Cost of automotive lithium-ion batteries operating at high upper cutoff voltages
Abstract
Here, the potential for operating automotive battery packs at high upper cutoff voltages (UCV) has been explored using preliminary data on eight cathode materials. The pack level energy density, specific energy, and battery cost are calculated using the spreadsheet tool BatPaC. The tool used experimental data for some cathode materials such as the lithiated oxides of nickel manganese cobalt (NMC), nickel cobalt aluminum (NCA), layered lithium- and manganese-rich nickel manganese cobalt (LMRNMC). The half-cell data were obtained at UCVs between 4.2 and 4.7 V vs. Li/Li+. The experimental data showed LMRNMC with the highest lithiation capacity gain, increasing from 176 mAh·g–1 at 4.2 V to 260 mAh·g–1 at 4.7 V; this advantage is partly offset by its lower average voltage. Assuming optimized cell materials/design and an area-specific impedance of 12 Ω•cm2 for all the materials, the BatPaC results indicate that the specific energies or energy densities of the battery electric vehicle (BEV) and plug-in hybrid electric vehicle (PHEV) battery packs with the LMRNMC and NMC cathodes can exceed 180 (BEV) and 160 (PHEV) Wh·kg–1 at UCV>4.6 V vs. Li/Li+. The costs of these battery packs are lowest at UCV = 4.7 V (vs. Li/Li+); estimated at 135–145 and 210–220 $·kWh–1more »
- Authors:
-
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Publication Date:
- Research Org.:
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE)
- OSTI Identifier:
- 1488410
- Alternate Identifier(s):
- OSTI ID: 1636542
- Grant/Contract Number:
- AC02-06CH11357
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Power Sources
- Additional Journal Information:
- Journal Volume: 403; Journal Issue: C; Journal ID: ISSN 0378-7753
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; 36 MATERIALS SCIENCE; 32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATION; Upper cutoff voltage; battery cost; cathode; high-energy high-voltage; lithium ion battery cost; specific energy
Citation Formats
Ahmed, Shabbir, Trask, Stephen E., Dees, Dennis W., Nelson, Paul A., Lu, Wenquan, Dunlop, Alison R., Polzin, Bryant J., and Jansen, Andrew N. Cost of automotive lithium-ion batteries operating at high upper cutoff voltages. United States: N. p., 2018.
Web. doi:10.1016/j.jpowsour.2018.09.037.
Ahmed, Shabbir, Trask, Stephen E., Dees, Dennis W., Nelson, Paul A., Lu, Wenquan, Dunlop, Alison R., Polzin, Bryant J., & Jansen, Andrew N. Cost of automotive lithium-ion batteries operating at high upper cutoff voltages. United States. https://doi.org/10.1016/j.jpowsour.2018.09.037
Ahmed, Shabbir, Trask, Stephen E., Dees, Dennis W., Nelson, Paul A., Lu, Wenquan, Dunlop, Alison R., Polzin, Bryant J., and Jansen, Andrew N. Fri .
"Cost of automotive lithium-ion batteries operating at high upper cutoff voltages". United States. https://doi.org/10.1016/j.jpowsour.2018.09.037. https://www.osti.gov/servlets/purl/1488410.
@article{osti_1488410,
title = {Cost of automotive lithium-ion batteries operating at high upper cutoff voltages},
author = {Ahmed, Shabbir and Trask, Stephen E. and Dees, Dennis W. and Nelson, Paul A. and Lu, Wenquan and Dunlop, Alison R. and Polzin, Bryant J. and Jansen, Andrew N.},
abstractNote = {Here, the potential for operating automotive battery packs at high upper cutoff voltages (UCV) has been explored using preliminary data on eight cathode materials. The pack level energy density, specific energy, and battery cost are calculated using the spreadsheet tool BatPaC. The tool used experimental data for some cathode materials such as the lithiated oxides of nickel manganese cobalt (NMC), nickel cobalt aluminum (NCA), layered lithium- and manganese-rich nickel manganese cobalt (LMRNMC). The half-cell data were obtained at UCVs between 4.2 and 4.7 V vs. Li/Li+. The experimental data showed LMRNMC with the highest lithiation capacity gain, increasing from 176 mAh·g–1 at 4.2 V to 260 mAh·g–1 at 4.7 V; this advantage is partly offset by its lower average voltage. Assuming optimized cell materials/design and an area-specific impedance of 12 Ω•cm2 for all the materials, the BatPaC results indicate that the specific energies or energy densities of the battery electric vehicle (BEV) and plug-in hybrid electric vehicle (PHEV) battery packs with the LMRNMC and NMC cathodes can exceed 180 (BEV) and 160 (PHEV) Wh·kg–1 at UCV>4.6 V vs. Li/Li+. The costs of these battery packs are lowest at UCV = 4.7 V (vs. Li/Li+); estimated at 135–145 and 210–220 $·kWh–1 for BEV and PHEV packs, respectively.},
doi = {10.1016/j.jpowsour.2018.09.037},
journal = {Journal of Power Sources},
number = C,
volume = 403,
place = {United States},
year = {Fri Sep 28 00:00:00 EDT 2018},
month = {Fri Sep 28 00:00:00 EDT 2018}
}
Web of Science
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