skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

This content will become publicly available on May 16, 2020

Title: Inducing selectivity and chirality in group IV metal coordination with high-denticity hydroxypyridinones

Abstract

Hydroxypyridinone ligand 3,4,3-LI(1,2-HOPO) exhibits remarkable charge-based selectivity for octacoordinated tetravalent cations, forming stable chiral complexes over a very broad pH range.

Authors:
ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [3]
  1. Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, USA
  2. Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, USA, Department of Chemistry
  3. Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, USA, Department of Nuclear Engineering
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1513038
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Dalton Transactions
Additional Journal Information:
Journal Name: Dalton Transactions; Journal ID: ISSN 1477-9226
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Deblonde, Gauthier J. -P., Lohrey, Trevor D., and Abergel, Rebecca J. Inducing selectivity and chirality in group IV metal coordination with high-denticity hydroxypyridinones. United Kingdom: N. p., 2019. Web. doi:10.1039/C9DT01031A.
Deblonde, Gauthier J. -P., Lohrey, Trevor D., & Abergel, Rebecca J. Inducing selectivity and chirality in group IV metal coordination with high-denticity hydroxypyridinones. United Kingdom. doi:10.1039/C9DT01031A.
Deblonde, Gauthier J. -P., Lohrey, Trevor D., and Abergel, Rebecca J. Tue . "Inducing selectivity and chirality in group IV metal coordination with high-denticity hydroxypyridinones". United Kingdom. doi:10.1039/C9DT01031A.
@article{osti_1513038,
title = {Inducing selectivity and chirality in group IV metal coordination with high-denticity hydroxypyridinones},
author = {Deblonde, Gauthier J. -P. and Lohrey, Trevor D. and Abergel, Rebecca J.},
abstractNote = {Hydroxypyridinone ligand 3,4,3-LI(1,2-HOPO) exhibits remarkable charge-based selectivity for octacoordinated tetravalent cations, forming stable chiral complexes over a very broad pH range.},
doi = {10.1039/C9DT01031A},
journal = {Dalton Transactions},
number = ,
volume = ,
place = {United Kingdom},
year = {2019},
month = {1}
}

Journal Article:
Free Publicly Available Full Text
This content will become publicly available on May 16, 2020
Publisher's Version of Record

Save / Share:

Works referenced in this record:

A short history of SHELX
journal, December 2007

  • Sheldrick, George M.
  • Acta Crystallographica Section A Foundations of Crystallography, Vol. 64, Issue 1, p. 112-122
  • DOI: 10.1107/S0108767307043930

Specific sequestering agents for the actinides. 16. Synthesis and initial biological testing of polydentate oxohydroxypyridinecarboxylate ligands
journal, January 1988

  • White, David L.; Durbin, Patricia W.; Jeung, Nylan
  • Journal of Medicinal Chemistry, Vol. 31, Issue 1, p. 11-18
  • DOI: 10.1021/jm00396a005

Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides
journal, September 1976


Separation of zirconium and hafnium using Diphonix® chelating ion-exchange resin
journal, February 2009


Cymothoe sangaris�:? An Extremely Stable and Highly Luminescent 1,2-Hydroxypyridinonate Chelate of Eu(III)
July 2006

  • Moore, Evan G.; Xu, Jide; Jocher, Christoph J.
  • Journal of the American Chemical Society, Vol. 128, Issue 33, p. 10648-10649
  • DOI: 10.1021/ja062597+