Development of a gall-resistant stainless-steel hardfacing alloy
Abstract
Here, this work details the development of a new cobalt-free stainless steel powder metallurgy hardfacing alloy designed to replace Stellite 6, a cobalt-based hardfacing alloy used in nuclear valve applications. The fundamental strategy centers on alloying stainless steels with up to 0.5 wt% nitrogen, which is shown to increase both the volume fraction of hard phase precipitates and the strain-hardening rate of the matrix. The resultant alloy, Nitromaxx, exhibits galling performance that is comparable to Stellite 6, up to 350 °C. This performance is attributed to the suppression of strain localization events associated with galling. In particular, transmission electron microscopy and diffraction measurements from tensile tests show that the nitrogen addition decreases the calculated matrix stacking fault energy and enhances both deformation-induced martensite transformation at room temperature and deformation twinning at elevated temperature. These strain-hardening mechanisms, coupled with the increase in precipitate volume fraction, effectively suppress localization and enhance galling resistance up to 350 °C. Lastly, the enhanced galling resistance cannot be rationalized in terms of tensile stress-strain response alone.
- Authors:
-
- California Polytechnic State University, San Luis Obispo, CA (United States)
- The Ohio State Univ., Columbus, OH (United States). Dept. Materials Science and Engineering
- The Electric Power Research Institute, Charlotte, NC (United States)
- Univ. of Tennessee, Knoxville, TN (United States). Dept. Mechanical, Aerospace, and Biomedical Engineering
- Brazilian Nanotechnology National Laboratory-LNNano, Campinas, SP (Brazil)
- Publication Date:
- Research Org.:
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1471842
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Materials & Design
- Additional Journal Information:
- Journal Volume: 143; Journal Issue: C; Journal ID: ISSN 0264-1275
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; Wear; Alloy design; Stainless steel; Phase transformation; Twinning; Stacking fault energy
Citation Formats
Smith, Ryan, Doran, Marc, Gandy, David, Babu, Suresh, Wu, Leonardo, Ramirez, Antonio J., and Anderson, Peter M. Development of a gall-resistant stainless-steel hardfacing alloy. United States: N. p., 2018.
Web. doi:10.1016/j.matdes.2018.01.020.
Smith, Ryan, Doran, Marc, Gandy, David, Babu, Suresh, Wu, Leonardo, Ramirez, Antonio J., & Anderson, Peter M. Development of a gall-resistant stainless-steel hardfacing alloy. United States. https://doi.org/10.1016/j.matdes.2018.01.020
Smith, Ryan, Doran, Marc, Gandy, David, Babu, Suresh, Wu, Leonardo, Ramirez, Antonio J., and Anderson, Peter M. Fri .
"Development of a gall-resistant stainless-steel hardfacing alloy". United States. https://doi.org/10.1016/j.matdes.2018.01.020. https://www.osti.gov/servlets/purl/1471842.
@article{osti_1471842,
title = {Development of a gall-resistant stainless-steel hardfacing alloy},
author = {Smith, Ryan and Doran, Marc and Gandy, David and Babu, Suresh and Wu, Leonardo and Ramirez, Antonio J. and Anderson, Peter M.},
abstractNote = {Here, this work details the development of a new cobalt-free stainless steel powder metallurgy hardfacing alloy designed to replace Stellite 6, a cobalt-based hardfacing alloy used in nuclear valve applications. The fundamental strategy centers on alloying stainless steels with up to 0.5 wt% nitrogen, which is shown to increase both the volume fraction of hard phase precipitates and the strain-hardening rate of the matrix. The resultant alloy, Nitromaxx, exhibits galling performance that is comparable to Stellite 6, up to 350 °C. This performance is attributed to the suppression of strain localization events associated with galling. In particular, transmission electron microscopy and diffraction measurements from tensile tests show that the nitrogen addition decreases the calculated matrix stacking fault energy and enhances both deformation-induced martensite transformation at room temperature and deformation twinning at elevated temperature. These strain-hardening mechanisms, coupled with the increase in precipitate volume fraction, effectively suppress localization and enhance galling resistance up to 350 °C. Lastly, the enhanced galling resistance cannot be rationalized in terms of tensile stress-strain response alone.},
doi = {10.1016/j.matdes.2018.01.020},
journal = {Materials & Design},
number = C,
volume = 143,
place = {United States},
year = {Fri Jan 12 00:00:00 EST 2018},
month = {Fri Jan 12 00:00:00 EST 2018}
}
Web of Science
Figures / Tables:
Works referenced in this record:
Nitrogen Containing Austenitic Stainless Steels
journal, October 2006
- Speidel, M. O.
- Materialwissenschaft und Werkstofftechnik, Vol. 37, Issue 10
Temperature Dependence of Tensile Behaviors of Nitrogen-Alloyed Austenitic Stainless Steels
journal, February 2010
- Wang, Wei; Yan, Wei; Yang, Ke
- Journal of Materials Engineering and Performance, Vol. 19, Issue 8
The Effect of Chemical Composition and Heat Treatment Conditions on Stacking Fault Energy for Fe-Cr-Ni Austenitic Stainless Steel
journal, August 2013
- Yonezawa, Toshio; Suzuki, Ken; Ooki, Suguru
- Metallurgical and Materials Transactions A, Vol. 44, Issue 13
Revisiting Stacking Fault Energy of Steels
journal, December 2015
- Das, Arpan
- Metallurgical and Materials Transactions A, Vol. 47, Issue 2
Creep–fatigue interaction behavior of 316LN austenitic stainless steel with varying nitrogen content
journal, December 2015
- Prasad Reddy, G. V.; Sandhya, R.; Sankaran, S.
- Materials & Design, Vol. 88
Kinetics of strain-induced martensitic nucleation
journal, April 1975
- Olson, G. B.; Cohen, Morris
- Metallurgical Transactions A, Vol. 6, Issue 4
A constitutive model for analyzing martensite formation in austenitic steels deforming at high strain rates
journal, February 2012
- Zaera, R.; Rodríguez-Martínez, J. A.; Casado, A.
- International Journal of Plasticity, Vol. 29
A microstructural investigation on deformation mechanisms of Fe–18Cr–12Mn–0.05C metastable austenitic steels containing different amounts of nitrogen
journal, October 2015
- Kermanpur, A.; Behjati, P.; Han, J.
- Materials & Design, Vol. 82
In situ observation of strain and phase transformation in plastically deformed 301 austenitic stainless steel
journal, December 2016
- Das, Yadunandan B.; Forsey, Alexander N.; Simm, Thomas H.
- Materials & Design, Vol. 112
Strength, damage and fracture behaviors of high-nitrogen austenitic stainless steel processed by high-pressure torsion
journal, February 2015
- Dong, F. Y.; Zhang, P.; Pang, J. C.
- Scripta Materialia, Vol. 96
A study on high temperature gas nitriding and tempering heat treatment in 17Cr–1Ni–0.5C
journal, May 2009
- Lee, H. W.; Kong, J. H.; Lee, D. J.
- Materials & Design, Vol. 30, Issue 5
A galling-resistant substitute for silicon nickel
journal, August 2003
- Budinski, Kenneth G.; Budinski, Michael K.; Kohler, Mark S.
- Wear, Vol. 255, Issue 1-6
Deformation behavior of additively manufactured GP1 stainless steel
journal, June 2017
- Clausen, B.; Brown, D. W.; Carpenter, J. S.
- Materials Science and Engineering: A, Vol. 696
Effect of processing parameters on microstructure and tensile properties of austenitic stainless steel 304L made by directed energy deposition additive manufacturing
journal, May 2016
- Wang, Zhuqing; Palmer, Todd A.; Beese, Allison M.
- Acta Materialia, Vol. 110
Wear Evaluation of High Interstitial Stainless Steels
journal, July 2008
- Rawers, J. C.; Tylczak, J. H.; Alman, D. E.
- Tribology Transactions, Vol. 51, Issue 4
Twinning and strain-induced f.c.c. → h.c.p. transformation on the mechanical properties of CoNiCrMo alloys
journal, November 1976
- Rémy, L.; Pineau, A.
- Materials Science and Engineering, Vol. 26, Issue 1
Effect of stacking fault energy on work hardening behaviors in Fe–Mn–Si–C high manganese steels by varying silicon and carbon contents
journal, November 2015
- Xiong, Renlong; Peng, Huabei; Wang, Shanling
- Materials & Design, Vol. 85
Strain hardening and transformation mechanism of deformation-induced martensite transformation in metastable austenitic stainless steels
journal, August 1991
- Fang, X. F.; Dahl, W.
- Materials Science and Engineering: A, Vol. 141, Issue 2
Formation of shear bands and strain-induced martensite during plastic deformation of metastable austenitic stainless steels
journal, October 2007
- Talonen, J.; Hänninen, H.
- Acta Materialia, Vol. 55, Issue 18
The unlubricated adhesive wear resistance of metastable austenitic stainless steels containing silicon
journal, April 1977
- Dumbleton, John H.; Douthett, Joseph A.
- Wear, Vol. 42, Issue 2
The Compressive Response of Idealized Cermetlike Materials
journal, April 2015
- Bele, Eral; Deshpande, Vikram S.
- Journal of Applied Mechanics, Vol. 82, Issue 4
Deformation twinning in high-nitrogen austenitic stainless steel
journal, June 2007
- Lee, T. -H.; Oh, C. -S.; Kim, S. -J.
- Acta Materialia, Vol. 55, Issue 11
Nitrogen in chromium–manganese stainless steels: a review on the evaluation of stacking fault energy by computational thermodynamics
journal, March 2013
- Mosecker, Linda; Saeed-Akbari, Alireza
- Science and Technology of Advanced Materials, Vol. 14, Issue 3
Effect of nitrogen on stacking fault energy of f.c.c. iron-based alloys
journal, March 1999
- Yakubtsov, I. A.; Ariapour, A.; Perovic, D. D.
- Acta Materialia, Vol. 47, Issue 4
Thermodynamic modeling of the stacking fault energy of austenitic steels
journal, February 2011
- Curtze, S.; Kuokkala, V. -T.; Oikari, A.
- Acta Materialia, Vol. 59, Issue 3
Temperature dependence of stacking fault energy in close-packed metals and alloys
journal, November 1978
- Rémy, L.; Pineau, A.; Thomas, B.
- Materials Science and Engineering, Vol. 36, Issue 1
The role of stacking fault energy on galling and wear behavior
journal, January 1982
- Bhansali, K. J.; Miller, A. E.
- Wear, Vol. 75, Issue 2
Effect of alloying and heat treatment on the structure and tribological properties of nitrogen-bearing stainless austenitic steels under abrasive and adhesive wear
journal, May 2007
- Korshunov, L. G.; Goikhenberg, Yu. N.; Chernenko, N. K.
- Metal Science and Heat Treatment, Vol. 49, Issue 5-6
The temperature dependence of the wear resistance of iron-base NOREM 02 hardfacing alloy
journal, February 2000
- Kim, Jun-Ki; Kim, Seon-Jin
- Wear, Vol. 237, Issue 2
In situ X-ray diffraction analysis of strain-induced transformations in Fe- and Co-base hardfacing alloys
journal, March 2015
- Smith, R. T.; Lolla, T.; Gandy, D.
- Scripta Materialia, Vol. 98
Thermo-Calc & DICTRA, computational tools for materials science
journal, June 2002
- Andersson, J-O; Helander, Thomas; Höglund, Lars
- Calphad, Vol. 26, Issue 2
High Nitrogen Steels. Nitrogen in Iron and Steel.
journal, January 1996
- Gavriljuk, Valentin G.
- ISIJ International, Vol. 36, Issue 7
Relation between lattice expansion and nitrogen content in expanded phase in austenitic stainless steel and CoCr alloys
journal, July 2011
- Manova, D.; Lutz, J.; Gerlach, J. W.
- Surface and Coatings Technology, Vol. 205
Modelling kinetics of strain-induced martensite transformation during plastic deformation of austenitic stainless steel
journal, November 2016
- Ahmedabadi, Parag M.; Kain, Vivekanand; Agrawal, Ashika
- Materials & Design, Vol. 109
Twin-induced grain boundary engineering for 316 austenitic stainless steel
journal, November 2006
- Michiuchi, M.; Kokawa, H.; Wang, Z. J.
- Acta Materialia, Vol. 54, Issue 19
Stacking Fault Energy in Silicon
journal, October 1962
- Aerts, E.; Delavignette, P.; Siems, R.
- Journal of Applied Physics, Vol. 33, Issue 10
Stacking fault energies of seven commercial austenitic stainless steels
journal, July 1975
- Schramm, R. E.; Reed, R. P.
- Metallurgical Transactions A, Vol. 6, Issue 7
The influence of manganese content on the stacking fault and austenite/ε-martensite interfacial energies in Fe–Mn–(Al–Si) steels investigated by experiment and theory
journal, April 2014
- Pierce, D. T.; Jiménez, J. A.; Bentley, J.
- Acta Materialia, Vol. 68
Figures / Tables found in this record: