Correlating Preparative Approaches with Electrochemical Performance of Fe3O4-MWNT Composites Used as Anodes in Li-Ion Batteries
Abstract
Fe3O4 nanoparticles (NPs) with an average size of 8-10 nm and a loading ratio of 50 wt% have been successfully attached onto the external surfaces of multi-walled carbon nanotubes (MWNTs) by means of three different preparative approaches, namely a sonication method, a covalent attachment protocol, as well as a non-covalent π-π interaction strategy. Specifically, the Fe3O4 NPs associated with the sonication method lie directly on the outer surfaces of the MWNTs. Particles covalently attached onto the MWNTs formed amide chemical bonds through the mediation of the amorphous (3- aminopropyl) triethoxysilane (APTES) linker. Finally, particles were anchored noncovalently onto the underlying conjugated MWNTs via an aromatic 4-mercaptobenzoic acid (4-MBA) linker. Both structural and electrochemical characterization protocols have been used to systematically correlate the electrode performance with the corresponding attachment strategies. Fe3O4-MWNT composites generated by the π-π interaction strategy delivered 813, 768, 729, 796, 630, 580, 522, and 762 mAh/g under rates of 200, 400, 800, 100, 1200, 1600, 2000, and 100 mA/g, with 72% retention between cycles 2 and 80, demonstrating both higher capacity and better cycling stability as compared with analogues derived from the physical sonication as well as covalent attachment strategies. This finding may be attributed to the enhancedmore »
- Authors:
-
- State Univ. of New York (SUNY), Stony Brook, NY (United States)
- State Univ. of New York (SUNY), Stony Brook, NY (United States); Brookhaven National Lab. (BNL), Upton, NY (United States)
- Publication Date:
- Research Org.:
- Brookhaven National Laboratory (BNL), Upton, NY (United States); Energy Frontier Research Centers (EFRC) (United States). Center for Mesoscale Transport Properties (m2M)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1466619
- Report Number(s):
- BNL-207970-2018-JAAM
Journal ID: ISSN 2162-8769
- Grant/Contract Number:
- SC0012704; SC0012673
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ECS Journal of Solid State Science and Technology
- Additional Journal Information:
- Journal Volume: 6; Journal Issue: 6; Journal ID: ISSN 2162-8769
- Publisher:
- Electrochemical Society
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; magnetite; multi-walled carbon nanotubes; anode materials; Li-ion batteries; attachment modality
Citation Formats
Wang, Lei, Li, Yue Ru, Li, Jing, Zou, Shihui, Stach, Eric A., Takeuchi, Kenneth J., Takeuchi, Esther S., Marschilok, Amy C., and Wong, Stanislaus S. Correlating Preparative Approaches with Electrochemical Performance of Fe3O4-MWNT Composites Used as Anodes in Li-Ion Batteries. United States: N. p., 2017.
Web. doi:10.1149/2.0231706jss.
Wang, Lei, Li, Yue Ru, Li, Jing, Zou, Shihui, Stach, Eric A., Takeuchi, Kenneth J., Takeuchi, Esther S., Marschilok, Amy C., & Wong, Stanislaus S. Correlating Preparative Approaches with Electrochemical Performance of Fe3O4-MWNT Composites Used as Anodes in Li-Ion Batteries. United States. https://doi.org/10.1149/2.0231706jss
Wang, Lei, Li, Yue Ru, Li, Jing, Zou, Shihui, Stach, Eric A., Takeuchi, Kenneth J., Takeuchi, Esther S., Marschilok, Amy C., and Wong, Stanislaus S. Thu .
"Correlating Preparative Approaches with Electrochemical Performance of Fe3O4-MWNT Composites Used as Anodes in Li-Ion Batteries". United States. https://doi.org/10.1149/2.0231706jss. https://www.osti.gov/servlets/purl/1466619.
@article{osti_1466619,
title = {Correlating Preparative Approaches with Electrochemical Performance of Fe3O4-MWNT Composites Used as Anodes in Li-Ion Batteries},
author = {Wang, Lei and Li, Yue Ru and Li, Jing and Zou, Shihui and Stach, Eric A. and Takeuchi, Kenneth J. and Takeuchi, Esther S. and Marschilok, Amy C. and Wong, Stanislaus S.},
abstractNote = {Fe3O4 nanoparticles (NPs) with an average size of 8-10 nm and a loading ratio of 50 wt% have been successfully attached onto the external surfaces of multi-walled carbon nanotubes (MWNTs) by means of three different preparative approaches, namely a sonication method, a covalent attachment protocol, as well as a non-covalent π-π interaction strategy. Specifically, the Fe3O4 NPs associated with the sonication method lie directly on the outer surfaces of the MWNTs. Particles covalently attached onto the MWNTs formed amide chemical bonds through the mediation of the amorphous (3- aminopropyl) triethoxysilane (APTES) linker. Finally, particles were anchored noncovalently onto the underlying conjugated MWNTs via an aromatic 4-mercaptobenzoic acid (4-MBA) linker. Both structural and electrochemical characterization protocols have been used to systematically correlate the electrode performance with the corresponding attachment strategies. Fe3O4-MWNT composites generated by the π-π interaction strategy delivered 813, 768, 729, 796, 630, 580, 522, and 762 mAh/g under rates of 200, 400, 800, 100, 1200, 1600, 2000, and 100 mA/g, with 72% retention between cycles 2 and 80, demonstrating both higher capacity and better cycling stability as compared with analogues derived from the physical sonication as well as covalent attachment strategies. This finding may be attributed to the enhanced charge and ion transport coupled with retention of physical contact with the underlying MWNTs after a large volume change during cycling. Our collective results suggest that the non-covalent π-π attachment modality is a more effective preparative strategy for enhancing the performance of MWNT-Fe3O4 composite electrodes after a full discharge process.},
doi = {10.1149/2.0231706jss},
journal = {ECS Journal of Solid State Science and Technology},
number = 6,
volume = 6,
place = {United States},
year = {Thu Feb 16 00:00:00 EST 2017},
month = {Thu Feb 16 00:00:00 EST 2017}
}
Web of Science
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