Controlling Dissolution and Transformation of Zeolitic Imidazolate Frameworks by using Electron‐Beam‐Induced Amorphization

Conrad, Sabrina; Kumar, Prashant; Xue, Feng; Ren, Limin; Henning, Sheryl; Xiao, Chunhong; Mkhoyan, K. Andre; Tsapatsis, Michael

doi:10.1002/anie.201809921

Title: Controlling Dissolution and Transformation of Zeolitic Imidazolate Frameworks by using Electron‐Beam‐Induced Amorphization

Abstract

Abstract Amorphous zeolitic imidazolate frameworks (ZIFs) offer promising applications as novel functional materials. Herein, amorphization of ZIF‐L through scanning‐electron‐beam exposure is demonstrated, based on amorphization of individual ZIF‐L crystals. The amorphized ZIF product has drastically increased stability against dissolution in water. An electron dose that allows for complete preservation of amorphous particles after immersion in water is established, resulting in new shapes of amorphous ZIF‐L with spatial control at the sub‐micrometer length scale. Changed water stability as a consequence of scanning‐electron‐beam exposure is demonstrated for three additional metal–organic frameworks (ZIF‐8, Zn(BeIm)OAc, MIL‐101), highlighting the potential use of an electron beam for top‐down MOF patterning. Lastly, recrystallization of ZIF‐L in the presence of linker is studied and shows distinct differences for crystalline and amorphized material.

Authors:

Conrad, Sabrina ^[1]; Kumar, Prashant ^[1]; Xue, Feng ^[1]; Ren, Limin ^[1]; Henning, Sheryl ^[2]; Xiao, Chunhong ^[2];

^[1];

^[1]

Department of Chemical Engineering and Materials Science University of Minnesota Washington Ave SE Minneapolis MN 55455 USA
Thermo Fisher Scientific 5225 Verona Road Madison WI 53711 USA

Publication Date:: Wed Sep 19 00:00:00 EDT 2018

Sponsoring Org.:: USDOE

OSTI Identifier:: 1472171

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Angewandte Chemie (International Edition)

Additional Journal Information:: Journal Name: Angewandte Chemie (International Edition) Journal Volume: 57 Journal Issue: 41; Journal ID: ISSN 1433-7851

Publisher:: Wiley Blackwell (John Wiley & Sons)

Country of Publication:: Germany

Language:: English

Citation Formats


                    Conrad, Sabrina, Kumar, Prashant, Xue, Feng, Ren, Limin, Henning, Sheryl, Xiao, Chunhong, Mkhoyan, K. Andre, and Tsapatsis, Michael. Controlling Dissolution and Transformation of Zeolitic Imidazolate Frameworks by using Electron‐Beam‐Induced Amorphization.  Germany: N. p., 2018. 
Web.  doi:10.1002/anie.201809921.

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                    Conrad, Sabrina, Kumar, Prashant, Xue, Feng, Ren, Limin, Henning, Sheryl, Xiao, Chunhong, Mkhoyan, K. Andre, & Tsapatsis, Michael. Controlling Dissolution and Transformation of Zeolitic Imidazolate Frameworks by using Electron‐Beam‐Induced Amorphization.  Germany.  https://doi.org/10.1002/anie.201809921

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                    Conrad, Sabrina, Kumar, Prashant, Xue, Feng, Ren, Limin, Henning, Sheryl, Xiao, Chunhong, Mkhoyan, K. Andre, and Tsapatsis, Michael. Wed .  
"Controlling Dissolution and Transformation of Zeolitic Imidazolate Frameworks by using Electron‐Beam‐Induced Amorphization".  Germany.  https://doi.org/10.1002/anie.201809921.

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@article{osti_1472171,

  title        = {Controlling Dissolution and Transformation of Zeolitic Imidazolate Frameworks by using Electron‐Beam‐Induced Amorphization},

  author       = {Conrad, Sabrina and Kumar, Prashant and Xue, Feng and Ren, Limin and Henning, Sheryl and Xiao, Chunhong and Mkhoyan, K. Andre and Tsapatsis, Michael},

  abstractNote = {Abstract Amorphous zeolitic imidazolate frameworks (ZIFs) offer promising applications as novel functional materials. Herein, amorphization of ZIF‐L through scanning‐electron‐beam exposure is demonstrated, based on amorphization of individual ZIF‐L crystals. The amorphized ZIF product has drastically increased stability against dissolution in water. An electron dose that allows for complete preservation of amorphous particles after immersion in water is established, resulting in new shapes of amorphous ZIF‐L with spatial control at the sub‐micrometer length scale. Changed water stability as a consequence of scanning‐electron‐beam exposure is demonstrated for three additional metal–organic frameworks (ZIF‐8, Zn(BeIm)OAc, MIL‐101), highlighting the potential use of an electron beam for top‐down MOF patterning. Lastly, recrystallization of ZIF‐L in the presence of linker is studied and shows distinct differences for crystalline and amorphized material.},

  doi          = {10.1002/anie.201809921},

  journal      = {Angewandte Chemie (International Edition)},

  number       = 41,

  volume       = 57,

  place        = {Germany},

  year         = {Wed Sep 19 00:00:00 EDT 2018},

  month        = {Wed Sep 19 00:00:00 EDT 2018}

}

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Title: Controlling Dissolution and Transformation of Zeolitic Imidazolate Frameworks by using Electron‐Beam‐Induced Amorphization

Abstract

Citation Formats

Heteroepitaxially Grown Zeolitic Imidazolate Framework Membranes with Unprecedented Propylene/Propane Separation Performances journal, September 2015

Transmission Electron Microscopy book, January 2009

Facile Mechanosynthesis of Amorphous Zeolitic Imidazolate Frameworks journal, September 2011

Kovalente postsynthetische Funktionalisierung einer ZIF-90-MOF-Membran zur Erhöhung ihrer Wasserstoffselektivität journal, March 2011

Amorphization of Metal–Organic Framework MOF-5 by Electrical Discharge journal, February 2011

Chemical vapour deposition of zeolitic imidazolate framework thin films journal, December 2015

Top-down patterning of Zeolitic Imidazolate Framework composite thin films by deep X-ray lithography journal, January 2012

A two-dimensional zeolitic imidazolate framework with a cushion-shaped cavity for CO2 adsorption journal, January 2013

Electron diffraction and HRTEM imaging of beam-sensitive materials journal, July 2011

Stripping off hydrogens in imidazole triggered by the attachment of a single electron journal, January 2017

Radiation damage in the TEM and SEM journal, August 2004

Control of radiation damage in the TEM journal, April 2013

Covalent Post-Functionalization of Zeolitic Imidazolate Framework ZIF-90 Membrane for Enhanced Hydrogen Selectivity journal, March 2011

Thermal Amorphization of Zeolitic Imidazolate Frameworks journal, February 2011

Exceptional chemical and thermal stability of zeolitic imidazolate frameworks journal, June 2006

Amorphous metal–organic frameworks for drug delivery journal, January 2015

Ball-Milling-Induced Amorphization of Zeolitic Imidazolate Frameworks (ZIFs) for the Irreversible Trapping of Iodine journal, April 2013

Reversible pressure-induced amorphization of a zeolitic imidazolate framework (ZIF-4) journal, January 2011

Crystals as Molecules Postsynthesis Covalent Functionalization of Zeolitic Imidazolate Frameworks journal, September 2008

Structure and Properties of an Amorphous Metal-Organic Framework journal, March 2010

Selective gas adsorption and separation in metal–organic frameworks journal, January 2009

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Crystal Transformation in Zeolitic-Imidazolate Framework journal, October 2014

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An updated roadmap for the integration of metal–organic frameworks with electronic devices and chemical sensors journal, January 2017

Pressure-Induced Amorphization and Porosity Modification in a Metal−Organic Framework journal, December 2009

Heteroepitaxially Grown Zeolitic Imidazolate Framework Membranes with Unprecedented Propylene/Propane Separation Performances
journal, September 2015

Transmission Electron Microscopy
book, January 2009

Facile Mechanosynthesis of Amorphous Zeolitic Imidazolate Frameworks
journal, September 2011

Kovalente postsynthetische Funktionalisierung einer ZIF-90-MOF-Membran zur Erhöhung ihrer Wasserstoffselektivität
journal, March 2011

Amorphization of Metal–Organic Framework MOF-5 by Electrical Discharge
journal, February 2011

Chemical vapour deposition of zeolitic imidazolate framework thin films
journal, December 2015

Top-down patterning of Zeolitic Imidazolate Framework composite thin films by deep X-ray lithography
journal, January 2012

A two-dimensional zeolitic imidazolate framework with a cushion-shaped cavity for CO2 adsorption
journal, January 2013

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journal, July 2011

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journal, January 2017

Radiation damage in the TEM and SEM
journal, August 2004

Control of radiation damage in the TEM
journal, April 2013

Covalent Post-Functionalization of Zeolitic Imidazolate Framework ZIF-90 Membrane for Enhanced Hydrogen Selectivity
journal, March 2011

Thermal Amorphization of Zeolitic Imidazolate Frameworks
journal, February 2011

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journal, June 2006

Amorphous metal–organic frameworks for drug delivery
journal, January 2015

Ball-Milling-Induced Amorphization of Zeolitic Imidazolate Frameworks (ZIFs) for the Irreversible Trapping of Iodine
journal, April 2013

Reversible pressure-induced amorphization of a zeolitic imidazolate framework (ZIF-4)
journal, January 2011

Crystals as Molecules Postsynthesis Covalent Functionalization of Zeolitic Imidazolate Frameworks
journal, September 2008

Structure and Properties of an Amorphous Metal-Organic Framework
journal, March 2010

Selective gas adsorption and separation in metal–organic frameworks
journal, January 2009

MOF positioning technology and device fabrication
journal, January 2014

Tetrahedral vs Octahedral Zinc Complexes with Ligands of Biological Interest: A DFT/CDM Study
journal, November 2000

Crystal Transformation in Zeolitic-Imidazolate Framework
journal, October 2014

Transition from ZIF-L-Co to ZIF-67: a new insight into the structural evolution of zeolitic imidazolate frameworks (ZIFs) in aqueous systems
journal, January 2015

Zeolitic imidazolate framework materials: recent progress in synthesis and applications
journal, January 2014

Transmission electron microscopy on metal–organic frameworks – a review
journal, January 2017

Synthesis, Structure, and Carbon Dioxide Capture Properties of Zeolitic Imidazolate Frameworks
journal, January 2010

Amorphous Metal–Organic Frameworks
journal, April 2014

The Silica-Like Extended Polymorphism of Cobalt(II) Imidazolate Three-Dimensional Frameworks: X-ray Single-Crystal Structures and Magnetic Properties
journal, November 2003

Thermal Amorphization of Zeolitic Imidazolate Frameworks
journal, February 2011

An updated roadmap for the integration of metal–organic frameworks with electronic devices and chemical sensors
journal, January 2017

Pressure-Induced Amorphization and Porosity Modification in a Metal−Organic Framework
journal, December 2009