Viscoelastic optical nonlocality of low-loss epsilon-near-zero nanofilms
Abstract
Optical nonlocalities are elusive and hardly observable in traditional plasmonic materials like noble and alkali metals. Here we report experimental observation of viscoelastic nonlocalities in the infrared optical response of epsilon-near-zero nanofilms made of low-loss doped cadmium-oxide. The nonlocality is detectable thanks to the low damping rate of conduction electrons and the virtual absence of interband transitions at infrared wavelengths. We describe the motion of conduction electrons using a hydrodynamic model for a viscoelastic fluid, and find excellent agreement with experimental results. The electrons’ elasticity blue-shifts the infrared plasmonic resonance associated with the main epsilon-near-zero mode, and triggers the onset of higher-order resonances due to the excitation of electron-pressure modes above the bulk plasma frequency. We also provide evidence of the existence of nonlocal damping, i.e., viscosity, in the motion of optically-excited conduction electrons using a combination of spectroscopic ellipsometry data and predictions based on the viscoelastic hydrodynamic model.
- Authors:
-
- Univ. of Padova (Italy)
- US Army AMRDEC, Redstone Arsenal, AL (United STates)
- Univ. of Brescia (Italy)
- Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
- North Carolina State Univ., Raleigh, NC (United States)
- Publication Date:
- Research Org.:
- Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
- Sponsoring Org.:
- USDOE National Nuclear Security Administration (NNSA)
- OSTI Identifier:
- 1469653
- Report Number(s):
- SAND2017-9205J
Journal ID: ISSN 2045-2322; PII: 27655
- Grant/Contract Number:
- AC04-94AL85000
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Scientific Reports
- Additional Journal Information:
- Journal Volume: 8; Journal Issue: 1; Journal ID: ISSN 2045-2322
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 42 ENGINEERING
Citation Formats
de Ceglia, Domenico, Scalora, Michael, Vincenti, Maria A., Campione, Salvatore, Kelley, Kyle, Runnerstrom, Evan L., Maria, Jon-Paul, Keeler, Gordon A., and Luk, Ting S. Viscoelastic optical nonlocality of low-loss epsilon-near-zero nanofilms. United States: N. p., 2018.
Web. doi:10.1038/s41598-018-27655-z.
de Ceglia, Domenico, Scalora, Michael, Vincenti, Maria A., Campione, Salvatore, Kelley, Kyle, Runnerstrom, Evan L., Maria, Jon-Paul, Keeler, Gordon A., & Luk, Ting S. Viscoelastic optical nonlocality of low-loss epsilon-near-zero nanofilms. United States. https://doi.org/10.1038/s41598-018-27655-z
de Ceglia, Domenico, Scalora, Michael, Vincenti, Maria A., Campione, Salvatore, Kelley, Kyle, Runnerstrom, Evan L., Maria, Jon-Paul, Keeler, Gordon A., and Luk, Ting S. Tue .
"Viscoelastic optical nonlocality of low-loss epsilon-near-zero nanofilms". United States. https://doi.org/10.1038/s41598-018-27655-z. https://www.osti.gov/servlets/purl/1469653.
@article{osti_1469653,
title = {Viscoelastic optical nonlocality of low-loss epsilon-near-zero nanofilms},
author = {de Ceglia, Domenico and Scalora, Michael and Vincenti, Maria A. and Campione, Salvatore and Kelley, Kyle and Runnerstrom, Evan L. and Maria, Jon-Paul and Keeler, Gordon A. and Luk, Ting S.},
abstractNote = {Optical nonlocalities are elusive and hardly observable in traditional plasmonic materials like noble and alkali metals. Here we report experimental observation of viscoelastic nonlocalities in the infrared optical response of epsilon-near-zero nanofilms made of low-loss doped cadmium-oxide. The nonlocality is detectable thanks to the low damping rate of conduction electrons and the virtual absence of interband transitions at infrared wavelengths. We describe the motion of conduction electrons using a hydrodynamic model for a viscoelastic fluid, and find excellent agreement with experimental results. The electrons’ elasticity blue-shifts the infrared plasmonic resonance associated with the main epsilon-near-zero mode, and triggers the onset of higher-order resonances due to the excitation of electron-pressure modes above the bulk plasma frequency. We also provide evidence of the existence of nonlocal damping, i.e., viscosity, in the motion of optically-excited conduction electrons using a combination of spectroscopic ellipsometry data and predictions based on the viscoelastic hydrodynamic model.},
doi = {10.1038/s41598-018-27655-z},
journal = {Scientific Reports},
number = 1,
volume = 8,
place = {United States},
year = {Tue Jun 19 00:00:00 EDT 2018},
month = {Tue Jun 19 00:00:00 EDT 2018}
}
Web of Science
Works referenced in this record:
Resonance shifts and spill-out effects in self-consistent hydrodynamic nanoplasmonics
journal, May 2015
- Toscano, Giuseppe; Straubel, Jakob; Kwiatkowski, Alexander
- Nature Communications, Vol. 6, Issue 1
Infrared Absorption at Longitudinal Optic Frequency in Cubic Crystal Films
journal, June 1963
- Berreman, D. W.
