Framework Doping of Ni Enhances Pseudocapacitive Na-Ion Storage of (Ni)MnO2 Layered Birnessite

Shan, Xiaoqiang; Guo, Fenghua; Page, Katharine; Neuefeind, Joerg C.; Ravel, Bruce; Abeykoon, A. M. Milinda; Kwon, Gihan; Olds, Daniel; Su, Dong; Teng, Xiaowei

doi:10.1021/acs.chemmater.9b02568

Title: Framework Doping of Ni Enhances Pseudocapacitive Na-Ion Storage of (Ni)MnO₂ Layered Birnessite

Abstract

We report a (Ni)MnO₂ layered birnessite material with a framwork doping of Ni ions as the cathode for much enhanced aqueous Na-ion storage. Characterized by neutron total scattering and pair distribution function (PDF) analysis, in situ XRD, in situ X-ray PDF, XANES, and XPS, the synergistic interaction between disordered [NiO₆] and ordered [MnO₆] octahedra contribute to the enhanced specific capacity and cycle life (63 mAh g^–1 at 0.2 A g^–1 after 2000 full-cell cycles). Electro-kinetic analysis and structural characterizations show that stable local structure is maintained by [MO₆] octahedra during charge–discharge processes, while disordered [NiO₆] octahedra significantly improve pseudocapacitive redox charge storage. As a result, this finding may pave a new way for designing a new type of low-cost and high performance layered electrode materials.

Authors:

Shan, Xiaoqiang ^[1]; Guo, Fenghua ^[1];

^[2]; Neuefeind, Joerg C. ^[2]; Ravel, Bruce ^[3]; Abeykoon, A. M. Milinda ^[4]; Kwon, Gihan ^[4]; Olds, Daniel ^[4];

^[5];

^[1]

Univ. of New Hampshire, Durham, NH (United States). Dept. of Chemical Engineering
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical and Engineering Materials Div.
National Inst. of Standards and Technology, Upton, NY (United States). Synchrotron Science Group at NSLS-II
Brookhaven National Lab. (BNL), Upton, NY (United States). National Synchrotron Light Source II
Brookhaven National Lab. (BNL), Upton, NY (United States). Center for Functional Nanomaterials

Publication Date:: Wed Oct 09 00:00:00 EDT 2019

Research Org.:: Brookhaven National Lab. (BNL), Upton, NY (United States); Univ. of New Hampshire, Durham, NH (United States); Xiaowei Teng/University of New Hampshire

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1574120

Alternate Identifier(s):: OSTI ID: 1594475; OSTI ID: 1594480

Report Number(s):: BNL-212311-2019-JAAM
Journal ID: ISSN 0897-4756

Grant/Contract Number:: SC0012704; SC0018922

Resource Type:: Accepted Manuscript

Journal Name:: Chemistry of Materials

Additional Journal Information:: Journal Volume: 31; Journal Issue: 21; Journal ID: ISSN 0897-4756

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; 25 ENERGY STORAGE

Citation Formats


                    Shan, Xiaoqiang, Guo, Fenghua, Page, Katharine, Neuefeind, Joerg C., Ravel, Bruce, Abeykoon, A. M. Milinda, Kwon, Gihan, Olds, Daniel, Su, Dong, and Teng, Xiaowei. Framework Doping of Ni Enhances Pseudocapacitive Na-Ion Storage of (Ni)MnO2 Layered Birnessite.  United States: N. p., 2019. 
Web.  doi:10.1021/acs.chemmater.9b02568.

Copy to clipboard


                    Shan, Xiaoqiang, Guo, Fenghua, Page, Katharine, Neuefeind, Joerg C., Ravel, Bruce, Abeykoon, A. M. Milinda, Kwon, Gihan, Olds, Daniel, Su, Dong, & Teng, Xiaowei. Framework Doping of Ni Enhances Pseudocapacitive Na-Ion Storage of (Ni)MnO2 Layered Birnessite.  United States.  https://doi.org/10.1021/acs.chemmater.9b02568

Copy to clipboard


                    Shan, Xiaoqiang, Guo, Fenghua, Page, Katharine, Neuefeind, Joerg C., Ravel, Bruce, Abeykoon, A. M. Milinda, Kwon, Gihan, Olds, Daniel, Su, Dong, and Teng, Xiaowei. Wed .  
"Framework Doping of Ni Enhances Pseudocapacitive Na-Ion Storage of (Ni)MnO2 Layered Birnessite".  United States.  https://doi.org/10.1021/acs.chemmater.9b02568.  https://www.osti.gov/servlets/purl/1574120.

