Amine additive reactions induced by the soft Lewis acidity of Pb 2+ in halide perovskites. Part I: evidence for Pb–alkylamide formation

Kerner, Ross A.; Schloemer, Tracy H.; Schulz, Philip; Berry, Joseph J.; Schwartz, Jeffrey; Sellinger, Alan; Rand, Barry P.

doi:10.1039/C8TC04871A

Title: Amine additive reactions induced by the soft Lewis acidity of Pb ²⁺ in halide perovskites. Part I: evidence for Pb–alkylamide formation

Journal Article · 14 November 2018 · Journal of Materials Chemistry C

DOI: https://doi.org/10.1039/C8TC04871A · OSTI ID:1524327

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^[2]; Schulz, Philip ^[3];

^[4]; Schwartz, Jeffrey ^[1];

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Princeton Univ., NJ (United States)
Colorado School of Mines, Golden, CO (United States)
National Renewable Energy Lab. (NREL), Golden, CO (United States); Centre National de la Recherche Scientifique (CNRS), Palaiseau (France). Inst. Potovoltaique d'lle de France (IPVF)
National Renewable Energy Lab. (NREL), Golden, CO (United States)
Colorado School of Mines, Golden, CO (United States); National Renewable Energy Lab. (NREL), Golden, CO (United States)

Simple aliphatic amine additives are shown to react with PbI₂in perovskite inks to form amido Pb and alkylammonium species.

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Research Organization:: National Renewable Energy Laboratory (NREL), Golden, CO (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Solar Energy Technologies Office (EE-4S)

Grant/Contract Number:: AC36-08GO28308

OSTI ID:: 1524327

Report Number(s):: NREL/JA--5K00-74034

Journal Information:: Journal of Materials Chemistry C, Journal Name: Journal of Materials Chemistry C Journal Issue: 18 Vol. 7; ISSN JMCCCX; ISSN 2050-7526

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Amine additive reactions induced by the soft Lewis acidity of Pb ²⁺ in halide perovskites. Part II: impacts of amido Pb impurities in methylammonium lead triiodide thin films Kerner, Ross A.; Schloemer, Tracy H.; Schulz, Philip Journal of Materials Chemistry C, Vol. 7, Issue 18 https://doi.org/10.1039/c8tc04872j	journal	January 2019
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Verringerung schädlicher Defekte für leistungsstarke Metallhalogenid‐Perowskit‐Solarzellen Ono, Luis K.; Liu, Shengzhong (Frank); Qi, Yabing Angewandte Chemie, Vol. 132, Issue 17 https://doi.org/10.1002/ange.201905521	journal	April 2020
Reducing Detrimental Defects for High‐Performance Metal Halide Perovskite Solar Cells Ono, Luis K.; Liu, Shengzhong (Frank); Qi, Yabing Angewandte Chemie International Edition, Vol. 59, Issue 17 https://doi.org/10.1002/anie.201905521	journal	January 2020
Amine additive reactions induced by the soft Lewis acidity of Pb ²⁺ in halide perovskites. Part II: impacts of amido Pb impurities in methylammonium lead triiodide thin films Kerner, Ross A.; Schloemer, Tracy H.; Schulz, Philip Journal of Materials Chemistry C, Vol. 7, Issue 18 https://doi.org/10.1039/c8tc04872j	journal	January 2019
Acetonitrile based single step slot-die compatible perovskite ink for flexible photovoltaics Burkitt, Daniel; Swartwout, Richard; McGettrick, James RSC Advances, Vol. 9, Issue 64 https://doi.org/10.1039/c9ra06631d	journal	January 2019
The nature of the methylamine–MAPbI ₃ complex: fundamentals of gas-induced perovskite liquefaction and crystallization Bogachuk, Dmitry; Wagner, Lukas; Mastroianni, Simone Journal of Materials Chemistry A, Vol. 8, Issue 19 https://doi.org/10.1039/d0ta02494e	journal	January 2020
Operational stability of perovskite light emitting diodes Dong, Qi; Lei, Lei; Mendes, Juliana Journal of Physics: Materials, Vol. 3, Issue 1 https://doi.org/10.1088/2515-7639/ab60c4	journal	January 2020

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36 MATERIALS SCIENCE
71 CLASSICAL AND QUANTUM MECHANICS
GENERAL PHYSICS
additives
amines
crystal impurities
inclusions
layered semiconductors
metal halides
molecules
morphology
optoelectronic devices
passivation
perovskites

Title: Amine additive reactions induced by the soft Lewis acidity of Pb 2+ in halide perovskites. Part I: evidence for Pb–alkylamide formation

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References (34)

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Title: Amine additive reactions induced by the soft Lewis acidity of Pb ²⁺ in halide perovskites. Part I: evidence for Pb–alkylamide formation