- Physical Review, Vol. 130, Issue 6
Quantum hydrodynamic theory for plasmonics: Impact of the electron density tail
journal, May 2016
- Ciracì, Cristian; Della Sala, Fabio
- Physical Review B, Vol. 93, Issue 20
Enhanced third harmonic generation from the epsilon-near-zero modes of ultrathin films
journal, April 2015
- Luk, Ting S.; de Ceglia, Domenico; Liu, Sheng
- Applied Physics Letters, Vol. 106, Issue 15, Article No. 151103
Quantum hydrodynamic model for the nonlinear electron dynamics in thin metal films
journal, October 2008
- Crouseilles, N.; Hervieux, P. -A.; Manfredi, G.
- Physical Review B, Vol. 78, Issue 15
Nonlinear plasmonics
journal, November 2012
- Kauranen, Martti; Zayats, Anatoly V.
- Nature Photonics, Vol. 6, Issue 11
Bandgap and effective mass of epitaxial cadmium oxide
journal, January 2008
- Jefferson, P. H.; Hatfield, S. A.; Veal, T. D.
- Applied Physics Letters, Vol. 92, Issue 2
Surface Plasmons on Smooth and Rough Surfaces and on Gratings
book, January 1988
- Raether, Heinz
- Springer Tracts in Modern Physics
Low-Loss Plasmonic Metamaterials
journal, January 2011
- Boltasseva, A.; Atwater, H. A.
- Science, Vol. 331, Issue 6015, p. 290-291
Theory of epsilon-near-zero modes in ultrathin films
journal, March 2015
- Campione, Salvatore; Brener, Igal; Marquier, Francois
- Physical Review B, Vol. 91, Issue 12, Article No. 121408(R)
Femtosecond optical polarization switching using a cadmium oxide-based perfect absorber
journal, May 2017
- Yang, Yuanmu; Kelley, Kyle; Sachet, Edward
- Nature Photonics, Vol. 11, Issue 6
Enhanced third-harmonic generation in Si-compatible epsilon-near-zero indium tin oxide nanolayers
journal, January 2015
- Capretti, Antonio; Wang, Yu; Engheta, Nader
- Optics Letters, Vol. 40, Issue 7
Nanoscale Control of Optical Heating in Complex Plasmonic Systems
journal, January 2010
- Baffou, Guillaume; Quidant, Romain; García de Abajo, F. Javier
- ACS Nano, Vol. 4, Issue 2
Nonlocal Effects in the Plasmons of Strongly Interacting Nanoparticles, Dimers, and Waveguides
journal, October 2008
- García de Abajo, F. Javier
- The Journal of Physical Chemistry C, Vol. 112, Issue 46
Large optical nonlinearity of indium tin oxide in its epsilon-near-zero region
journal, April 2016
- Alam, M. Z.; De Leon, I.; Boyd, R. W.
