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Title: Internal energy dependence of the photodissociation dynamics of O3- using cryogenic photoelectron-photofragment coincidence spectroscopy

Abstract

Photoelectron-photofragment coincidence (PPC) spectra of ozonide, O3-, were measured at 388 nm (Ehν = 3.20 eV) using a newly constructed cryogenic octopole accumulation trap coupled to a PPC spectrometer. The photoelectron spectra reveal three processes consisting of a stable photodetachment channel, and two distinct photodissociation pathways yielding (1) O2 + O- or (2) O + O2-. The first photodissociation pathway is observed in the PPC spectra by photodetachment of the O- product by a second photon, and produces electronically excited O2(1Δg). The O2- product of the second photodissociation pathway undergoes autodetachment for O2-(2Πg, v" > 4), a process greatly enhanced by vibrational excitation of the precursor O3-. Cooling anions thermalized at 300 K to <17 K in a cryogenic octopole accumulation trap essentially turns off this autodetachment pathway. The product kinetic energy distribution in coincidence with the autodetached electrons from O2-(v′′ = 4) exhibits resolved features consistent with bend (ν2), asymmetric stretch (ν3) and a stretching combination band (ν1 + ν3) in the intermediate electronic state, illustrating the insights that can be gained from kinematically complete measurements. Finally, these results are discussed in the context of the low-lying excited states of O3-.

Authors:
 [1];  [1];  [1]; ORCiD logo [1]
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  1. Univ. of California, San Diego, CA (United States). Dept. of Chemistry and Biochemistry
Publication Date:
Research Org.:
Univ. of California, San Diego, CA (United States)
Sponsoring Org.:
USDOE Office of Science (SC)
OSTI Identifier:
1535315
Alternate Identifier(s):
OSTI ID: 1378813
Grant/Contract Number:  
FG03-98ER14879
Resource Type:
Accepted Manuscript
Journal Name:
Journal of Chemical Physics
Additional Journal Information:
Journal Volume: 147; Journal Issue: 9; Journal ID: ISSN 0021-9606
Publisher:
American Institute of Physics (AIP)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; chemistry; physics

Citation Formats

Shen, Ben B., Benitez, Yanice, Lunny, Katharine G., and Continetti, Robert E. Internal energy dependence of the photodissociation dynamics of O3- using cryogenic photoelectron-photofragment coincidence spectroscopy. United States: N. p., 2017. Web. doi:10.1063/1.4986500.
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Shen, Ben B., Benitez, Yanice, Lunny, Katharine G., & Continetti, Robert E. Internal energy dependence of the photodissociation dynamics of O3- using cryogenic photoelectron-photofragment coincidence spectroscopy. United States. https://doi.org/10.1063/1.4986500
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Shen, Ben B., Benitez, Yanice, Lunny, Katharine G., and Continetti, Robert E. Wed . "Internal energy dependence of the photodissociation dynamics of O3- using cryogenic photoelectron-photofragment coincidence spectroscopy". United States. https://doi.org/10.1063/1.4986500. https://www.osti.gov/servlets/purl/1535315.
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@article{osti_1535315,
title = {Internal energy dependence of the photodissociation dynamics of O3- using cryogenic photoelectron-photofragment coincidence spectroscopy},
author = {Shen, Ben B. and Benitez, Yanice and Lunny, Katharine G. and Continetti, Robert E.},
abstractNote = {Photoelectron-photofragment coincidence (PPC) spectra of ozonide, O3-, were measured at 388 nm (Ehν = 3.20 eV) using a newly constructed cryogenic octopole accumulation trap coupled to a PPC spectrometer. The photoelectron spectra reveal three processes consisting of a stable photodetachment channel, and two distinct photodissociation pathways yielding (1) O2 + O- or (2) O + O2-. The first photodissociation pathway is observed in the PPC spectra by photodetachment of the O- product by a second photon, and produces electronically excited O2(1Δg). The O2- product of the second photodissociation pathway undergoes autodetachment for O2-(2Πg, v" > 4), a process greatly enhanced by vibrational excitation of the precursor O3-. Cooling anions thermalized at 300 K to <17 K in a cryogenic octopole accumulation trap essentially turns off this autodetachment pathway. The product kinetic energy distribution in coincidence with the autodetached electrons from O2-(v′′ = 4) exhibits resolved features consistent with bend (ν2), asymmetric stretch (ν3) and a stretching combination band (ν1 + ν3) in the intermediate electronic state, illustrating the insights that can be gained from kinematically complete measurements. Finally, these results are discussed in the context of the low-lying excited states of O3-.},
doi = {10.1063/1.4986500},
journal = {Journal of Chemical Physics},
number = 9,
volume = 147,
place = {United States},
year = {Wed Sep 06 00:00:00 EDT 2017},
month = {Wed Sep 06 00:00:00 EDT 2017}
}
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Works referenced in this record:

