Chemical Stability via Radical Decomposition Using Silicotungstic Acid Moieties for Polymer Electrolyte Fuel Cells

Motz, Andrew R.; Kuo, Mei-Chen; Bender, Guido; Pivovar, Bryan S.; Herring, Andrew M.

doi:10.1149/2.1361814jes

Title: Chemical Stability via Radical Decomposition Using Silicotungstic Acid Moieties for Polymer Electrolyte Fuel Cells

Journal Article · Tue Nov 20 00:00:00 UTC 2018 · Journal of the Electrochemical Society

DOI: https://doi.org/10.1149/2.1361814jes · OSTI ID:1482850

Motz, Andrew R.; Kuo, Mei-Chen; Bender, Guido; Pivovar, Bryan S.;

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Research Organization:: National Renewable Energy Laboratory (NREL), Golden, CO (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Fuel Cell Technologies Office (EE-3F)

Grant/Contract Number:: AC36-08GO28308; EE0006363

OSTI ID:: 1482850

Report Number(s):: NREL/JA--5900-73180; /jes/165/14/F1264.atom

Journal Information:: Journal of the Electrochemical Society, Journal Name: Journal of the Electrochemical Society Journal Issue: 14 Vol. 165; ISSN 0013-4651

Publisher:: The Electrochemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

References (39)

