Experimental evidence for chemo-mechanical coupling during carbon mineralization in ultramafic rocks
Abstract
It is known that storing carbon dioxide in the subsurface as carbonate minerals has the benefit of long-term stability and immobility. Ultramafic rock formations have been suggested as a potential reservoir for this type of storage due to the availability of cations to react with dissolved carbon dioxide and the fast reaction rates associated with minerals common in ultramafic formations; however, the rapid reactions have the potential to couple with the mechanical and hydraulic behavior of the rocks and little is known about the extent and mechanisms of this coupling. In this study, we argue that the dissolution of primary minerals and the precipitation of secondary minerals along pre-existing fractures in samples lead to reductions in both the apparent Young's modulus and shear strength of aggregates, accompanied by reduction in permeability. Hydrostatic and triaxial deformation experiments were run on dunite samples saturated with de-ionized water and carbon dioxide-rich solutions while stress, strain, permeability and pore fluid chemistry were monitored. Sample microstructures were examined after reaction and deformation using scanning electron microscopy (SEM). The results show that channelized dissolution and carbonate mineral precipitation in the samples saturated with carbon dioxide-rich solutions modify the structure of grain boundaries, leading to the observedmore »
- Authors:
- Publication Date:
- Research Org.:
- Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1476539
- Alternate Identifier(s):
- OSTI ID: 1549601
- Grant/Contract Number:
- AC02-05CH11231; FG-0207ER15916; FE-0004375; SC0001114; AC04-94AL85000
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Earth and Planetary Science Letters
- Additional Journal Information:
- Journal Volume: 474; Journal Issue: C; Journal ID: ISSN 0012-821X
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 58 GEOSCIENCES
Citation Formats
Lisabeth, H. P., Zhu, W., Kelemen, P. B., and Ilgen, A. Experimental evidence for chemo-mechanical coupling during carbon mineralization in ultramafic rocks. United States: N. p., 2017.
Web. doi:10.1016/j.epsl.2017.06.045.
Lisabeth, H. P., Zhu, W., Kelemen, P. B., & Ilgen, A. Experimental evidence for chemo-mechanical coupling during carbon mineralization in ultramafic rocks. United States. https://doi.org/10.1016/j.epsl.2017.06.045
Lisabeth, H. P., Zhu, W., Kelemen, P. B., and Ilgen, A. Fri .
"Experimental evidence for chemo-mechanical coupling during carbon mineralization in ultramafic rocks". United States. https://doi.org/10.1016/j.epsl.2017.06.045. https://www.osti.gov/servlets/purl/1476539.
@article{osti_1476539,
title = {Experimental evidence for chemo-mechanical coupling during carbon mineralization in ultramafic rocks},
author = {Lisabeth, H. P. and Zhu, W. and Kelemen, P. B. and Ilgen, A.},
abstractNote = {It is known that storing carbon dioxide in the subsurface as carbonate minerals has the benefit of long-term stability and immobility. Ultramafic rock formations have been suggested as a potential reservoir for this type of storage due to the availability of cations to react with dissolved carbon dioxide and the fast reaction rates associated with minerals common in ultramafic formations; however, the rapid reactions have the potential to couple with the mechanical and hydraulic behavior of the rocks and little is known about the extent and mechanisms of this coupling. In this study, we argue that the dissolution of primary minerals and the precipitation of secondary minerals along pre-existing fractures in samples lead to reductions in both the apparent Young's modulus and shear strength of aggregates, accompanied by reduction in permeability. Hydrostatic and triaxial deformation experiments were run on dunite samples saturated with de-ionized water and carbon dioxide-rich solutions while stress, strain, permeability and pore fluid chemistry were monitored. Sample microstructures were examined after reaction and deformation using scanning electron microscopy (SEM). The results show that channelized dissolution and carbonate mineral precipitation in the samples saturated with carbon dioxide-rich solutions modify the structure of grain boundaries, leading to the observed reductions in stiffness, strength and permeability. A geochemical model was run to help interpret fluid chemical data, and we find that the apparent reaction rates in our experiments are faster than rates calculated from powder reactors, suggesting mechanically enhanced reaction rates. In conclusion, we find that chemo-mechanical coupling during carbon mineralization in dunites leads to substantial modification of mechanical and hydraulic behavior that needs to be accounted for in future modeling efforts of in situ carbon mineralization projects.},
doi = {10.1016/j.epsl.2017.06.045},
journal = {Earth and Planetary Science Letters},
number = C,
volume = 474,
place = {United States},
year = {Fri Sep 01 00:00:00 EDT 2017},
month = {Fri Sep 01 00:00:00 EDT 2017}
}
Web of Science
Works referenced in this record:
Experimental Study of Carbon Sequestration Reactions Controlled by the Percolation of CO 2 -Rich Brine through Peridotites
journal, February 2009
- Andreani, M.; Luquot, L.; Gouze, P.