Copy to clipboard


                    
@article{osti_1574120,

  title        = {Framework Doping of Ni Enhances Pseudocapacitive Na-Ion Storage of (Ni)MnO2 Layered Birnessite},

  author       = {Shan, Xiaoqiang and Guo, Fenghua and Page, Katharine and Neuefeind, Joerg C. and Ravel, Bruce and Abeykoon, A. M. Milinda and Kwon, Gihan and Olds, Daniel and Su, Dong and Teng, Xiaowei},

  abstractNote = {We report a (Ni)MnO2 layered birnessite material with a framwork doping of Ni ions as the cathode for much enhanced aqueous Na-ion storage. Characterized by neutron total scattering and pair distribution function (PDF) analysis, in situ XRD, in situ X-ray PDF, XANES, and XPS, the synergistic interaction between disordered [NiO6] and ordered [MnO6] octahedra contribute to the enhanced specific capacity and cycle life (63 mAh g–1 at 0.2 A g–1 after 2000 full-cell cycles). Electro-kinetic analysis and structural characterizations show that stable local structure is maintained by [MO6] octahedra during charge–discharge processes, while disordered [NiO6] octahedra significantly improve pseudocapacitive redox charge storage. As a result, this finding may pave a new way for designing a new type of low-cost and high performance layered electrode materials.},

  doi          = {10.1021/acs.chemmater.9b02568},

  journal      = {Chemistry of Materials},

  number       = 21,

  volume       = 31,

  place        = {United States},

  year         = {Wed Oct 09 00:00:00 EDT 2019},

  month        = {Wed Oct 09 00:00:00 EDT 2019}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

Accepted Manuscript (DOE)

Publisher's Version of Record

https://doi.org/10.1021/acs.chemmater.9b02568

Other availability

Search WorldCat to find libraries that may hold this journal

Citation Metrics:

Cited by: 31 works

Citation information provided by
Web of Science

Figures / Tables:

Figure 1: (a) TEM image of the (Ni)MnO₂ nanosheet material; (b) HAADF TEM and EELS mapping of the (Ni)MnO₂ material; (c) HRTEM of the (Ni)MnO₂ material, where the inset shows the SAED pattern of the (Ni)MnO₂ material; (d) XRD patterns of the (Ni)MnO₂ material compared with MnO₂; (e) comparisons ofmore »

All figures and tables (8 total)

Save / Share:

Export Metadata

Save to My Library

Figures / Tables found in this record:

Figures/Tables have been extracted from DOE-funded journal article accepted manuscripts.

Similar Records in DOE PAGES and OSTI.GOV collections:

Exemption of lattice collapse in Ni–MnO₂ birnessite regulated by the structural water mobility

Journal Article Shan, Xiaoqiang ; Pidathala, Ranga Teja ; Kim, SaeWon ; ... - Journal of Materials Chemistry. A

Lattice collapse and associated mechanical fracture frequently occur in Li-intercalated metal oxide cathodes at the deep charge state upon Li-ion removal, governed by chemical compositions and the resulting electron density of the oxygen atoms. However, similar lattice collapse for metal oxide electrodes in aqueous storage and its mitigation have not been well studied. In this work, we reported the lattice collapse of MnO₂ layered birnessite during the aqueous de-sodiation process at high voltage due to the structural water motion, as evidenced by in situ XRD. Unlike non-aqueous Li-intercalated electrodes, Ni-dopants mitigated the lattice collapse of birnessite at deep charge states.more »« less
https://doi.org/10.1039/d1ta06716h

Full Text Available
Structural water and disordered structure promote aqueous sodium-ion energy storage in sodium-birnessite

Journal Article Shan, Xiaoqiang ; Guo, Fenghua ; Charles, Daniel S. ; ... - Nature Communications

Birnessite is a low-cost and environmentally friendly layered material for aqueous electrochemical energy storage; however, its storage capacity is poor due to its narrow potential window in aqueous electrolyte and low redox activity. Herein we report a sodium rich disordered birnessite (Na_0.27MnO₂) for aqueous sodium-ion electrochemical storage with a much-enhanced capacity and cycling life (83 mAh g^-1 after 5000 cycles in full-cell). Neutron total scattering and in situ X-ray diffraction measurements show that both structural water and the Na-rich disordered structure contribute to the improved electrochemical performance of current cathode material. Particularly, the co-deintercalation of the hydrated water and sodium-ionmore »« less
Cited by 67
https://doi.org/10.1038/s41467-019-12939-3
Surface and Structural Investigation of a MnO _x Birnessite‐Type Water Oxidation Catalyst Formed under Photocatalytic Conditions

Journal Article Deibert, Benjamin J. ; Zhang, Jingming ; Smith, Paul F. ; ... - Chemistry - A European Journal

Abstract Catalytically active MnO _x species have been reported to form in situ from various Mn‐complexes during electrocatalytic and solution‐based water oxidation when employing cerium(IV) ammonium ammonium nitrate (CAN) oxidant as a sacrificial reagent. The full structural characterization of these oxides may be complicated by the presence of support material and lack of a pure bulk phase. For the first time, we show that highly active MnO _x catalysts form without supports in situ under photocatalytic conditions. Our most active ⁴ MnO _x catalyst (∼0.84 mmol O ₂ mol Mn ⁻¹ s ⁻¹ ) forms from amore »« less
Cited by 25
https://doi.org/10.1002/chem.201501930
High-Energy and Stable Subfreezing Aqueous Zn–MnO₂ Batteries with Selective and Pseudocapacitive Zn-Ion Insertion in MnO₂

Journal Article Gao, Siyuan ; Li, Bomin ; Tan, Haiyan ; ... - Advanced Materials

Abstract One major challenge of aqueous Zn–MnO ₂ batteries for practical applications is their unacceptable performance below freezing temperatures. Here the use of simple Zn(ClO ₄ ) ₂ aqueous electrolytes is described for all‐weather Zn–MnO ₂ batteries even down to −60 °C. The symmetric, bulky ClO ₄ ⁻ anion effectively disrupts hydrogen bonds between water molecules and provides intrinsic ion diffusion even while frozen, and enables ≈260 mAh g ⁻¹ on MnO ₂ cathodes at −30 °C . It is identified that subfreezing cycling shifts the reaction mechanism on the MnO ₂ cathode from unstable H ⁺ insertion to predominantly pseudocapacitive Znmore »« less
https://doi.org/10.1002/adma.202201510

Full Text Available
High-Mass Loading of Flower-like Ni-MoS₂ microspheres Toward Efficient Intercalation pseudocapacitive Electrode

Journal Article Panchu, Sarojini Jeeva ; Raju, Kumar ; Singh, Prashant ; ... - ACS Applied Energy Materials

This work reports the exploration of intercalation pseudocapacitance in a thicker electrode of flowerlike Ni-doped MoS₂ microspheres that features a mass loading of ~10 mg/cm² without sacrificing the gravimetric capacitance (~425 F/g at 5 mV/s). Integration of Ni atoms into MoS₂ microspheres not only stabilized the structural integrity but also ameliorated the rapid intercalation and deintercalation of electrolyte ions even at a commercial-level mass loading. The energy instability by Ni doping significantly changed the local bonding behavior and the overall electronic structure of MoS₂, facilitating the breaking of the MoS₂ layer and generation of more active edge sites, which aremore »« less
https://doi.org/10.1021/acsaem.2c03257

Full Text Available

Similar Records

Title: Framework Doping of Ni Enhances Pseudocapacitive Na-Ion Storage of (Ni)MnO2 Layered Birnessite

Abstract

Citation Formats

Figures / Tables:

Title: Framework Doping of Ni Enhances Pseudocapacitive Na-Ion Storage of (Ni)MnO₂ Layered Birnessite