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Title: Amine additive reactions induced by the soft Lewis acidity of Pb 2+ in halide perovskites. Part II: impacts of amido Pb impurities in methylammonium lead triiodide thin films

Abstract

The beneficial and detrimental effects of amido Pb impurities incorporated in methylammonium lead triiodide thin films are characterized by photoemission spectroscopy.

Authors:
ORCiD logo [1]; ORCiD logo [2];  [3]; ORCiD logo [4];  [1]; ORCiD logo [5]; ORCiD logo [1]
  1. Princeton Univ., NJ (United States)
  2. Colorado School of Mines, Golden, CO (United States)
  3. National Renewable Energy Lab. (NREL), Golden, CO (United States); Centre National de la Recherche Scientifique (CNRS), Palaiseau (France). Institut Photovoltaïque d’Ile de France (IPVF)
  4. National Renewable Energy Lab. (NREL), Golden, CO (United States)
  5. Colorado School of Mines, Golden, CO (United States); National Renewable Energy Lab. (NREL), Golden, CO (United States)
Publication Date:
Research Org.:
National Renewable Energy Lab. (NREL), Golden, CO (United States)
Sponsoring Org.:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Solar Energy Technologies Office (EE-4S)
OSTI Identifier:
1483337
Alternate Identifier(s):
OSTI ID: 1524328
Report Number(s):
NREL/JA-5K00-74035
Journal ID: ISSN 2050-7526; JMCCCX
Grant/Contract Number:  
AC36-08GO28308
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Journal of Materials Chemistry C
Additional Journal Information:
Journal Volume: 7; Journal Issue: 18; Journal ID: ISSN 2050-7526
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; 71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS; additives; amines; crystal impurities; inclusions; layered semiconductors; metal halides; molecules; morphology; optoelectronic devices; passivation; perovskites

Citation Formats

Kerner, Ross A., Schloemer, Tracy H., Schulz, Philip, Berry, Joseph J., Schwartz, Jeffrey, Sellinger, Alan, and Rand, Barry P. Amine additive reactions induced by the soft Lewis acidity of Pb2+ in halide perovskites. Part II: impacts of amido Pb impurities in methylammonium lead triiodide thin films. United States: N. p., 2019. Web. doi:10.1039/C8TC04872J.
Kerner, Ross A., Schloemer, Tracy H., Schulz, Philip, Berry, Joseph J., Schwartz, Jeffrey, Sellinger, Alan, & Rand, Barry P. Amine additive reactions induced by the soft Lewis acidity of Pb2+ in halide perovskites. Part II: impacts of amido Pb impurities in methylammonium lead triiodide thin films. United States. doi:10.1039/C8TC04872J.
Kerner, Ross A., Schloemer, Tracy H., Schulz, Philip, Berry, Joseph J., Schwartz, Jeffrey, Sellinger, Alan, and Rand, Barry P. Fri . "Amine additive reactions induced by the soft Lewis acidity of Pb2+ in halide perovskites. Part II: impacts of amido Pb impurities in methylammonium lead triiodide thin films". United States. doi:10.1039/C8TC04872J.
@article{osti_1483337,
title = {Amine additive reactions induced by the soft Lewis acidity of Pb2+ in halide perovskites. Part II: impacts of amido Pb impurities in methylammonium lead triiodide thin films},
author = {Kerner, Ross A. and Schloemer, Tracy H. and Schulz, Philip and Berry, Joseph J. and Schwartz, Jeffrey and Sellinger, Alan and Rand, Barry P.},
abstractNote = {The beneficial and detrimental effects of amido Pb impurities incorporated in methylammonium lead triiodide thin films are characterized by photoemission spectroscopy.},
doi = {10.1039/C8TC04872J},
journal = {Journal of Materials Chemistry C},
number = 18,
volume = 7,
place = {United States},
year = {2019},
month = {11}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1039/C8TC04872J

Citation Metrics:
Cited by: 3 works
Citation information provided by
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Works referenced in this record:

Light-Induced Degradation of CH 3 NH 3 PbI 3 Hybrid Perovskite Thin Film
journal, February 2017

  • Li, Youzhen; Xu, Xuemei; Wang, Congcong
  • The Journal of Physical Chemistry C, Vol. 121, Issue 7
  • DOI: 10.1021/acs.jpcc.6b11853

Chemical Reduction of Intrinsic Defects in Thicker Heterojunction Planar Perovskite Solar Cells
journal, April 2017


Metal Halide Perovskite Polycrystalline Films Exhibiting Properties of Single Crystals
journal, September 2017


Efficient perovskite light-emitting diodes featuring nanometre-sized crystallites
journal, January 2017


Unraveling the Light-Induced Degradation Mechanisms of CH 3 NH 3 PbI 3 Perovskite Films
journal, November 2017

  • Nickel, Norbert H.; Lang, Felix; Brus, Victor V.
  • Advanced Electronic Materials, Vol. 3, Issue 12
  • DOI: 10.1002/aelm.201700158

Amine-Based Passivating Materials for Enhanced Optical Properties and Performance of Organic–Inorganic Perovskites in Light-Emitting Diodes
journal, April 2017

  • Lee, Seungjin; Park, Jong Hyun; Lee, Bo Ram
  • The Journal of Physical Chemistry Letters, Vol. 8, Issue 8
  • DOI: 10.1021/acs.jpclett.7b00372

Ultrahigh sensitivity of methylammonium lead tribromide perovskite single crystals to environmental gases
journal, July 2016

  • Fang, Hong-Hua; Adjokatse, Sampson; Wei, Haotong
  • Science Advances, Vol. 2, Issue 7
  • DOI: 10.1126/sciadv.1600534

Unveiling the Influence of pH on the Crystallization of Hybrid Perovskites, Delivering Low Voltage Loss Photovoltaics
journal, October 2017


Thermal degradation of CH 3 NH 3 PbI 3 perovskite into NH 3 and CH 3 I gases observed by coupled thermogravimetry–mass spectrometry analysis
journal, January 2016

  • Juarez-Perez, Emilio J.; Hawash, Zafer; Raga, Sonia R.
  • Energy & Environmental Science, Vol. 9, Issue 11
  • DOI: 10.1039/C6EE02016J

HPbI 3 : A New Precursor Compound for Highly Efficient Solution-Processed Perovskite Solar Cells
journal, January 2015


The precipitation of lead during decomposition of lead iodide by electron irradiation
journal, July 1961


Unravelling the Improved Electronic and Structural Properties of Methylammonium Lead Iodide Deposited from Acetonitrile
journal, October 2018


Impact of White Light Illumination on the Electronic and Chemical Structures of Mixed Halide and Single Crystal Perovskites
journal, March 2017

  • Zu, Feng-Shuo; Amsalem, Patrick; Salzmann, Ingo
  • Advanced Optical Materials, Vol. 5, Issue 9
  • DOI: 10.1002/adom.201700139

Amine additive reactions induced by the soft Lewis acidity of Pb 2+ in halide perovskites. Part I: evidence for Pb–alkylamide formation
journal, January 2019

  • Kerner, Ross A.; Schloemer, Tracy H.; Schulz, Philip
  • Journal of Materials Chemistry C, Vol. 7, Issue 18
  • DOI: 10.1039/c8tc04871a

A low viscosity, low boiling point, clean solvent system for the rapid crystallisation of highly specular perovskite films
journal, January 2017

  • Noel, Nakita K.; Habisreutinger, Severin N.; Wenger, Bernard
  • Energy & Environmental Science, Vol. 10, Issue 1
  • DOI: 10.1039/C6EE02373H

Charge Trapping in Photovoltaically Active Perovskites and Related Halogenoplumbate Compounds
journal, March 2014

  • Shkrob, Ilya A.; Marin, Timothy W.
  • The Journal of Physical Chemistry Letters, Vol. 5, Issue 7
  • DOI: 10.1021/jz5004022

Strong Covalency-Induced Recombination Centers in Perovskite Solar Cell Material CH 3 NH 3 PbI 3
journal, October 2014

  • Agiorgousis, Michael L.; Sun, Yi-Yang; Zeng, Hao
  • Journal of the American Chemical Society, Vol. 136, Issue 41
  • DOI: 10.1021/ja5079305

Improving the stability and performance of perovskite solar cells via off-the-shelf post-device ligand treatment
journal, January 2018

  • Zhang, Hong; Ren, Xingang; Chen, Xiwen
  • Energy & Environmental Science, Vol. 11, Issue 8
  • DOI: 10.1039/C8EE00580J

Continuous-wave lasing in an organic–inorganic lead halide perovskite semiconductor
journal, November 2017


Enhanced Thermal Stability in Perovskite Solar Cells by Assembling 2D/3D Stacking Structures
journal, January 2018


Recombination Kinetics in Organic-Inorganic Perovskites: Excitons, Free Charge, and Subgap States
journal, September 2014


Observation and Mediation of the Presence of Metallic Lead in Organic–Inorganic Perovskite Films
journal, June 2015

  • Sadoughi, Golnaz; Starr, David E.; Handick, Evelyn
  • ACS Applied Materials & Interfaces, Vol. 7, Issue 24
  • DOI: 10.1021/acsami.5b02237

Solar cell efficiency tables (version 51)
journal, December 2017

  • Green, Martin A.; Hishikawa, Yoshihiro; Dunlop, Ewan D.
  • Progress in Photovoltaics: Research and Applications, Vol. 26, Issue 1
  • DOI: 10.1002/pip.2978

Methylamine-Gas-Induced Defect-Healing Behavior of CH 3 NH 3 PbI 3 Thin Films for Perovskite Solar Cells
journal, June 2015

  • Zhou, Zhongmin; Wang, Zaiwei; Zhou, Yuanyuan
  • Angewandte Chemie International Edition, Vol. 54, Issue 33
  • DOI: 10.1002/anie.201504379

Defect Tolerance in Methylammonium Lead Triiodide Perovskite
journal, July 2016


Is Excess PbI 2 Beneficial for Perovskite Solar Cell Performance?
journal, January 2016

  • Liu, Fangzhou; Dong, Qi; Wong, Man Kwong
  • Advanced Energy Materials, Vol. 6, Issue 7
  • DOI: 10.1002/aenm.201502206