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Title: Predicting High-Temperature Decomposition of Lithiated Graphite: Part II. Passivation Layer Evolution and the Role of Surface Area

Abstract

Abstract not provided.

Authors:
ORCiD logo; ORCiD logo; ORCiD logo
Publication Date:
Research Org.:
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
Sponsoring Org.:
USDOE Office of Electricity (OE)
OSTI Identifier:
1487160
Alternate Identifier(s):
OSTI ID: 1492378; OSTI ID: 1492379
Report Number(s):
SAND-2018-11870J; SAND-2018-13302J
Journal ID: ISSN 0013-4651; /jes/165/16/A3891.atom
Grant/Contract Number:  
AC04-94AL85000
Resource Type:
Published Article
Journal Name:
Journal of the Electrochemical Society
Additional Journal Information:
Journal Name: Journal of the Electrochemical Society Journal Volume: 165 Journal Issue: 16; Journal ID: ISSN 0013-4651
Publisher:
The Electrochemical Society
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE; Batteries; Batteries - Lithium; Lithiated Graphite; Solid Electrolyte Interphase; Thermal Runaway

Citation Formats

Shurtz, Randy C., Engerer, Jeffrey D., and Hewson, John C. Predicting High-Temperature Decomposition of Lithiated Graphite: Part II. Passivation Layer Evolution and the Role of Surface Area. United States: N. p., 2018. Web. doi:10.1149/2.0171814jes.
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Shurtz, Randy C., Engerer, Jeffrey D., & Hewson, John C. Predicting High-Temperature Decomposition of Lithiated Graphite: Part II. Passivation Layer Evolution and the Role of Surface Area. United States. https://doi.org/10.1149/2.0171814jes
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Shurtz, Randy C., Engerer, Jeffrey D., and Hewson, John C. Fri . "Predicting High-Temperature Decomposition of Lithiated Graphite: Part II. Passivation Layer Evolution and the Role of Surface Area". United States. https://doi.org/10.1149/2.0171814jes.
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@article{osti_1487160,
title = {Predicting High-Temperature Decomposition of Lithiated Graphite: Part II. Passivation Layer Evolution and the Role of Surface Area},
author = {Shurtz, Randy C. and Engerer, Jeffrey D. and Hewson, John C.},
abstractNote = {Abstract not provided.},
doi = {10.1149/2.0171814jes},
journal = {Journal of the Electrochemical Society},
number = 16,
volume = 165,
place = {United States},
year = {Fri Dec 14 00:00:00 EST 2018},
month = {Fri Dec 14 00:00:00 EST 2018}
}
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Journal Article:
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Publisher's Version of Record
https://doi.org/10.1149/2.0171814jes
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Cited by: 18 works
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Table 1 Table 1: Definition of symbols used in this work
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Works referenced in this record:

Revealing SEI Morphology: In-Depth Analysis of a Modeling Approach
journal, January 2017

  • Single, Fabian; Horstmann, Birger; Latz, Arnulf
  • Journal of The Electrochemical Society, Vol. 164, Issue 11
  • DOI: 10.1149/2.0121711jes

Modeling detailed chemistry and transport for solid-electrolyte-interface (SEI) films in Li–ion batteries
journal, December 2011

Differential Scanning Calorimetry Study of the Reactivity of Carbon Anodes in Plastic Li-Ion Batteries
journal, January 1998

  • Pasquier, A. Du
  • Journal of The Electrochemical Society, Vol. 145, Issue 2
  • DOI: 10.1149/1.1838287

A Comparison Between the High Temperature Electrode /Electrolyte Reactions of Li[sub x]CoO[sub 2] and Li[sub x]Mn[sub 2]O[sub 4]
journal, January 2001

  • MacNeil, D. D.; Hatchard, T. D.; Dahn, J. R.
  • Journal of The Electrochemical Society, Vol. 148, Issue 7
  • DOI: 10.1149/1.1375798

Effects of particle size on the thermal stability of lithiated graphite anode
journal, April 2009

The formation and stability of the solid electrolyte interface on the graphite anode
journal, December 2014

A Critical Review of Thermal Issues in Lithium-Ion Batteries
journal, January 2011

  • Bandhauer, Todd M.; Garimella, Srinivas; Fuller, Thomas F.
  • Journal of The Electrochemical Society, Vol. 158, Issue 3, p. R1-R25
  • DOI: 10.1149/1.3515880

Electronic Structure Modeling of Electrochemical Reactions at Electrode/Electrolyte Interfaces in Lithium Ion Batteries
journal, December 2012

  • Leung, Kevin
  • The Journal of Physical Chemistry C, Vol. 117, Issue 4
  • DOI: 10.1021/jp308929a