Highly Stable, Low Gas Crossover, Proton-Conducting Phenylated Polyphenylenes Adamski, Michael; Skalski, Thomas J. G.; Britton, Benjamin Angewandte Chemie, Vol. 129, Issue 31 https://doi.org/10.1002/ange.201703916	journal	June 2017
Cover Picture: Copolymerization of Divinylsilyl-11-silicotungstic Acid with Butyl Acrylate and Hexanediol Diacrylate: Synthesis of a Highly Proton-Conductive Membrane for Fuel-Cell Applications (ChemSusChem 3/2009) Horan, James L.; Genupur, Anitha; Ren, Hui ChemSusChem, Vol. 2, Issue 3 https://doi.org/10.1002/cssc.200990008	journal	March 2009
Über den Bau einiger Heteropolysäuren Signer, R.; Gross, H. Helvetica Chimica Acta, Vol. 17, Issue 1 https://doi.org/10.1002/hlca.193401701135	journal	January 1934
Rate constants for some reactions of free radicals with haloacetates in aqueous solution Maruthamuthu, Pichai; Padmaja, S.; Huie, Robert E. International Journal of Chemical Kinetics, Vol. 27, Issue 6 https://doi.org/10.1002/kin.550270610	journal	June 1995
Pulsed radiolysis of aqueous solutions of salts of phophotungstic acids of the 18th and 17th series Ershov, B. G.; Sukhov, N. L.; Kartashev, N. I. Bulletin of the Academy of Sciences of the USSR Division of Chemical Science, Vol. 30, Issue 6 https://doi.org/10.1007/BF00950269	journal	June 1981
The M06 suite of density functionals for main group thermochemistry, thermochemical kinetics, noncovalent interactions, excited states, and transition elements: two new functionals and systematic testing of four M06-class functionals and 12 other functionals Zhao, Yan; Truhlar, Donald G. Theoretical Chemistry Accounts, Vol. 120, Issue 1-3 https://doi.org/10.1007/s00214-007-0310-x	journal	July 2007
Radiation effect on poly (p-sodium styrene sulphonate) of different degrees of polymerization in aqueous solution: pulse radiolysis and steady state study Bhardwaj, Y. K.; Mohan, H.; Sabharwal, S. Radiation Physics and Chemistry, Vol. 62, Issue 2-3 https://doi.org/10.1016/S0969-806X(01)00196-7	journal	September 2001
Fuel cell early markets: Techno-economic feasibility study of PEMFC-based drivetrains in materials handling vehicles Larriba, Tomás; Garde, Raquel; Santarelli, Massimo International Journal of Hydrogen Energy, Vol. 38, Issue 5 https://doi.org/10.1016/j.ijhydene.2012.11.048	journal	February 2013
Studies of heteropoly acid/polyvinylidenedifluoride–hexafluoroproylene composite membranes and implication for the use of heteropoly acids as the proton conducting component in a fuel cell membrane Malers, Jennifer L.; Sweikart, Mary-Ann; Horan, James L. Journal of Power Sources, Vol. 172, Issue 1 https://doi.org/10.1016/j.jpowsour.2007.02.009	journal	October 2007
Structure/property relationship of Nafion XL composite membranes Shi, Shouwen; Weber, Adam Z.; Kusoglu, Ahmet Journal of Membrane Science, Vol. 516 https://doi.org/10.1016/j.memsci.2016.06.004	journal	October 2016
New Insights into Perfluorinated Sulfonic-Acid Ionomers Kusoglu, Ahmet; Weber, Adam Z. Chemical Reviews, Vol. 117, Issue 3 https://doi.org/10.1021/acs.chemrev.6b00159	journal	January 2017
Oxidation of Reduced Keggin Heteropolytungstates by Dioxygen in Water Catalyzed by Cu(II) Kim, Mooeung; Weinstock, Ira A.; Geletii, Yurii V. ACS Catalysis, Vol. 5, Issue 12 https://doi.org/10.1021/acscatal.5b01771	journal	October 2015
Photo- and Electrochromism of Polyoxometalates and Related Materials Yamase, Toshihiro Chemical Reviews, Vol. 98, Issue 1 https://doi.org/10.1021/cr9604043	journal	February 1998
Synthesis, structure, spectroscopic properties, and hydrolytic chemistry of organophosphonoyl polyoxotungstates of formula [C6H5P(O)]2Xn+W11O39(8-n)- (Xn+ = P5+, Si4+) Kim, Gyu Shik; Hagen, Karl S.; Hill, Craig L. Inorganic Chemistry, Vol. 31, Issue 25 https://doi.org/10.1021/ic00051a025	journal	December 1992
Pulse radiolytic studies of aqueous manganese(II) perchlorate solutions Pick-Kaplan, Miriam; Rabani, Joseph The Journal of Physical Chemistry, Vol. 80, Issue 17 https://doi.org/10.1021/j100558a003	journal	August 1976
Selective Formation of Hydrogen and Hydroxyl Radicals by Electron Beam Irradiation and Their Reactivity with Perfluorosulfonated Acid Ionomer Ghassemzadeh, Lida; Peckham, Timothy J.; Weissbach, Thomas Journal of the American Chemical Society, Vol. 135, Issue 42 https://doi.org/10.1021/ja408032p	journal	October 2013
Fast Proton Conduction Facilitated by Minimum Water in a Series of Divinylsilyl-11-silicotungstic Acid- co -Butyl Acrylate- co -Hexanediol Diacrylate Polymers Horan, James L.; Lingutla, Anitha; Ren, Hui The Journal of Physical Chemistry C, Vol. 118, Issue 1 https://doi.org/10.1021/jp4089657	journal	December 2013
Photoredox Chemistry in Oxide Clusters. Photochromic and Redox Properties of Polyoxometalates in Connection with Analog Solid State Colloidal Systems Gómez-Romero, Pedro; Casañ-Pastor, Nieves The Journal of Physical Chemistry, Vol. 100, Issue 30 https://doi.org/10.1021/jp953326g	journal	January 1996
Current understanding of chemical degradation mechanisms of perfluorosulfonic acid membranes and their mitigation strategies: a review Zatoń, M.; Rozière, J.; Jones, D. J. Sustainable Energy & Fuels, Vol. 1, Issue 3 https://doi.org/10.1039/C7SE00038C	journal	January 2017