Ultrafast Study of the Photodissociation and Recombination of Aqueous O 3 -
journal, January 1996

  • Walhout, Peter K.; Silva, Carlos; Barbara, Paul F.
  • The Journal of Physical Chemistry, Vol. 100, Issue 13
  • DOI: 10.1021/jp953412g

Photodissociation dynamics of O3− at 523 nm
journal, January 1996

Reaction dynamics of temperature-variable anion water clusters studied with crossed beams and by direct dynamics
journal, January 2012

Photoelectron–multiple-photofragment coincidence spectrometer
journal, May 1999

  • Hanold, K. A.; Luong, A. K.; Clements, T. G.
  • Review of Scientific Instruments, Vol. 70, Issue 5
  • DOI: 10.1063/1.1149751

Three-Body Dissociation Dynamics of Excited States of O 3 (D 2 O)
journal, December 1999

  • Luong, A. K.; Clements, T. G.; Continetti, R. E.
  • The Journal of Physical Chemistry A, Vol. 103, Issue 49
  • DOI: 10.1021/jp991975c

Photoelectron imaging and photodissociation of ozonide in O 3 − ⋅ (O 2 ) n ( n = 1-4) clusters
journal, March 2015

  • Mann, Jennifer E.; Troyer, Mary E.; Jarrold, Caroline Chick
  • The Journal of Chemical Physics, Vol. 142, Issue 12
  • DOI: 10.1063/1.4916048

Excited state dynamics in clusters of oxygen
journal, January 1997

  • Li, Runjun; Hanold, Karl A.; Garner, Mark C.
  • Faraday Discussions, Vol. 108
  • DOI: 10.1039/a705823c

Photodestruction of NO2− using time resolved multicoincidence detection photofragment spectroscopy
journal, May 2004

The Only Stable State of O 2 - Is the X 2 Π g Ground State and It (Still!) Has an Adiabatic Electron Detachment Energy of 0.45 eV
journal, October 2003

  • Ervin, Kent M.; Anusiewicz, Iwona; Skurski, Piotr
  • The Journal of Physical Chemistry A, Vol. 107, Issue 41
  • DOI: 10.1021/jp0357323

The low lying electronic states of O − 3
journal, July 1993

  • Koch, Wolfram; Frenking, Gernot; Steffen, G.
  • The Journal of Chemical Physics, Vol. 99, Issue 2
  • DOI: 10.1063/1.465371

Photoelectron–photofragment coincidence studies of the dissociative photodetachment of O4−
journal, December 1998

Visible spectrum photofragmentation of O 3 − (H 2 O) n , n ≤ 16
journal, October 2014

  • Lehman, Julia H.; Lineberger, W. Carl
  • The Journal of Chemical Physics, Vol. 141, Issue 15
  • DOI: 10.1063/1.4898373

Total cross sections for dissociative electron attachment to ozone caused by the 2 A 2 Feshbach resonance
journal, December 2004

  • Nestmann, Bernd M.; Brems, Vincent; Dora, Amar
  • Journal of Physics B: Atomic, Molecular and Optical Physics, Vol. 38, Issue 1
  • DOI: 10.1088/0953-4075/38/1/007

