Magnetocaloric effect of gadolinium in high magnetic fields

Gottschall, T.; Kuz'min, M. D.; Skokov, K. P.; Skourski, Y.; Fries, M.; Gutfleisch, O.; Zavareh, M. Ghorbani; Schlagel, D. L.; Mudryk, Y.; Pecharsky, V.; Wosnitza, J.

doi:10.1103/PhysRevB.99.134429

Title: Magnetocaloric effect of gadolinium in high magnetic fields

Abstract

The magnetocaloric effect of gadolinium has been inspected directly in pulsed magnetic fields up to 62 T. The maximum observed adiabatic temperature change is ΔT_ad = 60.5 K, the initial temperature T₀ being just above 300 K. The field dependence of ΔT_ad is found to follow the usual H^2/3 law, with a small correction in H^4/3. Yet, as H is increased, a radical change is observed in the dependence of ΔT_ad on T₀, at H = const. The familiar caret-shaped peak situated at T₀ = T_C becomes distinctly asymmetric, its high-temperature slope becoming more gentle and evolving into a broad plateau. For yet higher magnetic fields, μ₀H ≳ 140 T, calculations predict a complete disappearance of the maximum near T_C and an emergence of a new very broad maximum far above T_C.

Authors:

Gottschall, T. ^[1]; Kuz'min, M. D. ^[2]; Skokov, K. P. ^[3]; Skourski, Y. ^[1]; Fries, M. ^[3]; Gutfleisch, O. ^[3]; Zavareh, M. Ghorbani ^[1]; Schlagel, D. L. ^[4]; Mudryk, Y. ^[4]; Pecharsky, V. ^[4]; Wosnitza, J. ^[5]

Helmholtz-Zentrum Dresden-Rossendorf (HZDR), Dresden (Germany)
Aix-Marseille Université, Marseille (Germany)
Technische Universität Darmstadt, Darmstadt (Germany)
Ames Lab. and Iowa State Univ., Ames, IA (United States)
Helmholtz-Zentrum Dresden-Rossendorf (HZDR), Dresden (Germany); Technische Universität, Dresden (Germany)

Publication Date:: Fri Apr 19 00:00:00 EDT 2019

Research Org.:: Ames Laboratory (AMES), Ames, IA (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1514889

Alternate Identifier(s):: OSTI ID: 1507805

Report Number(s):: IS-J-9935
Journal ID: ISSN 2469-9950; PRBMDO

Grant/Contract Number:: SPP 1599; HRSF-0045; AC02-07CH11358

Resource Type:: Accepted Manuscript

Journal Name:: Physical Review B

Additional Journal Information:: Journal Volume: 99; Journal Issue: 13; Journal ID: ISSN 2469-9950

Publisher:: American Physical Society (APS)

Country of Publication:: United States

Language:: English

Subject:: 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY

Citation Formats


                    Gottschall, T., Kuz'min, M. D., Skokov, K. P., Skourski, Y., Fries, M., Gutfleisch, O., Zavareh, M. Ghorbani, Schlagel, D. L., Mudryk, Y., Pecharsky, V., and Wosnitza, J. Magnetocaloric effect of gadolinium in high magnetic fields.  United States: N. p., 2019. 
Web.  doi:10.1103/PhysRevB.99.134429.

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                    Gottschall, T., Kuz'min, M. D., Skokov, K. P., Skourski, Y., Fries, M., Gutfleisch, O., Zavareh, M. Ghorbani, Schlagel, D. L., Mudryk, Y., Pecharsky, V., & Wosnitza, J. Magnetocaloric effect of gadolinium in high magnetic fields.  United States.  https://doi.org/10.1103/PhysRevB.99.134429

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                    Gottschall, T., Kuz'min, M. D., Skokov, K. P., Skourski, Y., Fries, M., Gutfleisch, O., Zavareh, M. Ghorbani, Schlagel, D. L., Mudryk, Y., Pecharsky, V., and Wosnitza, J. Fri .  
"Magnetocaloric effect of gadolinium in high magnetic fields".  United States.  https://doi.org/10.1103/PhysRevB.99.134429.  https://www.osti.gov/servlets/purl/1514889.

