Cascade anchoring strategy for general mass production of high-loading single-atomic metal-nitrogen catalysts
Abstract
Although single-atomically dispersed metal-Nx on carbon support (M-NC) has great potential in heterogeneous catalysis, the scalable synthesis of such single-atom catalysts (SACs) with high-loading metal-Nx is greatly challenging since the loading and single-atomic dispersion have to be balanced at high temperature for forming metal-Nx. Herein, we develop a general cascade anchoring strategy for the mass production of a series of M-NC SACs with a metal loading up to 12.1 wt%. Systematic investigation reveals that the chelation of metal ions, physical isolation of chelate complex upon high loading, and the binding with N-species at elevated temperature are essential to achieving high-loading M-NC SACs. As a demonstration, high-loading Fe-NC SAC shows superior electrocatalytic performance for O2 reduction and Ni-NC SAC exhibits high electrocatalytic activity for CO2 reduction. The strategy paves a universal way to produce stable M-NC SAC with high-density metal-Nx sites for diverse high-performance applications.
- Authors:
-
[6];
[6];
[4];
- Chinese Academy of Sciences (CAS), Beijing (China); Univ. of Chinese Academy of Sciences, Beijing (China)
- Chinese Academy of Sciences (CAS), Beijing (China); Sichuan Normal Univ., Chengdu (China)
- Univ. of Chinese Academy of Sciences, Beijing (China); Chinese Academy of Sciences (CAS), Beijing (China)
- Chinese Academy of Sciences (CAS), Beijing (China)
- Univ. of Chinese Academy of Sciences, Beijing (China); Chinese Academy of Sciences, Shanghai (China)
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Publication Date:
- Research Org.:
- Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC)
- OSTI Identifier:
- 1559195
- Grant/Contract Number:
- AC02-05CH11231
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nature Communications
- Additional Journal Information:
- Journal Volume: 10; Journal Issue: 1; Journal ID: ISSN 2041-1723
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Zhao, Lu, Zhang, Yun, Huang, Lin-Bo, Liu, Xiao-Zhi, Zhang, Qing-Hua, He, Chao, Wu, Ze-Yuan, Zhang, Lin-Juan, Wu, Jinpeng, Yang, Wanli, Gu, Lin, Hu, Jin-Song, and Wan, Li-Jun. Cascade anchoring strategy for general mass production of high-loading single-atomic metal-nitrogen catalysts. United States: N. p., 2019.
Web. doi:10.1038/s41467-019-09290-y.
Zhao, Lu, Zhang, Yun, Huang, Lin-Bo, Liu, Xiao-Zhi, Zhang, Qing-Hua, He, Chao, Wu, Ze-Yuan, Zhang, Lin-Juan, Wu, Jinpeng, Yang, Wanli, Gu, Lin, Hu, Jin-Song, & Wan, Li-Jun. Cascade anchoring strategy for general mass production of high-loading single-atomic metal-nitrogen catalysts. United States. https://doi.org/10.1038/s41467-019-09290-y
Zhao, Lu, Zhang, Yun, Huang, Lin-Bo, Liu, Xiao-Zhi, Zhang, Qing-Hua, He, Chao, Wu, Ze-Yuan, Zhang, Lin-Juan, Wu, Jinpeng, Yang, Wanli, Gu, Lin, Hu, Jin-Song, and Wan, Li-Jun. Wed .
"Cascade anchoring strategy for general mass production of high-loading single-atomic metal-nitrogen catalysts". United States. https://doi.org/10.1038/s41467-019-09290-y. https://www.osti.gov/servlets/purl/1559195.
@article{osti_1559195,
title = {Cascade anchoring strategy for general mass production of high-loading single-atomic metal-nitrogen catalysts},
author = {Zhao, Lu and Zhang, Yun and Huang, Lin-Bo and Liu, Xiao-Zhi and Zhang, Qing-Hua and He, Chao and Wu, Ze-Yuan and Zhang, Lin-Juan and Wu, Jinpeng and Yang, Wanli and Gu, Lin and Hu, Jin-Song and Wan, Li-Jun},
abstractNote = {Although single-atomically dispersed metal-Nx on carbon support (M-NC) has great potential in heterogeneous catalysis, the scalable synthesis of such single-atom catalysts (SACs) with high-loading metal-Nx is greatly challenging since the loading and single-atomic dispersion have to be balanced at high temperature for forming metal-Nx. Herein, we develop a general cascade anchoring strategy for the mass production of a series of M-NC SACs with a metal loading up to 12.1 wt%. Systematic investigation reveals that the chelation of metal ions, physical isolation of chelate complex upon high loading, and the binding with N-species at elevated temperature are essential to achieving high-loading M-NC SACs. As a demonstration, high-loading Fe-NC SAC shows superior electrocatalytic performance for O2 reduction and Ni-NC SAC exhibits high electrocatalytic activity for CO2 reduction. The strategy paves a universal way to produce stable M-NC SAC with high-density metal-Nx sites for diverse high-performance applications.},
doi = {10.1038/s41467-019-09290-y},
journal = {Nature Communications},
number = 1,
volume = 10,
place = {United States},
year = {Wed Mar 20 00:00:00 EDT 2019},
month = {Wed Mar 20 00:00:00 EDT 2019}
}
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Works referenced in this record:
Atomic cobalt on nitrogen-doped graphene for hydrogen generation
journal, October 2015
- Fei, Huilong; Dong, Juncai; Arellano-Jiménez, M. Josefina
- Nature Communications, Vol. 6, Issue 1
Spectroscopic studies of iron(III) complexes of D-saccharose and D-glucose in the solid state and in solution
journal, September 1996
- Nagy, L.; Gajda, T.; Kürti, J.
