Joint Charge Storage for High‐Rate Aqueous Zinc–Manganese Dioxide Batteries
Abstract
Abstract Aqueous rechargeable zinc–manganese dioxide batteries show great promise for large‐scale energy storage due to their use of environmentally friendly, abundant, and rechargeable Zn metal anodes and MnO 2 cathodes. In the literature various intercalation and conversion reaction mechanisms in MnO 2 have been reported, but it is not clear how these mechanisms can be simultaneously manipulated to improve the charge storage and transport properties. A systematical study to understand the charge storage mechanisms in a layered δ‐MnO 2 cathode is reported. An electrolyte‐dependent reaction mechanism in δ‐MnO 2 is identified. Nondiffusion controlled Zn 2+ intercalation in bulky δ‐MnO 2 and control of H + conversion reaction pathways over a wide C‐rate charge–discharge range facilitate high rate performance of the δ‐MnO 2 cathode without sacrificing the energy density in optimal electrolytes. The Zn‐δ‐MnO 2 system delivers a discharge capacity of 136.9 mAh g −1 at 20 C and capacity retention of 93% over 4000 cycles with this joint charge storage mechanism. This study opens a new gateway for the design of high‐rate electrode materials by manipulating the effective redox reactions in electrode materials for rechargeable batteries.
- Authors:
-
[4]
- Energy &, Environment Directorate Pacific Northwest National Laboratory Richland WA 99354 USA, College of Engineering and Applied Sciences Nanjing University Nanjing 210093 China
- Environmental Molecular Sciences Laboratory Pacific Northwest National Laboratory Richland WA 99354 USA
- Physical Sciences Division Pacific Northwest National Laboratory Richland WA 99354 USA
- Energy &, Environment Directorate Pacific Northwest National Laboratory Richland WA 99354 USA
- College of Engineering and Applied Sciences Nanjing University Nanjing 210093 China
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1545406
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- Advanced Materials
- Additional Journal Information:
- Journal Name: Advanced Materials Journal Volume: 31 Journal Issue: 29; Journal ID: ISSN 0935-9648
- Publisher:
- Wiley Blackwell (John Wiley & Sons)
- Country of Publication:
- Germany
- Language:
- English
Citation Formats
Jin, Yan, Zou, Lianfeng, Liu, Lili, Engelhard, Mark H., Patel, Rajankumar L., Nie, Zimin, Han, Kee Sung, Shao, Yuyan, Wang, Chongmin, Zhu, Jia, Pan, Huilin, and Liu, Jun. Joint Charge Storage for High‐Rate Aqueous Zinc–Manganese Dioxide Batteries. Germany: N. p., 2019.
Web. doi:10.1002/adma.201900567.
Jin, Yan, Zou, Lianfeng, Liu, Lili, Engelhard, Mark H., Patel, Rajankumar L., Nie, Zimin, Han, Kee Sung, Shao, Yuyan, Wang, Chongmin, Zhu, Jia, Pan, Huilin, & Liu, Jun. Joint Charge Storage for High‐Rate Aqueous Zinc–Manganese Dioxide Batteries. Germany. https://doi.org/10.1002/adma.201900567
Jin, Yan, Zou, Lianfeng, Liu, Lili, Engelhard, Mark H., Patel, Rajankumar L., Nie, Zimin, Han, Kee Sung, Shao, Yuyan, Wang, Chongmin, Zhu, Jia, Pan, Huilin, and Liu, Jun. Mon .
"Joint Charge Storage for High‐Rate Aqueous Zinc–Manganese Dioxide Batteries". Germany. https://doi.org/10.1002/adma.201900567.
@article{osti_1545406,
title = {Joint Charge Storage for High‐Rate Aqueous Zinc–Manganese Dioxide Batteries},
author = {Jin, Yan and Zou, Lianfeng and Liu, Lili and Engelhard, Mark H. and Patel, Rajankumar L. and Nie, Zimin and Han, Kee Sung and Shao, Yuyan and Wang, Chongmin and Zhu, Jia and Pan, Huilin and Liu, Jun},
abstractNote = {Abstract Aqueous rechargeable zinc–manganese dioxide batteries show great promise for large‐scale energy storage due to their use of environmentally friendly, abundant, and rechargeable Zn metal anodes and MnO 2 cathodes. In the literature various intercalation and conversion reaction mechanisms in MnO 2 have been reported, but it is not clear how these mechanisms can be simultaneously manipulated to improve the charge storage and transport properties. A systematical study to understand the charge storage mechanisms in a layered δ‐MnO 2 cathode is reported. An electrolyte‐dependent reaction mechanism in δ‐MnO 2 is identified. Nondiffusion controlled Zn 2+ intercalation in bulky δ‐MnO 2 and control of H + conversion reaction pathways over a wide C‐rate charge–discharge range facilitate high rate performance of the δ‐MnO 2 cathode without sacrificing the energy density in optimal electrolytes. The Zn‐δ‐MnO 2 system delivers a discharge capacity of 136.9 mAh g −1 at 20 C and capacity retention of 93% over 4000 cycles with this joint charge storage mechanism. This study opens a new gateway for the design of high‐rate electrode materials by manipulating the effective redox reactions in electrode materials for rechargeable batteries.},
doi = {10.1002/adma.201900567},
journal = {Advanced Materials},
number = 29,
volume = 31,
place = {Germany},
year = {Mon Jun 03 00:00:00 EDT 2019},
month = {Mon Jun 03 00:00:00 EDT 2019}
}
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