Anisotropic magnetocaloric effect in single crystals of
Abstract
We report a systematic investigation of dc magnetization and ac susceptibility, as well as anisotropic magnetocaloric effect in bulk CrI3 single crystals. A second-stage magnetic transition was observed just below the Curie temperature Tc, indicating a two-step magnetic ordering. The low temperature thermal demagnetization could be well fitted by the spin-wave model rather than the single-particle model, confirming its localized magnetism. The maximum magnetic entropy change -ΔS$$max\atop{M}$$ ~5.65 J kg-1 K-1 and the corresponding adiabatic temperature change ΔTad ~2.34 K are achieved from heat capacity analysis with the magnetic field up to 9 T. Anisotropy of ΔSM (T,H) was further investigated by isothermal magnetization, showing that the difference of -ΔS$$max\atop{M}$$ between the $ab$ plane and the c axis reaches a maximum value ~1.56 J kg-1 K-1 with the field change of 5 T. In conclusion, with the scaling analysis of ΔSM, the rescaled ΔSM (T,H) curves collapse onto a universal curve, indicating a second-order type of the magnetic transition. Furthermore, the -ΔS$$max\atop{M}$$ follows the power law of Hn with n = 0.64 (1), and the relative cooling power depends on Hm with m = 1.12 (1) .
- Authors:
-
- Brookhaven National Lab. (BNL), Upton, NY (United States). Condensed Matter Physics and Materials Science Dept.
- Publication Date:
- Research Org.:
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1462402
- Alternate Identifier(s):
- OSTI ID: 1438066
- Report Number(s):
- BNL-207871-2018-JAAM
Journal ID: ISSN 2469-9950; PRBMDO; TRN: US1902163
- Grant/Contract Number:
- SC0012704
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Physical Review B
- Additional Journal Information:
- Journal Volume: 97; Journal Issue: 17; Journal ID: ISSN 2469-9950
- Publisher:
- American Physical Society (APS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY
Citation Formats
Liu, Yu, and Petrovic, Cedomir. Anisotropic magnetocaloric effect in single crystals of CrI3. United States: N. p., 2018.
Web. doi:10.1103/PhysRevB.97.174418.
Liu, Yu, & Petrovic, Cedomir. Anisotropic magnetocaloric effect in single crystals of CrI3. United States. https://doi.org/10.1103/PhysRevB.97.174418
Liu, Yu, and Petrovic, Cedomir. Mon .
"Anisotropic magnetocaloric effect in single crystals of CrI3". United States. https://doi.org/10.1103/PhysRevB.97.174418. https://www.osti.gov/servlets/purl/1462402.
@article{osti_1462402,
title = {Anisotropic magnetocaloric effect in single crystals of CrI3},
author = {Liu, Yu and Petrovic, Cedomir},
abstractNote = {We report a systematic investigation of dc magnetization and ac susceptibility, as well as anisotropic magnetocaloric effect in bulk CrI3 single crystals. A second-stage magnetic transition was observed just below the Curie temperature Tc, indicating a two-step magnetic ordering. The low temperature thermal demagnetization could be well fitted by the spin-wave model rather than the single-particle model, confirming its localized magnetism. The maximum magnetic entropy change -ΔS$max\atop{M}$ ~5.65 J kg-1 K-1 and the corresponding adiabatic temperature change ΔTad ~2.34 K are achieved from heat capacity analysis with the magnetic field up to 9 T. Anisotropy of ΔSM (T,H) was further investigated by isothermal magnetization, showing that the difference of -ΔS$max\atop{M}$ between the $ab$ plane and the c axis reaches a maximum value ~1.56 J kg-1 K-1 with the field change of 5 T. In conclusion, with the scaling analysis of ΔSM, the rescaled ΔSM (T,H) curves collapse onto a universal curve, indicating a second-order type of the magnetic transition. Furthermore, the -ΔS$max\atop{M}$ follows the power law of Hn with n = 0.64 (1), and the relative cooling power depends on Hm with m = 1.12 (1) .},
doi = {10.1103/PhysRevB.97.174418},
journal = {Physical Review B},
number = 17,
volume = 97,
place = {United States},
year = {Mon May 21 00:00:00 EDT 2018},
month = {Mon May 21 00:00:00 EDT 2018}
}
Web of Science
Figures / Tables:
Works referenced in this record:
Critical exponents from field theory
journal, May 1980
- Le Guillou, J. C.; Zinn-Justin, J.
- Physical Review B, Vol. 21, Issue 9
Review of the magnetocaloric effect in manganite materials
journal, January 2007
- Phan, Manh-Huong; Yu, Seong-Cho
- Journal of Magnetism and Magnetic Materials, Vol. 308, Issue 2
Magnetic behavior and spin-lattice coupling in cleavable van der Waals layered crystals
journal, June 2017
- McGuire, Michael A.; Clark, Genevieve; Kc, Santosh
- Physical Review Materials, Vol. 1, Issue 1
Field dependence of the magnetocaloric effect in materials with a second order phase transition: A master curve for the magnetic entropy change
journal, November 2006
- Franco, V.; Blázquez, J. S.; Conde, A.
