Synthesis and Characterization of 2 × 4 Tunnel Structured Manganese Dioxides as Cathodes in Rechargeable Li, Na, and Mg Batteries
Abstract
Sodium containing 2 × 4 (0.46nm × 0.92nm) tunnel structured manganese dioxide (Na-2 × 4-MnO2) nanofibers are hydrothermally synthesized here. The nanofibrous Na-2 × 4-MnO2 was thoroughly characterized using X-ray diffraction (XRD), thermogravimetric analysis (TGA), inductively coupled plasma optical emission spectroscopy (ICP-OES), N2 sorption, and electron microscopy (SEM and TEM) and is assigned a formula of Na0.25MnO2.0.16H2O. The electrochemistry of Na-2 × 4-MnO2 in non-aqueous Li, Na and Mg batteries is compared for the first time and first cycle delivered capacities were found to be 152mAh/g, 86mAh/g, and 307mAh/g, respectively. Characterization of the active material after electrochemical tests demonstrated that Na-2 × 4-MnO2 preserved both its crystallographic structure and nanofibrous morphology after cycling in Na and Li cells, however, Na-2 × 4-MnO2 lost its crystalline structure after cycling in a Mg based system.
- Authors:
-
[1];
[2];
[2];
[4];
[4];
[5]
- Kennesaw State Univ., GA (United States). Dept. of Chemistry and Biochemistry; Brookhaven National Lab. (BNL), Upton, NY (United States). Energy and Photon Sciences Directorate
- Stony Brook Univ., NY (United States). Dept. of Chemistry
- Brookhaven National Lab. (BNL), Upton, NY (United States). Energy and Photon Sciences Directorate
- Brookhaven National Lab. (BNL), Upton, NY (United States). Energy and Photon Sciences Directorate; Stony Brook Univ., NY (United States). Dept. of Chemistry. Dept. of Materials Science and Engineering
- Stony Brook Univ., NY (United States). Dept. of Chemistry. Dept. of Materials Science and Engineering
- Publication Date:
- Research Org.:
- Energy Frontier Research Centers (EFRC) (United States). Center for Mesoscale Transport Properties (m2mt); Brookhaven National Lab. (BNL), Upton, NY (United States); Stony Brook Univ., NY (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF)
- OSTI Identifier:
- 1503510
- Report Number(s):
- BNL-211466-2019-JAAM
Journal ID: ISSN 0013-4651
- Grant/Contract Number:
- SC0012704; SC0012673; 1109408
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of the Electrochemical Society
- Additional Journal Information:
- Journal Volume: 166; Journal Issue: 4; Journal ID: ISSN 0013-4651
- Publisher:
- The Electrochemical Society
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; batteries; battery; cathode materials; manganese oxide
Citation Formats
Poyraz, Altug S., Quilty, Calvin D., Housel, Lisa M., Hu, Xiaobing, Bruck, Andrea M., Li, Yue Ru, Yin, Jiefu, Zhang, Bingjie, Huang, Jianping, Wu, Lijun, Zhu, Yimei, Takeuchi, Esther S., Marschilok, Amy C., and Takeuchi, Kenneth J. Synthesis and Characterization of 2 × 4 Tunnel Structured Manganese Dioxides as Cathodes in Rechargeable Li, Na, and Mg Batteries. United States: N. p., 2019.
Web. doi:10.1149/2.1341902jes.
Poyraz, Altug S., Quilty, Calvin D., Housel, Lisa M., Hu, Xiaobing, Bruck, Andrea M., Li, Yue Ru, Yin, Jiefu, Zhang, Bingjie, Huang, Jianping, Wu, Lijun, Zhu, Yimei, Takeuchi, Esther S., Marschilok, Amy C., & Takeuchi, Kenneth J. Synthesis and Characterization of 2 × 4 Tunnel Structured Manganese Dioxides as Cathodes in Rechargeable Li, Na, and Mg Batteries. United States. https://doi.org/10.1149/2.1341902jes
Poyraz, Altug S., Quilty, Calvin D., Housel, Lisa M., Hu, Xiaobing, Bruck, Andrea M., Li, Yue Ru, Yin, Jiefu, Zhang, Bingjie, Huang, Jianping, Wu, Lijun, Zhu, Yimei, Takeuchi, Esther S., Marschilok, Amy C., and Takeuchi, Kenneth J. Sat .
"Synthesis and Characterization of 2 × 4 Tunnel Structured Manganese Dioxides as Cathodes in Rechargeable Li, Na, and Mg Batteries". United States. https://doi.org/10.1149/2.1341902jes. https://www.osti.gov/servlets/purl/1503510.
@article{osti_1503510,
title = {Synthesis and Characterization of 2 × 4 Tunnel Structured Manganese Dioxides as Cathodes in Rechargeable Li, Na, and Mg Batteries},
author = {Poyraz, Altug S. and Quilty, Calvin D. and Housel, Lisa M. and Hu, Xiaobing and Bruck, Andrea M. and Li, Yue Ru and Yin, Jiefu and Zhang, Bingjie and Huang, Jianping and Wu, Lijun and Zhu, Yimei and Takeuchi, Esther S. and Marschilok, Amy C. and Takeuchi, Kenneth J.},
abstractNote = {Sodium containing 2 × 4 (0.46nm × 0.92nm) tunnel structured manganese dioxide (Na-2 × 4-MnO2) nanofibers are hydrothermally synthesized here. The nanofibrous Na-2 × 4-MnO2 was thoroughly characterized using X-ray diffraction (XRD), thermogravimetric analysis (TGA), inductively coupled plasma optical emission spectroscopy (ICP-OES), N2 sorption, and electron microscopy (SEM and TEM) and is assigned a formula of Na0.25MnO2.0.16H2O. The electrochemistry of Na-2 × 4-MnO2 in non-aqueous Li, Na and Mg batteries is compared for the first time and first cycle delivered capacities were found to be 152mAh/g, 86mAh/g, and 307mAh/g, respectively. Characterization of the active material after electrochemical tests demonstrated that Na-2 × 4-MnO2 preserved both its crystallographic structure and nanofibrous morphology after cycling in Na and Li cells, however, Na-2 × 4-MnO2 lost its crystalline structure after cycling in a Mg based system.},
doi = {10.1149/2.1341902jes},
journal = {Journal of the Electrochemical Society},
number = 4,
volume = 166,
place = {United States},
year = {Sat Mar 02 00:00:00 EST 2019},
month = {Sat Mar 02 00:00:00 EST 2019}
}
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