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Title: Influence of Coordination Environment of Anchored Single‐Site Cobalt Catalyst on CO 2 Hydrogenation

Authors:
 [1];  [1];  [1];  [2];  [3]; ORCiD logo [1]
  1. Department of Chemical EngineeringUniversity of South Carolina 541 Main Street Columbia SC-29208 USA
  2. Chemical Engineering DivisionArgonne National Lab 9700 S Cass Ave Lemont IL-60439 USA
  3. Chemical Engineering DivisionArgonne National Lab 9700 S Cass Ave Lemont IL-60439 USA, Department of Physics Center for Synchrotron Research and InstrumentationIllinois Institute of Technology 3101 South Dearborn St. Chicago IL-60616 USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1579470
Grant/Contract Number:  
AC02-06CH11357
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
ChemCatChem
Additional Journal Information:
Journal Name: ChemCatChem; Journal ID: ISSN 1867-3880
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
Germany
Language:
English

Citation Formats

Jimenez, Juan D., Wen, Cun, Royko, Michael M., Kropf, Arthur J., Segre, Carlo, and Lauterbach, Jochen. Influence of Coordination Environment of Anchored Single‐Site Cobalt Catalyst on CO 2 Hydrogenation. Germany: N. p., 2019. Web. doi:10.1002/cctc.201901676.
Jimenez, Juan D., Wen, Cun, Royko, Michael M., Kropf, Arthur J., Segre, Carlo, & Lauterbach, Jochen. Influence of Coordination Environment of Anchored Single‐Site Cobalt Catalyst on CO 2 Hydrogenation. Germany. doi:10.1002/cctc.201901676.
Jimenez, Juan D., Wen, Cun, Royko, Michael M., Kropf, Arthur J., Segre, Carlo, and Lauterbach, Jochen. Mon . "Influence of Coordination Environment of Anchored Single‐Site Cobalt Catalyst on CO 2 Hydrogenation". Germany. doi:10.1002/cctc.201901676.
@article{osti_1579470,
title = {Influence of Coordination Environment of Anchored Single‐Site Cobalt Catalyst on CO 2 Hydrogenation},
author = {Jimenez, Juan D. and Wen, Cun and Royko, Michael M. and Kropf, Arthur J. and Segre, Carlo and Lauterbach, Jochen},
abstractNote = {},
doi = {10.1002/cctc.201901676},
journal = {ChemCatChem},
number = ,
volume = ,
place = {Germany},
year = {2019},
month = {12}
}

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Works referenced in this record:

ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT
journal, June 2005


Unveiling Active Sites of CO 2 Reduction on Nitrogen-Coordinated and Atomically Dispersed Iron and Cobalt Catalysts
journal, March 2018


Powering the planet: Chemical challenges in solar energy utilization
journal, October 2006

  • Lewis, N. S.; Nocera, D. G.
  • Proceedings of the National Academy of Sciences, Vol. 103, Issue 43, p. 15729-15735
  • DOI: 10.1073/pnas.0603395103

Synthesis and Characterization of Cobalt Hydroxide, Cobalt Oxyhydroxide, and Cobalt Oxide Nanodiscs
journal, November 2009

  • Yang, Jing; Liu, Hongwei; Martens, Wayde N.
  • The Journal of Physical Chemistry C, Vol. 114, Issue 1
  • DOI: 10.1021/jp908548f

Catalytic N−H Bond Activation and Breaking by a Well-Defined Co II 1 O 4 Site of a Heterogeneous Catalyst
journal, January 2018

  • Khivantsev, Konstantin; Biancardi, Alessandro; Fathizadeh, Mahdi
  • ChemCatChem, Vol. 10, Issue 4
  • DOI: 10.1002/cctc.201701268

Active sites for CO 2 hydrogenation to methanol on Cu/ZnO catalysts
journal, March 2017


CO 2 Reduction on Supported Ru/Al 2 O 3 Catalysts: Cluster Size Dependence of Product Selectivity
journal, October 2013

  • Kwak, Ja Hun; Kovarik, Libor; Szanyi, János
  • ACS Catalysis, Vol. 3, Issue 11
  • DOI: 10.1021/cs400381f

Evidence of Highly Active Cobalt Oxide Catalyst for the Fischer–Tropsch Synthesis and CO 2 Hydrogenation
journal, January 2014

  • Melaet, Gérôme; Ralston, Walter T.; Li, Cheng-Shiuan
  • Journal of the American Chemical Society, Vol. 136, Issue 6
  • DOI: 10.1021/ja412447q

Sintering of Catalytic Nanoparticles: Particle Migration or Ostwald Ripening?
journal, April 2013

  • Hansen, Thomas W.; DeLaRiva, Andrew T.; Challa, Sivakumar R.
  • Accounts of Chemical Research, Vol. 46, Issue 8
  • DOI: 10.1021/ar3002427

Photocatalytic water oxidation by very small cobalt domains on a silica surface
journal, January 2013

  • Ahn, Hyun S.; Yano, Junko; Tilley, T. Don
  • Energy & Environmental Science, Vol. 6, Issue 10
  • DOI: 10.1039/c3ee42067a

The kinetics of precipitation from supersaturated solid solutions
journal, April 1961


Identification of active sites in CO oxidation and water-gas shift over supported Pt catalysts
journal, September 2015


