Dipole-bound excited states and resonant photoelectron imaging of phenoxide and thiophenoxide anions

Zhu, Guo-Zhu; Qian, Chen-Hui; Wang, Lai-Sheng

doi:10.1063/1.5049715

Title: Dipole-bound excited states and resonant photoelectron imaging of phenoxide and thiophenoxide anions

Journal Article · 22 October 2018 · Journal of Chemical Physics

DOI: https://doi.org/10.1063/1.5049715 · OSTI ID:1594592

^[1]; Qian, Chen-Hui ^[2];

^[2]

Brown Univ., Providence, RI (United States). Dept. of Chemistry; Brown University
Brown Univ., Providence, RI (United States). Dept. of Chemistry

We report photodetachment and resonant photoelectron-imaging studies of cryogenically cooled phenoxide (C₆H₅O^–) and thiophenoxide (C₆H₅S^–) anions. In a previous study, a dipole-bound excited state was observed for C₆H₅O^– at 97 cm^–1 below the detachment threshold. Eight resonant photoelectron spectra were obtained via excitations to eight vibrational levels of the dipole-bound state (DBS) followed by autodetachment. In this paper, we present a complete photodetachment spectrum of C₆H₅O^– covering a spectral range 2600 cm^–1 above the detachment threshold and revealing nine additional vibrational resonances of the DBS. We also report the first observation of a dipole-bound excited state for C₆H₅S^–, 39 cm^–1 below its detachment threshold of 18 982 cm^–1. Photodetachment spectroscopy covering a spectral range 1500 cm^–1 above the threshold reveals twelve vibrational resonances for the DBS of C₆H₅S^–. By tuning the detachment laser to the vibrational resonances in the DBS of C₆H₅O^– and C₆H₅S^–, we obtain highly non-Franck-Condon resonant photoelectron spectra, as a result of mode-selectivity and the Δv = –1 propensity rule for vibrational autodetachment. Five new fundamental vibrational frequencies are obtained for the ground state of the C₆H₅O (X²B₁) radical. Intramolecular inelastic scattering is observed in some of the resonant photoelectron spectra, leading to the excitation of the Franck-Condon-inactive lowest-frequency bending mode (ν₂₀) of C₆H₅O. The first excited state of C₆H₅O (A²B₂) is observed to be 0.953 eV above the ground state. Twelve resonant photoelectron spectra are obtained for C₆H₅S^–, allowing the measurements of seven fundamental vibrational frequencies of the C₆H₅S radical, whereas the non-resonant photoelectron spectrum exhibits only a single Franck-Condon active mode. The current study again demonstrates that the combination of photodetachment spectroscopy and resonant photoelectron spectroscopy is a powerful technique to obtain vibrational information about polar radical species.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Brown Univ., Providence, RI (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Chemical Sciences, Geosciences & Biosciences Division

Grant/Contract Number:: SC0018679

OSTI ID:: 1594592

Journal Information:: Journal of Chemical Physics, Journal Name: Journal of Chemical Physics Journal Issue: 16 Vol. 149; ISSN 0021-9606

Publisher:: American Institute of Physics (AIP)Copyright Statement

Country of Publication:: United States

Language:: English

References (87)

Intramolecular Orbital Alignment Observed in the Photodissociation of [D1]Thiophenol Lim, Jeong Sik; Lim, Ivan S.; Lee, Kyoung-Seok Angewandte Chemie, Vol. 118, Issue 38 https://doi.org/10.1002/ange.200601985	journal	September 2006
Observation of Mode-Specific Vibrational Autodetachment from Dipole-Bound States of Cold Anions Liu, Hong-Tao; Ning, Chuan-Gang; Huang, Dao-Ling Angewandte Chemie, Vol. 125, Issue 34 https://doi.org/10.1002/ange.201304695	journal	July 2013
Vibrational Spectroscopy of the Dehydrogenated Uracil Radical by Autodetachment of Dipole-Bound Excited States of Cold Anions Liu, Hong-Tao; Ning, Chuan-Gang; Huang, Dao-Ling Angewandte Chemie, Vol. 126, Issue 9 https://doi.org/10.1002/ange.201310323	journal	January 2014
Intramolecular Orbital Alignment Observed in the Photodissociation of [D1]Thiophenol Lim, Jeong Sik; Lim, Ivan S.; Lee, Kyoung-Seok Angewandte Chemie International Edition, Vol. 45, Issue 38 https://doi.org/10.1002/anie.200601985	journal	September 2006
Observation of Mode-Specific Vibrational Autodetachment from Dipole-Bound States of Cold Anions Liu, Hong-Tao; Ning, Chuan-Gang; Huang, Dao-Ling Angewandte Chemie International Edition, Vol. 52, Issue 34 https://doi.org/10.1002/anie.201304695	journal	July 2013
Vibrational Spectroscopy of the Dehydrogenated Uracil Radical by Autodetachment of Dipole-Bound Excited States of Cold Anions Liu, Hong-Tao; Ning, Chuan-Gang; Huang, Dao-Ling Angewandte Chemie International Edition, Vol. 53, Issue 9 https://doi.org/10.1002/anie.201310323	journal	January 2014
Electron energy loss spectroscopy: the vibration spectroscopy of surfaces Ibach, H. Surface Science, Vol. 299-300 https://doi.org/10.1016/0039-6028(94)90650-5	journal	January 1994
Ultraviolet photoelectron spectroscopy of the phenide, benzyl and phenoxide anions, with ab initio calculations Gunion, Robert F.; Gilles, Mary K.; Polak, Mark L. International Journal of Mass Spectrometry and Ion Processes, Vol. 117 https://doi.org/10.1016/0168-1176(92)80115-h	journal	September 1992
Spectroscopy and kinetics of thiophenoxy radicals in the gas phase Shibuya, Kazuhiko; Nemoto, Masahiro; Yanagibori, Akihiko Chemical Physics, Vol. 121, Issue 2 https://doi.org/10.1016/0301-0104(88)90030-4	journal	April 1988
Multipole-bound molecular anions Compton, Robert N.; Hammer, Nathan I. Advances in Gas Phase Ion Chemistry https://doi.org/10.1016/S1071-9687(01)80010-1	book	January 2001
Resonant photoelectron imaging of deprotonated uracil anion via vibrational levels of a dipole-bound excited state Huang, Dao-Ling; Liu, Hong-Tao; Ning, Chuan-Gang Chemical Physics, Vol. 482 https://doi.org/10.1016/j.chemphys.2016.06.003	journal	January 2017
Rotational auto-detachment of dipole-bound anions Ard, S. G.; Compton, R. N.; Garrett, W. R. Chemical Physics Letters, Vol. 650 https://doi.org/10.1016/j.cplett.2016.03.011	journal	April 2016
Photodetachment spectroscopy and resonant photoelectron imaging of cryogenically-cooled deprotonated 2-hydroxypyrimidine anions Huang, Dao-Ling; Zhu, Guo-Zhu; Liu, Yuan Journal of Molecular Spectroscopy, Vol. 332 https://doi.org/10.1016/j.jms.2016.10.021	journal	February 2017
Destruction of benene in high-temperature flames: Chemistry of benene and phenol Shandross, Richard A.; Longwell, John P.; Howard, Jack B. Symposium (International) on Combustion, Vol. 26, Issue 1 https://doi.org/10.1016/s0082-0784(96)80279-7	journal	January 1996
Three-Dimensional Diabatic Potential Energy Surfaces for the Photodissociation of Thiophenol Lin, Guang-Shuang-Mu; Xie, Changjian; Xie, Daiqian The Journal of Physical Chemistry A, Vol. 121, Issue 44 https://doi.org/10.1021/acs.jpca.7b09070	journal	October 2017
