Tuning martensitic transitions in (MnNiSi)0.65(Fe2Ge)0.35 through heat treatment and hydrostatic pressure
Abstract
A first-order magneto-structural transition from a ferromagnetic orthorhombic TiNiSi-type martensite phase to a paramagnetic hexagonal Ni2In-type austenite phase was observed in (MnNiSi)0.65(Fe2Ge)0.35. In this work, we demonstrate that the first-order magneto-structural transition temperature for a given composition is tunable over a wide temperature range through heat treatment and hydrostatic pressure. The first-order transition temperature was reduced by over 100 K as the annealing temperature went from 600 to 900 °C, and this first-order transition was converted to second order when the sample was annealed at 1000 °C. The maximum magnetic-induced isothermal entropy change with μ0ΔH=7 T reaches -58 J/kg K for the sample annealed at 600 °C, and the relative cooling power reaches 558 J/kg for the sample annealed at 700 °C. Similar to the influence of annealing temperatures, the first-order martensitic transition temperatures were reduced as the application of hydrostatic pressure increased until they were converted to second order. Our results suggest that the (MnNiSi)0.65(Fe2Ge)0.35 system is a promising platform for tuning magneto-structural transitions and the associated magnetocaloric effects. Furthermore, a similar heat treatment methodology or application of hydrostatic pressure can be applied to MnNiSi-based shape memory alloys to tailor their working transition temperatures.
- Authors:
-
- Louisiana State Univ., Baton Rouge, LA (United States)
- Southern Illinois Univ., Carbondale, IL (United States)
- Publication Date:
- Research Org.:
- Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS); Louisiana State Univ., Baton Rouge, LA (United States); Southern Illinois Univ., Carbondale, IL (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1484787
- Alternate Identifier(s):
- OSTI ID: 1872463
- Grant/Contract Number:
- AC02-06CH11357; FG02-13ER46946; FG02-06ER46291; SC0012432; NSF-DMR- 1306392; SC0010521
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Applied Physics
- Additional Journal Information:
- Journal Volume: 124; Journal Issue: 20; Journal ID: ISSN 0021-8979
- Publisher:
- American Institute of Physics (AIP)
- Country of Publication:
- United States
- Language:
- ENGLISH
- Subject:
- 36 MATERIALS SCIENCE; Shape memory effect; Smart materials; Magnetism; Entropy; Phase transitions; Materials heat treatment; 32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATION; magnetocaloric effect; phase transitions
Citation Formats
Chen, Jing-Han, Us Saleheen, Ahmad, Karna, Sunil K., Young, David P., Dubenko, Igor, Ali, Naushad, and Stadler, Shane. Tuning martensitic transitions in (MnNiSi)0.65(Fe2Ge)0.35 through heat treatment and hydrostatic pressure. United States: N. p., 2018.
Web. doi:10.1063/1.5051551.
Chen, Jing-Han, Us Saleheen, Ahmad, Karna, Sunil K., Young, David P., Dubenko, Igor, Ali, Naushad, & Stadler, Shane. Tuning martensitic transitions in (MnNiSi)0.65(Fe2Ge)0.35 through heat treatment and hydrostatic pressure. United States. https://doi.org/10.1063/1.5051551
Chen, Jing-Han, Us Saleheen, Ahmad, Karna, Sunil K., Young, David P., Dubenko, Igor, Ali, Naushad, and Stadler, Shane. Wed .
"Tuning martensitic transitions in (MnNiSi)0.65(Fe2Ge)0.35 through heat treatment and hydrostatic pressure". United States. https://doi.org/10.1063/1.5051551. https://www.osti.gov/servlets/purl/1484787.
@article{osti_1484787,
title = {Tuning martensitic transitions in (MnNiSi)0.65(Fe2Ge)0.35 through heat treatment and hydrostatic pressure},
author = {Chen, Jing-Han and Us Saleheen, Ahmad and Karna, Sunil K. and Young, David P. and Dubenko, Igor and Ali, Naushad and Stadler, Shane},
abstractNote = {A first-order magneto-structural transition from a ferromagnetic orthorhombic TiNiSi-type martensite phase to a paramagnetic hexagonal Ni2In-type austenite phase was observed in (MnNiSi)0.65(Fe2Ge)0.35. In this work, we demonstrate that the first-order magneto-structural transition temperature for a given composition is tunable over a wide temperature range through heat treatment and hydrostatic pressure. The first-order transition temperature was reduced by over 100 K as the annealing temperature went from 600 to 900 °C, and this first-order transition was converted to second order when the sample was annealed at 1000 °C. The maximum magnetic-induced isothermal entropy change with μ0ΔH=7 T reaches -58 J/kg K for the sample annealed at 600 °C, and the relative cooling power reaches 558 J/kg for the sample annealed at 700 °C. Similar to the influence of annealing temperatures, the first-order martensitic transition temperatures were reduced as the application of hydrostatic pressure increased until they were converted to second order. Our results suggest that the (MnNiSi)0.65(Fe2Ge)0.35 system is a promising platform for tuning magneto-structural transitions and the associated magnetocaloric effects. Furthermore, a similar heat treatment methodology or application of hydrostatic pressure can be applied to MnNiSi-based shape memory alloys to tailor their working transition temperatures.},
doi = {10.1063/1.5051551},
journal = {Journal of Applied Physics},
number = 20,
volume = 124,
place = {United States},
year = {Wed Nov 28 00:00:00 EST 2018},
month = {Wed Nov 28 00:00:00 EST 2018}
}
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