- Science, Vol. 352, Issue 6287
Enhanced Solar-to-Hydrogen Generation with Broadband Epsilon-Near-Zero Nanostructured Photocatalysts
journal, May 2017
- Tian, Yi; García de Arquer, Francisco Pelayo; Dinh, Cao-Thang
- Advanced Materials, Vol. 29, Issue 27
Coupling of Epsilon-Near-Zero Mode to Gap Plasmon Mode for Flat-Top Wideband Perfect Light Absorption
journal, December 2017
- Hendrickson, Joshua R.; Vangala, Shivashankar; Dass, Chandriker
- ACS Photonics, Vol. 5, Issue 3
Predicted Radiation of Plasma Oscillations in Metal Films
journal, September 1958
- Ferrell, Richard A.
- Physical Review, Vol. 111, Issue 5
Bridging quantum and classical plasmonics with a quantum-corrected model
journal, January 2012
- Esteban, Ruben; Borisov, Andrei G.; Nordlander, Peter
- Nature Communications, Vol. 3, Issue 1
Determining the nonparabolicity factor of the CdO conduction band using indium doping and the Drude theory
journal, October 2012
- Mendelsberg, Rueben J.; Zhu, Yuankun; Anders, André
- Journal of Physics D: Applied Physics, Vol. 45, Issue 42
Scalable, ultra-resistant structural colors based on network metamaterials
journal, September 2016
- Galinski, Henning; Favraud, Gael; Dong, Hao
- Light: Science & Applications, Vol. 6, Issue 5
Broadband polarization-independent resonant light absorption using ultrathin plasmonic super absorbers
journal, November 2011
- Aydin, Koray; Ferry, Vivian E.; Briggs, Ryan M.
- Nature Communications, Vol. 2, Article No. 517
Experimental verification of epsilon-near-zero plasmon polariton modes in degenerately doped semiconductor nanolayers
journal, January 2016
- Campione, Salvatore; Kim, Iltai; de Ceglia, Domenico
- Optics Express, Vol. 24, Issue 16
Plasma Losses by Fast Electrons in Thin Films
journal, June 1957
- Ritchie, R. H.
- Physical Review, Vol. 106, Issue 5
Quantum plasmonics
journal, June 2013
- Tame, M. S.; McEnery, K. R.; Özdemir, Ş. K.
- Nature Physics, Vol. 9, Issue 6
Real and Imaginary Properties of Epsilon-Near-Zero Materials
journal, September 2016
- Javani, Mohammad H.; Stockman, Mark I.
- Physical Review Letters, Vol. 117, Issue 10
Directional perfect absorption using deep subwavelength low-permittivity films
journal, August 2014
- Luk, Ting S.; Campione, Salvatore; Kim, Iltai
- Physical Review B, Vol. 90, Issue 8, Article No. 085411
Experimental Verification of Optically Excited Longitudinal Plasmons
journal, February 1971
- Lindau, I.; Nilsson, P. O.
- Physica Scripta, Vol. 3, Issue 2
Biosensing with plasmonic nanosensors
journal, June 2008
- Anker, Jeffrey N.; Hall, W. Paige; Lyandres, Olga
- Nature Materials, Vol. 7, Issue 6
Berreman mode and epsilon near zero mode
journal, January 2012
- Vassant, Simon; Hugonin, Jean-Paul; Marquier, Francois
- Optics Express, Vol. 20, Issue 21, p. 23971-23977
Plasmon dispersion in single-crystal magnesium
journal, June 1976
- Chen, C. H.
- Journal of Physics C: Solid State Physics, Vol. 9, Issue 12
Electric field enhancement in -near-zero slabs under TM-polarized oblique incidence
journal, January 2013
- Campione, Salvatore; de Ceglia, Domenico; Vincenti, Maria Antonietta
- Physical Review B, Vol. 87, Issue 3, Article No. 035120
Electron energy-loss spectroscopy in the TEM
journal, December 2008
- Egerton, R. F.
- Reports on Progress in Physics, Vol. 72, Issue 1
The mean free path of electrons in metals
journal, January 1952
- Sondheimer, E. H.
- Advances in Physics, Vol. 1, Issue 1
Plasmonics: Merging Photonics and Electronics at Nanoscale Dimensions
journal, January 2006
- Ozbay, E.
- Science, Vol. 311, Issue 5758
Dysprosium-doped cadmium oxide as a gateway material for mid-infrared plasmonics
journal, February 2015
- Sachet, Edward; Shelton, Christopher T.; Harris, Joshua S.
