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Correlation between cation order/disorder and the electrocaloric effect in the MLCCs of complex perovskite ferroelectrics
Abstract
The physical properties (dielectric, ferroelectric, piezoelectric, etc.) of complex perovskite ferroelectrics depend on the degree of order/disorder and the scale of the ordered domains. In this study, the electrocaloric (EC) properties of three representative complex perovskite ferroelectrics, Pb(Mg1/3Nb2/3)O3-8PbTiO3 (PMN-8PT), 1mol% Sm-doped Pb(Mg1/3Nb2/3)O3-8PbTiO3 (1S-PMN-8PT) and Pb(Sc1/2Ta1/2)O3 (PST) are evaluated. Multi-layer ceramic capacitors (MLCCs) with identical structural configurations were fabricated for these three compounds, and their EC properties were characterized by direct measurement using a thermocouple. The EC temperature change of PMN-8PT, 1S-PMN-8PT and PST MLCCs under 20 V μm–1 at room temperature were found to be 1.42 K, 1.54 K, and 3.10 K, respectively. X-ray diffraction and high-resolution transmission electron microscopy data suggests that the high EC performance of PST is related to the ordering of B-site cations (Sc3+ and Ta5+) with the ordering parameter S = 0.82 and a long coherence length of ~100 nm, such that the sample transitioned from a relaxor ferroelectric to a normal ferroelectric. Furthermore, these results provide pathway towards design of high performance EC materials required for solid state refrigeration and air-conditioning technologies.
- Authors:
-
[1];
[1];
- Pennsylvania State Univ., University Park, PA (United States)
- Michigan Technological Univ., Houghton, MI (United States)
- U.S. Army Combat Capabilities Development Command Aviation & Missile Center, Redstone Arsenal, AL (United States)
- Publication Date:
- Research Org.:
- Pennsylvania State Univ., University Park, PA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1973393
- Grant/Contract Number:
- SC0021118
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Acta Materialia
- Additional Journal Information:
- Journal Volume: 254; Journal ID: ISSN 1359-6454
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; electrocalorics; complex perovskite ferroelectrics; disorder; multi-layer ceramic capacitors
Citation Formats
Yan, Yongke, Geng, Liwei D., Cheng, Li-Qian, Li, Xiaotian, Leng, Haoyang, Wang, Ke, Poudel, Bed, Nozariasbmarz, Amin, Sanghadasa, Mohan, Trolier-McKinstry, Susan, Zhang, Qi-Ming, Wang, Yu U., and Priya, Shashank. Correlation between cation order/disorder and the electrocaloric effect in the MLCCs of complex perovskite ferroelectrics. United States: N. p., 2023.
Web. doi:10.1016/j.actamat.2023.118990.
Yan, Yongke, Geng, Liwei D., Cheng, Li-Qian, Li, Xiaotian, Leng, Haoyang, Wang, Ke, Poudel, Bed, Nozariasbmarz, Amin, Sanghadasa, Mohan, Trolier-McKinstry, Susan, Zhang, Qi-Ming, Wang, Yu U., & Priya, Shashank. Correlation between cation order/disorder and the electrocaloric effect in the MLCCs of complex perovskite ferroelectrics. United States. https://doi.org/10.1016/j.actamat.2023.118990
Yan, Yongke, Geng, Liwei D., Cheng, Li-Qian, Li, Xiaotian, Leng, Haoyang, Wang, Ke, Poudel, Bed, Nozariasbmarz, Amin, Sanghadasa, Mohan, Trolier-McKinstry, Susan, Zhang, Qi-Ming, Wang, Yu U., and Priya, Shashank. Tue .
"Correlation between cation order/disorder and the electrocaloric effect in the MLCCs of complex perovskite ferroelectrics". United States. https://doi.org/10.1016/j.actamat.2023.118990.
@article{osti_1973393,
title = {Correlation between cation order/disorder and the electrocaloric effect in the MLCCs of complex perovskite ferroelectrics},
author = {Yan, Yongke and Geng, Liwei D. and Cheng, Li-Qian and Li, Xiaotian and Leng, Haoyang and Wang, Ke and Poudel, Bed and Nozariasbmarz, Amin and Sanghadasa, Mohan and Trolier-McKinstry, Susan and Zhang, Qi-Ming and Wang, Yu U. and Priya, Shashank},
abstractNote = {The physical properties (dielectric, ferroelectric, piezoelectric, etc.) of complex perovskite ferroelectrics depend on the degree of order/disorder and the scale of the ordered domains. In this study, the electrocaloric (EC) properties of three representative complex perovskite ferroelectrics, Pb(Mg1/3Nb2/3)O3-8PbTiO3 (PMN-8PT), 1mol% Sm-doped Pb(Mg1/3Nb2/3)O3-8PbTiO3 (1S-PMN-8PT) and Pb(Sc1/2Ta1/2)O3 (PST) are evaluated. Multi-layer ceramic capacitors (MLCCs) with identical structural configurations were fabricated for these three compounds, and their EC properties were characterized by direct measurement using a thermocouple. The EC temperature change of PMN-8PT, 1S-PMN-8PT and PST MLCCs under 20 V μm–1 at room temperature were found to be 1.42 K, 1.54 K, and 3.10 K, respectively. X-ray diffraction and high-resolution transmission electron microscopy data suggests that the high EC performance of PST is related to the ordering of B-site cations (Sc3+ and Ta5+) with the ordering parameter S = 0.82 and a long coherence length of ~100 nm, such that the sample transitioned from a relaxor ferroelectric to a normal ferroelectric. Furthermore, these results provide pathway towards design of high performance EC materials required for solid state refrigeration and air-conditioning technologies.},
doi = {10.1016/j.actamat.2023.118990},
journal = {Acta Materialia},
number = ,
volume = 254,
place = {United States},
year = {Tue May 09 00:00:00 EDT 2023},
month = {Tue May 09 00:00:00 EDT 2023}
}
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