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@article{osti_1514889,

  title        = {Magnetocaloric effect of gadolinium in high magnetic fields},

  author       = {Gottschall, T. and Kuz'min, M. D. and Skokov, K. P. and Skourski, Y. and Fries, M. and Gutfleisch, O. and Zavareh, M. Ghorbani and Schlagel, D. L. and Mudryk, Y. and Pecharsky, V. and Wosnitza, J.},

  abstractNote = {The magnetocaloric effect of gadolinium has been inspected directly in pulsed magnetic fields up to 62 T. The maximum observed adiabatic temperature change is ΔTad = 60.5 K, the initial temperature T0 being just above 300 K. The field dependence of ΔTad is found to follow the usual H2/3 law, with a small correction in H4/3. Yet, as H is increased, a radical change is observed in the dependence of ΔTad on T0, at H = const. The familiar caret-shaped peak situated at T0 = TC becomes distinctly asymmetric, its high-temperature slope becoming more gentle and evolving into a broad plateau. For yet higher magnetic fields, μ0H ≳ 140 T, calculations predict a complete disappearance of the maximum near TC and an emergence of a new very broad maximum far above TC.},

  doi          = {10.1103/PhysRevB.99.134429},

  journal      = {Physical Review B},

  number       = 13,

  volume       = 99,

  place        = {United States},

  year         = {Fri Apr 19 00:00:00 EDT 2019},

  month        = {Fri Apr 19 00:00:00 EDT 2019}

}

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Works referenced in this record:

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Dynamics of the magnetoelastic phase transition and adiabatic temperature change in ${Mn}_{1.3}$ ${Fe}_{0.7}$ $P_{0.5}$ ${Si}_{0.55}$
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Dynamical Effects of the Martensitic Transition in Magnetocaloric Heusler Alloys from Direct $Δ T_{ad}$ Measurements under Different Magnetic-Field-Sweep Rates
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Gottschall, T.; Skokov, K. P.; Scheibel, F.
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Gutfleisch, O.; Gottschall, T.; Fries, M.
Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 374, Issue 2074
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Direct measurements of the magnetocaloric effect in pulsed magnetic fields: The example of the Heusler alloy Ni ₅₀ Mn ₃₅ In ₁₅
journal, February 2015

Ghorbani Zavareh, M.; Salazar Mejía, C.; Nayak, A. K.
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Direct measurements of inverse magnetocaloric effects in metamagnetic shape-memory alloy NiCoMnIn
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Direct Measurement of the Magnetocaloric Effect in $La (Fe, Si, Co)_{13}$ Compounds in Pulsed Magnetic Fields
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Zavareh, M. Ghorbani; Skourski, Y.; Skokov, K. P.
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Works referencing / citing this record:

Making a Cool Choice: The Materials Library of Magnetic Refrigeration
journal, July 2019

Gottschall, Tino; Skokov, Konstantin P.; Fries, Maximilian
Advanced Energy Materials, Vol. 9, Issue 34
DOI: 10.1002/aenm.201901322

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Title: Magnetocaloric effect of gadolinium in high magnetic fields

Abstract

Citation Formats

Magnetic heat pumping near room temperature journal, August 1976

Dynamics of the magnetoelastic phase transition and adiabatic temperature change in Mn 1.3 Fe 0.7 P 0.5 Si 0.55 journal, May 2019

Dependence of the inverse magnetocaloric effect on the field-change rate in Mn 3 GaC and its relationship to the kinetics of the phase transition journal, June 2015

Giant magnetocaloric effect driven by structural transitions journal, May 2012

Pulsed high-magnetic-field experiments: New insights into the magnetocaloric effect in Ni-Mn-In Heusler alloys journal, May 2015

High-field magnetization of Ho 2 Fe 17 journal, June 2011

Elastic Moduli and Ultrasonic Attenuation of Gadolinium, Terbium, Dysprosium, Holmium, and Erbium from 4.2 to 300°K journal, October 1968

Dynamical Effects of the Martensitic Transition in Magnetocaloric Heusler Alloys from Direct Δ T ad Measurements under Different Magnetic-Field-Sweep Rates journal, February 2016