Dissociative electron attachment to ozone using a high-resolution crossed beams technique
journal, June 1996

Vibrational Characterization of Simple Peptides Using Cryogenic Infrared Photodissociation of H 2 -Tagged, Mass-Selected Ions
journal, April 2011

  • Kamrath, Michael Z.; Garand, Etienne; Jordan, Peter A.
  • Journal of the American Chemical Society, Vol. 133, Issue 16
  • DOI: 10.1021/ja200849g

Resonances in collisions of low-energy electrons with ozone: Experimental elastic and vibrationally inelastic differential cross sections and dissociative attachment spectra
journal, October 1996

  • Allan, Michael; Asmis, Knut R.; Popovic, Duska B.
  • Journal of Physics B: Atomic, Molecular and Optical Physics, Vol. 29, Issue 20
  • DOI: 10.1088/0953-4075/29/20/024

Oxygen cluster anions revisited: Solvent-mediated dissociation of the core O 4 − anion
journal, March 2012

  • Khuseynov, Dmitry; Goebbert, Daniel J.; Sanov, Andrei
  • The Journal of Chemical Physics, Vol. 136, Issue 9
  • DOI: 10.1063/1.3691104

Dissociative electron attachment (DEA) in ozone 0 - 10 eV
journal, October 1996

  • Walker, Isobel C.; Gingell, John M.; Mason, Nigel J.
  • Journal of Physics B: Atomic, Molecular and Optical Physics, Vol. 29, Issue 20
  • DOI: 10.1088/0953-4075/29/20/025

Slow photoelectron velocity-map imaging spectroscopy of cold negative ions
journal, December 2012

  • Hock, Christian; Kim, Jongjin B.; Weichman, Marissa L.
  • The Journal of Chemical Physics, Vol. 137, Issue 24
  • DOI: 10.1063/1.4772406

Interconnection of Reactive Oxygen Species Chemistry across the Interfaces of Atmospheric, Environmental, and Biological Processes
journal, February 2015

  • Anglada, Josep M.; Martins-Costa, Marilia; Francisco, Joseph S.
  • Accounts of Chemical Research, Vol. 48, Issue 3
  • DOI: 10.1021/ar500412p

Low Energy Dissociative Electron Attachment to Ozone
journal, June 1999

Simple radio-frequency power source for ion guides and ion traps
journal, September 1997

  • Jones, Ronald M.; Gerlich, Dieter; Anderson, Scott L.
  • Review of Scientific Instruments, Vol. 68, Issue 9
  • DOI: 10.1063/1.1148297

Ab initio studies on the electronic excited states and photodissociation of O3 anion
journal, May 1998

  • Cui, Qiang; Morokuma, Keiji
  • The Journal of Chemical Physics, Vol. 108, Issue 18
  • DOI: 10.1063/1.476322

Dissociative-electron-attachment cross sections: A comparative study of NO 2 and O 3
journal, November 2003

Production of vibrationally autodetaching in low-energy electron impact on ozone
journal, August 1996

  • Allan, Michael; Asmis, Knut R.; Popovic, Duska B.
  • Journal of Physics B: Atomic, Molecular and Optical Physics, Vol. 29, Issue 15
  • DOI: 10.1088/0953-4075/29/15/020

Development of a low-temperature photoelectron spectroscopy instrument using an electrospray ion source and a cryogenically controlled ion trap
journal, July 2008

  • Wang, Xue-Bin; Wang, Lai-Sheng
  • Review of Scientific Instruments, Vol. 79, Issue 7
  • DOI: 10.1063/1.2957610

Theory of the photodissociation of ozone in the Hartley continuum; effect of vibrational excitation and O(1D) atom velocity distribution
journal, January 2005

  • Baloïtcha, Ezinvi; Balint-Kurti, Gabriel G.
  • Physical Chemistry Chemical Physics, Vol. 7, Issue 22
  • DOI: 10.1039/b511640f

Simplified radio-frequency generator for driving ion guides, traps, and other capacitive loads
journal, January 2000