- Journal of Radioanalytical and Nuclear Chemistry Articles, Vol. 209, Issue 1
Photodegradation Performance of g-C 3 N 4 Fabricated by Directly Heating Melamine
journal, September 2009
- Yan, S. C.; Li, Z. S.; Zou, Z. G.
- Langmuir, Vol. 25, Issue 17
Transition-metal saccharide chemistry: synthesis, spectroscopy, electrochemistry and magnetic susceptibility studies of iron(III) complexes of mono- and disaccharides
journal, July 1995
- Geetha, Kuppuswamy; Raghavan, Meenakshi S. S.; Kulshreshtha, Shailendra K.
- Carbohydrate Research, Vol. 271, Issue 2
Au Sub-Nanoclusters on TiO 2 toward Highly Efficient and Selective Electrocatalyst for N 2 Conversion to NH 3 at Ambient Conditions
journal, February 2017
- Shi, Miao-Miao; Bao, Di; Wulan, Ba-Ri
- Advanced Materials, Vol. 29, Issue 17
In situ electrochemical quantification of active sites in Fe–N/C non-precious metal catalysts
journal, October 2016
- Malko, Daniel; Kucernak, Anthony; Lopes, Thiago
- Nature Communications, Vol. 7, Issue 1
Uncoordinated Amine Groups of Metal–Organic Frameworks to Anchor Single Ru Sites as Chemoselective Catalysts toward the Hydrogenation of Quinoline
journal, July 2017
- Wang, Xin; Chen, Wenxing; Zhang, Lei
- Journal of the American Chemical Society, Vol. 139, Issue 28
Low-Temperature Cluster Catalysis
journal, March 2004
- Judai, Ken; Abbet, Stéphane; Wörz, Anke S.
- Journal of the American Chemical Society, Vol. 126, Issue 9
Iced photochemical reduction to synthesize atomically dispersed metals by suppressing nanocrystal growth
journal, November 2017
- Wei, Hehe; Huang, Kai; Wang, Da
- Nature Communications, Vol. 8, Issue 1
Recent Advances in Atomic Metal Doping of Carbon-based Nanomaterials for Energy Conversion
journal, April 2017
- Bayatsarmadi, Bita; Zheng, Yao; Vasileff, Anthony
- Small, Vol. 13, Issue 21
Iron(III) complexes of sugar-type ligands
journal, May 1986
- Nagy, L.; Burger, K.; Kürti, J.
- Inorganica Chimica Acta, Vol. 124, Issue 1
Stabilization of Single Metal Atoms on Graphitic Carbon Nitride
journal, January 2017
- Chen, Zupeng; Mitchell, Sharon; Vorobyeva, Evgeniya
- Advanced Functional Materials, Vol. 27, Issue 8
N-doped carbon nanomaterials are durable catalysts for oxygen reduction reaction in acidic fuel cells
journal, February 2015
- Shui, Jianglan; Wang, Min; Du, Feng
- Science Advances, Vol. 1, Issue 1
Promotion of oxygen reduction by a bio-inspired tethered iron phthalocyanine carbon nanotube-based catalyst
journal, June 2013
- Cao, Ruiguo; Thapa, Ranjit; Kim, Hyejung
- Nature Communications, Vol. 4, Issue 1
Isolated Single Iron Atoms Anchored on N-Doped Porous Carbon as an Efficient Electrocatalyst for the Oxygen Reduction Reaction
journal, April 2017
- Chen, Yuanjun; Ji, Shufang; Wang, Yanggang
- Angewandte Chemie International Edition, Vol. 56, Issue 24
In situ formation of molecular Ni-Fe active sites on heteroatom-doped graphene as a heterogeneous electrocatalyst toward oxygen evolution
journal, March 2018
- Wang, Jiong; Gan, Liyong; Zhang, Wenyu
- Science Advances, Vol. 4, Issue 3
Operando spectroscopy study of the carbon dioxide electro-reduction by iron species on nitrogen-doped carbon
journal, March 2018
- Genovese, Chiara; Schuster, Manfred E.; Gibson, Emma K.
- Nature Communications, Vol. 9, Issue 1
Simultaneous Nitrogen Doping and Reduction of Graphene Oxide
journal, November 2009
- Li, Xiaolin; Wang, Hailiang; Robinson, Joshua T.
- Journal of the American Chemical Society, Vol. 131, Issue 43
Single-Atom Catalysts: A New Frontier in Heterogeneous Catalysis
journal, April 2013
- Yang, Xiao-Feng; Wang, Aiqin; Qiao, Botao
- Accounts of Chemical Research, Vol. 46, Issue 8
High-Performance Electrocatalysts for Oxygen Reduction Derived from Polyaniline, Iron, and Cobalt
journal, April 2011
- Wu, G.; More, K. L.; Johnston, C. M.
