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Title: Energetics of defect production in fluorite-structured CeO 2 induced by highly ionizing radiation

Authors:
; ; ;
Publication Date:
Sponsoring Org.:
USDOE National Nuclear Security Administration (NNSA)
OSTI Identifier:
1471437
Grant/Contract Number:  
SC0001089; AC02-06CH11357; NA-0002006
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Physical Review Materials
Additional Journal Information:
Journal Name: Physical Review Materials Journal Volume: 2 Journal Issue: 9; Journal ID: ISSN 2475-9953
Publisher:
American Physical Society
Country of Publication:
United States
Language:
English

Citation Formats

Shelyug, A., Palomares, R. I., Lang, M., and Navrotsky, A. Energetics of defect production in fluorite-structured CeO 2 induced by highly ionizing radiation. United States: N. p., 2018. Web. doi:10.1103/PhysRevMaterials.2.093607.
Shelyug, A., Palomares, R. I., Lang, M., & Navrotsky, A. Energetics of defect production in fluorite-structured CeO 2 induced by highly ionizing radiation. United States. doi:10.1103/PhysRevMaterials.2.093607.
Shelyug, A., Palomares, R. I., Lang, M., and Navrotsky, A. Wed . "Energetics of defect production in fluorite-structured CeO 2 induced by highly ionizing radiation". United States. doi:10.1103/PhysRevMaterials.2.093607.
@article{osti_1471437,
title = {Energetics of defect production in fluorite-structured CeO 2 induced by highly ionizing radiation},
author = {Shelyug, A. and Palomares, R. I. and Lang, M. and Navrotsky, A.},
abstractNote = {},
doi = {10.1103/PhysRevMaterials.2.093607},
journal = {Physical Review Materials},
number = 9,
volume = 2,
place = {United States},
year = {2018},
month = {9}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1103/PhysRevMaterials.2.093607

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Works referenced in this record:

Defect accumulation in ThO2 irradiated with swift heavy ions
journal, May 2014

  • Tracy, Cameron L.; McLain Pray, J.; Lang, Maik
  • Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Vol. 326
  • DOI: 10.1016/j.nimb.2013.08.070

First-principles computational study of defect clustering in solid solutions of ThO 2 with trivalent oxides
journal, November 2010

  • Alexandrov, Vitaly; Grønbech-Jensen, Niels; Navrotsky, Alexandra
  • Physical Review B, Vol. 82, Issue 17
  • DOI: 10.1103/PhysRevB.82.174115

Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides
journal, September 1976


Nuclear track irradiations at GSI
journal, June 1980


Change in magnetic properties induced by swift heavy ion irradiation in CeO2
journal, September 2012

  • Shimizu, K.; Kosugi, S.; Tahara, Y.
  • Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Vol. 286
  • DOI: 10.1016/j.nimb.2012.01.008

Raman and x‐ray studies of Ce 1− x RE x O 2− y , where RE=La, Pr, Nd, Eu, Gd, and Tb
journal, August 1994

  • McBride, J. R.; Hass, K. C.; Poindexter, B. D.
  • Journal of Applied Physics, Vol. 76, Issue 4
  • DOI: 10.1063/1.357593

Recovery and restructuring induced by fission energy ions in high burnup nuclear fuel
journal, March 2009

  • Kinoshita, M.; Yasunaga, K.; Sonoda, T.
  • Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Vol. 267, Issue 6
  • DOI: 10.1016/j.nimb.2009.02.022

Energetics of radiation damage in natural zircon (ZrSiO4)
journal, July 1994

  • Ellsworth, Susan; Navrotsky, Alexandra; Ewing, Rodney C.
  • Physics and Chemistry of Minerals, Vol. 21, Issue 3
  • DOI: 10.1007/BF00203144

GSAS-II : the genesis of a modern open-source all purpose crystallography software package
journal, March 2013


Swift heavy ions in magnetic insulators: A damage-cross-section velocity effect
journal, July 1993


Radiation tolerance of fluorite-structured oxides subjected to swift heavy ion irradiation
journal, May 2009

  • Garrido, Frédérico; Moll, Sandra; Sattonnay, Gaël
  • Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Vol. 267, Issue 8-9
  • DOI: 10.1016/j.nimb.2009.01.070

Grain size effects on irradiated CeO2, ThO2, and UO2
journal, November 2018


Lattice strain in irradiated materials unveils a prevalent defect evolution mechanism
journal, January 2018


A Coulomb explosion theoretical model of femtosecond laser ablation materials
journal, December 2011

  • Lin, XiaoHui; Chen, HaiQuan; Jiang, ShuYun
  • Science China Technological Sciences, Vol. 55, Issue 3
  • DOI: 10.1007/s11431-011-4702-8

Applicability of CeO2 as a surrogate for PuO2 in a MOX fuel development
journal, August 2008


Reduced cerium oxide as an efficient and durable high temperature desulfurization sorbent
journal, November 2000


SRIM – The stopping and range of ions in matter (2010)
journal, June 2010

  • Ziegler, James F.; Ziegler, M. D.; Biersack, J. P.
  • Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Vol. 268, Issue 11-12
  • DOI: 10.1016/j.nimb.2010.02.091

Making tracks: electronic excitation roles in forming swift heavy ion tracks
journal, November 2009


Radiation Tolerance of Complex Oxides
journal, August 2000


Progress and new directions in high temperature calorimetry revisited
journal, April 1997


Accommodation of excess oxygen in fluorite dioxides
journal, December 2013


Effect of grain size and microstructure on radiation stability of CeO 2 : an extensive study
journal, January 2014

  • Grover, V.; Shukla, R.; Kumari, Renu
  • Phys. Chem. Chem. Phys., Vol. 16, Issue 48
  • DOI: 10.1039/C4CP04215H

Quantum Origin of the Oxygen Storage Capability of Ceria
journal, September 2002


Lattice distortions and oxygen vacancies produced in Au+-irradiated nanocrystalline cubic zirconia
journal, October 2011


First-principles study on cerium ion behavior in irradiated cerium dioxide
journal, September 2009


Some recent developments in the characterization of ceria-based catalysts
journal, July 2001


Effect of ion velocity on creation of point defects halos of latent tracks in LiF
journal, September 2017

  • Volkov, A. E.; Schwartz, K.; Medvedev, N. A.
  • Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Vol. 407
  • DOI: 10.1016/j.nimb.2017.05.065

The high burn-up structure in nuclear fuel
journal, December 2010


Direct Measurement of Surface Energy of CeO2 by Differential Scanning Calorimetry
journal, September 2011


Size dependency variation in lattice parameter and valency states in nanocrystalline cerium oxide
journal, September 2005

  • Deshpande, Sameer; Patil, Swanand; Kuchibhatla, Satyanarayana VNT
  • Applied Physics Letters, Vol. 87, Issue 13
  • DOI: 10.1063/1.2061873

In situ defect annealing of swift heavy ion irradiated CeO 2 and ThO 2 using synchrotron X-ray diffraction and a hydrothermal diamond anvil cell
journal, April 2015

  • Palomares, Raul I.; Tracy, Cameron L.; Zhang, Fuxiang
  • Journal of Applied Crystallography, Vol. 48, Issue 3
  • DOI: 10.1107/S160057671500477X

Study of CeO 2 and Its Native Defects by Density Functional Theory with Repulsive Potential
journal, October 2014

  • Huang, Bolong; Gillen, Roland; Robertson, John
  • The Journal of Physical Chemistry C, Vol. 118, Issue 42
  • DOI: 10.1021/jp506625h

Alpha-irradiation damage in CeO 2 , UO 2 and PuO 2
journal, January 1984


Binomial distribution function for intuitive understanding of fluence dependence of non-amorphized ion-track area
journal, October 2010

  • Ishikawa, N.; Ohhara, K.; Ohta, Y.
  • Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Vol. 268, Issue 19
  • DOI: 10.1016/j.nimb.2010.06.006

