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Title: Magnetostructural phase transitions and magnetocaloric effect in (Gd5-xScx)Si1.8Ge2.2

Abstract

Future advancements in magnetocaloric refrigeration/heat pumping technologies depend on the discovery of new materials that demonstrate large, tunable magnetocaloric effects (MCEs) in the vicinity of coupled magnetic and structural phase transitions that occur reversibly with minimum hysteresis. Here, with this in mind, we investigate phase transitions, microstructure, magnetic, thermal, magnetocaloric, and transport properties of (Gd5-xScx)Si1.8Ge2.2 compounds. Replacement of magnetic Gd with non-magnetic Sc in Gd5-xScxSi1.8Ge2.2 increases the ferromagnetic to paramagnetic first order phase transition temperature, TC, with only a minor reduction in MCE when x ≤ 0.2. We also demonstrate that hydrostatic pressure further increases TC and reduces the hysteresis of the first order phase transition in Gd4.8Sc0.2Si1.8Ge2.2 from 7 to 4 K. Temperature-dependent x-ray powder diffraction study of Gd4.8Sc0.2Si1.8Ge2.2 confirms the monoclinic ↔ orthorhombic structural transformation at TC, in agreement with magnetic, calorimetric, and electrical transport measurements. In addition to the substantial magnetocaloric effect, a large magnetoresistance of ~20% is also observed in Gd4.8Sc0.2Si1.8Ge2.2 for ΔH = 50 kOe in the vicinity of the magnetostructural transition. Finally, in a drastic reversal of the initial doping behavior further additions of Sc (x > 0.2) suppress formation of the monoclinic phase, change the nature of the transition from first-to second-order, andmore » reduce both the transition temperature and magnetocaloric effect.« less

Authors:
 [1];  [2];  [2];  [3]
  1. Ames Lab. and Iowa State Univ., Ames, IA (United States); Iowa State Univ., Ames, IA (United States). Dept. of Mechanical Engineering
  2. Ames Lab. and Iowa State Univ., Ames, IA (United States)
  3. Ames Lab. and Iowa State Univ., Ames, IA (United States); Iowa State Univ., Ames, IA (United States). Dept. of Materials Science and Engineering
Publication Date:
Research Org.:
Ames Lab., Ames, IA (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1415793
Alternate Identifier(s):
OSTI ID: 1549002
Report Number(s):
IS-J-9519
Journal ID: ISSN 1359-6454; PII: S1359645417310297; TRN: US1800852
Grant/Contract Number:  
AC02-07CH11358
Resource Type:
Accepted Manuscript
Journal Name:
Acta Materialia
Additional Journal Information:
Journal Volume: 145; Journal Issue: C; Journal ID: ISSN 1359-6454
Publisher:
Elsevier
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; Structural transition; Magnetoresistance; Magnetocaloric

Citation Formats

Rudolph, Kirk, Pathak, Arjun K., Mudryk, Yaroslav, and Pecharsky, Vitalij K. Magnetostructural phase transitions and magnetocaloric effect in (Gd5-xScx)Si1.8Ge2.2. United States: N. p., 2017. Web. https://doi.org/10.1016/j.actamat.2017.12.024.
Rudolph, Kirk, Pathak, Arjun K., Mudryk, Yaroslav, & Pecharsky, Vitalij K. Magnetostructural phase transitions and magnetocaloric effect in (Gd5-xScx)Si1.8Ge2.2. United States. https://doi.org/10.1016/j.actamat.2017.12.024
Rudolph, Kirk, Pathak, Arjun K., Mudryk, Yaroslav, and Pecharsky, Vitalij K. Thu . "Magnetostructural phase transitions and magnetocaloric effect in (Gd5-xScx)Si1.8Ge2.2". United States. https://doi.org/10.1016/j.actamat.2017.12.024. https://www.osti.gov/servlets/purl/1415793.
@article{osti_1415793,
title = {Magnetostructural phase transitions and magnetocaloric effect in (Gd5-xScx)Si1.8Ge2.2},
author = {Rudolph, Kirk and Pathak, Arjun K. and Mudryk, Yaroslav and Pecharsky, Vitalij K.},
abstractNote = {Future advancements in magnetocaloric refrigeration/heat pumping technologies depend on the discovery of new materials that demonstrate large, tunable magnetocaloric effects (MCEs) in the vicinity of coupled magnetic and structural phase transitions that occur reversibly with minimum hysteresis. Here, with this in mind, we investigate phase transitions, microstructure, magnetic, thermal, magnetocaloric, and transport properties of (Gd5-xScx)Si1.8Ge2.2 compounds. Replacement of magnetic Gd with non-magnetic Sc in Gd5-xScxSi1.8Ge2.2 increases the ferromagnetic to paramagnetic first order phase transition temperature, TC, with only a minor reduction in MCE when x ≤ 0.2. We also demonstrate that hydrostatic pressure further increases TC and reduces the hysteresis of the first order phase transition in Gd4.8Sc0.2Si1.8Ge2.2 from 7 to 4 K. Temperature-dependent x-ray powder diffraction study of Gd4.8Sc0.2Si1.8Ge2.2 confirms the monoclinic ↔ orthorhombic structural transformation at TC, in agreement with magnetic, calorimetric, and electrical transport measurements. In addition to the substantial magnetocaloric effect, a large magnetoresistance of ~20% is also observed in Gd4.8Sc0.2Si1.8Ge2.2 for ΔH = 50 kOe in the vicinity of the magnetostructural transition. Finally, in a drastic reversal of the initial doping behavior further additions of Sc (x > 0.2) suppress formation of the monoclinic phase, change the nature of the transition from first-to second-order, and reduce both the transition temperature and magnetocaloric effect.},
doi = {10.1016/j.actamat.2017.12.024},
journal = {Acta Materialia},
number = C,
volume = 145,
place = {United States},
year = {2017},
month = {12}
}

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    Works referencing / citing this record:

    Lanthanum Dilution Effects on the Giant Magnetocaloric Gd 5 Si 1.8 Ge 2.2 Compound
    journal, September 2018

    • Andrade, Vivian M.; Belo, João H.; Reis, Mario S.
    • physica status solidi (b), Vol. 255, Issue 10
    • DOI: 10.1002/pssb.201800101

    The influence of titanium substitution on the magnetic, magnetocaloric, and magnetoelastic properties of Gd 5 Si 2 Ge 2
    journal, August 2018

    • Nikitin, S. A.; Smirnov, A. V.; Ovchenkova, I. A.
    • Journal of Applied Physics, Vol. 124, Issue 8
    • DOI: 10.1063/1.5036723