The Study of Electrolyte Solutions Based on Ethylene and Diethyl Carbonates for Rechargeable Li Batteries
journal, January 1995

  • Aurbach, Doron
  • Journal of The Electrochemical Society, Vol. 142, Issue 9
  • DOI: 10.1149/1.2048659

Spatial Heterogeneities and Onset of Passivation Breakdown at Lithium Anode Interfaces
journal, September 2017

  • Leung, Kevin; Jungjohann, Katherine L.
  • The Journal of Physical Chemistry C, Vol. 121, Issue 37
  • DOI: 10.1021/acs.jpcc.7b06983

The Reaction of Charged Cathodes with Nonaqueous Solvents and Electrolytes: I. Li[sub 0.5]CoO[sub 2]
journal, January 2001

  • MacNeil, D. D.; Dahn, J. R.
  • Journal of The Electrochemical Society, Vol. 148, Issue 11
  • DOI: 10.1149/1.1407245

Comparison of the Reactions Between Li[sub 7/3]Ti[sub 5/3]O[sub 4] or LiC[sub 6] and Nonaqueous Solvents or Electrolytes Using Accelerating Rate Calorimetry
journal, January 2004

  • Jiang, Junwei; Chen, Jun; Dahn, J. R.
  • Journal of The Electrochemical Society, Vol. 151, Issue 12
  • DOI: 10.1149/1.1817698

Electrolytes and Interphases in Li-Ion Batteries and Beyond
journal, October 2014

High-voltage positive electrode materials for lithium-ion batteries
journal, January 2017

  • Li, Wangda; Song, Bohang; Manthiram, Arumugam
  • Chemical Society Reviews, Vol. 46, Issue 10
  • DOI: 10.1039/C6CS00875E

Edge/basal/defect ratios in graphite and their influence on the thermal stability of lithium ion batteries
journal, June 2016

Accelerating Rate Calorimetry Study on the Thermal Stability of Lithium Intercalated Graphite in Electrolyte. I. Experimental
journal, June 1999

  • Richard, M. N.
  • Journal of The Electrochemical Society, Vol. 146, Issue 6
  • DOI: 10.1149/1.1391893

Electrochemical Intercalation of Bis(Trifluoromethanesulfonyl) Imide Anion into Various Graphites for Dual-Ion Cells
journal, April 2013

Lithium Ion Battery Safety
journal, January 2012

  • Orendorff, C. J.; Doughty, D. H.
  • Interface magazine, Vol. 21, Issue 2
  • DOI: 10.1149/2.F02122if

Effect of ionic composition on thermal properties of energetic ionic liquids
journal, May 2018

Effects of solvents and salts on the thermal stability of LiC6
journal, October 2004

Advanced Model for Solid Electrolyte Interphase Electrodes in Liquid and Polymer Electrolytes
journal, January 1997

  • Peled, E.
  • Journal of The Electrochemical Society, Vol. 144, Issue 8
  • DOI: 10.1149/1.1837858

On the Thermal Behavior of Lithium Intercalated Graphites
journal, January 2011

  • Haik, Ortal; Ganin, Svetlana; Gershinsky, Gregory
  • Journal of The Electrochemical Society, Vol. 158, Issue 8
  • DOI: 10.1149/1.3598173

Predicting High-Temperature Decomposition of Lithiated Graphite: Part I. Review of Phenomena and a Comprehensive Model
journal, January 2018

  • Shurtz, Randy C.; Engerer, Jeffrey D.; Hewson, John C.
  • Journal of The Electrochemical Society, Vol. 165, Issue 16
  • DOI: 10.1149/2.0541816jes

Thermal Model of Cylindrical and Prismatic Lithium-Ion Cells
journal, January 2001

  • Hatchard, T. D.; MacNeil, D. D.; Basu, A.
  • Journal of The Electrochemical Society, Vol. 148, Issue 7
  • DOI: 10.1149/1.1377592

A three-dimensional thermal abuse model for lithium-ion cells
journal, July 2007

Thermal stability of LiPF6/EC+DEC electrolyte with charged electrodes for lithium ion batteries
journal, October 2005

Challenges in the development of advanced Li-ion batteries: a review
journal, January 2011

  • Etacheri, Vinodkumar; Marom, Rotem; Elazari, Ran
  • Energy & Environmental Science, Vol. 4, Issue 9
  • DOI: 10.1039/c1ee01598b

Solubility of Lithium Salts Formed on the Lithium-Ion Battery Negative Electrode Surface in Organic Solvents
journal, January 2009

  • Tasaki, Ken; Goldberg, Alex; Lian, Jian-Jie
  • Journal of The Electrochemical Society, Vol. 156, Issue 12
  • DOI: 10.1149/1.3239850

Studies of Li and Mn-Rich Li x [MnNiCo]O 2 Electrodes: Electrochemical Performance, Structure, and the Effect of the Aluminum Fluoride Coating
journal, January 2013

  • Amalraj, Francis; Talianker, Michael; Markovsky, Boris
  • Journal of The Electrochemical Society, Vol. 160, Issue 11
  • DOI: 10.1149/2.091311jes

Recent studies of the lithium-liquid electrolyte interface Electrochemical, morphological and spectral studies of a few important systems
journal, March 1995

Solvent Diffusion Model for Aging of Lithium-Ion Battery Cells
journal, January 2004

  • Ploehn, Harry J.; Ramadass, Premanand; White, Ralph E.
  • Journal of The Electrochemical Society, Vol. 151, Issue 3
  • DOI: 10.1149/1.1644601

Influence of Graphite Characteristics on the Electrochemical Intercalation of Bis(trifluoromethanesulfonyl) imide Anions into a Graphite-Based Cathode
journal, January 2013

  • Placke, Tobias; Rothermel, Sergej; Fromm, Olga
  • Journal of The Electrochemical Society, Vol. 160, Issue 11
  • DOI: 10.1149/2.027311jes

Simulation of Abuse Behavior of Lithium-Ion Batteries
journal, January 2012

  • Spotnitz, R.; Muller, R. P.
  • Interface magazine, Vol. 21, Issue 2
  • DOI: 10.1149/2.F06122if

A General Discussion of Li Ion Battery Safety
journal, January 2012

  • Doughty, D. H.; Roth, E. P.
  • Interface magazine, Vol. 21, Issue 2
  • DOI: 10.1149/2.F03122if

Comparison of the Thermal Stability of Lithiated Graphite in LiBOB EC/DEC and in LiPF[sub 6] EC/DEC
journal, January 2003

  • Jiang, J.; Dahn, J. R.
  • Electrochemical and Solid-State Letters, Vol. 6, Issue 9
  • DOI: 10.1149/1.1592911

A Mathematical Model for the Lithium-Ion Negative Electrode Solid Electrolyte Interphase
journal, January 2004

  • Christensen, John; Newman, John
  • Journal of The Electrochemical Society, Vol. 151, Issue 11
  • DOI: 10.1149/1.1804812

Using Atomic Layer Deposition to Hinder Solvent Decomposition in Lithium Ion Batteries: First-Principles Modeling and Experimental Studies
journal, September 2011

  • Leung, Kevin; Qi, Yue; Zavadil, Kevin R.
  • Journal of the American Chemical Society, Vol. 133, Issue 37
  • DOI: 10.1021/ja205119g

Thermal abuse performance of high-power 18650 Li-ion cells
journal, April 2004

An Investigation of the Effect of Graphite Degradation on Irreversible Capacity in Lithium-ion Cells
journal, January 2008

  • Hardwick, Laurence J.; Marcinek, Marek; Beer, Leanne
  • Journal of The Electrochemical Society, Vol. 155, Issue 6
  • DOI: 10.1149/1.2903882

Computational Exploration of the Li-Electrode|Electrolyte Interface in the Presence of a Nanometer Thick Solid-Electrolyte Interphase Layer
journal, September 2016

Review—SEI: Past, Present and Future
journal, January 2017

  • Peled, E.; Menkin, S.
  • Journal of The Electrochemical Society, Vol. 164, Issue 7
  • DOI: 10.1149/2.1441707jes

Comparison of the Reactivity of Various Carbon Electrode Materials with Electrolyte at Elevated Temperature
journal, January 1999

  • MacNeil, D. D.
  • Journal of The Electrochemical Society, Vol. 146, Issue 10
  • DOI: 10.1149/1.1392520

An Autocatalytic Mechanism for the Reaction of Li[sub x]CoO[sub 2] in Electrolyte at Elevated Temperature
journal, January 2000

  • MacNeil, D. D.; Christensen, L.; Landucci, J.
  • Journal of The Electrochemical Society, Vol. 147, Issue 3
  • DOI: 10.1149/1.1393299
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    Figures / Tables found in this record:

    Table 1 (p. 19)table
    Table 2 (p. 20)table
    Table A-1 (p. 21)table
    Table A-1 (continued) (p. 21)table
    Table A-1 (continued) (p. 22)table
    Table A-1 (continued) (p. 23)table
    Figure 1 (p. 24)figure
    Figure 2 (p. 25)figure
    Figure 3 (p. 26)figure
    Figure 4 (p. 27)figure
    Figure 5 (p. 28)figure
    Figure 6 (p. 29)figure
    Figure A-1 (p. 30)figure
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