Room-Temperature Electrocaloric Effect in Layered Ferroelectric CuInP2S6 for Solid-State Refrigeration

Si, Mengwei; Saha, Atanu K.; Liao, Pai -Ying; Gao, Shengjie; Neumayer, Sabine M.; Jian, Jie; Qin, Jingkai; Wisinger, Nina Balke; Wang, Haiyan; Maksymovych, Petro; Wu, Wenzhuo; Gupta, Sumeet K.; Ye, Peide D.

doi:10.1021/acsnano.9b01491

Title: Room-Temperature Electrocaloric Effect in Layered Ferroelectric CuInP₂S₆ for Solid-State Refrigeration

Abstract

A material with reversible temperature change capability under an external electric field, known as the electrocaloric effect (ECE), has long been considered as a promising solid-state cooling solution. However, electrocaloric (EC) performance of EC materials generally is not sufficiently high for real cooling applications. As a result, exploring EC materials with high performance is of great interest and importance. Here, we report on the ECE of ferroelectric materials with van der Waals layered structure (CuInP2S6 or CIPS in this work in particular). Over 60% polarization charge change is observed within a temperature change of only 10 K at Curie temperature. Large adiabatic temperature change (|ΔT|) of 3.3 K and isothermal entropy change (|ΔS|) of 5.8 J kg^–1 K^–1 at |ΔE| = 142.0 kV cm^–1 and at 315 K (above and near room temperature) are achieved, with a large EC strength (|ΔT|/|ΔE|) of 29.5 mK cm kV^–1. Furthermore, the ECE of CIPS is also investigated theoretically by numerical simulation, and a further EC performance projection is provided.

Authors:

^[1]; Saha, Atanu K. ^[1]; Liao, Pai -Ying ^[1]; Gao, Shengjie ^[1];

^[2]; Jian, Jie ^[1]; Qin, Jingkai ^[1];

^[2];

^[1]; Maksymovych, Petro ^[2];

^[1]; Gupta, Sumeet K. ^[1];

^[1]

Purdue Univ., West Lafayette, IN (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Publication Date:: Fri Aug 02 00:00:00 EDT 2019

Research Org.:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1560477

Grant/Contract Number:: AC05-00OR22725

Resource Type:: Accepted Manuscript

Journal Name:: ACS Nano

Additional Journal Information:: Journal Volume: 13; Journal Issue: 8; Journal ID: ISSN 1936-0851

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; CuInP2S6; ferroelectrics; electrocaloric effect; two-dimensional; room temperature

Citation Formats


                    Si, Mengwei, Saha, Atanu K., Liao, Pai -Ying, Gao, Shengjie, Neumayer, Sabine M., Jian, Jie, Qin, Jingkai, Wisinger, Nina Balke, Wang, Haiyan, Maksymovych, Petro, Wu, Wenzhuo, Gupta, Sumeet K., and Ye, Peide D. Room-Temperature Electrocaloric Effect in Layered Ferroelectric CuInP2S6 for Solid-State Refrigeration.  United States: N. p., 2019. 
Web.  doi:10.1021/acsnano.9b01491.

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                    Si, Mengwei, Saha, Atanu K., Liao, Pai -Ying, Gao, Shengjie, Neumayer, Sabine M., Jian, Jie, Qin, Jingkai, Wisinger, Nina Balke, Wang, Haiyan, Maksymovych, Petro, Wu, Wenzhuo, Gupta, Sumeet K., & Ye, Peide D. Room-Temperature Electrocaloric Effect in Layered Ferroelectric CuInP2S6 for Solid-State Refrigeration.  United States.  https://doi.org/10.1021/acsnano.9b01491

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                    Si, Mengwei, Saha, Atanu K., Liao, Pai -Ying, Gao, Shengjie, Neumayer, Sabine M., Jian, Jie, Qin, Jingkai, Wisinger, Nina Balke, Wang, Haiyan, Maksymovych, Petro, Wu, Wenzhuo, Gupta, Sumeet K., and Ye, Peide D. Fri .  
"Room-Temperature Electrocaloric Effect in Layered Ferroelectric CuInP2S6 for Solid-State Refrigeration".  United States.  https://doi.org/10.1021/acsnano.9b01491.  https://www.osti.gov/servlets/purl/1560477.

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@article{osti_1560477,

  title        = {Room-Temperature Electrocaloric Effect in Layered Ferroelectric CuInP2S6 for Solid-State Refrigeration},

  author       = {Si, Mengwei and Saha, Atanu K. and Liao, Pai -Ying and Gao, Shengjie and Neumayer, Sabine M. and Jian, Jie and Qin, Jingkai and Wisinger, Nina Balke and Wang, Haiyan and Maksymovych, Petro and Wu, Wenzhuo and Gupta, Sumeet K. and Ye, Peide D.},

  abstractNote = {A material with reversible temperature change capability under an external electric field, known as the electrocaloric effect (ECE), has long been considered as a promising solid-state cooling solution. However, electrocaloric (EC) performance of EC materials generally is not sufficiently high for real cooling applications. As a result, exploring EC materials with high performance is of great interest and importance. Here, we report on the ECE of ferroelectric materials with van der Waals layered structure (CuInP2S6 or CIPS in this work in particular). Over 60% polarization charge change is observed within a temperature change of only 10 K at Curie temperature. Large adiabatic temperature change (|ΔT|) of 3.3 K and isothermal entropy change (|ΔS|) of 5.8 J kg–1 K–1 at |ΔE| = 142.0 kV cm–1 and at 315 K (above and near room temperature) are achieved, with a large EC strength (|ΔT|/|ΔE|) of 29.5 mK cm kV–1. Furthermore, the ECE of CIPS is also investigated theoretically by numerical simulation, and a further EC performance projection is provided.},

  doi          = {10.1021/acsnano.9b01491},

  journal      = {ACS Nano},

  number       = 8,

  volume       = 13,

  place        = {United States},

  year         = {Fri Aug 02 00:00:00 EDT 2019},

  month        = {Fri Aug 02 00:00:00 EDT 2019}

}

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https://doi.org/10.1021/acsnano.9b01491

