Dual‐IR Window/Electrode Operando Attenuated Total Reflection‐IR Absorption Spectroscopy for Battery Research

Ataee‐Esfahani, Hamed; Chen, De‐Jun; Tong, YuYe J.

doi:10.1002/batt.201800068

Title: Dual‐IR Window/Electrode Operando Attenuated Total Reflection‐IR Absorption Spectroscopy for Battery Research

Abstract

Abstract We report a novel dual‐IR window/electrode operando infrared (IR) spectroscopy method for battery research. In addition to keeping all the features of the in‐situ/operando IR spectroscopic methodologies for batteries reported in the literature so far, the dual‐IR window/electrode configuration reported herein offers a unique advantage of accessing both, anode and cathode processes quasi‐simultaneously by rotating the dual‐window/electrode IR battery cell 180° step‐wise in the same operando real‐battery‐like cell. The proof‐of‐concept studies demonstrated clearly its investigative advantages in gaining broader insights into the chemistry of batteries during charging/discharging and beyond.

Authors:

Ataee‐Esfahani, Hamed ^[1]; Chen, De‐Jun ^[1]; Tong, YuYe J. ^[1]

Department of Chemistry Georgetown University 37^th &, O St, NW Washington DC 20057 United States

Publication Date:: Tue Nov 20 00:00:00 EST 2018

Sponsoring Org.:: USDOE

OSTI Identifier:: 1482847

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Batteries & Supercaps

Additional Journal Information:: Journal Name: Batteries & Supercaps Journal Volume: 2 Journal Issue: 1; Journal ID: ISSN 2566-6223

Publisher:: Wiley Blackwell (John Wiley & Sons)

Country of Publication:: Germany

Language:: English

Citation Formats


                    Ataee‐Esfahani, Hamed, Chen, De‐Jun, and Tong, YuYe J. Dual‐IR Window/Electrode Operando Attenuated Total Reflection‐IR Absorption Spectroscopy for Battery Research.  Germany: N. p., 2018. 
Web.  doi:10.1002/batt.201800068.

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                    Ataee‐Esfahani, Hamed, Chen, De‐Jun, & Tong, YuYe J. Dual‐IR Window/Electrode Operando Attenuated Total Reflection‐IR Absorption Spectroscopy for Battery Research.  Germany.  https://doi.org/10.1002/batt.201800068

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                    Ataee‐Esfahani, Hamed, Chen, De‐Jun, and Tong, YuYe J. Tue .  
"Dual‐IR Window/Electrode Operando Attenuated Total Reflection‐IR Absorption Spectroscopy for Battery Research".  Germany.  https://doi.org/10.1002/batt.201800068.

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@article{osti_1482847,

  title        = {Dual‐IR Window/Electrode Operando Attenuated Total Reflection‐IR Absorption Spectroscopy for Battery Research},

  author       = {Ataee‐Esfahani, Hamed and Chen, De‐Jun and Tong, YuYe J.},

  abstractNote = {Abstract We report a novel dual‐IR window/electrode operando infrared (IR) spectroscopy method for battery research. In addition to keeping all the features of the in‐situ/operando IR spectroscopic methodologies for batteries reported in the literature so far, the dual‐IR window/electrode configuration reported herein offers a unique advantage of accessing both, anode and cathode processes quasi‐simultaneously by rotating the dual‐window/electrode IR battery cell 180° step‐wise in the same operando real‐battery‐like cell. The proof‐of‐concept studies demonstrated clearly its investigative advantages in gaining broader insights into the chemistry of batteries during charging/discharging and beyond.},

  doi          = {10.1002/batt.201800068},

  journal      = {Batteries & Supercaps},

  number       = 1,

  volume       = 2,

  place        = {Germany},

  year         = {Tue Nov 20 00:00:00 EST 2018},

  month        = {Tue Nov 20 00:00:00 EST 2018}

}

Copy to clipboard

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https://doi.org/10.1002/batt.201800068

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Title: Dual‐IR Window/Electrode Operando Attenuated Total Reflection‐IR Absorption Spectroscopy for Battery Research

Abstract

Citation Formats

The Chemistry of Electrolyte Reduction on Silicon Electrodes Revealed by in Situ ATR-FTIR Spectroscopy journal, June 2017

Dual-Electrode In Situ Infrared Spectroscopy for Fuel Cells journal, December 2015

A review of the features and analyses of the solid electrolyte interphase in Li-ion batteries journal, September 2010

Lithium Batteries and Cathode Materials journal, October 2004

In Situ Surface-Enhanced Infrared Spectroscopy to Identify Oxygen Reduction Products in Nonaqueous Metal–Oxygen Batteries journal, August 2017

Isotope Ratio, Oscillator Strength, and Band Positions from CO2 IR Spectra: A Physical Chemistry Experiment journal, March 1995

In situ methods for Li-ion battery research: A review of recent developments journal, August 2015

Effect of carbon substrate on SEI composition and morphology journal, November 2004

