Super Charge Separation and High Voltage Phase in NaxMnO2
Abstract
NaxMnO2 shows Mn3+ and Mn4+ charge separation with the charge stripe ordering upon Na deintercalation at x = 5/8. In this paper it is shown that, surprisingly, at lower Na compositions of 5/8 > x ≥ 1/18 the phase evolution pathway of NaxMnO2 upon Na deintercalation shows a unique phenomenon of super charge separation, where the Mn3+ and Mn4+ ions fully charge-separate into charge superplanes formed by succession of charge stripes in the third dimension. Furthermore, the Mn3+ superplanes attract Na ions electronically, and dominate the antiferromagnetic interactions in NaMnO2. Na ions in Mn3+ superplanes also naturally pillar the MnO2 layers to form the unusual O1 phases with large interlayer distances at x < 1/3, which dominates the unique electrochemical behavior of NaMnO2.
- Authors:
-
- Harvard Univ., Cambridge, MA (United States)
- Argonne National Lab. (ANL), Argonne, IL (United States)
- North Carolina State Univ., Raleigh, NC (United States)
- National Inst. of Standards and Technology (NIST), Gaithersburg, MD (United States)
- Publication Date:
- Research Org.:
- Argonne National Laboratory (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- Harvard University; USDOE
- OSTI Identifier:
- 1524584
- Alternate Identifier(s):
- OSTI ID: 1479523
- Grant/Contract Number:
- AC02-06CH11357; AC02‐06CH11357
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Advanced Functional Materials (Online)
- Additional Journal Information:
- Journal Name: Advanced Functional Materials (Online); Journal Volume: 28; Journal Issue: 50; Journal ID: ISSN 1616-3028
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; Na ion batteries; magnetic properties of sodium manganese oxides; novel high-voltage phases; reversible asymmetric structural evolutions; super charge-separations
Citation Formats
Chen, Xi, Wang, Yichao, Wiaderek, Kamila, Sang, Xiahan, Borkiewicz, Olaf, Chapman, Karena, LeBeau, James, Lynn, Jeffrey, and Li, Xin. Super Charge Separation and High Voltage Phase in NaxMnO2. United States: N. p., 2018.
Web. doi:10.1002/adfm.201805105.
Chen, Xi, Wang, Yichao, Wiaderek, Kamila, Sang, Xiahan, Borkiewicz, Olaf, Chapman, Karena, LeBeau, James, Lynn, Jeffrey, & Li, Xin. Super Charge Separation and High Voltage Phase in NaxMnO2. United States. https://doi.org/10.1002/adfm.201805105
Chen, Xi, Wang, Yichao, Wiaderek, Kamila, Sang, Xiahan, Borkiewicz, Olaf, Chapman, Karena, LeBeau, James, Lynn, Jeffrey, and Li, Xin. Sun .
"Super Charge Separation and High Voltage Phase in NaxMnO2". United States. https://doi.org/10.1002/adfm.201805105. https://www.osti.gov/servlets/purl/1524584.
@article{osti_1524584,
title = {Super Charge Separation and High Voltage Phase in NaxMnO2},
author = {Chen, Xi and Wang, Yichao and Wiaderek, Kamila and Sang, Xiahan and Borkiewicz, Olaf and Chapman, Karena and LeBeau, James and Lynn, Jeffrey and Li, Xin},
abstractNote = {NaxMnO2 shows Mn3+ and Mn4+ charge separation with the charge stripe ordering upon Na deintercalation at x = 5/8. In this paper it is shown that, surprisingly, at lower Na compositions of 5/8 > x ≥ 1/18 the phase evolution pathway of NaxMnO2 upon Na deintercalation shows a unique phenomenon of super charge separation, where the Mn3+ and Mn4+ ions fully charge-separate into charge superplanes formed by succession of charge stripes in the third dimension. Furthermore, the Mn3+ superplanes attract Na ions electronically, and dominate the antiferromagnetic interactions in NaMnO2. Na ions in Mn3+ superplanes also naturally pillar the MnO2 layers to form the unusual O1 phases with large interlayer distances at x < 1/3, which dominates the unique electrochemical behavior of NaMnO2.},
doi = {10.1002/adfm.201805105},
journal = {Advanced Functional Materials (Online)},
number = 50,
volume = 28,
place = {United States},
year = {Sun Oct 21 00:00:00 EDT 2018},
month = {Sun Oct 21 00:00:00 EDT 2018}
}
Web of Science
Figures / Tables:
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