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Cited by: 45 works

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Figures / Tables:

Figure 1: (a) Top- and side-view of CIPS, showing an ABC sulfur stacking, filled by Cu, In and P-P pairs and separated by a van der Waals gap as a ferroelectric insulator with van der Waals layered structure. (b) HAADF-STEM image of thin CIPS flake viewed along [001] axis andmore »

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Figures / Tables found in this record:

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Title: Room-Temperature Electrocaloric Effect in Layered Ferroelectric CuInP2S6 for Solid-State Refrigeration

Abstract

Citation Formats

Figures / Tables:

Giant Electrocaloric Effect in Thin-Film PbZr0.95Ti0.05O3 journal, March 2006

Large Electrocaloric Effect in Ferroelectric Polymers Near Room Temperature journal, August 2008

Organic and inorganic relaxor ferroelectrics with giant electrocaloric effect journal, October 2010

Electrocaloric Materials journal, August 2011

Electrocaloric materials for future solid-state refrigeration technologies journal, July 2012

Caloric materials near ferroic phase transitions journal, April 2014

Giant Electrocaloric Response Over A Broad Temperature Range in Modified BaTiO 3 Ceramics journal, September 2013

Ferroelectric Polymer Nanocomposites for Room-Temperature Electrocaloric Refrigeration journal, January 2015

Direct and indirect measurements on electrocaloric effect: Recent developments and perspectives journal, September 2016

Highly efficient electrocaloric cooling with electrostatic actuation journal, September 2017

Large Electrocaloric Effect in Relaxor Ferroelectric and Antiferroelectric Lanthanum Doped Lead Zirconate Titanate Ceramics journal, March 2017

Direct Measurement of Large Electrocaloric Effect in Ba(Zr x Ti 1– x )O 3 Ceramics journal, January 2018

Enhancement of the electrocaloric effect over a wide temperature range in PLZT ceramics by doping with Gd3+ and Sn4+ ions journal, April 2019

CuInP 2 S 6 Room Temperature Layered Ferroelectric journal, May 2015

Room-temperature ferroelectricity in CuInP2S6 ultrathin flakes journal, August 2016

Out-of-Plane Piezoelectricity and Ferroelectricity in Layered α-In 2 Se 3 Nanoflakes journal, August 2017

Ferroelectric switching of a two-dimensional metal journal, July 2018

Ferroelectric Field-Effect Transistors Based on MoS 2 and CuInP 2 S 6 Two-Dimensional van der Waals Heterostructure journal, June 2018

Room-temperature crystal structure of the layered phase CuIInIIIP2S6 journal, March 1995

Raman spectroscopy study of the ferrielectric-paraelectric transition in layered CuInP 2 S 6 journal, October 1998

The effects of microstructure on the electrocaloric properties of Pb(Zr,Sn,Ti)O 3 ceramics journal, October 1981

Anisotropic thermal properties and ferroelectric phase transitions in layered CuInP2S6 and CuInP2Se6 crystals journal, December 2017

CXXIII. The dielectric properties of barium titanate single crystals in the region of their upper transition temperature journal, October 1953

Double Hysteresis Loop of BaTi O 3 at the Curie Point journal, August 1953

Discontinuous Field‐Induced Transitions in Barium Titanate above the Curie Point journal, December 1956

Tunable quadruple-well ferroelectric van der Waals crystals journal, November 2019

Cation role in the thermal properties of layered materials M 1 + M 3 + P 2 ( S , Se ) 6 ( M 1 + = Cu , Ag ; M 3 + = In , Bi ) journal, October 2019

Title: Room-Temperature Electrocaloric Effect in Layered Ferroelectric CuInP₂S₆ for Solid-State Refrigeration

Giant Electrocaloric Effect in Thin-Film PbZr0.95Ti0.05O3
journal, March 2006

Large Electrocaloric Effect in Ferroelectric Polymers Near Room Temperature
journal, August 2008

Organic and inorganic relaxor ferroelectrics with giant electrocaloric effect
journal, October 2010

Electrocaloric Materials
journal, August 2011

Electrocaloric materials for future solid-state refrigeration technologies
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Caloric materials near ferroic phase transitions
journal, April 2014

Giant Electrocaloric Response Over A Broad Temperature Range in Modified BaTiO ₃ Ceramics
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Ferroelectric Polymer Nanocomposites for Room-Temperature Electrocaloric Refrigeration
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Direct and indirect measurements on electrocaloric effect: Recent developments and perspectives
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Highly efficient electrocaloric cooling with electrostatic actuation
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Large Electrocaloric Effect in Relaxor Ferroelectric and Antiferroelectric Lanthanum Doped Lead Zirconate Titanate Ceramics
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Direct Measurement of Large Electrocaloric Effect in Ba(Zr _x Ti _{1– x} )O ₃ Ceramics
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Enhancement of the electrocaloric effect over a wide temperature range in PLZT ceramics by doping with Gd3+ and Sn4+ ions
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Double Hysteresis Loop of BaTi $O_{3}$ at the Curie Point
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