Inducing selectivity and chirality in group IV metal coordination with high-denticity hydroxypyridinones

Deblonde, Gauthier J. -P.; Lohrey, Trevor D.; Abergel, Rebecca J.

doi:10.1039/C9DT01031A

Title: Inducing selectivity and chirality in group IV metal coordination with high-denticity hydroxypyridinones

Journal Article · 10 June 2019 · Dalton Transactions

DOI: https://doi.org/10.1039/C9DT01031A · OSTI ID:1513038

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Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, USA
Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, USA, Department of Chemistry
Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, USA, Department of Nuclear Engineering

Hydroxypyridinone ligand 3,4,3-LI(1,2-HOPO) exhibits remarkable charge-based selectivity for octacoordinated tetravalent cations, forming stable chiral complexes over a very broad pH range.

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Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1513038

Journal Information:: Dalton Transactions, Journal Name: Dalton Transactions Journal Issue: 23 Vol. 48; ISSN 1477-9226; ISSN ICHBD9

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

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