- Environmental Science & Technology, Vol. 43, Issue 4
Chemistry of aqueous mineral carbonation for carbon sequestration and explanation of experimental results
journal, January 2006
- Chen, Zhong-Ying; O'Connor, William K.; Gerdemann, S. J.
- Environmental Progress, Vol. 25, Issue 2
Permeability of thermally cracked granite
journal, May 1992
- Darot, Michel; Gueguen, Yves; Baratin, Marie-Laure
- Geophysical Research Letters, Vol. 19, Issue 9
Influence of amorphous silica layer formation on the dissolution rate of olivine at 90°C and elevated pCO2
journal, May 2011
- Daval, Damien; Sissmann, Olivier; Menguy, Nicolas
- Chemical Geology, Vol. 284, Issue 1-2
Dissolution and deformation in fractured carbonates caused by flow of CO2-rich brine under reservoir conditions
journal, June 2013
- Elkhoury, Jean E.; Ameli, Pasha; Detwiler, Russell L.
- International Journal of Greenhouse Gas Control, Vol. 16
Chemical and morphological changes during olivine carbonation for CO2 storage in the presence of NaCl and NaHCO3
journal, January 2014
- Gadikota, Greeshma; Matter, Juerg; Kelemen, Peter
- Physical Chemistry Chemical Physics, Vol. 16, Issue 10
Reactive transport modelling of the impact of CO2 injection on the clayey cap rock at Sleipner (North Sea)
journal, April 2005
- Gaus, Irina; Azaroual, Mohamed; Czernichowski-Lauriol, Isabelle
- Chemical Geology, Vol. 217, Issue 3-4
Forsterite dissolution and magnesite precipitation at conditions relevant for deep saline aquifer storage and sequestration of carbon dioxide
journal, April 2005
- Giammar, Daniel E.; Bruant, Robert G.; Peters, Catherine A.
- Chemical Geology, Vol. 217, Issue 3-4
Incipient hydration of mantle lithosphere at ridges: A reactive-percolation experiment
journal, June 2013
- Godard, Marguerite; Luquot, Linda; Andreani, Muriel
- Earth and Planetary Science Letters, Vol. 371-372
Mechanics of seismic instabilities induced by the recovery of hydrocarbons
journal, January 1992
- Grasso, J. -R.
- Pure and Applied Geophysics PAGEOPH, Vol. 139, Issue 3-4
CO2 geological storage: The environmental mineralogy perspective
journal, February 2011
- Guyot, François; Daval, Damien; Dupraz, Sébastien
- Comptes Rendus Geoscience, Vol. 343, Issue 2-3
Measurement and Correlation of Solubility Data for CO 2 in NaHCO 3 Aqueous Solution
journal, April 2011
- Han, Xiaoying; Yu, Zhihui; Qu, Jingkui
- Journal of Chemical & Engineering Data, Vol. 56, Issue 4
Dissolution kinetics of fosteritic olivine at 90–150°C including effects of the presence of CO2
journal, September 2006
- Hänchen, M.; Prigiobbe, V.; Storti, G.
- Geochimica et Cosmochimica Acta, Vol. 70, Issue 17
Geomechanical Factors Affecting Geological Storage of CO2 in Depleted Oil and Gas Reservoirs
journal, October 2005
- Hawkes, C. D.; McLellan, P. J.; Bachu, S.
- Journal of Canadian Petroleum Technology, Vol. 44, Issue 10
Microstructure and porosity evolution during experimental carbonation of a natural peridotite
journal, December 2012
- Hövelmann, Jörn; Austrheim, Håkon; Jamtveit, Bjørn
- Chemical Geology, Vol. 334
Reaction-assisted hierarchical fracturing during serpentinization
journal, March 2008
- Iyer, K.; Jamtveit, B.; Mathiesen, J.
- Earth and Planetary Science Letters, Vol. 267, Issue 3-4
SUPCRT92: A software package for calculating the standard molal thermodynamic properties of minerals, gases, aqueous species, and reactions from 1 to 5000 bar and 0 to 1000°C
journal, August 1992
- Johnson, James W.; Oelkers, Eric H.; Helgeson, Harold C.
- Computers & Geosciences, Vol. 18, Issue 7
Olivine dissolution and carbonation under conditions relevant for in situ carbon storage
journal, May 2014
- Johnson, Natalie C.; Thomas, Burt; Maher, Kate
- Chemical Geology, Vol. 373
Reaction-driven cracking during retrograde metamorphism: Olivine hydration and carbonation
journal, September 2012
- Kelemen, Peter B.; Hirth, Greg
- Earth and Planetary Science Letters, Vol. 345-348
In situ carbonation of peridotite for CO2 storage
journal, November 2008
- Kelemen, P. B.; Matter, J.
- Proceedings of the National Academy of Sciences, Vol. 105, Issue 45
Rates and Mechanisms of Mineral Carbonation in Peridotite: Natural Processes and Recipes for Enhanced, in situ CO 2 Capture and Storage
journal, May 2011
- Kelemen, Peter B.; Matter, Juerg; Streit, Elisabeth E.