- Applied Physics Letters, Vol. 89, Issue 22
Discovery of intrinsic ferromagnetism in two-dimensional van der Waals crystals
journal, April 2017
- Gong, Cheng; Li, Lin; Li, Zhenglu
- Nature, Vol. 546, Issue 7657
Magnetic structure of the new layered ferromagnetic chromium hexatellurosilicate Cr2Si2Te6
journal, March 1991
- Carteaux, V.; Ouvrard, G.; Grenier, J. C.
- Journal of Magnetism and Magnetic Materials, Vol. 94, Issue 1-2
Scaling laws for the magnetocaloric effect in second order phase transitions: From physics to applications for the characterization of materials
journal, May 2010
- Franco, V.; Conde, A.
- International Journal of Refrigeration, Vol. 33, Issue 3
Three-dimensional magnetic critical behavior in
journal, January 2018
- Liu, Yu; Petrovic, C.
- Physical Review B, Vol. 97, Issue 1
Magnetic properties of Co-rich amorphous alloys containing Cr/Mn
journal, November 1993
- Das, A.; Majumdar, A. K.
- Journal of Magnetism and Magnetic Materials, Vol. 128, Issue 1-2
Static critical phenomena in ferromagnets with quenched disorder
journal, November 1985
- Kaul, S. N.
- Journal of Magnetism and Magnetic Materials, Vol. 53, Issue 1-2
Magnetic anisotropy of the single-crystalline ferromagnetic insulator Cr 2 Ge 2 Te 6
journal, February 2016
- Zhang, Xiao; Zhao, Yuelei; Song, Qi
- Japanese Journal of Applied Physics, Vol. 55, Issue 3
Electrical control of 2D magnetism in bilayer CrI3
journal, April 2018
- Huang, Bevin; Clark, Genevieve; Klein, Dahlia R.
- Nature Nanotechnology, Vol. 13, Issue 7
Low-temperature magnetization and spin-wave excitations in amorphous Ni-rich transition-metal—metalloid alloys
journal, May 1983
- Kaul, S. N.
- Physical Review B, Vol. 27, Issue 9
Magnetocaloric Properties of Zinc-Nickel Ferrites Around Room Temperature
journal, February 2017
- Maalam, K. El; Fkhar, L.; Hamedoun, M.
- Journal of Superconductivity and Novel Magnetism, Vol. 30, Issue 7
Coupling of Crystal Structure and Magnetism in the Layered, Ferromagnetic Insulator CrI 3
journal, January 2015
- McGuire, Michael A.; Dixit, Hemant; Cooper, Valentino R.
- Chemistry of Materials, Vol. 27, Issue 2
Recent Developments in Magnetic Refrigeration
journal, July 1999
- Gschneidner Jr., K. A.; Pecharsky, V. K.; Pecharsky, A. O.
- Materials Science Forum, Vol. 315-317
Field dependence of the magnetocaloric effect in core-shell nanoparticles
journal, May 2010
- Franco, V.; Conde, A.; Sidhaye, Deepti
- Journal of Applied Physics, Vol. 107, Issue 9
Crystallographic, magnetic and electronic structures of a new layered ferromagnetic compound Cr 2 Ge 2 Te 6
journal, January 1995
- Carteaux, V.; Brunet, D.; Ouvrard, G.
- Journal of Physics: Condensed Matter, Vol. 7, Issue 1
Layer-dependent ferromagnetism in a van der Waals crystal down to the monolayer limit
journal, June 2017
- Huang, Bevin; Clark, Genevieve; Navarro-Moratalla, Efrén
- Nature, Vol. 546, Issue 7657
Synthesis and crystal structure of a new layered phase: The chromium hexatellurosilicate Cr2Si2Te6
journal, March 1988
- Ouvrard, G.; Sandre, E.; Brec, R.
- Journal of Solid State Chemistry, Vol. 73, Issue 1
Spin-wave, Stoner single-particle and correlated particle-hole pair contributions to thermal demagnetization in amorphous Fe 90+x Zr 10-x
journal, June 1991
- Kaul, S. N.
- Journal of Physics: Condensed Matter, Vol. 3, Issue 22
Magnetocaloric effect in Er- and Eu-substituted ferromagnetic La-Sr manganites
journal, April 2005
- Amaral, J. S.; Reis, M. S.; Amaral, V. S.
- Journal of Magnetism and Magnetic Materials, Vol. 290-291
Ultrathin nanosheets of CrSiTe 3 : a semiconducting two-dimensional ferromagnetic material
journal, January 2016
- Lin, Ming-Wei; Zhuang, Houlong L.; Yan, Jiaqiang
- Journal of Materials Chemistry C, Vol. 4, Issue 2
Computational discovery of ferromagnetic semiconducting single-layer
journal, July 2015
- Zhuang, Houlong L.; Xie, Yu; Kent, P. R. C.