Quantum Mechanical Screening of Single-Atom Bimetallic Alloys for the Selective Reduction of CO 2 to C 1 Hydrocarbons
journal, October 2016


Quantification of Zinc Atoms in a Surface Alloy on Copper in an Industrial-Type Methanol Synthesis Catalyst
journal, April 2014

  • Kuld, Sebastian; Conradsen, Christian; Moses, Poul Georg
  • Angewandte Chemie International Edition, Vol. 53, Issue 23
  • DOI: 10.1002/anie.201311073

Water Oxidation by Cobalt Centers on Various Oxide Surfaces: The Effects of Oxide Surface Acidity and Oxygen Atom Affinity on Catalysis
journal, March 2015

  • Ahn, Hyun S.; Yano, Junko; Tilley, T. Don
  • ACS Catalysis, Vol. 5, Issue 4
  • DOI: 10.1021/cs502120f

Isolated Metal Atom Geometries as a Strategy for Selective Heterogeneous Hydrogenations
journal, March 2012

  • Kyriakou, Georgios; Boucher, Matthew B.; Jewell, April D.
  • Science, Vol. 335, Issue 6073
  • DOI: 10.1126/science.1215864

Cobalt Particle Size Effects in the Fischer−Tropsch Reaction Studied with Carbon Nanofiber Supported Catalysts
journal, March 2006

  • Bezemer, G. Leendert; Bitter, Johannes H.; Kuipers, Herman P. C. E.
  • Journal of the American Chemical Society, Vol. 128, Issue 12
  • DOI: 10.1021/ja058282w

Recent advances in catalytic hydrogenation of carbon dioxide
journal, January 2011

  • Wang, Wei; Wang, Shengping; Ma, Xinbin
  • Chemical Society Reviews, Vol. 40, Issue 7
  • DOI: 10.1039/c1cs15008a

Highly active copper-ceria and copper-ceria-titania catalysts for methanol synthesis from CO2
journal, July 2014


Direct Low-Temperature Deposition of Crystallized CoOOH Films by Potentiostatic Electrolysis
journal, January 2005

  • Pauporté, T.; Mendoza, L.; Cassir, M.
  • Journal of The Electrochemical Society, Vol. 152, Issue 2
  • DOI: 10.1149/1.1842044

Real-space multiple-scattering calculation and interpretation of x-ray-absorption near-edge structure
journal, September 1998


Low-temperature water-gas shift reaction over Cu- and Ni-loaded cerium oxide catalysts
journal, August 2000


Single-Site Heterogeneous Catalysts
journal, October 2005

  • Thomas, John Meurig; Raja, Robert; Lewis, Dewi W.
  • Angewandte Chemie International Edition, Vol. 44, Issue 40, p. 6456-6482
  • DOI: 10.1002/anie.200462473

Low-temperature oxidation of CO catalysed by Co3O4 nanorods
journal, April 2009

  • Xie, Xiaowei; Li, Yong; Liu, Zhi-Quan
  • Nature, Vol. 458, Issue 7239, p. 746-749
  • DOI: 10.1038/nature07877

Selective propane dehydrogenation with single-site CoII on SiO2 by a non-redox mechanism
journal, February 2015


X-ray nanoscopy of cobalt Fischer–Tropsch catalysts at work
journal, January 2013

  • Cats, Korneel H.; Gonzalez-Jimenez, Ines D.; Liu, Yijin
  • Chemical Communications, Vol. 49, Issue 41
  • DOI: 10.1039/c3cc00160a

Low-Temperature Restructuring of CeO 2 -Supported Ru Nanoparticles Determines Selectivity in CO 2 Catalytic Reduction
journal, September 2018

  • Aitbekova, Aisulu; Wu, Liheng; Wrasman, Cody J.
  • Journal of the American Chemical Society, Vol. 140, Issue 42
  • DOI: 10.1021/jacs.8b07615

IFEFFIT  : interactive XAFS analysis and FEFF fitting
journal, March 2001


A combined in situ XAS-XRPD-Raman study of Fischer–Tropsch synthesis over a carbon supported Co catalyst
journal, April 2013


Heterogeneous Catalysis on Atomically Dispersed Supported Metals: CO 2 Reduction on Multifunctional Pd Catalysts
journal, August 2013

  • Kwak, Ja Hun; Kovarik, Libor; Szanyi, János
  • ACS Catalysis, Vol. 3, Issue 9
  • DOI: 10.1021/cs4001392

Catalysis mechanisms of CO 2 and CO methanation
journal, January 2016

  • Miao, Bin; Ma, Su Su Khine; Wang, Xin
  • Catalysis Science & Technology, Vol. 6, Issue 12
  • DOI: 10.1039/C6CY00478D

The synthesis of highly dispersed noble and base metals on silica via strong electrostatic adsorption: I. Amorphous silica
journal, December 2008


Size-Controlled Model Co Nanoparticle Catalysts for CO 2 Hydrogenation: Synthesis, Characterization, and Catalytic Reactions
journal, May 2012

  • Iablokov, Viacheslav; Beaumont, Simon K.; Alayoglu, Selim
  • Nano Letters, Vol. 12, Issue 6
  • DOI: 10.1021/nl300973b

Synthesis, characterization and in situ DRIFTS during the CO2 hydrogenation reaction over supported cobalt catalysts
journal, November 2011