- Nature Materials, Vol. 14, Issue 4
Hydrodynamic theory of an electron gas
journal, December 1999
- Tokatly, I.; Pankratov, O.
- Physical Review B, Vol. 60, Issue 23
Quantum conductivity for metal–insulator–metal nanostructures
journal, January 2014
- Haus, Joseph W.; de Ceglia, Domenico; Vincenti, Maria Antonietta
- Journal of the Optical Society of America B, Vol. 31, Issue 2
Island size effects in nanoparticle-enhanced photodetectors
journal, December 1998
- Stuart, Howard R.; Hall, Dennis G.
- Applied Physics Letters, Vol. 73, Issue 26
Current-dependent potential for nonlocal absorption in quantum hydrodynamic theory
journal, June 2017
- Ciracì, Cristian
- Physical Review B, Vol. 95, Issue 24
Quantum Plasmonics: Nonlinear Effects in the Field Enhancement of a Plasmonic Nanoparticle Dimer
journal, February 2012
- Marinica, D. C.; Kazansky, A. K.; Nordlander, P.
- Nano Letters, Vol. 12, Issue 3
Manipulating thermal emission with spatially static fluctuating fields in arbitrarily shaped epsilon-near-zero bodies
journal, March 2018
- Liberal, Iñigo; Engheta, Nader
- Proceedings of the National Academy of Sciences, Vol. 115, Issue 12
Broadband Epsilon-near-Zero Reflectors Enhance the Quantum Efficiency of Thin Solar Cells at Visible and Infrared Wavelengths
journal, February 2017
- Labelle, A. J.; Bonifazi, M.; Tian, Y.
- ACS Applied Materials & Interfaces, Vol. 9, Issue 6
Elasticity of an electron liquid
journal, September 1999
- Conti, S.; Vignale, G.
- Physical Review B, Vol. 60, Issue 11
Spatial Nonlocality in the Optical Response of Metal Nanoparticles
journal, September 2011
- David, Christin; García de Abajo, F. Javier
- The Journal of Physical Chemistry C, Vol. 115, Issue 40
Epsilon-near-zero Al-doped ZnO for ultrafast switching at telecom wavelengths
journal, January 2015
- Kinsey, N.; DeVault, C.; Kim, J.
- Optica, Vol. 2, Issue 7
Submicrometer Epsilon-Near-Zero Electroabsorption Modulators Enabled by High-Mobility Cadmium Oxide
journal, August 2017
- Campione, Salvatore; Wood, Michael G.; Serkland, Darwin K.
- IEEE Photonics Journal, Vol. 9, Issue 4
A generalized non-local optical response theory for plasmonic nanostructures
journal, May 2014
- Mortensen, N. A.; Raza, S.; Wubs, M.
- Nature Communications, Vol. 5, Issue 1
The mean free path of electrons in metals
journal, September 2001
- Sondheimer, E. H.
- Advances in Physics, Vol. 50, Issue 6
Scalable, ultra-resistant structural colors based on network metamaterials
text, January 2017
- Galinski, Henning; Favraud, Gael; Dong, Hao
- ETH Zurich
Resonance shifts and spill-out effects in self-consistent hydrodynamic nanoplasmonics
text, January 2015
- Toscano, Giuseppe; Straubel, Jakob; Kwiatkowski, Alexander
- Universität Regensburg
Quantum plasmonics
conference, September 2013
- Fyodorov, Ilya; Sarychev, Andrey K.; Tartakovsky, Gennady
- SPIE NanoScience + Engineering, SPIE Proceedings
Quantum Conductivity for Metal-Insulator-Metal Nanostructures
text, January 2013
- Haus, Joseph W.; de Ceglia, Domenico; Vincenti, Maria Antonietta
- arXiv
Scalable, ultra-resistant structural colors based on network metamaterials
preprint, January 2016
- Galinski, Henning; Favraud, Gael; Dong, Hao
- arXiv
Enhanced Solar-to-Hydrogen Generation with Broadband Epsilon-Near-Zero Nanostructured Photocatalysts
journal, May 2017
- Tian, Yi; García de Arquer, Francisco Pelayo; Dinh, Cao-Thang
- Advanced Materials, Vol. 29, Issue 27
Broadband Epsilon-near-Zero Reflectors Enhance the Quantum Efficiency of Thin Solar Cells at Visible and Infrared Wavelengths
journal, February 2017
- Labelle, A. J.; Bonifazi, M.; Tian, Y.