Conformation-Selective Resonant Photoelectron Spectroscopy via Dipole-Bound States of Cold Anions Huang, Dao-Ling; Liu, Hong-Tao; Ning, Chuan-Gang The Journal of Physical Chemistry Letters, Vol. 6, Issue 12 https://doi.org/10.1021/acs.jpclett.5b00963	journal	May 2015
Protein Radicals in Enzyme Catalysis Stubbe, JoAnne; van der Donk, Wilfred A. Chemical Reviews, Vol. 98, Issue 2 https://doi.org/10.1021/cr9400875	journal	April 1998
Ultraviolet Resonance Raman Spectroscopy and General Valence Force Field Analysis of Phenolate and Phenoxyl Radical Mukherjee, Arka; McGlashen, Michael L.; Spiro, Thomas G. The Journal of Physical Chemistry, Vol. 99, Issue 14 https://doi.org/10.1021/j100014a007	journal	April 1995
Resonance Raman spectra and structure of phenylthiyl radical Tripathi, G. N. R.; Sun, Qun; Armstrong, David A. The Journal of Physical Chemistry, Vol. 96, Issue 13 https://doi.org/10.1021/j100192a031	journal	June 1992
Similarities and Differences between Phenoxyl and Tyrosine Phenoxyl Radical Structures, Vibrational Frequencies, and Spin Densities Qin, Yue; Wheeler, Ralph A. Journal of the American Chemical Society, Vol. 117, Issue 22 https://doi.org/10.1021/ja00127a022	journal	June 1995
Propensity rules for vibration-induced electron detachment of anions Simons, Jack Journal of the American Chemical Society, Vol. 103, Issue 14 https://doi.org/10.1021/ja00404a002	journal	July 1981
Photodetachment of electrons from phenoxides and thiophenoxide Richardson, Jeffery H.; Stephenson, L. M.; Brauman, John I. Journal of the American Chemical Society, Vol. 97, Issue 11 https://doi.org/10.1021/ja00844a008	journal	May 1975
Vibrations of the Phenoxyl Radical Spanget-Larsen, Jens; Gil, Michał; Gorski, Alexandr Journal of the American Chemical Society, Vol. 123, Issue 45 https://doi.org/10.1021/ja0113596	journal	November 2001
Photodissociation Dynamics of Phenol: Multistate Trajectory Simulations including Tunneling Xu, Xuefei; Zheng, Jingjing; Yang, Ke R. Journal of the American Chemical Society, Vol. 136, Issue 46 https://doi.org/10.1021/ja509016a	journal	November 2014
Nonadiabatic Tunneling in Photodissociation of Phenol Xie, Changjian; Ma, Jianyi; Zhu, Xiaolei Journal of the American Chemical Society, Vol. 138, Issue 25 https://doi.org/10.1021/jacs.6b03288	journal	June 2016
Structures, Electron Affinities, and Harmonic Vibrational Frequencies of C ₆ H ₅ X/C ₆ H ₅ X ^- (X = N, S, NH, PH, CH ₂ , and SiH ₂ ) Xu, Wenguo; Gao, Aifang The Journal of Physical Chemistry A, Vol. 110, Issue 3 https://doi.org/10.1021/jp052198l	journal	January 2006
Photodissociation Dynamics of Phenol ^† Tseng, Chien-Ming; Lee, Yuan T.; Lin, Ming-Fu The Journal of Physical Chemistry A, Vol. 111, Issue 38 https://doi.org/10.1021/jp073282z	journal	September 2007
Theoretical Investigation of Molecular Properties of the First Excited State of the Phenoxyl Radical Cheng, Chi-Wen; Lee, Yuan-Pern; Witek, Henryk A. The Journal of Physical Chemistry A, Vol. 112, Issue 12 https://doi.org/10.1021/jp711267w	journal	March 2008
Molecular Anions Simons, Jack The Journal of Physical Chemistry A, Vol. 112, Issue 29 https://doi.org/10.1021/jp711490b	journal	July 2008
Near-Ultraviolet Photodissociation of Thiophenol ^† Devine, Adam L.; Nix, Michael G. D.; Dixon, Richard N. The Journal of Physical Chemistry A, Vol. 112, Issue 39 https://doi.org/10.1021/jp802019v	journal	October 2008
Direct versus Indirect H Atom Elimination from Photoexcited Phenol Molecules Iqbal, Azhar; Pegg, Lara-Jane; Stavros, Vasilios G. The Journal of Physical Chemistry A, Vol. 112, Issue 39 https://doi.org/10.1021/jp802155b	journal	October 2008
