applications
journal, January 2002

  • Tegus, O.; Brück, E.; Buschow, K. H. J.
  • Nature, Vol. 415, Issue 6868
  • DOI: 10.1038/415150a

Thermopower behavior in the Gd5(Si0.1Ge0.9)4 magnetocaloric compound from 4 to 300 K
journal, April 2002

  • Sousa, J. B.; Braga, M. E.; Correia, F. C.
  • Journal of Applied Physics, Vol. 91, Issue 7
  • DOI: 10.1063/1.1459612

Barocaloric effect in the magnetocaloric prototype Gd5Si2Ge2
journal, August 2012

  • Yuce, Suheyla; Barrio, Maria; Emre, Baris
  • Applied Physics Letters, Vol. 101, Issue 7
  • DOI: 10.1063/1.4745920

A Matter of Size and Stress: Understanding the First-Order Transition in Materials for Solid-State Refrigeration
journal, July 2017

  • Gottschall, Tino; Benke, Dimitri; Fries, Maximilian
  • Advanced Functional Materials, Vol. 27, Issue 32
  • DOI: 10.1002/adfm.201606735

LaFe11.6Si1.4Hy/Sn magnetocaloric composites by hot pressing
journal, July 2016


“Nanoscale Zippers” in the Crystalline Solid. Structural Variations in the Giant Magnetocaloric Material Gd 5 Si 1.5 Ge 2.5
journal, April 2003

  • Choe, Wonyoung; Miller, Gordon J.; Meyers, John
  • Chemistry of Materials, Vol. 15, Issue 7
  • DOI: 10.1021/cm020928l

Magnetocaloric effect: From materials research to refrigeration devices
journal, April 2018


Magnetocaloric effect in Gd5Si2Ge2∕Gd composite materials
journal, April 2006

  • Yue, M.; Zhang, J.; Zeng, H.
  • Journal of Applied Physics, Vol. 99, Issue 8
  • DOI: 10.1063/1.2158971

Metamagnetism Seeded by Nanostructural Features of Single-Crystalline Gd 5 Si 2 Ge 2
journal, October 2009

  • Moore, James D.; Morrison, Kelly; Perkins, Garry K.
  • Advanced Materials, Vol. 21, Issue 37
  • DOI: 10.1002/adma.200900093

Novel La(Fe,Si) 13 /Cu Composites for Magnetic Cooling
journal, June 2012

  • Lyubina, Julia; Hannemann, Ullrich; Cohen, Lesley F.
  • Advanced Energy Materials, Vol. 2, Issue 11
  • DOI: 10.1002/aenm.201200297

Giant Magnetocaloric Effect in Gd5(Si2Ge2)
journal, June 1997


Crystallography, anisotropic metamagnetism, and magnetocaloric effect in Tb 5 Si 2.2 Ge 1.8
journal, January 2007


The performance of a large-scale rotary magnetic refrigerator
journal, January 2014


Magnetic heat pumping near room temperature
journal, August 1976

  • Brown, G. V.
  • Journal of Applied Physics, Vol. 47, Issue 8
  • DOI: 10.1063/1.323176

Magnetic-field-induced structural phase transition in Gd 5 ( S i 1.8 Ge 2.2 )
journal, December 1998


Development and experimental results from a 1 kW prototype AMR
journal, January 2014


Performance analysis of reciprocating magnetic liquefiers
journal, December 1994


The irreversible structural change in Mn 1.1 Fe 0.9 P 0.8 Ge 0.2 : Evidence for a magnetic driver
journal, May 2017

  • Liu, Xubo; Ryan, D. H.; Cranswick, L. M. D.
  • AIP Advances, Vol. 7, Issue 5
  • DOI: 10.1063/1.4973287

Hydrostatic pressure control of the magnetostructural phase transition in Gd 5 Si 2 Ge 2 single crystals
journal, July 2005


Effects of hysteresis and Brayton cycle constraints on magnetocaloric refrigerant performance
journal, May 2018

  • Brown, T. D.; Buffington, T.; Shamberger, P. J.
  • Journal of Applied Physics, Vol. 123, Issue 18
  • DOI: 10.1063/1.5022467

Magnetocaloric refrigeration near room temperature (invited)
journal, March 2007

  • Brück, E.; Tegus, O.; Thanh, D. T. C.
  • Journal of Magnetism and Magnetic Materials, Vol. 310, Issue 2
  • DOI: 10.1016/j.jmmm.2006.10.1146

Suppression of magnetostructural transition on GdSiGe thin film after thermal cyclings
journal, January 2017


The evolution of magnetocaloric heat-pump devices
journal, April 2018

  • Zimm, Carl; Boeder, Andre; Mueller, Bryant
  • MRS Bulletin, Vol. 43, Issue 4
  • DOI: 10.1557/mrs.2018.71

Thermopower and electrical resistivity behavior near the martensitic transition in Gd5(SixGe1−x)4 magnetocaloric compounds
journal, April 2005

  • Pinto, R. P.; Sousa, J. B.; Correia, F. C.
  • Journal of Magnetism and Magnetic Materials, Vol. 290-291
  • DOI: 10.1016/j.jmmm.2004.11.331

The room temperature metastable/stable phase relationships in the pseudo-binary Gd5Si4–Gd5Ge4 system
journal, May 2002


Large reversible caloric effect in FeRh thin films via a dual-stimulus multicaloric cycle
journal, May 2016

  • Liu, Yang; Phillips, Lee C.; Mattana, Richard
  • Nature Communications, Vol. 7, Issue 1
  • DOI: 10.1038/ncomms11614

Effect of alloying on the giant magnetocaloric effect of Gd5(Si2Ge2)
journal, March 1997


Magnetocaloric Materials
journal, August 2000


Contributions to Hysteresis in Magnetocaloric Materials
journal, September 2017


The giant magnetocaloric effect of optimally prepared Gd5Si2Ge2
journal, April 2003

  • Pecharsky, A. O.; Gschneidner, K. A.; Pecharsky, V. K.
  • Journal of Applied Physics, Vol. 93, Issue 8
  • DOI: 10.1063/1.1558210

Materials Challenges for High Performance Magnetocaloric Refrigeration Devices
journal, September 2012

  • Smith, Anders; Bahl, Christian R. H.; Bjørk, Rasmus
  • Advanced Energy Materials, Vol. 2, Issue 11
  • DOI: 10.1002/aenm.201200167

Training effects in Gd 5 Ge 4 : role of microstructure
journal, June 2006

  • Manekar, Meghmalhar; Chattopadhyay, M. K.; Kaul, R.
  • Journal of Physics: Condensed Matter, Vol. 18, Issue 26
  • DOI: 10.1088/0953-8984/18/26/020

Recent developments in magnetocaloric materials
journal, May 2005

  • Gschneidner, K. A.; Pecharsky, V. K.; Tsokol, A. O.
  • Reports on Progress in Physics, Vol. 68, Issue 6, p. 1479-1539
  • DOI: 10.1088/0034-4885/68/6/R04

Reducing Thermal Hysteresis in Epitaxial Ni-Mn-Ga-Co Films by Transformation Cycling
journal, November 2017

  • Diestel, Anett; Chekhonin, Paul; Niemann, Robert
  • physica status solidi (b), Vol. 255, Issue 2
  • DOI: 10.1002/pssb.201700330

Microstructural analysis of twinned β Gd 5 Si 2 Ge 2
journal, July 2002


Best practices in evaluation of the magnetocaloric effect from bulk magnetization measurements
journal, July 2018


Caloric materials near ferroic phase transitions
journalarticle, January 2014


“Nanoscale Zippers” in the Crystalline Solid. Structural Variations in the Giant Magnetocaloric Material Gd5Si1.5Ge2.5
journal, July 2003