- ACS Applied Materials & Interfaces, Vol. 9, Issue 6
Coupling of Epsilon-Near-Zero Mode to Gap Plasmon Mode for Flat-Top Wideband Perfect Light Absorption
journal, December 2017
- Hendrickson, Joshua R.; Vangala, Shivashankar; Dass, Chandriker
- ACS Photonics, Vol. 5, Issue 3
Quantum Plasmonics: Nonlinear Effects in the Field Enhancement of a Plasmonic Nanoparticle Dimer
journal, February 2012
- Marinica, D. C.; Kazansky, A. K.; Nordlander, P.
- Nano Letters, Vol. 12, Issue 3
Nanoscale Control of Optical Heating in Complex Plasmonic Systems
journal, January 2010
- Baffou, Guillaume; Quidant, Romain; García de Abajo, F. Javier
- ACS Nano, Vol. 4, Issue 2
A generalized non-local optical response theory for plasmonic nanostructures
journal, May 2014
- Mortensen, N. A.; Raza, S.; Wubs, M.
- Nature Communications, Vol. 5, Issue 1
Biosensing with plasmonic nanosensors
journal, June 2008
- Anker, Jeffrey N.; Hall, W. Paige; Lyandres, Olga
- Nature Materials, Vol. 7, Issue 6
Dysprosium-doped cadmium oxide as a gateway material for mid-infrared plasmonics
journal, February 2015
- Sachet, Edward; Shelton, Christopher T.; Harris, Joshua S.
- Nature Materials, Vol. 14, Issue 4
Nonlinear plasmonics
journal, November 2012
- Kauranen, Martti; Zayats, Anatoly V.
- Nature Photonics, Vol. 6, Issue 11
Quantum plasmonics
journal, June 2013
- Tame, M. S.; McEnery, K. R.; Özdemir, Ş. K.
- Nature Physics, Vol. 9, Issue 6
Island size effects in nanoparticle-enhanced photodetectors
journal, December 1998
- Stuart, Howard R.; Hall, Dennis G.
- Applied Physics Letters, Vol. 73, Issue 26
Bandgap and effective mass of epitaxial cadmium oxide
journal, January 2008
- Jefferson, P. H.; Hatfield, S. A.; Veal, T. D.
- Applied Physics Letters, Vol. 92, Issue 2
Manipulating thermal emission with spatially static fluctuating fields in arbitrarily shaped epsilon-near-zero bodies
journal, March 2018
- Liberal, Iñigo; Engheta, Nader
- Proceedings of the National Academy of Sciences, Vol. 115, Issue 12
The mean free path of electrons in metals
journal, September 2001
- Sondheimer, E. H.
- Advances in Physics, Vol. 50, Issue 6
Plasmon dispersion in single-crystal magnesium
journal, June 1976
- Chen, C. H.
- Journal of Physics C: Solid State Physics, Vol. 9, Issue 12
Experimental Verification of Optically Excited Longitudinal Plasmons
journal, February 1971
- Lindau, I.; Nilsson, P. O.
- Physica Scripta, Vol. 3, Issue 2
Electron energy-loss spectroscopy in the TEM
journal, December 2008
- Egerton, R. F.
- Reports on Progress in Physics, Vol. 72, Issue 1
Density response function and the dynamic structure factor of thin metal films: Nonlocal effects
journal, February 1979
- Eguiluz, Adolfo
- Physical Review B, Vol. 19, Issue 4
Hydrodynamic model for the degenerate free-electron gas: Generalization to arbitrary frequencies
journal, March 1995
- Halevi, P.
- Physical Review B, Vol. 51, Issue 12
Plasmon Response of a Quantum-Confined Electron Gas Probed by Core-Level Photoemission
journal, May 2011
- Özer, Mustafa M.; Moon, Eun Ju; Eguiluz, Adolfo G.