Theoretical Investigation of Molecular Properties of the First Excited State of the Thiophenoxyl Radical Cheng, Chi-Wen; Lee, Yuan-Pern; Witek, Henryk A. The Journal of Physical Chemistry A, Vol. 112, Issue 47 https://doi.org/10.1021/jp805045s	journal	November 2008
Atmospheric Chemistry of the Phenoxy Radical, C ₆ H ₅ O(•): UV Spectrum and Kinetics of Its Reaction with NO, NO ₂ , and O ₂ Platz, J.; Nielsen, O. J.; Wallington, T. J. The Journal of Physical Chemistry A, Vol. 102, Issue 41 https://doi.org/10.1021/jp982221l	journal	October 1998
Direct Observation of Hydrogen Tunneling Dynamics in Photoexcited Phenol Roberts, Gareth M.; Chatterley, Adam S.; Young, Jamie D. The Journal of Physical Chemistry Letters, Vol. 3, Issue 3 https://doi.org/10.1021/jz2016318	journal	January 2012
Formation and consumption of single-ring aromatic hydrocarbons and their precursors in premixed acetylene, ethylene and benzene flamesElectronic supplementary information (ESI) available: Thermodynamic and kinetic property data. See http://www.rsc.org/suppdata/cp/b1/b110089k/ Richter, Henning; Howard, Jack B. Physical Chemistry Chemical Physics, Vol. 4, Issue 11 https://doi.org/10.1039/b110089k	journal	April 2002
Excited-state hydrogen detachment and hydrogen transfer driven by repulsive 1πσ* states: A new paradigm for nonradiative decay in aromatic biomolecules Sobolewski, A. L.; Domcke, W.; Dedonder-Lardeux, C. Physical Chemistry Chemical Physics, Vol. 4, Issue 7 https://doi.org/10.1039/b110941n	journal	February 2002
Coupling between dipole-bound and valence states: the nitromethane anion Sommerfeld, Thomas Physical Chemistry Chemical Physics, Vol. 4, Issue 12 https://doi.org/10.1039/b202143a	journal	May 2002
Slow photoelectron velocity-map imaging spectroscopy of the phenoxide and thiophenoxide anions Kim, Jongjin B.; Yacovitch, Tara I.; Hock, Christian Physical Chemistry Chemical Physics, Vol. 13, Issue 38 https://doi.org/10.1039/c1cp22211b	journal	January 2011
Comparing molecular photofragmentation dynamics in the gas and liquid phases Harris, Stephanie J.; Murdock, Daniel; Zhang, Yuyuan Physical Chemistry Chemical Physics, Vol. 15, Issue 18 https://doi.org/10.1039/c3cp50756d	journal	January 2013
Full-dimensional potentials and state couplings and multidimensional tunneling calculations for the photodissociation of phenol Yang, Ke R.; Xu, Xuefei; Zheng, Jingjing Chem. Sci., Vol. 5, Issue 12 https://doi.org/10.1039/c4sc01967a	journal	January 2014
Application of phenolic radicals for antioxidants, as active materials in batteries, magnetic materials and ligands for metal-complexes Jähnert, Thomas; Hager, Martin D.; Schubert, Ulrich S. Journal of Materials Chemistry A, Vol. 2, Issue 37 https://doi.org/10.1039/c4ta03023k	journal	January 2014
Are the three hydroxyphenyl radical isomers created equal? – The role of the phenoxy radical – Hemberger, P.; da Silva, G.; Trevitt, A. J. Physical Chemistry Chemical Physics, Vol. 17, Issue 44 https://doi.org/10.1039/c5cp05346c	journal	January 2015
Probing the vibrational spectroscopy of the deprotonated thymine radical by photodetachment and state-selective autodetachment photoelectron spectroscopy via dipole-bound states Huang, Dao-Ling; Liu, Hong-Tao; Ning, Chuan-Gang Chemical Science, Vol. 6, Issue 5 https://doi.org/10.1039/c5sc00704f	journal	January 2015
The diffuse interstellar bands: a dipole-bound state hypothesis Sarre, P. J. Monthly Notices of the Royal Astronomical Society, Vol. 313, Issue 1 https://doi.org/10.1046/j.1365-8711.2000.03388.x	journal	March 2000