- Annual Review of Earth and Planetary Sciences, Vol. 39, Issue 1
Effect of Secondary Phase Formation on the Carbonation of Olivine
journal, August 2010
- King, Helen E.; Plümper, Oliver; Putnis, Andrew
- Environmental Science & Technology, Vol. 44, Issue 16
Degradation of Well Cement by CO 2 under Geologic Sequestration Conditions
journal, July 2007
- Kutchko, Barbara G.; Strazisar, Brian R.; Dzombak, David A.
- Environmental Science & Technology, Vol. 41, Issue 13
Carbon dioxide disposal in carbonate minerals
journal, January 1995
- Lackner, Klaus S.; Wendt, Christopher H.; Butt, Darryl P.
- Energy, Vol. 20, Issue 11, p. 1153-1170
Assessing the economic feasibility of regional deep saline aquifer CO2 injection and storage: A geomechanics-based workflow applied to the Rose Run sandstone in Eastern Ohio, USA
journal, April 2008
- Lucier, A.; Zoback, M.
- International Journal of Greenhouse Gas Control, Vol. 2, Issue 2
Experimental determination of porosity and permeability changes induced by injection of CO2 into carbonate rocks
journal, July 2009
- Luquot, L.; Gouze, P.
- Chemical Geology, Vol. 265, Issue 1-2
Chemical and Mechanical Properties of Wellbore Cement Altered by CO 2 -Rich Brine Using a Multianalytical Approach
journal, January 2013
- Mason, Harris E.; Du Frane, Wyatt L.; Walsh, Stuart D. C.
- Environmental Science & Technology, Vol. 47, Issue 3
Rapid carbon mineralization for permanent disposal of anthropogenic carbon dioxide emissions
journal, June 2016
- Matter, J. M.; Stute, M.; Snaebjornsdottir, S. O.
- Science, Vol. 352, Issue 6291
Fracture toughness and subcritical crack growth during high-temperature tensile deformation of Westerly granite and Black gabbro
journal, June 1985
- Meredith, P. G.; Atkinson, B. K.
- Physics of the Earth and Planetary Interiors, Vol. 39, Issue 1
Solution to the volume problem in serpentinization
journal, January 1992
- O'Hanley, David S.
- Geology, Vol. 20, Issue 8
Olivine reactivity with CO2 and H2O on a microscale: Implications for carbon sequestration
journal, January 2012
- Olsson, J.; Bovet, N.; Makovicky, E.
- Geochimica et Cosmochimica Acta, Vol. 77
Carbonate mineralization in percolated olivine aggregates: Linking effects of crystallographic orientation and fluid flow
journal, February 2015
- Peuble, S.; Andreani, M.; Godard, M.
- American Mineralogist, Vol. 100, Issue 2-3
CO2 geological storage in olivine rich basaltic aquifers: New insights from reactive-percolation experiments
journal, January 2015
- Peuble, Steve; Godard, Marguerite; Luquot, Linda
- Applied Geochemistry, Vol. 52
Emplacement of the Twin Sisters dunite, Washington
journal, June 1963
- Ragan, D. M.
- American Journal of Science, Vol. 261, Issue 6
The Geomechanics of CO2 Storage in Deep Sedimentary Formations
journal, January 2012
- Rutqvist, Jonny
- Geotechnical and Geological Engineering, Vol. 30, Issue 3
Peridotite dissolution and carbonation rates at fracture surfaces under conditions relevant for in situ mineralization of CO2
journal, April 2013
- van Noort, R.; Spiers, C. J.; Drury, M. R.
- Geochimica et Cosmochimica Acta, Vol. 106
Geologic carbon storage is unlikely to trigger large earthquakes and reactivate faults through which CO 2 could leak
journal, April 2015
- Vilarrasa, Victor; Carrera, Jesus
- Proceedings of the National Academy of Sciences, Vol. 112, Issue 19
The effect of cracks on the compressibility of rock
journal, January 1965
- Walsh, J. B.
- Journal of Geophysical Research, Vol. 70, Issue 2
Effect of CO 2 -induced reactions on the mechanical behaviour of fractured wellbore cement
journal, September 2016
- Wolterbeek, Timotheus K. T.; Hangx, Suzanne J. T.; Spiers, Christopher J.
- Geomechanics for Energy and the Environment, Vol. 7
Testing the cation-hydration effect on the crystallization of Ca-Mg-CO3 systems
journal, October 2013
- Xu, J.; Yan, C.; Zhang, F.
- Proceedings of the National Academy of Sciences, Vol. 110, Issue 44
Experimental evidence of reaction-induced fracturing during olivine carbonation: Fracturing During Olivine Carbonation
journal, September 2016
- Zhu, Wenlu; Fusseis, Florian; Lisabeth, Harrison
- Geophysical Research Letters, Vol. 43, Issue 18
Production-induced Normal Faulting in the Valhall and Ekofisk Oil Fields
journal, January 2002
- Zoback, M. D.; Zinke, J. C.
- Pure and Applied Geophysics, Vol. 159, Issue 1