Anodic Oxidation of Conductive Carbon and Ethylene Carbonate in High-Voltage Li-Ion Batteries Quantified by On-Line Electrochemical Mass Spectrometry journal, January 2015

CO[sub 2] Gas Evolution on Cathode Materials for Lithium-Ion Batteries journal, January 2007

Improving the Performance of Graphite/ LiNi 0.5 Mn 1.5 O 4 Cells at High Voltage and Elevated Temperature with Added Lithium Bis(oxalato) Borate (LiBOB) journal, January 2013

Lithiation Mechanism of Methylated Amorphous Silicon Unveiled by Operando ATR-FTIR Spectroscopy journal, January 2018

Spectroscopic Insight into Li-Ion Batteries during Operation: An Alternative Infrared Approach journal, November 2015

The state of understanding of the lithium-ion-battery graphite solid electrolyte interphase (SEI) and its relationship to formation cycling journal, August 2016

A Study of Highly Oriented Pyrolytic Graphite as a Model for the Graphite Anode in Li-Ion Batteries journal, January 1999

Challenges in the development of advanced Li-ion batteries: a review journal, January 2011

Electrolyte Reactions with the Surface of High Voltage LiNi[sub 0.5]Mn[sub 1.5]O[sub 4] Cathodes for Lithium-Ion Batteries journal, January 2010

Voltage Dependent Solid Electrolyte Interphase Formation in Silicon Electrodes: Monitoring the Formation of Organic Decomposition Products journal, December 2015

Solvation and Dynamics of Lithium Ions in Carbonate-Based Electrolytes during Cycling Followed by Operando Infrared Spectroscopy: The Example of NiSb 2 , a Typical Negative Conversion-Type Electrode Material for Lithium Batteries journal, November 2017

An Advanced Tool for the Selection of Electrolyte Components for Rechargeable Lithium Batteries journal, January 1998

In-Situ Infrared Spectroscopic Studies of Electrochemical Energy Conversion and Storage journal, December 2011

On the correlation between surface chemistry and performance of graphite negative electrodes for Li ion batteries journal, September 1999

Solid Electrolyte Interphase in Li-Ion Batteries: Evolving Structures Measured In situ by Neutron Reflectometry journal, May 2012

Issue and challenges facing rechargeable thin film lithium batteries journal, August 2008

Probing electrochemical reactions in organic cathode materials via in operando infrared spectroscopy journal, February 2018

Electrochemical investigation of carbonate-based electrolytes for high voltage lithium-ion cells journal, August 2013

Recycling of graphite anodes for the next generation of lithium ion batteries journal, December 2015

Identification of Diethyl 2,5-Dioxahexane Dicarboxylate and Polyethylene Carbonate as Decomposition Products of Ethylene Carbonate Based Electrolytes by Fourier Transform Infrared Spectroscopy journal, June 2014

Li-ion battery materials: present and future journal, June 2015

Analysis of the surface of lithium in organic electrolyte by atomic force microscopy, Fourier transform infrared spectroscopy and scanning auger electron microscopy journal, December 1998

In-situ electrogeneration of [2,2′-ethylenebis(nitrilomethylidyne)diphenolato]nickelate(I) — nickel(I) salen — as a catalyst for reductive intramolecular cyclizations of 6-iodo- and 6-bromo-1-phenyl-1-hexyne journal, August 1992

Infrared Spectroscopy of Carbon Materials: A Quantum Chemical Study of Model Compounds journal, July 2003

An Electrochemical Study of the Reactivity at the Lithium Electrolyte/Bare Lithium Metal Interface journal, January 1993

In-situ FTIR investigations on the reduction of vinylene electrolyte additives suitable for use in lithium-ion batteries journal, May 2004

Disordered Carbon Anode for Lithium-Ion Battery journal, January 2005

Atomic structure of sensitive battery materials and interfaces revealed by cryo–electron microscopy journal, October 2017

Laminated Thin Li-Ion Batteries Using a Liquid Electrolyte journal, January 2002

The effect of the charging protocol on the cycle life of a Li-ion battery journal, October 2006

The Li-Ion Rechargeable Battery: A Perspective journal, January 2013

Next-generation lithium-ion batteries: The promise of near-term advancements journal, May 2014

A review of advanced and practical lithium battery materials journal, January 2011

Mechanism of gas build-up in a Li-ion cell at elevated temperature journal, May 2004

Preparation and Evaluation of Graphite Oxide Reduced at 220 °C journal, October 2010

Vibrational spectroscopy at electrolyte/electrode interfaces with graphene gratings journal, June 2015

The Chemistry of Electrolyte Reduction on Silicon Electrodes Revealed by in Situ ATR-FTIR Spectroscopy
journal, June 2017

Dual-Electrode In Situ Infrared Spectroscopy for Fuel Cells
journal, December 2015

A review of the features and analyses of the solid electrolyte interphase in Li-ion batteries
journal, September 2010

Lithium Batteries and Cathode Materials
journal, October 2004

In Situ Surface-Enhanced Infrared Spectroscopy to Identify Oxygen Reduction Products in Nonaqueous Metal–Oxygen Batteries
journal, August 2017