Electronic states of the phenoxyl radical Radziszewski, J. George; Gil, Michal/; Gorski, Alexandr The Journal of Chemical Physics, Vol. 115, Issue 21 https://doi.org/10.1063/1.1415465	journal	December 2001
Reconstruction of Abel-transformable images: The Gaussian basis-set expansion Abel transform method Dribinski, Vladimir; Ossadtchi, Alexei; Mandelshtam, Vladimir A. Review of Scientific Instruments, Vol. 73, Issue 7 https://doi.org/10.1063/1.1482156	journal	July 2002
Ionization of Molecules at Low Energies Berry, R. Stephen The Journal of Chemical Physics, Vol. 45, Issue 4 https://doi.org/10.1063/1.1727742	journal	August 1966
H atom elimination from the πσ∗ state in the photodissociation of phenol Tseng, Chien-Ming; Lee, Yuan T.; Ni, Chi-Kung The Journal of Chemical Physics, Vol. 121, Issue 6 https://doi.org/10.1063/1.1781153	journal	January 2004
Two-dimensional charged particle image inversion using a polar basis function expansion Garcia, Gustavo A.; Nahon, Laurent; Powis, Ivan Review of Scientific Instruments, Vol. 75, Issue 11 https://doi.org/10.1063/1.1807578	journal	November 2004
High resolution photofragment translational spectroscopy studies of the near ultraviolet photolysis of phenol Nix, Michael G. D.; Devine, Adam L.; Cronin, Bríd The Journal of Chemical Physics, Vol. 125, Issue 13 https://doi.org/10.1063/1.2353818	journal	October 2006
Experimental and theoretical study of the photodissociation reaction of thiophenol at 243nm: Intramolecular orbital alignment of the phenylthiyl radical Lim, Ivan S.; Lim, Jeong Sik; Lee, Yoon Sup The Journal of Chemical Physics, Vol. 126, Issue 3 https://doi.org/10.1063/1.2424939	journal	January 2007
Development of a low-temperature photoelectron spectroscopy instrument using an electrospray ion source and a cryogenically controlled ion trap Wang, Xue-Bin; Wang, Lai-Sheng Review of Scientific Instruments, Vol. 79, Issue 7 https://doi.org/10.1063/1.2957610	journal	July 2008
Rovibronic bands of the Ã B22←X̃ B21 transition of C6H5O and C6D5O detected with cavity ringdown absorption near 1.2 μm Cheng, Chi-Wen; Witek, Henryk; Lee, Yuan-Pern The Journal of Chemical Physics, Vol. 129, Issue 15 https://doi.org/10.1063/1.2992077	journal	October 2008
Tunnelling under a conical intersection: Application to the product vibrational state distributions in the UV photodissociation of phenols Dixon, Richard N.; Oliver, Thomas A. A.; Ashfold, Michael N. R. The Journal of Chemical Physics, Vol. 134, Issue 19 https://doi.org/10.1063/1.3585609	journal	May 2011
Resonances in electron photodetachment cross sections Zimmerman, Albert H.; Brauman, John I. The Journal of Chemical Physics, Vol. 66, Issue 12 https://doi.org/10.1063/1.433860	journal	June 1977
The resonance Raman spectrum of phenoxyl radical Tripathi, G. N. R.; Schuler, Robert H. The Journal of Chemical Physics, Vol. 81, Issue 1 https://doi.org/10.1063/1.447373	journal	July 1984
Spectroscopy and dynamics of the dipole‐bound state of acetaldehyde enolate Mead, Roy D.; Lykke, Keith R.; Lineberger, W. C. The Journal of Chemical Physics, Vol. 81, Issue 11 https://doi.org/10.1063/1.447515	journal	December 1984
Structure and fundamental vibrations of phenoxyl radical Chipman, Daniel M.; Liu, Ruifeng; Zhou, Xuefeng The Journal of Chemical Physics, Vol. 100, Issue 7 https://doi.org/10.1063/1.467220	journal	April 1994
Density‐functional methods give accurate vibrational frequencies and spin densities for phenoxyl radical Qin, Yue; Wheeler, Ralph A. The Journal of Chemical Physics, Vol. 102, Issue 4 https://doi.org/10.1063/1.468901	journal	January 1995
Theoretical analysis of photoinduced H-atom elimination in thiophenol Venkatesan, T. S.; Ramesh, S. G.; Lan, Z. The Journal of Chemical Physics, Vol. 136, Issue 17 https://doi.org/10.1063/1.4709608	journal	May 2012