Mastering hysteresis in magnetocaloric materials journal, August 2016

Direct measurements of the magnetocaloric effect in pulsed magnetic fields: The example of the Heusler alloy Ni 50 Mn 35 In 15 journal, February 2015

Magnetic cooling near Curie temperatures above 300 K journal, June 1984

Magnetocaloric Materials journal, August 2000

Direct measurements of inverse magnetocaloric effects in metamagnetic shape-memory alloy NiCoMnIn journal, December 2014

Adiabatic measurements of magneto-caloric effects in pulsed high magnetic fields up to 55 T journal, July 2013

Direct Measurement of the Magnetocaloric Effect in La ( Fe , Si , Co ) 13 Compounds in Pulsed Magnetic Fields journal, July 2017

Magnetic properties of gadolinium in the region of paraprocess journal, September 1986

Dynamics of the magnetoelastic phase transition and adiabatic temperature change in Mn1.3Fe0.7P0.5Si0.55 text, January 2019

The Magnetocaloric Effect and its Applications reference-book, January 2016

Adiabatic measurements of magneto-caloric effects in pulsed high magnetic fields up to 55 T text, January 2013

Direct measurements of the magnetocaloric effect in pulsed magnetic fields: The example of the Heusler alloy Ni$_{50}$Mn$_{35}$In$_{15}$ text, January 2015

Making a Cool Choice: The Materials Library of Magnetic Refrigeration journal, July 2019

Magnetic heat pumping near room temperature
journal, August 1976

Dynamics of the magnetoelastic phase transition and adiabatic temperature change in ${Mn}_{1.3}$ ${Fe}_{0.7}$ $P_{0.5}$ ${Si}_{0.55}$
journal, May 2019

Dependence of the inverse magnetocaloric effect on the field-change rate in Mn ₃ GaC and its relationship to the kinetics of the phase transition
journal, June 2015

Giant magnetocaloric effect driven by structural transitions
journal, May 2012

Pulsed high-magnetic-field experiments: New insights into the magnetocaloric effect in Ni-Mn-In Heusler alloys
journal, May 2015

High-field magnetization of Ho $_{2}$ Fe $_{17}$
journal, June 2011

Elastic Moduli and Ultrasonic Attenuation of Gadolinium, Terbium, Dysprosium, Holmium, and Erbium from 4.2 to 300°K
journal, October 1968

Dynamical Effects of the Martensitic Transition in Magnetocaloric Heusler Alloys from Direct $Δ T_{ad}$ Measurements under Different Magnetic-Field-Sweep Rates
journal, February 2016

Mastering hysteresis in magnetocaloric materials
journal, August 2016

Direct measurements of the magnetocaloric effect in pulsed magnetic fields: The example of the Heusler alloy Ni ₅₀ Mn ₃₅ In ₁₅
journal, February 2015

Magnetic cooling near Curie temperatures above 300 K
journal, June 1984

Magnetocaloric Materials
journal, August 2000

Direct measurements of inverse magnetocaloric effects in metamagnetic shape-memory alloy NiCoMnIn
journal, December 2014

Adiabatic measurements of magneto-caloric effects in pulsed high magnetic fields up to 55 T
journal, July 2013

Direct Measurement of the Magnetocaloric Effect in $La (Fe, Si, Co)_{13}$ Compounds in Pulsed Magnetic Fields
journal, July 2017

Magnetic properties of gadolinium in the region of paraprocess
journal, September 1986

Dynamics of the magnetoelastic phase transition and adiabatic temperature change in Mn1.3Fe0.7P0.5Si0.55
text, January 2019

The Magnetocaloric Effect and its Applications
reference-book, January 2016

Adiabatic measurements of magneto-caloric effects in pulsed high magnetic fields up to 55 T
text, January 2013

Direct measurements of the magnetocaloric effect in pulsed magnetic fields: The example of the Heusler alloy Ni$_{50}$Mn$_{35}$In$_{15}$
text, January 2015

Making a Cool Choice: The Materials Library of Magnetic Refrigeration
journal, July 2019