- Physical Review Letters, Vol. 106, Issue 19
Optically Excited Longitudinal Plasmons in Potassium
journal, December 1971
- Anderegg, M.; Feuerbacher, B.; Fitton, B.
- Physical Review Letters, Vol. 27, Issue 23
Plasmonics: Merging Photonics and Electronics at Nanoscale Dimensions
journal, January 2006
- Ozbay, E.
- Science, Vol. 311, Issue 5758
Numerical tool to take nonlocal effects into account in metallo-dielectric multilayers
journal, January 2015
- Benedicto, Jessica; Pollès, Rémi; Ciracì, Cristian
- Journal of the Optical Society of America A, Vol. 32, Issue 8
Nonlinear quantum tunneling effects in nanoplasmonic environments: two-photon absorption and harmonic generation
journal, January 2014
- Haus, Joseph W.; de Ceglia, Domenico; Vincenti, Maria Antonietta
- Journal of the Optical Society of America B, Vol. 31, Issue 6
Nanoplasmonics: past, present, and glimpse into future
journal, January 2011
- Stockman, Mark I.
- Optics Express, Vol. 19, Issue 22
Resonance shifts and spill-out effects in self-consistent hydrodynamic nanoplasmonics
text, January 2014
- Toscano, Giuseppe; Straubel, Jakob; Kwiatkowski, Alexander
- arXiv
Scalable, ultra-resistant structural colors based on network metamaterials
preprint, January 2016
- Galinski, Henning; Favraud, Gael; Dong, Hao
- arXiv
Current-dependent exchange-correlation potential for non-local absorption in quantum hydrodynamic theory
text, January 2016
- Ciracì, Cristian
- arXiv
Works referencing / citing this record:
Modeling and observation of mid-infrared nonlocality in effective epsilon-near-zero ultranarrow coaxial apertures
journal, October 2019
- Yoo, Daehan; Vidal-Codina, Ferran; Ciracì, Cristian
- Nature Communications, Vol. 10, Issue 1
Nonlinear optical effects in epsilon-near-zero media
journal, June 2019
- Reshef, Orad; De Leon, Israel; Alam, M. Zahirul
- Nature Reviews Materials, Vol. 4, Issue 8
Quantum hydrodynamics for plasmas— Quo vadis ?
journal, September 2019
- Bonitz, M.; Moldabekov, Zh. A.; Ramazanov, T. S.
- Physics of Plasmas, Vol. 26, Issue 9
Study of second and third harmonic generation from an indium tin oxide nanolayer: Influence of nonlocal effects and hot electrons
journal, January 2020
- Rodríguez-Suné, L.; Scalora, M.; Johnson, A. S.
- APL Photonics, Vol. 5, Issue 1
Hydrodynamic acoustic plasmon resonances in semiconductor nanowires and their dimers
journal, January 2019
- Golestanizadeh, Tahereh; Zarifi, Abbas; Jalali, Tahmineh
- Journal of the Optical Society of America B, Vol. 36, Issue 10
Hydrodynamic acoustic plasmon resonances in semiconductor nanowires and their dimers
text, January 2019
- Golestanizadeh, Tahereh; Zarifi, Abbas; Jalali, Tahmineh
- arXiv
Study of second and third harmonic generation from an indium tin oxide nanolayer: influence of nonlocal effects and hot electrons
preprint, January 2019
- Rodriguez-Sune, Laura; Scalora, Michael; Johnson, Allan
- arXiv
Theory of Optical Nonlocality in Polar Dielectrics
text, January 2019
- Gubbin, Christopher R.; De Liberato, Simone
- arXiv
Study of second and third harmonic generation from an indium tin oxide nanolayer: influence of nonlocal effects and hot electrons
preprint, January 2019
- Rodriguez-Sune, Laura; Scalora, Michael; Johnson, Allan
- arXiv
Laplacian-Level Quantum Hydrodynamic Theory for Plasmonics
text, January 2020
- Baghramyan, Henrikh M.; Della Sala, Fabio; Ciracì, Cristian
- arXiv
Free electron nonlinearities in heavily doped semiconductors plasmonics
text, January 2020
- De Luca, Federico; Ortolani, Michele; Ciracì, Cristian
- arXiv