Direct observation of pitting corrosion evolutions on carbon steel surfaces at the nano-to-micro- scales
Abstract
The Cl¯-induced corrosion of metals and alloys is of relevance to a wide range of engineered materials, structures, and systems. Because of the challenges in studying pitting corrosion in a quantitative and statistically significant manner, its kinetics remain poorly understood. Herein, by direct, nano- to micro-scale observations using vertical scanning interferometry (VSI), we examine the temporal evolution of pitting corrosion on AISI 1045 carbon steel over large surface areas in Cl¯-free, and Cl¯-enriched solutions. Special focus is paid to examine the nucleation and growth of pits, and the associated formation of roughened regions on steel surfaces. By statistical analysis of hundreds of individual pits, three stages of pitting corrosion, namely, induction, propagation, and saturation, are quantitatively distinguished. By quantifying the kinetics of these processes, we contextualize our current understanding of electrochemical corrosion within a framework that considers spatial dynamics and morphology evolutions. In the presence of Cl¯ ions, corrosion is highly accelerated due to multiple autocatalytic factors including destabilization of protective surface oxide films and preservation of aggressive microenvironments within the pits, both of which promote continued pit nucleation and growth. Furthermore these findings offer new insights into predicting and modeling steel corrosion processes in mid-pH aqueous environments
- Authors:
-
- Univ. of California, Los Angeles, CA (United States)
- Publication Date:
- Research Org.:
- Univ. of California, Los Angeles, CA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1500090
- Grant/Contract Number:
- NE0008398
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Scientific Reports
- Additional Journal Information:
- Journal Volume: 8; Journal Issue: 1; Journal ID: ISSN 2045-2322
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE
Citation Formats
Guo, Peng, La Plante, Erika Callagon, Wang, Bu, Chen, Xin, Balonis, Magdalena, Bauchy, Mathieu, and Sant, Gaurav. Direct observation of pitting corrosion evolutions on carbon steel surfaces at the nano-to-micro- scales. United States: N. p., 2018.
Web. doi:10.1038/s41598-018-26340-5.
Guo, Peng, La Plante, Erika Callagon, Wang, Bu, Chen, Xin, Balonis, Magdalena, Bauchy, Mathieu, & Sant, Gaurav. Direct observation of pitting corrosion evolutions on carbon steel surfaces at the nano-to-micro- scales. United States. https://doi.org/10.1038/s41598-018-26340-5
Guo, Peng, La Plante, Erika Callagon, Wang, Bu, Chen, Xin, Balonis, Magdalena, Bauchy, Mathieu, and Sant, Gaurav. Tue .
"Direct observation of pitting corrosion evolutions on carbon steel surfaces at the nano-to-micro- scales". United States. https://doi.org/10.1038/s41598-018-26340-5. https://www.osti.gov/servlets/purl/1500090.
@article{osti_1500090,
title = {Direct observation of pitting corrosion evolutions on carbon steel surfaces at the nano-to-micro- scales},
author = {Guo, Peng and La Plante, Erika Callagon and Wang, Bu and Chen, Xin and Balonis, Magdalena and Bauchy, Mathieu and Sant, Gaurav},
abstractNote = {The Cl¯-induced corrosion of metals and alloys is of relevance to a wide range of engineered materials, structures, and systems. Because of the challenges in studying pitting corrosion in a quantitative and statistically significant manner, its kinetics remain poorly understood. Herein, by direct, nano- to micro-scale observations using vertical scanning interferometry (VSI), we examine the temporal evolution of pitting corrosion on AISI 1045 carbon steel over large surface areas in Cl¯-free, and Cl¯-enriched solutions. Special focus is paid to examine the nucleation and growth of pits, and the associated formation of roughened regions on steel surfaces. By statistical analysis of hundreds of individual pits, three stages of pitting corrosion, namely, induction, propagation, and saturation, are quantitatively distinguished. By quantifying the kinetics of these processes, we contextualize our current understanding of electrochemical corrosion within a framework that considers spatial dynamics and morphology evolutions. In the presence of Cl¯ ions, corrosion is highly accelerated due to multiple autocatalytic factors including destabilization of protective surface oxide films and preservation of aggressive microenvironments within the pits, both of which promote continued pit nucleation and growth. Furthermore these findings offer new insights into predicting and modeling steel corrosion processes in mid-pH aqueous environments},
doi = {10.1038/s41598-018-26340-5},
journal = {Scientific Reports},
number = 1,
volume = 8,
place = {United States},
year = {Tue May 22 00:00:00 EDT 2018},
month = {Tue May 22 00:00:00 EDT 2018}
}
Web of Science
Figures / Tables:
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