- Physical Review B, Vol. 92, Issue 3
Ferromagnetic Order, Strong Magnetocrystalline Anisotropy, and Magnetocaloric Effect in the Layered Telluride Fe 3−δ GeTe 2
journal, August 2015
- Verchenko, Valeriy Yu.; Tsirlin, Alexander A.; Sobolev, Alexei V.
- Inorganic Chemistry, Vol. 54, Issue 17
Strong spin-lattice coupling in CrSiTe 3
journal, April 2015
- Casto, L. D.; Clune, A. J.; Yokosuk, M. O.
- APL Materials, Vol. 3, Issue 4
Anisotropic Superexchange Interaction and Weak Ferromagnetism
journal, October 1960
- Moriya, Tôru
- Physical Review, Vol. 120, Issue 1
Magnetocaloric effect and magnetic refrigeration
journal, October 1999
- Pecharsky, Vitalij K.; Gschneidner Jr, Karl A.
- Journal of Magnetism and Magnetic Materials, Vol. 200, Issue 1-3
Magnetic cooling near Curie temperatures above 300 K
journal, June 1984
- Oesterreicher, H.; Parker, F. T.
- Journal of Applied Physics, Vol. 55, Issue 12
Giant tunneling magnetoresistance in spin-filter van der Waals heterostructures
journal, May 2018
- Song, Tiancheng; Cai, Xinghan; Tu, Matisse Wei-Yuan
- Science, Vol. 360, Issue 6394
On the origin of magnetic anisotropy in two dimensional CrI 3
journal, June 2017
- Lado, J. L.; Fernández-Rossier, J.
- 2D Materials, Vol. 4, Issue 3
Robust intrinsic ferromagnetism and half semiconductivity in stable two-dimensional single-layer chromium trihalides
journal, January 2015
- Zhang, Wei-Bing; Qu, Qian; Zhu, Peng
- Journal of Materials Chemistry C, Vol. 3, Issue 48
Ligand-field helical luminescence in a 2D ferromagnetic insulator
journal, December 2017
- Seyler, Kyle L.; Zhong, Ding; Klein, Dahlia R.
- Nature Physics, Vol. 14, Issue 3
Review of the Magnetocaloric Effect in Manganite Materials
journal, February 2007
- Phan, Manh-Huong; Yu, Seong-Cho
- ChemInform, Vol. 38, Issue 8
Discovery of Intrinsic Ferromagnetism in Two-Dimensional van der Waals Crystals
conference, January 2017
- Gong, Cheng; Li, Lin; Li, Zhenglu
- CLEO: Applications and Technology, Conference on Lasers and Electro-Optics
Robust Intrinsic Ferromagnetism and Half Semiconductivity in Stable Two-Dimensional Single-Layer Chromium Trihalides
text, January 2015
- Zhang, Wei-Bing; Qu, Qian; Zhu, Peng
- arXiv
Layer-dependent Ferromagnetism in a van der Waals Crystal down to the Monolayer Limit
text, January 2017
- Huang, Bevin; Clark, Genevieve; Navarro-Moratalla, Efren
- arXiv
On the origin of magnetic anisotropy in two dimensional CrI$_3$
text, January 2017
- Lado, J. L.; Fernández-Rossier, J.
- arXiv
Giant Tunneling Magnetoresistance in Spin-Filter van der Waals Heterostructures
text, January 2018
- Song, Tiancheng; Cai, Xinghan; Tu, Matisse Wei-Yuan
- arXiv
Electrical Control of 2D Magnetism in Bilayer CrI3
text, January 2018
- Huang, Bevin; Clark, Genevieve; Klein, Dahlia R.
- arXiv
Works referencing / citing this record:
Magnetic Entropy Scaling in Ferromagnetic Semiconductor CrGeTe 3
journal, June 2019
- Sun, Yan; Luo, Xuan
- physica status solidi (b), Vol. 256, Issue 11
Thickness-dependent magnetic order in CrI3 single crystals
journal, September 2019
- Liu, Yu; Wu, Lijun; Tong, Xiao
- Scientific Reports, Vol. 9, Issue 1
Magnetocaloric effect in cubically anisotropic magnets
journal, January 2019
- Hu, Yong; Hu, Tianyi; Chi, Xiaodan
- Applied Physics Letters, Vol. 114, Issue 2
Disorder-driven non-Fermi liquid behavior in itinerant ferromagnet α -Co 5 Ge 3
journal, January 2020
- Song, Meng; Xian, Cong; Wang, Yihao
- Journal of Physics: Condensed Matter, Vol. 32, Issue 15
Recent progress of spintronics based on emerging 2D materials: CrI 3 and Xenes
journal, December 2019
- Wei, Songrui; Tang, Xian; Liao, Xiaoqi
- Materials Research Express, Vol. 6, Issue 12
Thickness-dependent magnetic order in CrI$_3$ single crystals
text, January 2019
- Liu, Yu; Wu, Lijun; Tong, Xiao
- arXiv
Figures / Tables found in this record: