Streamlined Fabrication of Asymmetric Carbon Molecular Sieve Hollow Fiber Membranes
Abstract
A microporous polymer, polymer of intrinsic microporosity-1, was utilized as the polymeric precursor to simplify the formation of asymmetric carbon molecular sieve hollow fiber membranes. Unlike other methods, asymmetric carbon membranes were formed directly without cross-linking or other pretreatments. In addition, a facile defect removal treatment was developed that can easily be incorporated into a standard fiber solvent exchange procedure. The resulting asymmetric carbon membranes display extraordinary gas selectivities at or exceeding the upper bound for O2/N2, CO2/CH4, He/N2, and C2H4/C2H6. The simplified, two-step method greatly improves the ease of fabrication of defect-free asymmetric carbon hollow fiber membranes for challenging separations.
- Authors:
-
[1];
[1];
[1]
- Georgia Inst. of Technology, Atlanta, GA (United States). School of Chemical and Biomolecular Engineering
- Publication Date:
- Research Org.:
- Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
- Sponsoring Org.:
- USDOE National Nuclear Security Administration (NNSA)
- OSTI Identifier:
- 1560974
- Report Number(s):
- LLNL-JRNL-758249
Journal ID: ISSN 2637-6105; 946207
- Grant/Contract Number:
- AC52-07NA27344
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ACS Applied Polymer Materials
- Additional Journal Information:
- Journal Volume: 1; Journal Issue: 8; Journal ID: ISSN 2637-6105
- Publisher:
- ACS Publications
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE
Citation Formats
Jue, Melinda L., Ma, Yao, and Lively, Ryan P. Streamlined Fabrication of Asymmetric Carbon Molecular Sieve Hollow Fiber Membranes. United States: N. p., 2019.
Web. doi:10.1021/acsapm.9b00567.
Jue, Melinda L., Ma, Yao, & Lively, Ryan P. Streamlined Fabrication of Asymmetric Carbon Molecular Sieve Hollow Fiber Membranes. United States. https://doi.org/10.1021/acsapm.9b00567
Jue, Melinda L., Ma, Yao, and Lively, Ryan P. Fri .
"Streamlined Fabrication of Asymmetric Carbon Molecular Sieve Hollow Fiber Membranes". United States. https://doi.org/10.1021/acsapm.9b00567. https://www.osti.gov/servlets/purl/1560974.
@article{osti_1560974,
title = {Streamlined Fabrication of Asymmetric Carbon Molecular Sieve Hollow Fiber Membranes},
author = {Jue, Melinda L. and Ma, Yao and Lively, Ryan P.},
abstractNote = {A microporous polymer, polymer of intrinsic microporosity-1, was utilized as the polymeric precursor to simplify the formation of asymmetric carbon molecular sieve hollow fiber membranes. Unlike other methods, asymmetric carbon membranes were formed directly without cross-linking or other pretreatments. In addition, a facile defect removal treatment was developed that can easily be incorporated into a standard fiber solvent exchange procedure. The resulting asymmetric carbon membranes display extraordinary gas selectivities at or exceeding the upper bound for O2/N2, CO2/CH4, He/N2, and C2H4/C2H6. The simplified, two-step method greatly improves the ease of fabrication of defect-free asymmetric carbon hollow fiber membranes for challenging separations.},
doi = {10.1021/acsapm.9b00567},
journal = {ACS Applied Polymer Materials},
number = 8,
volume = 1,
place = {United States},
year = {Fri Jul 19 00:00:00 EDT 2019},
month = {Fri Jul 19 00:00:00 EDT 2019}
}
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Figure 1: Simplified schematic of the formation of CMS HFM modules at lab scale from (a) polyvinylidene fluoride (PVDF) fibers and (b) PIM-1 fibers.
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Creation of Well‐Defined “Mid‐Sized” Micropores in Carbon Molecular Sieve Membranes
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Creation of Well‐Defined “Mid‐Sized” Micropores in Carbon Molecular Sieve Membranes
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Figures / Tables found in this record:
Figures/Tables have been extracted from DOE-funded journal article accepted manuscripts.