Autodetachment spectroscopy and dynamics of dipole bound states of negative ions: ² A ₁ – ² B ₁ transitions of H ₂ CCC ⁻ Yokoyama, K.; Leach, Gary W.; Kim, Joseph B. The Journal of Chemical Physics, Vol. 105, Issue 24 https://doi.org/10.1063/1.472878	journal	December 1996
On the binding of electrons to nitromethane: Dipole and valence bound anions Compton, R. N.; Carman, H. S.; Desfrançois, C. The Journal of Chemical Physics, Vol. 105, Issue 9 https://doi.org/10.1063/1.472993	journal	September 1996
The dipole bound-to-covalent anion transformation in uracil Hendricks, J. H.; Lyapustina, S. A.; de Clercq, H. L. The Journal of Chemical Physics, Vol. 108, Issue 1 https://doi.org/10.1063/1.475360	journal	January 1998
Slow photoelectron velocity-map imaging spectroscopy of the C ₉ H ₇ (indenyl) and C ₁₃ H ₉ (fluorenyl) anions Kim, Jongjin B.; Weichman, Marissa L.; Yacovitch, Tara I. The Journal of Chemical Physics, Vol. 139, Issue 10 https://doi.org/10.1063/1.4820138	journal	September 2013
High-resolution photoelectron imaging of cold C60− anions and accurate determination of the electron affinity of C ₆₀ Huang, Dao-Ling; Dau, Phuong Diem; Liu, Hong-Tao The Journal of Chemical Physics, Vol. 140, Issue 22 https://doi.org/10.1063/1.4881421	journal	June 2014
The design and construction of a high-resolution velocity-map imaging apparatus for photoelectron spectroscopy studies of size-selected clusters León, Iker; Yang, Zheng; Liu, Hong-Tao Review of Scientific Instruments, Vol. 85, Issue 8 https://doi.org/10.1063/1.4891701	journal	August 2014
Communication: Observation of dipole-bound state and high-resolution photoelectron imaging of cold acetate anions Huang, Dao-Ling; Zhu, Guo-Zhu; Wang, Lai-Sheng The Journal of Chemical Physics, Vol. 142, Issue 9 https://doi.org/10.1063/1.4913924	journal	March 2015
Vibrational state-selective autodetachment photoelectron spectroscopy from dipole-bound states of cold 2-hydroxyphenoxide: o − HO(C ₆ H ₄ )O ⁻ Huang, Dao-Ling; Liu, Hong-Tao; Ning, Chuan-Gang The Journal of Chemical Physics, Vol. 142, Issue 12 https://doi.org/10.1063/1.4916122	journal	March 2015
Perspective: Electrospray photoelectron spectroscopy: From multiply-charged anions to ultracold anions Wang, Lai-Sheng The Journal of Chemical Physics, Vol. 143, Issue 4 https://doi.org/10.1063/1.4927086	journal	July 2015
Conformation-selective resonant photoelectron imaging from dipole-bound states of cold 3-hydroxyphenoxide Zhu, Guo-Zhu; Huang, Dao-Ling; Wang, Lai-Sheng The Journal of Chemical Physics, Vol. 147, Issue 1 https://doi.org/10.1063/1.4979331	journal	July 2017
Photodetachment Spectrum of l‐C ₃ \documentclass{aastex} \usepackage{amsbsy} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{bm} \usepackage{mathrsfs} \usepackage{pifont} \usepackage{stmaryrd} \usepackage{textcomp} \usepackage{portland,xspace} \usepackage{amsmath,amsxtra} \usepackage[OT2,OT1]{fontenc} \newcommand\cyr{ \renewcommand\rmdefault{wncyr} \renewcommand\sfdefault{wncyss} \renewcommand\encodingdefault{OT2} \normalfont \selectfont} \DeclareTextFontCommand{\textcyr}{\cyr} \pagestyle{empty} \DeclareMathSizes{10}{9}{7}{6} \begin{document} \landscape $\mathrm{H}\,^{-}_{2}$ \end{document} : The Role of Dipole Bound States for Electron Attachment in Interstellar Clouds Guthe, Felix; Tulej, Marek; Pachkov, Mikhail V. The Astrophysical Journal, Vol. 555, Issue 1 https://doi.org/10.1086/321465	journal	July 2001
Laboratory Optical Spectroscopy of the Thiophenoxy Radical and its Profile Simulation as a Diffuse Interstellar band Based on Rotational Distribution by Radiation and Collisions Araki, Mitsunori; Niwayama, Kei; Tsukiyama, Koichi The Astronomical Journal, Vol. 148, Issue 5 https://doi.org/10.1088/0004-6256/148/5/87	journal	October 2014
Laboratory Optical Spectroscopy of the Phenoxy Radical as a Candidate for Diffuse Interstellar Bands Araki, Mitsunori; Matsushita, Yuki; Tsukiyama, Koichi The Astronomical Journal, Vol. 150, Issue 4 https://doi.org/10.1088/0004-6256/150/4/113	journal	September 2015
THE POSSIBLE INTERSTELLAR ANION CH ₂ CN ^– : SPECTROSCOPIC CONSTANTS, VIBRATIONAL FREQUENCIES, AND OTHER CONSIDERATIONS Fortenberry, Ryan C.; Crawford, T. Daniel; Lee, Timothy J. The Astrophysical Journal, Vol. 762, Issue 2 https://doi.org/10.1088/0004-637x/762/2/121	journal	December 2012
Electron energy-loss spectroscopy in the TEM Egerton, R. F. Reports on Progress in Physics, Vol. 72, Issue 1 https://doi.org/10.1088/0034-4885/72/1/016502	journal	December 2008
Effects of Configuration Interaction on Intensities and Phase Shifts Fano, U. Physical Review, Vol. 124, Issue 6 https://doi.org/10.1103/physrev.124.1866	journal	December 1961
On the Behavior of Cross Sections Near Thresholds Wigner, Eugene P. Physical Review, Vol. 73, Issue 9 https://doi.org/10.1103/physrev.73.1002	journal	May 1948
Rotationally Resolved Photoelectron Angular Distributions from a Nonlinear Polyatomic Molecule Hockett, Paul; Staniforth, Michael; Reid, Katharine L. Physical Review Letters, Vol. 102, Issue 25 https://doi.org/10.1103/physrevlett.102.253002	journal	June 2009
Autodetachment Dynamics of Acrylonitrile Anion Revealed by Two-Dimensional Electron Impact Spectra Regeta, K.; Allan, M. Physical Review Letters, Vol. 110, Issue 20 https://doi.org/10.1103/physrevlett.110.203201	journal	May 2013
Observation of Excited Quadrupole-Bound States in Cold Anions Zhu, Guo-Zhu; Liu, Yuan; Wang, Lai-Sheng Physical Review Letters, Vol. 119, Issue 2 https://doi.org/10.1103/physrevlett.119.023002	journal	July 2017
Observation of Dipole-Bound States of Negative Ions Lykke, Keith R.; Mead, Roy D.; Lineberger, W. C. Physical Review Letters, Vol. 52, Issue 25 https://doi.org/10.1103/physrevlett.52.2221	journal	June 1984
Laboratory-Frame Photoelectron Angular Distributions in Anion Photodetachment: Insight into Electronic Structure and Intermolecular Interactions Sanov, Andrei Annual Review of Physical Chemistry, Vol. 65, Issue 1 https://doi.org/10.1146/annurev-physchem-040513-103656	journal	April 2014
P HOTOELECTRON A NGULAR D ISTRIBUTIONS Reid, Katharine L. Annual Review of Physical Chemistry, Vol. 54, Issue 1 https://doi.org/10.1146/annurev.physchem.54.011002.103814	journal	October 2003
T HEORY OF D IPOLE -B OUND A NIONS Jordan, Kenneth D.; Wang, Feng Annual Review of Physical Chemistry, Vol. 54, Issue 1 https://doi.org/10.1146/annurev.physchem.54.011002.103851	journal	October 2003
A Theoretical Study on the Electronic and Vibrational Structure of the Phenoxyl Radical Takahashi, Junko; Momose, Takamasa; Shida, Tadamasa Bulletin of the Chemical Society of Japan, Vol. 67, Issue 4 https://doi.org/10.1246/bcsj.67.964	journal	April 1994
The Possible Interstellar Anion CH2CN-: Spectroscopic Constants, Vibrational Frequencies, and Other Considerations Fortenberry, Ryan C.; Crawford, T. Daniel; Lee, Timothy J. arXiv https://doi.org/10.48550/arxiv.1305.1660	text	January 2013
Laboratory Optical Spectroscopy of Thiophenoxy Radical and Its Profile Simulation as a Diffuse Interstellar Band Based on Rotational Distribution by Radiation and Collisions Araki, Mitsunori; Niwayama, Kei; Tsukiyama, Koichi arXiv https://doi.org/10.48550/arxiv.1409.0182	text	January 2014