Coulomb Explosion and Thermal Spikes
journal, April 2002


Nanoscale phase transitions under extreme conditions within an ion track
journal, July 2010

  • Zhang, Jiaming; Lang, Maik; Ewing, Rodney C.
  • Journal of Materials Research, Vol. 25, Issue 7
  • DOI: 10.1557/JMR.2010.0180

Dynamic annealing of defects in irradiated zirconia-based ceramics
journal, March 2008

  • Devanathan, Ram; Weber, William J.
  • Journal of Materials Research, Vol. 23, Issue 3
  • DOI: 10.1557/JMR.2008.0104

Radiation stability of fluorite-type nuclear oxides
journal, June 2008

  • Garrido, Frédérico; Vincent, Laetitia; Nowicki, Lech
  • Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Vol. 266, Issue 12-13
  • DOI: 10.1016/j.nimb.2008.03.128

Characterization of swift heavy ion irradiation damage in ceria
journal, March 2015

  • Yablinsky, Clarissa A.; Devanathan, Ram; Pakarinen, Janne
  • Journal of Materials Research, Vol. 30, Issue 9
  • DOI: 10.1557/jmr.2015.43

Understanding Ceria Nanoparticles from First-Principles Calculations
journal, July 2007

  • Loschen, Christoph; Bromley, Stefan T.; Neyman, Konstantin M.
  • The Journal of Physical Chemistry C, Vol. 111, Issue 28
  • DOI: 10.1021/jp072787m

Redox Behavior of High-Surface-Area Rh-, Pt-, and Pd-Loaded Ce0.5Zr0.5O2Mixed Oxide
journal, February 1999

  • Fornasiero, Paolo; Kašpar, Jan; Sergo, Valter
  • Journal of Catalysis, Vol. 182, Issue 1
  • DOI: 10.1006/jcat.1998.2321

Lattice Defects and Oxygen Storage Capacity of Nanocrystalline Ceria and Ceria-Zirconia
journal, November 2000

  • Mamontov, E.; Egami, T.; Brezny, R.
  • The Journal of Physical Chemistry B, Vol. 104, Issue 47
  • DOI: 10.1021/jp0023011

Redox response of actinide materials to highly ionizing radiation
journal, January 2015

  • Tracy, Cameron L.; Lang, Maik; Pray, John M.
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms7133

Oxygen Defects and Surface Chemistry of Ceria: Quantum Chemical Studies Compared to Experiment
journal, December 2012

  • Paier, Joachim; Penschke, Christopher; Sauer, Joachim
  • Chemical Reviews, Vol. 113, Issue 6
  • DOI: 10.1021/cr3004949

Analysis of Intrinsic Defects in CeO 2 Using a Koopmans-Like GGA+ U Approach
journal, November 2011

  • Keating, Patrick R. L.; Scanlon, David O.; Morgan, Benjamin J.
  • The Journal of Physical Chemistry C, Vol. 116, Issue 3
  • DOI: 10.1021/jp2080034

PDFfit2 and PDFgui: computer programs for studying nanostructure in crystals
journal, July 2007


Thermodynamic and structural evolution of Dy2Ti2O7 pyrochlore after swift heavy ion irradiation
journal, February 2018


Electron Localization Determines Defect Formation on Ceria Substrates
journal, July 2005


Progress and new directions in high temperature calorimetry
journal, January 1977

  • Navrotsky, Alexandra
  • Physics and Chemistry of Minerals, Vol. 2, Issue 1-2
  • DOI: 10.1007/BF00307526

Molecular Dynamics Simulation of Fission Fragment Damage in Nuclear Fuel and Surrogate Material
journal, January 2017


Progress and New Directions in Calorimetry: A 2014 Perspective
journal, October 2014

  • Navrotsky, Alexandra
  • Journal of the American Ceramic Society, Vol. 97, Issue 11
  • DOI: 10.1111/jace.13278

Interface Energies of Nanocrystalline Doped Ceria: Effects of Manganese Segregation
journal, November 2015

  • Wu, Longjia; Aguiar, Jeffery A.; Dholabhai, Pratik P.
  • The Journal of Physical Chemistry C, Vol. 119, Issue 49
  • DOI: 10.1021/acs.jpcc.5b09255

Raman scattering in uranium dioxide
journal, August 1966


Atomic structure of ion tracks in Ceria
journal, May 2014

  • Takaki, S.; Yasuda, K.; Yamamoto, T.
  • Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Vol. 326
  • DOI: 10.1016/j.nimb.2013.10.077

Size dependent oxygen buffering capacity of ceria nanocrystals
journal, January 2010

  • Xu, Jiahui; Harmer, Jeffrey; Li, Guoqiang
  • Chemical Communications, Vol. 46, Issue 11
  • DOI: 10.1039/b923780a

Ab initio analysis of the defect structure of ceria
journal, April 2013


Adsorption of Gases in Multimolecular Layers
journal, February 1938

  • Brunauer, Stephen; Emmett, P. H.; Teller, Edward
  • Journal of the American Chemical Society, Vol. 60, Issue 2, p. 309-319
  • DOI: 10.1021/ja01269a023

Ordering of oxygen vacancies and excess charge localization in bulk ceria: A DFT + U study
journal, September 2014

  • Murgida, G. E.; Ferrari, V.; Ganduglia-Pirovano, M. Verónica
  • Physical Review B, Vol. 90, Issue 11
  • DOI: 10.1103/PhysRevB.90.115120

Energetics of stepwise disordering transformation in pyrochlores, RE2Ti2O7 (RE=Y, Gd and Dy)
journal, June 2012


Oxygen defects created in CeO2 irradiated with 200MeV Au ions
journal, March 2009

  • Ohhara, K.; Ishikawa, N.; Sakai, S.
  • Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Vol. 267, Issue 6
  • DOI: 10.1016/j.nimb.2009.02.034

Damage creation via electronic excitations in metallic targets part II : A theoretical model
journal, March 1993


Ab initio molecular dynamics simulations of low-energy recoil events in ThO 2 , CeO 2 , and ZrO 2
journal, August 2012


Ceria and Its Defect Structure: New Insights from a Combined Spectroscopic Approach
journal, March 2016

  • Filtschew, Anastasia; Hofmann, Kathrin; Hess, Christian
  • The Journal of Physical Chemistry C, Vol. 120, Issue 12
  • DOI: 10.1021/acs.jpcc.6b00959

Defect accumulation in swift heavy ion-irradiated CeO 2 and ThO 2
journal, January 2017

  • Palomares, Raul I.; Shamblin, Jacob; Tracy, Cameron L.
  • Journal of Materials Chemistry A, Vol. 5, Issue 24
  • DOI: 10.1039/C7TA02640D

Thermal annealing of natural, radiation-damaged pyrochlore
journal, January 2017

  • Zietlow, Peter; Beirau, Tobias; Mihailova, Boriana
  • Zeitschrift für Kristallographie - Crystalline Materials, Vol. 232, Issue 1-3
  • DOI: 10.1515/zkri-2016-1965

Stability and migration of charged oxygen interstitials in ThO2 and CeO2
journal, December 2013


Raman spectroscopy study of damage induced in cerium dioxide by swift heavy ion irradiations
journal, November 2017

  • Costantini, Jean-Marc; Miro, Sandrine; Gutierrez, Gaëlle
  • Journal of Applied Physics, Vol. 122, Issue 20
  • DOI: 10.1063/1.5011165

Heavy ion carcinogenesis and human space exploration
journal, May 2008

  • Durante, Marco; Cucinotta, Francis A.
  • Nature Reviews Cancer, Vol. 8, Issue 6, p. 465-472
  • DOI: 10.1038/nrc2391

Nanoscale Manipulation of Pyrochlore: New Nanocomposite Ionic Conductors
journal, September 2001