Silver-Containing α-MnO2 Nanorods: Electrochemistry in Na-Based Battery Systems

Huang, Jianping; Poyraz, Altug S.; Lee, Seung-Yong; Wu, Lijun; Zhu, Yimei; Marschilok, Amy C.; Takeuchi, Kenneth J.; Takeuchi, Esther S.

doi:10.1021/acsami.6b08549

Title: Silver-Containing α-MnO₂ Nanorods: Electrochemistry in Na-Based Battery Systems

Journal Article · 01 September 2016 · ACS Applied Materials and Interfaces

DOI: https://doi.org/10.1021/acsami.6b08549 · OSTI ID:1439851

Huang, Jianping ^[1]; Poyraz, Altug S. ^[2]; Lee, Seung-Yong ^[2]; Wu, Lijun ^[2]; Zhu, Yimei ^[2]; Marschilok, Amy C. ^[1]; Takeuchi, Kenneth J. ^[1]; Takeuchi, Esther S. ^[3]

Stony Brook Univ., NY (United States)
Brookhaven National Lab. (BNL), Upton, NY (United States)
Brookhaven National Lab. (BNL), Upton, NY (United States); Stony Brook Univ., NY (United States)

Manganese oxides are considered attractive cathode materials for rechargeable batteries due to the high abundance and environmental friendliness of manganese. In particular, cryptomelane and hollandite are desirable due to their ability to host cations within their octahedral molecular sieve (OMS-2) Alpha-MnO₂ structure. In this work, we investigate silver containing Alpha-MnO₂ structured materials (Ag_xMn₈O₁₆, x = 1.22, L-Ag-OMS-2 or 1.66, H-Ag-OMS-2) as host materials for Li ion and Na ion insertion/de-insertion. The results indicate a significant difference in the lithiation versus sodiation process the OMS-2 materials. Initial reduction of Ag_1.22Mn₈O₁₆ to 1.0 V delivered ~370 mAh/g. Cycling of Ag1.22Mn8O16 between voltage ranges of 3.8 - 1.7 V and 3.8 - 1.3 V in a Na battery delivered initial capacities of 113 and 247 mAh/g, respectively. In contrast, Ag1.66Mn8O16 delivered only 15 mAh/g, ~0.5 electron equivalents, to 1.7 and 1.3 volts. Study of the system by electrochemical impedance spectroscopy (EIS) showed a significant decrease in charge transfer resistance from 2029 Omega to 594 Omega after 1.5 electron equivalents per Ag_1.22Mn₈O₁₆ formula unit of Na ion insertion. In contrast, both Ag_1.22Mn₈O₁₆ and Ag_1.66Mn₈O₁₆ exhibited gradual impedance increases during lithiation. The formation of silver metal could be detected only in the sodiated material by X-ray diffraction (XRD). Thus, the impedance of Ag-OMS-2 decreases upon sodiation coincident with the formation of silver metal during the discharge process, consistent with the more favorable formation of silver metal during the sodiation process relative to the lithation process.

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Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States); Energy Frontier Research Centers (EFRC) (United States). Center for Mesoscale Transport Properties (m2M)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0012704; SC0012673

OSTI ID:: 1439851

Report Number(s):: BNL-113936-2017-JAAM

Journal Information:: ACS Applied Materials and Interfaces, Vol. 9, Issue 5; ISSN 1944-8244

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 37 works

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