Pore-Templated Growth of Catalytically Active Gold Nanoparticles within a Metal–Organic Framework

doi:10.1021/acs.chemmater.8b04983

Title: Pore-Templated Growth of Catalytically Active Gold Nanoparticles within a Metal–Organic Framework

Abstract

Obtaining persistently well-dispersed gold nano-particles (AuNPs) on solid support with optimum particle size for heterogeneous catalysis can be challenging. Here, we report on the channel-templated growth of AuNPs within a stable zirconium-based metal–organic framework, NU-1000, via channel-anchored monometallic precursors. Pair distribution function analysis of total X-ray scattering by the incorporated face-centered-cubic nanopar-ticles reveals a bimodal size distribution, with ca. 98% of the en-shrouded nanoparticles having a diameter that closely reflects the ~10 Å width of triangular pores and with ca. 2% closely reflecting the ~31 Å width of hexagonal pores of NU-1000. The resulting ma-terial is catalytically active (and recyclable) for condensed-phase hydrogenation of 4-nitrophenol to 4-aminophenol.

Authors:

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^[2];

^[3];

^[4]; Cui, Yuexing ^[1];

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Northwestern Univ., Evanston, IL (United States)
Northwestern Univ., Evanston, IL (United States); Argonne National Lab. (ANL), Lemont, IL (United States)
Northwestern Univ., Evanston, IL (United States); Kyoto Univ., Kyoto (Japan)
Northwestern Univ., Evanston, IL (United States); National Cheng Kung Univ., Tainan City (Taiwan)
Argonne National Lab. (ANL), Lemont, IL (United States); Stony Brook Univ., Stony Brook, NY (United States)

Publication Date:: 2019-02-25

Research Org.:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Workforce Development for Teachers and Scientists (WDTS)

OSTI Identifier:: 1524086

Grant/Contract Number:: AC02-06CH11357

Resource Type:: Accepted Manuscript

Journal Name:: Chemistry of Materials

Additional Journal Information:: Journal Volume: 31; Journal Issue: 5; Journal ID: ISSN 0897-4756

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats


                    Goswami, Subhadip, Noh, Hyunho, Redfern, Louis R., Otake, Ken-ichi, Kung, Chung -Wei, Cui, Yuexing, Chapman, Karena W., Farha, Omar K., and Hupp, Joseph T. Pore-Templated Growth of Catalytically Active Gold Nanoparticles within a Metal–Organic Framework.  United States: N. p., 2019. 
        Web.  doi:10.1021/acs.chemmater.8b04983.

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                    Goswami, Subhadip, Noh, Hyunho, Redfern, Louis R., Otake, Ken-ichi, Kung, Chung -Wei, Cui, Yuexing, Chapman, Karena W., Farha, Omar K., & Hupp, Joseph T. Pore-Templated Growth of Catalytically Active Gold Nanoparticles within a Metal–Organic Framework.  United States.  doi:10.1021/acs.chemmater.8b04983.

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                    Goswami, Subhadip, Noh, Hyunho, Redfern, Louis R., Otake, Ken-ichi, Kung, Chung -Wei, Cui, Yuexing, Chapman, Karena W., Farha, Omar K., and Hupp, Joseph T. Mon .  
        "Pore-Templated Growth of Catalytically Active Gold Nanoparticles within a Metal–Organic Framework".  United States.  doi:10.1021/acs.chemmater.8b04983.  https://www.osti.gov/servlets/purl/1524086.

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@article{osti_1524086,

  title        = {Pore-Templated Growth of Catalytically Active Gold Nanoparticles within a Metal–Organic Framework},

  author       = {Goswami, Subhadip and Noh, Hyunho and Redfern, Louis R. and Otake, Ken-ichi and Kung, Chung -Wei and Cui, Yuexing and Chapman, Karena W. and Farha, Omar K. and Hupp, Joseph T.},

  abstractNote = {Obtaining persistently well-dispersed gold nano-particles (AuNPs) on solid support with optimum particle size for heterogeneous catalysis can be challenging. Here, we report on the channel-templated growth of AuNPs within a stable zirconium-based metal–organic framework, NU-1000, via channel-anchored monometallic precursors. Pair distribution function analysis of total X-ray scattering by the incorporated face-centered-cubic nanopar-ticles reveals a bimodal size distribution, with ca. 98% of the en-shrouded nanoparticles having a diameter that closely reflects the ~10 Å width of triangular pores and with ca. 2% closely reflecting the ~31 Å width of hexagonal pores of NU-1000. The resulting ma-terial is catalytically active (and recyclable) for condensed-phase hydrogenation of 4-nitrophenol to 4-aminophenol.},

  doi          = {10.1021/acs.chemmater.8b04983},

  journal      = {Chemistry of Materials},

  number       = 5,

  volume       = 31,

  place        = {United States},

  year         = {2019},

  month        = {2}

}

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DOI: 10.1021/acs.chemmater.8b04983

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Works referencing / citing this record:

CCDC 1869375: Experimental Crystal Structure Determination
dataset, January 2019

Goswami, Subhadip; Noh, Hyunho; Redfern, Louis R.
Cambridge Crystallographic Data Centre
DOI: 10.5517/ccdc.csd.cc20r7fg

Controlled Growth of Ag Nanocrystals in a H‐Bonded Open Framework
journal, September 2019

Khodja, Walid; Collière, Vincent; Kahn, Myrtil L.
Chemistry – A European Journal, Vol. 25, Issue 60
DOI: 10.1002/chem.201903684

Nanofabrication of Au nanoparticles over conductive metallohydrogel nanofibers for nanocatalysis application
journal, January 2020

Dixit, Manish Kumar; Chery, Déborah; Mahendar, Chinthakuntla
Inorganic Chemistry Frontiers, Vol. 7, Issue 4
DOI: 10.1039/c9qi01514k

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Title: Pore-Templated Growth of Catalytically Active Gold Nanoparticles within a Metal–Organic Framework

Abstract

Citation Formats

CCDC 1869375: Experimental Crystal Structure Determination dataset, January 2019

Controlled Growth of Ag Nanocrystals in a H‐Bonded Open Framework journal, September 2019

Nanofabrication of Au nanoparticles over conductive metallohydrogel nanofibers for nanocatalysis application journal, January 2020

CCDC 1869375: Experimental Crystal Structure Determination
dataset, January 2019

Controlled Growth of Ag Nanocrystals in a H‐Bonded Open Framework
journal, September 2019

Nanofabrication of Au nanoparticles over conductive metallohydrogel nanofibers for nanocatalysis application
journal, January 2020