Zr-doped ceria additives for enhanced PEM fuel cell durability and radical scavenger stability Baker, Andrew M.; Williams, Stefan T. D.; Mukundan, Rangachary Journal of Materials Chemistry A, Vol. 5, Issue 29 https://doi.org/10.1039/C7TA03452K	journal	January 2017
Heteropoly acid functionalized fluoroelastomer with outstanding chemical durability and performance for vehicular fuel cells Motz, Andrew R.; Kuo, Mei-Chen; Horan, James L. Energy & Environmental Science, Vol. 11, Issue 6 https://doi.org/10.1039/C8EE00545A	journal	January 2018
Ab initio effective core potentials for molecular calculations. Potentials for K to Au including the outermost core orbitals Hay, P. Jeffrey; Wadt, Willard R. The Journal of Chemical Physics, Vol. 82, Issue 1, p. 299-310 https://doi.org/10.1063/1.448975	journal	January 1985
Critical Review of rate constants for reactions of hydrated electrons, hydrogen atoms and hydroxyl radicals (⋅OH/⋅O ⁻ in Aqueous Solution Buxton, George V.; Greenstock, Clive L.; Helman, W. Phillips Journal of Physical and Chemical Reference Data, Vol. 17, Issue 2 https://doi.org/10.1063/1.555805	journal	April 1988
Wavelength controlled production of SO4- radicals in the ultraviolet photolysis of ceric sulfate solutions Matthews, Rw Australian Journal of Chemistry, Vol. 37, Issue 3 https://doi.org/10.1071/CH9840475	journal	January 1984
The State of the Art of Electric, Hybrid, and Fuel Cell Vehicles Chan, C. C. Proceedings of the IEEE, Vol. 95, Issue 4 https://doi.org/10.1109/JPROC.2007.892489	journal	April 2007
Synthesis of a Polymer Electrolyte Based on Silicotungstic Acid, Performance, and Mechanical Durability in a Proton Exchange Membrane Fuel Cell Motz, Andrew R.; Kuo, Mei-Chen; Herring, Andrew M. ECS Transactions, Vol. 80, Issue 8 https://doi.org/10.1149/08008.0565ecst	journal	August 2017
Polymer Electrolyte Fuel Cell Model Springer, T. E. Journal of The Electrochemical Society, Vol. 138, Issue 8 https://doi.org/10.1149/1.2085971	journal	January 1991
The Effect of Heteropoly Acids on Stability of PFSA PEMs under Fuel Cell Operation Haugen, Gregory M.; Meng, Fanqin; Aieta, Niccolo V. Electrochemical and Solid-State Letters, Vol. 10, Issue 3 https://doi.org/10.1149/1.2409057	journal	January 2007
The Chemistry of Fuel Cell Membrane Chemical Degradation Coms, Frank D. 214th ECS Meeting, ECS Transactions https://doi.org/10.1149/1.2981859	conference	January 2008
Modeling and Simulation of the Degradation of Perfluorinated Ion-Exchange Membranes in PEM Fuel Cells Shah, A. A.; Ralph, T. R.; Walsh, F. C. Journal of The Electrochemical Society, Vol. 156, Issue 4 https://doi.org/10.1149/1.3077573	journal	January 2009
Radical (HO●, H● and HOO●) Formation and Ionomer Degradation in Polymer Electrolyte Fuel Cells Gubler, Lorenz; Dockheer, Sindy M.; Koppenol, Willem H. Journal of The Electrochemical Society, Vol. 158, Issue 7 https://doi.org/10.1149/1.3581040	journal	January 2011
Perspective—Prospects for Durable Hydrocarbon-Based Fuel Cell Membranes Gubler, Lorenz; Nauser, Thomas; Coms, Frank D. Journal of The Electrochemical Society, Vol. 165, Issue 6 https://doi.org/10.1149/2.0131806jes	journal	January 2018
Decreasing Membrane Degradation through Heteropolyacid Sub-layers Paul Brooker, R.; Bonville, Leonard J.; Slattery, Darlene K. Journal of The Electrochemical Society, Vol. 160, Issue 1 https://doi.org/10.1149/2.017302jes	journal	November 2012
Cerium Migration during PEM Fuel Cell Accelerated Stress Testing Baker, Andrew M.; Mukundan, Rangachary; Spernjak, Dusan Journal of The Electrochemical Society, Vol. 163, Issue 9 https://doi.org/10.1149/2.0181609jes	journal	January 2016
Accelerated Stress Testing of Fuel Cell Membranes Subjected to Combined Mechanical/Chemical Stressors and Cerium Migration Lai, Yeh-Hung; Rahmoeller, Kenneth M.; Hurst, James H. Journal of The Electrochemical Society, Vol. 165, Issue 6 https://doi.org/10.1149/2.0241806jes	journal	January 2018
Chemical Stability of Perfluorobis(sulfonyl)imide-Acid (PFIA) Ionomers in Open Circuit Voltage (OCV) Accelerated Test Conditions Yandrasits, Michael; Lindell, Matthew; Peppin, Daniel Journal of The Electrochemical Society, Vol. 165, Issue 6 https://doi.org/10.1149/2.0301806jes	journal	January 2018
Investigation of a Silicotungstic Acid Functionalized Carbon on Pt Activity and Durability for the Oxygen Reduction Reaction Mason, K. Sykes; Neyerlin, Kenneth C.; Kuo, Mei-Chen Journal of The Electrochemical Society, Vol. 159, Issue 12 https://doi.org/10.1149/2.068212jes	journal	January 2012
Cerium Ion Mobility and Diffusivity Rates in Perfluorosulfonic Acid Membranes Measured via Hydrogen Pump Operation Baker, Andrew M.; Babu, Siddharth Komini; Mukundan, Rangachary Journal of The Electrochemical Society, Vol. 164, Issue 12 https://doi.org/10.1149/2.1221712jes	journal	January 2017
Electrochemical Energy Conversion Herring, A. M.; Di Noto, V. Interface magazine, Vol. 24, Issue 2 https://doi.org/10.1149/2.F01152if	journal	January 2015

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Title: Chemical Stability via Radical Decomposition Using Silicotungstic Acid Moieties for Polymer Electrolyte Fuel Cells

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