- Science, Vol. 332, Issue 6028, p. 443-447
Understanding nano effects in catalysis
journal, May 2015
- Yang, Fan; Deng, Dehui; Pan, Xiulian
- National Science Review, Vol. 2, Issue 2
Understanding the High Activity of Fe–N–C Electrocatalysts in Oxygen Reduction: Fe/Fe 3 C Nanoparticles Boost the Activity of Fe–N x
journal, March 2016
- Jiang, Wen-Jie; Gu, Lin; Li, Li
- Journal of the American Chemical Society, Vol. 138, Issue 10
Single-atom catalysis of CO oxidation using Pt1/FeOx
journal, July 2011
- Qiao, Botao; Wang, Aiqin; Yang, Xiaofeng
- Nature Chemistry, Vol. 3, Issue 8
Photochemical route for synthesizing atomically dispersed palladium catalysts
journal, May 2016
- Liu, P.; Zhao, Y.; Qin, R.
- Science, Vol. 352, Issue 6287
Sintering of Catalytic Nanoparticles: Particle Migration or Ostwald Ripening?
journal, April 2013
- Hansen, Thomas W.; DeLaRiva, Andrew T.; Challa, Sivakumar R.
- Accounts of Chemical Research, Vol. 46, Issue 8
Platinum single-atom and cluster catalysis of the hydrogen evolution reaction
journal, November 2016
- Cheng, Niancai; Stambula, Samantha; Wang, Da
- Nature Communications, Vol. 7, Issue 1
Thermally stable single-atom platinum-on-ceria catalysts via atom trapping
journal, July 2016
- Jones, J.; Xiong, H.; DeLaRiva, A. T.
- Science, Vol. 353, Issue 6295
Graphitic Nanoshell/Mesoporous Carbon Nanohybrids as Highly Efficient and Stable Bifunctional Oxygen Electrocatalysts for Rechargeable Aqueous Na-Air Batteries
journal, January 2016
- Cheon, Jae Yeong; Kim, Kyoungho; Sa, Young Jin
- Advanced Energy Materials, Vol. 6, Issue 7
Synthesis–structure–performance correlation for polyaniline–Me–C non-precious metal cathode catalysts for oxygen reduction in fuel cells
journal, January 2011
- Wu, Gang; Johnston, Christina M.; Mack, Nathan H.
- Journal of Materials Chemistry, Vol. 21, Issue 30
Low-temperature carbon monoxide oxidation catalysed by regenerable atomically dispersed palladium on alumina
journal, September 2014
- Peterson, Eric J.; DeLaRiva, Andrew T.; Lin, Sen
- Nature Communications, Vol. 5, Issue 1
Single-Atom Catalysis in Mesoporous Photovoltaics: The Principle of Utility Maximization
journal, October 2014
- Shi, Yantao; Zhao, Chunyu; Wei, Haisheng
- Advanced Materials, Vol. 26, Issue 48
Metal-Organic Framework-Derived Bamboo-like Nitrogen-Doped Graphene Tubes as an Active Matrix for Hybrid Oxygen-Reduction Electrocatalysts
journal, November 2014
- Li, Qing; Pan, Hengyu; Higgins, Drew
- Small, Vol. 11, Issue 12
Identification of active sites in CO oxidation and water-gas shift over supported Pt catalysts
journal, September 2015
- Ding, K.; Gulec, A.; Johnson, A. M.
- Science, Vol. 350, Issue 6257
Cobalt-Embedded Nitrogen-Rich Carbon Nanotubes Efficiently Catalyze Hydrogen Evolution Reaction at All pH Values
journal, March 2014
- Zou, Xiaoxin; Huang, Xiaoxi; Goswami, Anandarup
- Angewandte Chemie International Edition, Vol. 53, Issue 17
Single Atom (Pd/Pt) Supported on Graphitic Carbon Nitride as an Efficient Photocatalyst for Visible-Light Reduction of Carbon Dioxide
journal, May 2016
- Gao, Guoping; Jiao, Yan; Waclawik, Eric R.
- Journal of the American Chemical Society, Vol. 138, Issue 19
Understanding activity and selectivity of metal-nitrogen-doped carbon catalysts for electrochemical reduction of CO2
journal, October 2017
- Ju, Wen; Bagger, Alexander; Hao, Guang-Ping
- Nature Communications, Vol. 8, Issue 1
Tuning selectivity of electrochemical reactions by atomically dispersed platinum catalyst
journal, March 2016
- Choi, Chang Hyuck; Kim, Minho; Kwon, Han Chang
- Nature Communications, Vol. 7, Issue 1
Direct Observations of Oxygen-induced Platinum Nanoparticle Ripening Studied by In Situ TEM
journal, June 2010
- Simonsen, Søren B.; Chorkendorff, Ib; Dahl, Søren
- Journal of the American Chemical Society, Vol. 132, Issue 23
An oxygen reduction electrocatalyst based on carbon nanotube–graphene complexes
journal, May 2012
- Li, Yanguang; Zhou, Wu; Wang, Hailiang
- Nature Nanotechnology, Vol. 7, Issue 6
High performance platinum single atom electrocatalyst for oxygen reduction reaction
journal, July 2017
- Liu, Jing; Jiao, Menggai; Lu, Lanlu
- Nature Communications, Vol. 8, Issue 1
A universal principle for a rational design of single-atom electrocatalysts
journal, April 2018
- Xu, Haoxiang; Cheng, Daojian; Cao, Dapeng
- Nature Catalysis, Vol. 1, Issue 5
Review on Recent Progress in Nitrogen-Doped Graphene: Synthesis, Characterization, and Its Potential Applications
journal, April 2012
- Wang, Haibo; Maiyalagan, Thandavarayan; Wang, Xin
- ACS Catalysis, Vol. 2, Issue 5
Single-Atom Pt as Co-Catalyst for Enhanced Photocatalytic H 2 Evolution
journal, January 2016
- Li, Xiaogang; Bi, Wentuan; Zhang, Lei
- Advanced Materials, Vol. 28, Issue 12
CO Oxidation on Au n /TiO 2 Catalysts Produced by Size-Selected Cluster Deposition
journal, May 2004
- Lee, Sungsik; Fan, Chaoyang; Wu, Tianpin
- Journal of the American Chemical Society, Vol. 126, Issue 18
Increased Silver Activity for Direct Propylene Epoxidation via Subnanometer Size Effects
journal, April 2010
- Lei, Y.; Mehmood, F.; Lee, S.
- Science, Vol. 328, Issue 5975, p. 224-228
Direct observation of noble metal nanoparticles transforming to thermally stable single atoms
journal, July 2018
- Wei, Shengjie; Li, Ang; Liu, Jin-Cheng
- Nature Nanotechnology, Vol. 13, Issue 9
A Polymer Encapsulation Strategy to Synthesize Porous Nitrogen-Doped Carbon-Nanosphere-Supported Metal Isolated-Single-Atomic-Site Catalysts
journal, March 2018
- Han, Aijuan; Chen, Wenxing; Zhang, Shaolong
- Advanced Materials, Vol. 30, Issue 15
Single-Atom Electrocatalysts
journal, October 2017
- Zhu, Chengzhou; Fu, Shaofang; Shi, Qiurong
- Angewandte Chemie International Edition, Vol. 56, Issue 45
In Situ Thermal Atomization To Convert Supported Nickel Nanoparticles into Surface-Bound Nickel Single-Atom Catalysts
journal, October 2018
- Yang, Jian; Qiu, Zongyang; Zhao, Changming
- Angewandte Chemie International Edition, Vol. 57, Issue 43
Aligned carbon nanotubes with built-in FeN 4 active sites for electrocatalytic reduction of oxygen
journal, January 2008
- Yang, Junbing; Liu, Di-Jia; Kariuki, Nancy N.
- Chem. Commun., Issue 3
X-ray absorption spectroscopy of biomimetic dye molecules for solar cells
journal, January 2009
- Cook, Peter L.; Liu, Xiaosong; Yang, Wanli
- The Journal of Chemical Physics, Vol. 131, Issue 19
Phenylenediamine-Based FeN x /C Catalyst with High Activity for Oxygen Reduction in Acid Medium and Its Active-Site Probing
journal, July 2014
- Wang, Qiang; Zhou, Zhi-You; Lai, Yu-Jiao
- Journal of the American Chemical Society, Vol. 136, Issue 31
Characterization of iron oxides by x-ray absorption at the oxygen K edgeusing a full multiple-scattering approach
journal, January 1997
- Wu, Z. Y.; Gota, S.; Jollet, F.
- Physical Review B, Vol. 55, Issue 4
A single iron site confined in a graphene matrix for the catalytic oxidation of benzene at room temperature
journal, December 2015
- Deng, Dehui; Chen, Xiaoqi; Yu, Liang
- Science Advances, Vol. 1, Issue 11
Synergetic interaction between neighbouring platinum monomers in CO2 hydrogenation
journal, March 2018
- Li, Hongliang; Wang, Liangbing; Dai, Yizhou
- Nature Nanotechnology, Vol. 13, Issue 5
Gold Supported on Thin Oxide Films: From Single Atoms to Nanoparticles
journal, August 2008
- Risse, Thomas; Shaikhutdinov, Shamil; Nilius, Niklas
- Accounts of Chemical Research, Vol. 41, Issue 8
Generation of subnanometric platinum with high stability during transformation of a 2D zeolite into 3D
journal, September 2016
- Liu, Lichen; Díaz, Urbano; Arenal, Raul
- Nature Materials, Vol. 16, Issue 1
Edge-Site Engineering of Atomically Dispersed Fe–N 4 by Selective C–N Bond Cleavage for Enhanced Oxygen Reduction Reaction Activities
journal, August 2018
- Jiang, Rui; Li, Li; Sheng, Tian
- Journal of the American Chemical Society, Vol. 140, Issue 37
Remarkable Performance of Ir 1 /FeO x Single-Atom Catalyst in Water Gas Shift Reaction
journal, October 2013
- Lin, Jian; Wang, Aiqin; Qiao, Botao
- Journal of the American Chemical Society, Vol. 135, Issue 41
Direct, Nonoxidative Conversion of Methane to Ethylene, Aromatics, and Hydrogen
journal, May 2014
- Guo, X.; Fang, G.; Li, G.
- Science, Vol. 344, Issue 6184
Direct atomic-level insight into the active sites of a high-performance PGM-free ORR catalyst
journal, August 2017
- Chung, Hoon T.; Cullen, David A.; Higgins, Drew
- Science, Vol. 357, Issue 6350
Single-atom dispersed Co–N–C catalyst: structure identification and performance for hydrogenative coupling of nitroarenes
journal, January 2016
- Liu, Wengang; Zhang, Leilei; Yan, Wensheng
- Chemical Science, Vol. 7, Issue 9
General synthesis and definitive structural identification of MN4C4 single-atom catalysts with tunable electrocatalytic activities
journal, January 2018
- Fei, Huilong; Dong, Juncai; Feng, Yexin
- Nature Catalysis, Vol. 1, Issue 1
Identification of Active Gold Nanoclusters on Iron Oxide Supports for CO Oxidation
journal, September 2008
- Herzing, A. A.; Kiely, C. J.; Carley, A. F.
- Science, Vol. 321, Issue 5894
Single Cobalt Atoms with Precise N-Coordination as Superior Oxygen Reduction Reaction Catalysts
journal, August 2016
- Yin, Peiqun; Yao, Tao; Wu, Yuen
- Angewandte Chemie International Edition, Vol. 55, Issue 36
Subnanometre platinum clusters as highly active and selective catalysts for the oxidative dehydrogenation of propane
journal, February 2009
- Vajda, Stefan; Pellin, Michael J.; Greeley, Jeffrey P.
- Nature Materials, Vol. 8, Issue 3
The Effect of Size-Dependent Nanoparticle Energetics on Catalyst Sintering
journal, October 2002
- Campbell, C. T.
- Science, Vol. 298, Issue 5594
Mild oxidation of methane to methanol or acetic acid on supported isolated rhodium catalysts
journal, November 2017
- Shan, Junjun; Li, Mengwei; Allard, Lawrence F.
- Nature, Vol. 551, Issue 7682
Cobalt-Embedded Nitrogen-Rich Carbon Nanotubes Efficiently Catalyze Hydrogen Evolution Reaction at All pH Values
journal, March 2014
- Zou, Xiaoxin; Huang, Xiaoxi; Goswami, Anandarup
- Angewandte Chemie, Vol. 126, Issue 17
Isolated Single Iron Atoms Anchored on N-Doped Porous Carbon as an Efficient Electrocatalyst for the Oxygen Reduction Reaction
journal, April 2017
- Chen, Yuanjun; Ji, Shufang; Wang, Yanggang
- Angewandte Chemie, Vol. 129, Issue 24
Single Cobalt Atoms with Precise N-Coordination as Superior Oxygen Reduction Reaction Catalysts
journal, August 2016
- Yin, Peiqun; Yao, Tao; Wu, Yuen
- Angewandte Chemie, Vol. 128, Issue 36
In Situ Thermal Atomization To Convert Supported Nickel Nanoparticles into Surface-Bound Nickel Single-Atom Catalysts
journal, October 2018
- Yang, Jian; Qiu, Zongyang; Zhao, Changming
- Angewandte Chemie, Vol. 130, Issue 43
Low-Temperature Cluster Catalysis.
journal, June 2004
- Judai, Ken; Abbet, Stephane; Woerz, Anke S.
- ChemInform, Vol. 35, Issue 23
Stabilization of Single Metal Atoms on Graphitic Carbon Nitride
text, January 2017
- Chen, Z.; Mitchell, S.; Vorobyeva, E.
- Apollo - University of Cambridge Repository
Review on Recent Progress in Nitrogen-Doped Graphene: Synthesis, Characterization, and Its Potential Applications
dataset, January 2014
- Maiyalagan, T.
- Figshare
Review on Recent Progress in Nitrogen-Doped Graphene: Synthesis, Characterization, and Its Potential Applications
dataset, January 2014
- Maiyalagan, T.
- figshare
Stabilization of Single Metal Atoms on Graphitic Carbon Nitride
text, January 2017
- Javier, Perez-Ramirez,; Zupeng, Chen,; Sharon, Mitchell,
- ETH Zurich
Stabilization of Single Metal Atoms on Graphitic Carbon Nitride
journal, January 2017
- Chen, Zupeng; Mitchell, Sharon; Vorobyeva, Evgeniya
- Advanced Functional Materials, Vol. 27, Issue 8
Single-Atom Catalysis in Mesoporous Photovoltaics: The Principle of Utility Maximization
journal, October 2014
- Shi, Yantao; Zhao, Chunyu; Wei, Haisheng
- Advanced Materials, Vol. 26, Issue 48
Single-Atom Pt as Co-Catalyst for Enhanced Photocatalytic H 2 Evolution
journal, January 2016
- Li, Xiaogang; Bi, Wentuan; Zhang, Lei
- Advanced Materials, Vol. 28, Issue 12
Au Sub-Nanoclusters on TiO 2 toward Highly Efficient and Selective Electrocatalyst for N 2 Conversion to NH 3 at Ambient Conditions
journal, February 2017
- Shi, Miao-Miao; Bao, Di; Wulan, Ba-Ri
- Advanced Materials, Vol. 29, Issue 17
A Polymer Encapsulation Strategy to Synthesize Porous Nitrogen-Doped Carbon-Nanosphere-Supported Metal Isolated-Single-Atomic-Site Catalysts
journal, March 2018
- Han, Aijuan; Chen, Wenxing; Zhang, Shaolong
- Advanced Materials, Vol. 30, Issue 15
Graphitic Nanoshell/Mesoporous Carbon Nanohybrids as Highly Efficient and Stable Bifunctional Oxygen Electrocatalysts for Rechargeable Aqueous Na-Air Batteries
journal, January 2016
- Cheon, Jae Yeong; Kim, Kyoungho; Sa, Young Jin
- Advanced Energy Materials, Vol. 6, Issue 7
Cobalt-Embedded Nitrogen-Rich Carbon Nanotubes Efficiently Catalyze Hydrogen Evolution Reaction at All pH Values
journal, March 2014
- Zou, Xiaoxin; Huang, Xiaoxi; Goswami, Anandarup
- Angewandte Chemie International Edition, Vol. 53, Issue 17
Single Cobalt Atoms with Precise N-Coordination as Superior Oxygen Reduction Reaction Catalysts
journal, August 2016
- Yin, Peiqun; Yao, Tao; Wu, Yuen
- Angewandte Chemie International Edition, Vol. 55, Issue 36
Single-Atom Electrocatalysts
journal, October 2017
- Zhu, Chengzhou; Fu, Shaofang; Shi, Qiurong
- Angewandte Chemie International Edition, Vol. 56, Issue 45
In Situ Thermal Atomization To Convert Supported Nickel Nanoparticles into Surface-Bound Nickel Single-Atom Catalysts
journal, October 2018
- Yang, Jian; Qiu, Zongyang; Zhao, Changming
- Angewandte Chemie International Edition, Vol. 57, Issue 43
Recent Advances in Atomic Metal Doping of Carbon-based Nanomaterials for Energy Conversion
journal, April 2017
- Bayatsarmadi, Bita; Zheng, Yao; Vasileff, Anthony
- Small, Vol. 13, Issue 21
Sintering of Catalytic Nanoparticles: Particle Migration or Ostwald Ripening?
journal, April 2013
- Hansen, Thomas W.; DeLaRiva, Andrew T.; Challa, Sivakumar R.
- Accounts of Chemical Research, Vol. 46, Issue 8
Gold Supported on Thin Oxide Films: From Single Atoms to Nanoparticles
journal, August 2008
- Risse, Thomas; Shaikhutdinov, Shamil; Nilius, Niklas
- Accounts of Chemical Research, Vol. 41, Issue 8
Remarkable Performance of Ir 1 /FeO x Single-Atom Catalyst in Water Gas Shift Reaction
journal, October 2013
- Lin, Jian; Wang, Aiqin; Qiao, Botao
- Journal of the American Chemical Society, Vol. 135, Issue 41
Phenylenediamine-Based FeN x /C Catalyst with High Activity for Oxygen Reduction in Acid Medium and Its Active-Site Probing
journal, July 2014
- Wang, Qiang; Zhou, Zhi-You; Lai, Yu-Jiao
- Journal of the American Chemical Society, Vol. 136, Issue 31
Simultaneous Nitrogen Doping and Reduction of Graphene Oxide
journal, November 2009
- Li, Xiaolin; Wang, Hailiang; Robinson, Joshua T.
- Journal of the American Chemical Society, Vol. 131, Issue 43
Single Atom (Pd/Pt) Supported on Graphitic Carbon Nitride as an Efficient Photocatalyst for Visible-Light Reduction of Carbon Dioxide
journal, May 2016
- Gao, Guoping; Jiao, Yan; Waclawik, Eric R.
- Journal of the American Chemical Society, Vol. 138, Issue 19
Uncoordinated Amine Groups of Metal–Organic Frameworks to Anchor Single Ru Sites as Chemoselective Catalysts toward the Hydrogenation of Quinoline
journal, July 2017
- Wang, Xin; Chen, Wenxing; Zhang, Lei
- Journal of the American Chemical Society, Vol. 139, Issue 28
Photodegradation Performance of g-C 3 N 4 Fabricated by Directly Heating Melamine
journal, September 2009
- Yan, S. C.; Li, Z. S.; Zou, Z. G.
- Langmuir, Vol. 25, Issue 17
Mild oxidation of methane to methanol or acetic acid on supported isolated rhodium catalysts
journal, November 2017
- Shan, Junjun; Li, Mengwei; Allard, Lawrence F.
- Nature, Vol. 551, Issue 7682
Single-atom catalysis of CO oxidation using Pt1/FeOx
journal, July 2011
- Qiao, Botao; Wang, Aiqin; Yang, Xiaofeng
- Nature Chemistry, Vol. 3, Issue 8
Platinum single-atom and cluster catalysis of the hydrogen evolution reaction
journal, November 2016
- Cheng, Niancai; Stambula, Samantha; Wang, Da
- Nature Communications, Vol. 7, Issue 1
High performance platinum single atom electrocatalyst for oxygen reduction reaction
journal, July 2017
- Liu, Jing; Jiao, Menggai; Lu, Lanlu
- Nature Communications, Vol. 8, Issue 1
Promotion of oxygen reduction by a bio-inspired tethered iron phthalocyanine carbon nanotube-based catalyst
journal, June 2013
- Cao, Ruiguo; Thapa, Ranjit; Kim, Hyejung
- Nature Communications, Vol. 4, Issue 1
Atomic cobalt on nitrogen-doped graphene for hydrogen generation
journal, October 2015
- Fei, Huilong; Dong, Juncai; Arellano-Jiménez, M. Josefina
- Nature Communications, Vol. 6, Issue 1
Subnanometre platinum clusters as highly active and selective catalysts for the oxidative dehydrogenation of propane
journal, February 2009
- Vajda, Stefan; Pellin, Michael J.; Greeley, Jeffrey P.
- Nature Materials, Vol. 8, Issue 3
An oxygen reduction electrocatalyst based on carbon nanotube–graphene complexes
journal, May 2012
- Li, Yanguang; Zhou, Wu; Wang, Hailiang
- Nature Nanotechnology, Vol. 7, Issue 6
Iced photochemical reduction to synthesize atomically dispersed metals by suppressing nanocrystal growth
journal, November 2017
- Wei, Hehe; Huang, Kai; Wang, Da
- Nature Communications, Vol. 8, Issue 1
Operando spectroscopy study of the carbon dioxide electro-reduction by iron species on nitrogen-doped carbon
journal, March 2018
- Genovese, Chiara; Schuster, Manfred E.; Gibson, Emma K.
- Nature Communications, Vol. 9, Issue 1
General synthesis and definitive structural identification of MN4C4 single-atom catalysts with tunable electrocatalytic activities
journal, January 2018
- Fei, Huilong; Dong, Juncai; Feng, Yexin
- Nature Catalysis, Vol. 1, Issue 1
Synthesis–structure–performance correlation for polyaniline–Me–C non-precious metal cathode catalysts for oxygen reduction in fuel cells
journal, January 2011
- Wu, Gang; Johnston, Christina M.; Mack, Nathan H.
- Journal of Materials Chemistry, Vol. 21, Issue 30
Fe–N bonding in a carbon nanotube–graphene complex for oxygen reduction: an XAS study
journal, January 2014
- Zhou, Jigang; Duchesne, Paul N.; Hu, Yongfeng
- Physical Chemistry Chemical Physics, Vol. 16, Issue 30
X-ray absorption spectroscopy of biomimetic dye molecules for solar cells
journal, January 2009
- Cook, Peter L.; Liu, Xiaosong; Yang, Wanli
- The Journal of Chemical Physics, Vol. 131, Issue 19
Understanding nano effects in catalysis
journal, May 2015
- Yang, Fan; Deng, Dehui; Pan, Xiulian
- National Science Review, Vol. 2, Issue 2
N-doped carbon nanomaterials are durable catalysts for oxygen reduction reaction in acidic fuel cells
journal, February 2015
- Shui, Jianglan; Wang, Min; Du, Feng
- Science Advances, Vol. 1, Issue 1
A single iron site confined in a graphene matrix for the catalytic oxidation of benzene at room temperature
journal, December 2015
- Deng, Dehui; Chen, Xiaoqi; Yu, Liang
- Science Advances, Vol. 1, Issue 11
In situ formation of molecular Ni-Fe active sites on heteroatom-doped graphene as a heterogeneous electrocatalyst toward oxygen evolution
journal, March 2018
- Wang, Jiong; Gan, Liyong; Zhang, Wenyu
- Science Advances, Vol. 4, Issue 3
The Effect of Size-Dependent Nanoparticle Energetics on Catalyst Sintering
journal, October 2002
- Campbell, C. T.
- Science, Vol. 298, Issue 5594
Identification of Active Gold Nanoclusters on Iron Oxide Supports for CO Oxidation
journal, September 2008
- Herzing, A. A.; Kiely, C. J.; Carley, A. F.
- Science, Vol. 321, Issue 5894
Increased Silver Activity for Direct Propylene Epoxidation via Subnanometer Size Effects
journal, April 2010
- Lei, Y.; Mehmood, F.; Lee, S.
- Science, Vol. 328, Issue 5975, p. 224-228
High-Performance Electrocatalysts for Oxygen Reduction Derived from Polyaniline, Iron, and Cobalt
journal, April 2011
- Wu, G.; More, K. L.; Johnston, C. M.
- Science, Vol. 332, Issue 6028, p. 443-447
Photochemical route for synthesizing atomically dispersed palladium catalysts
journal, May 2016
- Liu, P.; Zhao, Y.; Qin, R.
- Science, Vol. 352, Issue 6287
Thermally stable single-atom platinum-on-ceria catalysts via atom trapping
journal, July 2016
- Jones, J.; Xiong, H.; DeLaRiva, A. T.
- Science, Vol. 353, Issue 6295
Direct atomic-level insight into the active sites of a high-performance PGM-free ORR catalyst
journal, August 2017
- Chung, Hoon T.; Cullen, David A.; Higgins, Drew
- Science, Vol. 357, Issue 6350
Works referencing / citing this record:
Catalysis of a Single Transition Metal Site for Water Oxidation: From Mononuclear Molecules to Single Atoms
journal, December 2019
- Zhang, Huayang; Tian, Wenjie; Duan, Xiaoguang
- Advanced Materials, Vol. 32, Issue 18
Ambient Synthesis of Single‐Atom Catalysts from Bulk Metal via Trapping of Atoms by Surface Dangling Bonds
journal, September 2019
- Qu, Yunteng; Wang, Liguang; Li, Zhijun
- Advanced Materials, Vol. 31, Issue 44
A General Method for Transition Metal Single Atoms Anchored on Honeycomb‐Like Nitrogen‐Doped Carbon Nanosheets
journal, January 2020
- Zhang, Xiaoyan; Zhang, Shan; Yang, Yong
- Advanced Materials, Vol. 32, Issue 10
Oxygen Reduction Reactions on Single‐ or Few‐Atom Discrete Active Sites for Heterogeneous Catalysis
journal, September 2019
- Sharifi, Tiva; Gracia‐Espino, Eduardo; Chen, Anran
- Advanced Energy Materials, Vol. 10, Issue 11
When Nanozymes Meet Single‐Atom Catalysis
journal, October 2019
- Jiao, Lei; Yan, Hongye; Wu, Yu
- Angewandte Chemie, Vol. 132, Issue 7
When Nanozymes Meet Single‐Atom Catalysis
journal, February 2020
- Jiao, Lei; Yan, Hongye; Wu, Yu
- Angewandte Chemie International Edition, Vol. 59, Issue 7
Recent Progress in Precious Metal‐Free Carbon‐Based Materials towards the Oxygen Reduction Reaction: Activity, Stability, and Anti‐Poisoning
journal, November 2019
- Zhang, Ling; Li, Li; Chen, Hongmei
- Chemistry – A European Journal
Nitrogen‐Doped Porous Carbon Supported Nonprecious Metal Single‐Atom Electrocatalysts: from Synthesis to Application
journal, May 2019
- Guo, Jiaojiao; Huo, Juanjuan; Liu, Yan
- Small Methods, Vol. 3, Issue 9
Densely Populated Single Atom Catalysts
journal, November 2019
- Wu, Jiabin; Xiong, Liukang; Zhao, Bote
- Small Methods, Vol. 4, Issue 2
A ZIF-derived hierarchically porous Fe–Zn–N–C catalyst synthesized via a two-stage pyrolysis for the highly efficient oxygen reduction reaction in both acidic and alkaline media
journal, January 2019
- Li, Fang; Ding, Xiao-Bo; Cao, Qing-Cheng
- Chemical Communications, Vol. 55, Issue 93
Single atom electrocatalysts supported on graphene or graphene-like carbons
journal, January 2019
- Fei, Huilong; Dong, Juncai; Chen, Dongliang
- Chemical Society Reviews, Vol. 48, Issue 20
Atomic interface effect of a single atom copper catalyst for enhanced oxygen reduction reactions
journal, January 2019
- Jiang, Zhuoli; Sun, Wenming; Shang, Huishan
- Energy & Environmental Science, Vol. 12, Issue 12
Microwave-assisted depolymerization of various types of waste lignins over two-dimensional CuO/BCN catalysts
journal, January 2020
- Cao, Yang; Chen, Season S.; Tsang, Daniel C. W.
- Green Chemistry, Vol. 22, Issue 3
Synergistic catalysis between atomically dispersed Fe and a pyrrolic-N-C framework for CO 2 electroreduction
journal, January 2019
- Xu, Chaochen; Vasileff, Anthony; Wang, Dan
- Nanoscale Horizons, Vol. 4, Issue 6
Poly-phenylenediamine-derived atomically dispersed Ni sites for the electroreduction of CO 2 to CO
journal, January 2019
- Zheng, Yonglong; Han, Jianyu; Takele, Leta
- Inorganic Chemistry Frontiers, Vol. 6, Issue 7
A universal route to N-coordinated metals anchored on porous carbon nanosheets for highly efficient oxygen electrochemistry
journal, January 2019
- Ren, Jin-Tao; Yuan, Zhong-Yong
- Journal of Materials Chemistry A, Vol. 7, Issue 22
Photocatalytic nitrogen fixation: the role of defects in photocatalysts
journal, January 2019
- Cheng, Ming; Xiao, Chong; Xie, Yi
- Journal of Materials Chemistry A, Vol. 7, Issue 34
Preparation of Fe–N–C catalysts with FeN x ( x = 1, 3, 4) active sites and comparison of their activities for the oxygen reduction reaction and performances in proton exchange membrane fuel cells
journal, January 2019
- Li, Yongcheng; Liu, Xiaofang; Zheng, Lirong
- Journal of Materials Chemistry A, Vol. 7, Issue 45
Aerobic selective oxidation of methylaromatics to benzoic acids over Co@N/Co-CNTs with high loading CoN 4 species
journal, January 2019
- Chen, Bingfeng; Li, Shaopeng; Liu, Shoujie
- Journal of Materials Chemistry A, Vol. 7, Issue 48
Hydrogen peroxide electrochemical synthesis on hybrid double-atom (Pd–Cu) doped N vacancy g-C 3 N 4 : a novel design strategy for electrocatalyst screening
journal, January 2020
- Cao, Yongyong; Zhao, Chenxia; Fang, Qiaojun
- Journal of Materials Chemistry A, Vol. 8, Issue 5
Uncovering near-free platinum single-atom dynamics during electrochemical hydrogen evolution reaction
journal, February 2020
- Fang, Shi; Zhu, Xiaorong; Liu, Xiaokang
- Nature Communications, Vol. 11, Issue 1
Electrochemical deposition as a universal route for fabricating single-atom catalysts
journal, March 2020
- Zhang, Zhirong; Feng, Chen; Liu, Chunxiao
- Nature Communications, Vol. 11, Issue 1