Isotope Ratio, Oscillator Strength, and Band Positions from CO2 IR Spectra: A Physical Chemistry Experiment
journal, March 1995

In situ methods for Li-ion battery research: A review of recent developments
journal, August 2015

Effect of carbon substrate on SEI composition and morphology
journal, November 2004

Anodic Oxidation of Conductive Carbon and Ethylene Carbonate in High-Voltage Li-Ion Batteries Quantified by On-Line Electrochemical Mass Spectrometry
journal, January 2015

CO[sub 2] Gas Evolution on Cathode Materials for Lithium-Ion Batteries
journal, January 2007

Improving the Performance of Graphite/ LiNi _0.5 Mn _1.5 O ₄ Cells at High Voltage and Elevated Temperature with Added Lithium Bis(oxalato) Borate (LiBOB)
journal, January 2013

Lithiation Mechanism of Methylated Amorphous Silicon Unveiled by Operando ATR-FTIR Spectroscopy
journal, January 2018

Spectroscopic Insight into Li-Ion Batteries during Operation: An Alternative Infrared Approach
journal, November 2015

The state of understanding of the lithium-ion-battery graphite solid electrolyte interphase (SEI) and its relationship to formation cycling
journal, August 2016

A Study of Highly Oriented Pyrolytic Graphite as a Model for the Graphite Anode in Li-Ion Batteries
journal, January 1999

Challenges in the development of advanced Li-ion batteries: a review
journal, January 2011

Electrolyte Reactions with the Surface of High Voltage LiNi[sub 0.5]Mn[sub 1.5]O[sub 4] Cathodes for Lithium-Ion Batteries
journal, January 2010

Voltage Dependent Solid Electrolyte Interphase Formation in Silicon Electrodes: Monitoring the Formation of Organic Decomposition Products
journal, December 2015

Solvation and Dynamics of Lithium Ions in Carbonate-Based Electrolytes during Cycling Followed by Operando Infrared Spectroscopy: The Example of NiSb ₂ , a Typical Negative Conversion-Type Electrode Material for Lithium Batteries
journal, November 2017

An Advanced Tool for the Selection of Electrolyte Components for Rechargeable Lithium Batteries
journal, January 1998

In-Situ Infrared Spectroscopic Studies of Electrochemical Energy Conversion and Storage
journal, December 2011

On the correlation between surface chemistry and performance of graphite negative electrodes for Li ion batteries
journal, September 1999

Solid Electrolyte Interphase in Li-Ion Batteries: Evolving Structures Measured In situ by Neutron Reflectometry
journal, May 2012

Issue and challenges facing rechargeable thin film lithium batteries
journal, August 2008

Probing electrochemical reactions in organic cathode materials via in operando infrared spectroscopy
journal, February 2018

Electrochemical investigation of carbonate-based electrolytes for high voltage lithium-ion cells
journal, August 2013

Recycling of graphite anodes for the next generation of lithium ion batteries
journal, December 2015

Identification of Diethyl 2,5-Dioxahexane Dicarboxylate and Polyethylene Carbonate as Decomposition Products of Ethylene Carbonate Based Electrolytes by Fourier Transform Infrared Spectroscopy
journal, June 2014

Li-ion battery materials: present and future
journal, June 2015

Analysis of the surface of lithium in organic electrolyte by atomic force microscopy, Fourier transform infrared spectroscopy and scanning auger electron microscopy
journal, December 1998

In-situ electrogeneration of [2,2′-ethylenebis(nitrilomethylidyne)diphenolato]nickelate(I) — nickel(I) salen — as a catalyst for reductive intramolecular cyclizations of 6-iodo- and 6-bromo-1-phenyl-1-hexyne
journal, August 1992

Infrared Spectroscopy of Carbon Materials: A Quantum Chemical Study of Model Compounds
journal, July 2003

An Electrochemical Study of the Reactivity at the Lithium Electrolyte/Bare Lithium Metal Interface
journal, January 1993

In-situ FTIR investigations on the reduction of vinylene electrolyte additives suitable for use in lithium-ion batteries
journal, May 2004

Disordered Carbon Anode for Lithium-Ion Battery
journal, January 2005

Atomic structure of sensitive battery materials and interfaces revealed by cryo–electron microscopy
journal, October 2017

Laminated Thin Li-Ion Batteries Using a Liquid Electrolyte
journal, January 2002

The effect of the charging protocol on the cycle life of a Li-ion battery
journal, October 2006

The Li-Ion Rechargeable Battery: A Perspective
journal, January 2013

Next-generation lithium-ion batteries: The promise of near-term advancements
journal, May 2014

A review of advanced and practical lithium battery materials
journal, January 2011

Mechanism of gas build-up in a Li-ion cell at elevated temperature
journal, May 2004

Preparation and Evaluation of Graphite Oxide Reduced at 220 °C
journal, October 2010

Vibrational spectroscopy at electrolyte/electrode interfaces with graphene gratings
journal, June 2015