Amine additive reactions induced by the soft Lewis acidity of Pb 2+ in halide perovskites. Part I: evidence for Pb–alkylamide formation
Abstract
Simple aliphatic amine additives are shown to react with PbI 2 in perovskite inks to form amido Pb and alkylammonium species.
- Authors:
-
[1];
[2];
[4];
[5];
[1]
- Princeton Univ., NJ (United States)
- Colorado School of Mines, Golden, CO (United States)
- National Renewable Energy Lab. (NREL), Golden, CO (United States); Centre National de la Recherche Scientifique (CNRS), Palaiseau (France). Inst. Potovoltaique d'lle de France (IPVF)
- National Renewable Energy Lab. (NREL), Golden, CO (United States)
- Colorado School of Mines, Golden, CO (United States); National Renewable Energy Lab. (NREL), Golden, CO (United States)
- Publication Date:
- Research Org.:
- National Renewable Energy Lab. (NREL), Golden, CO (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE), Renewable Power Office. Solar Energy Technologies Office
- OSTI Identifier:
- 1524327
- Alternate Identifier(s):
- OSTI ID: 1484048
- Report Number(s):
- NREL/JA-5K00-74034
Journal ID: ISSN 2050-7526; JMCCCX
- Grant/Contract Number:
- AC36-08GO28308
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Materials Chemistry C
- Additional Journal Information:
- Journal Volume: 7; Journal Issue: 18; Journal ID: ISSN 2050-7526
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; 71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS; additives; amines; crystal impurities; inclusions; layered semiconductors; metal halides; molecules; morphology; optoelectronic devices; passivation; perovskites
Citation Formats
Kerner, Ross A., Schloemer, Tracy H., Schulz, Philip, Berry, Joseph J., Schwartz, Jeffrey, Sellinger, Alan, and Rand, Barry P. Amine additive reactions induced by the soft Lewis acidity of Pb 2+ in halide perovskites. Part I: evidence for Pb–alkylamide formation. United States: N. p., 2018.
Web. doi:10.1039/C8TC04871A.
Kerner, Ross A., Schloemer, Tracy H., Schulz, Philip, Berry, Joseph J., Schwartz, Jeffrey, Sellinger, Alan, & Rand, Barry P. Amine additive reactions induced by the soft Lewis acidity of Pb 2+ in halide perovskites. Part I: evidence for Pb–alkylamide formation. United States. https://doi.org/10.1039/C8TC04871A
Kerner, Ross A., Schloemer, Tracy H., Schulz, Philip, Berry, Joseph J., Schwartz, Jeffrey, Sellinger, Alan, and Rand, Barry P. Thu .
"Amine additive reactions induced by the soft Lewis acidity of Pb 2+ in halide perovskites. Part I: evidence for Pb–alkylamide formation". United States. https://doi.org/10.1039/C8TC04871A. https://www.osti.gov/servlets/purl/1524327.
@article{osti_1524327,
title = {Amine additive reactions induced by the soft Lewis acidity of Pb 2+ in halide perovskites. Part I: evidence for Pb–alkylamide formation},
author = {Kerner, Ross A. and Schloemer, Tracy H. and Schulz, Philip and Berry, Joseph J. and Schwartz, Jeffrey and Sellinger, Alan and Rand, Barry P.},
abstractNote = {Simple aliphatic amine additives are shown to react with PbI 2 in perovskite inks to form amido Pb and alkylammonium species.},
doi = {10.1039/C8TC04871A},
journal = {Journal of Materials Chemistry C},
number = 18,
volume = 7,
place = {United States},
year = {Thu Nov 15 00:00:00 EST 2018},
month = {Thu Nov 15 00:00:00 EST 2018}
}
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Works referenced in this record:
Amide Group Coordination to the Pb 2+ Ion
journal, January 1996
- Battistuzzi, Gianantonio; Borsari, Marco; Menabue, Ledi
- Inorganic Chemistry, Vol. 35, Issue 14
Tailored interfaces of unencapsulated perovskite solar cells for >1,000 hour operational stability
journal, January 2018
- Christians, Jeffrey A.; Schulz, Philip; Tinkham, Jonathan S.
- Nature Energy, Vol. 3, Issue 1
Chemical Reduction of Intrinsic Defects in Thicker Heterojunction Planar Perovskite Solar Cells
journal, April 2017
- Liu, Zonghao; Hu, Junnan; Jiao, Haoyang
- Advanced Materials, Vol. 29, Issue 23
Structures of Bare and Hydrated [Pb(AminoAcid-H)] + Complexes Using Infrared Multiple Photon Dissociation Spectroscopy
journal, October 2011
- Burt, Michael B.; Decker, Sarah G. A.; Atkins, Chad G.
- The Journal of Physical Chemistry B, Vol. 115, Issue 39
Amine additive reactions induced by the soft Lewis acidity of Pb 2+ in halide perovskites. Part II: impacts of amido Pb impurities in methylammonium lead triiodide thin films
journal, January 2019
- Kerner, Ross A.; Schloemer, Tracy H.; Schulz, Philip
- Journal of Materials Chemistry C, Vol. 7, Issue 18
Efficient perovskite light-emitting diodes featuring nanometre-sized crystallites
journal, January 2017
- Xiao, Zhengguo; Kerner, Ross A.; Zhao, Lianfeng
- Nature Photonics, Vol. 11, Issue 2
Cation Role in Structural and Electronic Properties of 3D Organic–Inorganic Halide Perovskites: A DFT Analysis
journal, May 2014
- Giorgi, Giacomo; Fujisawa, Jun-Ichi; Segawa, Hiroshi
- The Journal of Physical Chemistry C, Vol. 118, Issue 23
Perovskite solar cells: film formation and properties
journal, January 2015
- Song, Tze-Bin; Chen, Qi; Zhou, Huanping
- Journal of Materials Chemistry A, Vol. 3, Issue 17
Amine-Based Passivating Materials for Enhanced Optical Properties and Performance of Organic–Inorganic Perovskites in Light-Emitting Diodes
journal, April 2017
- Lee, Seungjin; Park, Jong Hyun; Lee, Bo Ram
- The Journal of Physical Chemistry Letters, Vol. 8, Issue 8
Perovskite–fullerene hybrid materials suppress hysteresis in planar diodes
journal, May 2015
- Xu, Jixian; Buin, Andrei; Ip, Alexander H.
- Nature Communications, Vol. 6, Issue 1
Unreacted PbI 2 as a Double-Edged Sword for Enhancing the Performance of Perovskite Solar Cells
journal, August 2016
- Jacobsson, T. Jesper; Correa-Baena, Juan-Pablo; Halvani Anaraki, Elham
- Journal of the American Chemical Society, Vol. 138, Issue 32
Lewis Acid–Base Adduct Approach for High Efficiency Perovskite Solar Cells
journal, January 2016
- Lee, Jin-Wook; Kim, Hui-Seon; Park, Nam-Gyu
- Accounts of Chemical Research, Vol. 49, Issue 2
One-Dimensional Coordination Polymers: Complexity and Diversity in Structures, Properties, and Applications
journal, February 2011
- Leong, Wei Lee; Vittal, Jagadese J.
- Chemical Reviews, Vol. 111, Issue 2
Unveiling the Influence of pH on the Crystallization of Hybrid Perovskites, Delivering Low Voltage Loss Photovoltaics
journal, October 2017
- Noel, Nakita K.; Congiu, Martina; Ramadan, Alexandra J.
- Joule, Vol. 1, Issue 2
Thermal transformations of lead oxides
journal, June 2008
- Gavrichev, K.; Bolshakov, A.; Kondakov, D.
- Journal of Thermal Analysis and Calorimetry, Vol. 92, Issue 3
Linking Chemistry at the TiO 2 /CH 3 NH 3 PbI 3 Interface to Current–Voltage Hysteresis
journal, May 2017
- Kerner, Ross A.; Rand, Barry P.
- The Journal of Physical Chemistry Letters, Vol. 8, Issue 10
Enhanced Photoluminescence and Solar Cell Performance via Lewis Base Passivation of Organic–Inorganic Lead Halide Perovskites
journal, September 2014
- Noel, Nakita K.; Abate, Antonio; Stranks, Samuel D.
- ACS Nano, Vol. 8, Issue 10
Unravelling the Improved Electronic and Structural Properties of Methylammonium Lead Iodide Deposited from Acetonitrile
journal, October 2018
- Ramadan, Alexandra J.; Noel, Nakita K.; Fearn, Sarah
- Chemistry of Materials, Vol. 30, Issue 21
A low viscosity, low boiling point, clean solvent system for the rapid crystallisation of highly specular perovskite films
journal, January 2017
- Noel, Nakita K.; Habisreutinger, Severin N.; Wenger, Bernard
- Energy & Environmental Science, Vol. 10, Issue 1
Fabrication of high quality perovskite films by modulating the Pb–O bonds in Lewis acid–base adducts
journal, January 2017
- Cao, X. B.; Li, C. L.; Zhi, L. L.
- Journal of Materials Chemistry A, Vol. 5, Issue 18
Influence of Solvent Coordination on Hybrid Organic–Inorganic Perovskite Formation
journal, November 2017
- Hamill, J. Clay; Schwartz, Jeffrey; Loo, Yueh-Lin
- ACS Energy Letters, Vol. 3, Issue 1
Coordination Polymers Versus Metal−Organic Frameworks
journal, July 2009
- Biradha, Kumar; Ramanan, Arunachalam; Vittal, Jagadese J.
- Crystal Growth & Design, Vol. 9, Issue 7
Enhanced Thermal Stability in Perovskite Solar Cells by Assembling 2D/3D Stacking Structures
journal, January 2018
- Lin, Yun; Bai, Yang; Fang, Yanjun
- The Journal of Physical Chemistry Letters, Vol. 9, Issue 3
Migration of Constituent Protons in Hybrid Organic–Inorganic Perovskite Triggers Intrinsic Doping
journal, November 2017
- Cardenas-Daw, Carlos; Simon, Thomas; Stolarczyk, Jacek K.
- Journal of the American Chemical Society, Vol. 139, Issue 46
Electrical Conductivity and Luminescence in Coordination Polymers Based on Copper(I)-Halides and Sulfur-Pyrimidine Ligands
journal, December 2011
- Gallego, Almudena; Castillo, Oscar; Gómez-García, Carlos J.
- Inorganic Chemistry, Vol. 51, Issue 1
Thermal Behavior of Methylammonium Lead-Trihalide Perovskite Photovoltaic Light Harvesters
journal, October 2014
- Dualeh, Amalie; Gao, Peng; Seok, Sang Il
- Chemistry of Materials, Vol. 26, Issue 21
Photoluminescence Lifetimes Exceeding 8 μs and Quantum Yields Exceeding 30% in Hybrid Perovskite Thin Films by Ligand Passivation
journal, July 2016
- deQuilettes, Dane W.; Koch, Susanne; Burke, Sven
- ACS Energy Letters, Vol. 1, Issue 2
Spontaneous Attachment of Amines to Carbon and Metallic Surfaces
journal, October 2006
- Gallardo, Iluminada; Pinson, Jean; Vilà, Neus
- The Journal of Physical Chemistry B, Vol. 110, Issue 39
Degradation of Highly Alloyed Metal Halide Perovskite Precursor Inks: Mechanism and Storage Solutions
journal, March 2018
- Dou, Benjia; Wheeler, Lance M.; Christians, Jeffrey A.
- ACS Energy Letters, Vol. 3, Issue 4
High efficiency methylammonium lead triiodide perovskite solar cells: the relevance of non-stoichiometric precursors
journal, January 2015
- Roldán-Carmona, C.; Gratia, P.; Zimmermann, I.
- Energy & Environmental Science, Vol. 8, Issue 12
Methylamine-Gas-Induced Defect-Healing Behavior of CH 3 NH 3 PbI 3 Thin Films for Perovskite Solar Cells
journal, June 2015
- Zhou, Zhongmin; Wang, Zaiwei; Zhou, Yuanyuan
- Angewandte Chemie International Edition, Vol. 54, Issue 33
Defect Tolerance in Methylammonium Lead Triiodide Perovskite
journal, July 2016
- Steirer, K. Xerxes; Schulz, Philip; Teeter, Glenn
- ACS Energy Letters, Vol. 1, Issue 2
Works referencing / citing this record:
Verringerung schädlicher Defekte für leistungsstarke Metallhalogenid‐Perowskit‐Solarzellen
journal, April 2020
- Ono, Luis K.; Liu, Shengzhong (Frank); Qi, Yabing
- Angewandte Chemie, Vol. 132, Issue 17
Reducing Detrimental Defects for High‐Performance Metal Halide Perovskite Solar Cells
journal, January 2020
- Ono, Luis K.; Liu, Shengzhong (Frank); Qi, Yabing
- Angewandte Chemie International Edition, Vol. 59, Issue 17
Amine additive reactions induced by the soft Lewis acidity of Pb 2+ in halide perovskites. Part II: impacts of amido Pb impurities in methylammonium lead triiodide thin films
journal, January 2019
- Kerner, Ross A.; Schloemer, Tracy H.; Schulz, Philip
- Journal of Materials Chemistry C, Vol. 7, Issue 18
Acetonitrile based single step slot-die compatible perovskite ink for flexible photovoltaics
journal, January 2019
- Burkitt, Daniel; Swartwout, Richard; McGettrick, James
- RSC Advances, Vol. 9, Issue 64
The nature of the methylamine–MAPbI 3 complex: fundamentals of gas-induced perovskite liquefaction and crystallization
journal, January 2020
- Bogachuk, Dmitry; Wagner, Lukas; Mastroianni, Simone
- Journal of Materials Chemistry A, Vol. 8, Issue 19
Operational stability of perovskite light emitting diodes
journal, January 2020
- Dong, Qi; Lei, Lei; Mendes, Juliana
- Journal of Physics: Materials, Vol. 3, Issue 1