Cited By (5)

High-resolution photoelectron imaging and resonant photoelectron spectroscopy via noncovalently bound excited states of cryogenically cooled anions Zhu, Guo-Zhu; Wang, Lai-Sheng Chemical Science, Vol. 10, Issue 41 https://doi.org/10.1039/c9sc03861b	journal	January 2019
Tautomer‐Specific Resonant Photoelectron Imaging of Deprotonated Cytosine Anions Zhu, Guo‐Zhu; Qian, Chen‐Hui; Wang, Lai‐Sheng Angewandte Chemie, Vol. 131, Issue 23 https://doi.org/10.1002/ange.201903444	journal	April 2019
Tautomer-Specific Resonant Photoelectron Imaging of Deprotonated Cytosine Anions Zhu, Guo-Zhu; Qian, Chen-Hui; Wang, Lai-Sheng Angewandte Chemie International Edition, Vol. 58, Issue 23 https://doi.org/10.1002/anie.201903444	journal	April 2019
On the stability of a dipole-bound state in the presence of a molecule Castellani, Maria Elena; Anstöter, Cate S.; Verlet, Jan R. R. Physical Chemistry Chemical Physics, Vol. 21, Issue 44 https://doi.org/10.1039/c9cp04942h	journal	January 2019
High-resolution photoelectron imaging and resonant photoelectron spectroscopy via noncovalently bound excited states of cryogenically cooled anions Zhu, Guo-Zhu; Wang, Lai-Sheng Chemical Science, Vol. 10, Issue 41 https://doi.org/10.1039/c9sc03861b	journal	January 2019

Similar Records

Vibrational state-selective autodetachment photoelectron spectroscopy from dipole-bound states of cold 2-hydroxyphenoxide: o − HO(C{sub 6}H{sub 4})O{sup −}

Journal Article · 2015 · Journal of Chemical Physics · OSTI ID:22410268

Huang, Dao-Ling; Wang, Lai-Sheng; Liu, Hong-Tao; +1 more

Photodetachment spectroscopy and resonant photoelectron imaging of the 2-naphthoxide anion via dipole-bound excited states

Journal Article · 2020 · Journal of Chemical Physics · OSTI ID:1775300

Qian, Chen-Hui; Zhu, Guo-Zhu; Zhang, Yue-Rou; +1 more

Photodetachment spectroscopy and resonant photoelectron imaging of cryogenically cooled 1-pyrenolate

Journal Article · 2021 · Journal of Chemical Physics · OSTI ID:1775306

Qian, Chen-Hui; Zhang, Yue-Rou; Yuan, Dao-Fu; +1 more

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Title: Dipole-bound excited states and resonant photoelectron imaging of phenoxide and thiophenoxide anions

Citation Formats

References (87)

Cited By (5)

Similar Records

Related Subjects