  • Jones, Ronald M.; Anderson, Scott L.
  • Review of Scientific Instruments, Vol. 71, Issue 11
  • DOI: 10.1063/1.1318914

Resonances in Electron Impact on Diatomic Molecules
journal, July 1973

Photodissociation spectroscopy of 03−
journal, January 1978

  • Cosby, P. C.; Moseley, J. T.; Peterson, J. R.
  • The Journal of Chemical Physics, Vol. 69, Issue 6
  • DOI: 10.1063/1.436874

Laser photoelectron, photodetachment, and photodestruction spectra of O − 3
journal, March 1979

  • Novick, Stewart E.; Engelking, Paul C.; Jones, Patrick L.
  • The Journal of Chemical Physics, Vol. 70, Issue 6
  • DOI: 10.1063/1.437842

Negative Ion Formation in Ozone
journal, November 1961

  • Curran, R. K.
  • The Journal of Chemical Physics, Vol. 35, Issue 5
  • DOI: 10.1063/1.1732155

Time‐of‐Flight Mass Spectrometer with Improved Resolution
journal, December 1955

  • Wiley, W. C.; McLaren, I. H.
  • Review of Scientific Instruments, Vol. 26, Issue 12
  • DOI: 10.1063/1.1715212

Contribution of Feshbach resonance to the 1.3 − eV dissociative-electron-attachment cross section of ozone
journal, January 2005

Photodissociation of vibrationally excited ozone
journal, June 1980

  • Zittel, P. F.; Little, D. D.
  • The Journal of Chemical Physics, Vol. 72, Issue 11
  • DOI: 10.1063/1.439085

Laser photodissociation of O 3 − by triple quadrupole mass spectrometry
journal, June 1981

  • Hiller, J. F.; Vestal, M. L.
  • The Journal of Chemical Physics, Vol. 74, Issue 11
  • DOI: 10.1063/1.441053

Stability and Dissociation Dynamics of the Low-Lying Excited States of Ozone
journal, September 1997

  • Garner, M. C.; Hanold, K. A.; Resat, M. Sowa
  • The Journal of Physical Chemistry A, Vol. 101, Issue 36
  • DOI: 10.1021/jp9703519

Study of low‐lying electronic states of ozone by anion photoelectron spectroscopy of O − 3
journal, July 1994

  • Arnold, Don W.; Xu, Cangshan; Kim, Eun H.
  • The Journal of Chemical Physics, Vol. 101, Issue 2
  • DOI: 10.1063/1.467745

Cross sections for the dissociative electron attachment to ozone
journal, August 1999

  • Rangwala, S. A.; Kumar, S. V. K.; Krishnakumar, E.
  • Journal of Physics B: Atomic, Molecular and Optical Physics, Vol. 32, Issue 15
  • DOI: 10.1088/0953-4075/32/15/311

Photodissociation spectroscopy of O−3 and O−3⋅H2O. 4170–4700 Å
journal, January 1979

  • Smith, G. P.; Lee, L. C.
  • The Journal of Chemical Physics, Vol. 71, Issue 5
  • DOI: 10.1063/1.438571

Photoelectron-photofragment coincidence spectroscopy in a cryogenically cooled linear electrostatic ion beam trap
journal, October 2011

  • Johnson, Christopher J.; Shen, Ben B.; Poad, Berwyck L. J.
  • Review of Scientific Instruments, Vol. 82, Issue 10
  • DOI: 10.1063/1.3641875

Photodetachment Imaging Study of the Vinoxide Anion †
journal, September 2004

  • Bowen, M. Shane; Continetti, Robert E.
  • The Journal of Physical Chemistry A, Vol. 108, Issue 39
  • DOI: 10.1021/jp040083w

Ozone photolysis: Strong isotopologue/isotopomer selectivity in the stratosphere: ISOTOPIC SELECTIVITY OF OZONE PHOTOLYSIS
journal, April 2014

  • Ndengué, Steve; Madronich, Sasha; Gatti, Fabien
  • Journal of Geophysical Research: Atmospheres, Vol. 119, Issue 7
  • DOI: 10.1002/2013jd020033
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