Elevated‐Temperature 3D Printing of Hybrid Solid‐State Electrolyte for Li‐Ion Batteries
Abstract
Abstract While 3D printing of rechargeable batteries has received immense interest in advancing the next generation of 3D energy storage devices, challenges with the 3D printing of electrolytes still remain. Additional processing steps such as solvent evaporation were required for earlier studies of electrolyte fabrication, which hindered the simultaneous production of electrode and electrolyte in an all‐3D‐printed battery. Here, a novel method is demonstrated to fabricate hybrid solid‐state electrolytes using an elevated‐temperature direct ink writing technique without any additional processing steps. The hybrid solid‐state electrolyte consists of solid poly(vinylidene fluoride‐hexafluoropropylene) matrices and a Li + ‐conducting ionic‐liquid electrolyte. The ink is modified by adding nanosized ceramic fillers to achieve the desired rheological properties. The ionic conductivity of the inks is 0.78 × 10 −3 S cm −1 . Interestingly, a continuous, thin, and dense layer is discovered to form between the porous electrolyte layer and the electrode, which effectively reduces the interfacial resistance of the solid‐state battery. Compared to the traditional methods of solid‐state battery assembly, the directly printed electrolyte helps to achieve higher capacities and a better rate performance. The direct fabrication of electrolyte from printable inks at an elevated temperature will shed new light on the design ofmore »
- Authors:
-
[1];
- Department of Mechanical and Industrial Engineering University of Illinois at Chicago Chicago IL 60607 USA
- Department of Mechanical Engineering‐Engineering Mechanics Michigan Technological University Houghton MI 49931 USA
- Department of Mechanical and Industrial Engineering University of Illinois at Chicago Chicago IL 60607 USA, Chemical Science and Engineering Division Argonne National Laboratory Chicago IL 60439 USA
- Department of Bioengineering University of Illinois at Chicago Chicago IL 60607 USA
- Chemical Science and Engineering Division Argonne National Laboratory Chicago IL 60439 USA
- Department of Mechanical and Industrial Engineering University of Illinois at Chicago Chicago IL 60607 USA, Department of Mechanical Engineering‐Engineering Mechanics Michigan Technological University Houghton MI 49931 USA
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1465897
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- Advanced Materials
- Additional Journal Information:
- Journal Name: Advanced Materials Journal Volume: 30 Journal Issue: 39; Journal ID: ISSN 0935-9648
- Publisher:
- Wiley Blackwell (John Wiley & Sons)
- Country of Publication:
- Germany
- Language:
- English
Citation Formats
Cheng, Meng, Jiang, Yizhou, Yao, Wentao, Yuan, Yifei, Deivanayagam, Ramasubramonian, Foroozan, Tara, Huang, Zhennan, Song, Boao, Rojaee, Ramin, Shokuhfar, Tolou, Pan, Yayue, Lu, Jun, and Shahbazian‐Yassar, Reza. Elevated‐Temperature 3D Printing of Hybrid Solid‐State Electrolyte for Li‐Ion Batteries. Germany: N. p., 2018.
Web. doi:10.1002/adma.201800615.
Cheng, Meng, Jiang, Yizhou, Yao, Wentao, Yuan, Yifei, Deivanayagam, Ramasubramonian, Foroozan, Tara, Huang, Zhennan, Song, Boao, Rojaee, Ramin, Shokuhfar, Tolou, Pan, Yayue, Lu, Jun, & Shahbazian‐Yassar, Reza. Elevated‐Temperature 3D Printing of Hybrid Solid‐State Electrolyte for Li‐Ion Batteries. Germany. https://doi.org/10.1002/adma.201800615
Cheng, Meng, Jiang, Yizhou, Yao, Wentao, Yuan, Yifei, Deivanayagam, Ramasubramonian, Foroozan, Tara, Huang, Zhennan, Song, Boao, Rojaee, Ramin, Shokuhfar, Tolou, Pan, Yayue, Lu, Jun, and Shahbazian‐Yassar, Reza. Tue .
"Elevated‐Temperature 3D Printing of Hybrid Solid‐State Electrolyte for Li‐Ion Batteries". Germany. https://doi.org/10.1002/adma.201800615.
@article{osti_1465897,
title = {Elevated‐Temperature 3D Printing of Hybrid Solid‐State Electrolyte for Li‐Ion Batteries},
author = {Cheng, Meng and Jiang, Yizhou and Yao, Wentao and Yuan, Yifei and Deivanayagam, Ramasubramonian and Foroozan, Tara and Huang, Zhennan and Song, Boao and Rojaee, Ramin and Shokuhfar, Tolou and Pan, Yayue and Lu, Jun and Shahbazian‐Yassar, Reza},
abstractNote = {Abstract While 3D printing of rechargeable batteries has received immense interest in advancing the next generation of 3D energy storage devices, challenges with the 3D printing of electrolytes still remain. Additional processing steps such as solvent evaporation were required for earlier studies of electrolyte fabrication, which hindered the simultaneous production of electrode and electrolyte in an all‐3D‐printed battery. Here, a novel method is demonstrated to fabricate hybrid solid‐state electrolytes using an elevated‐temperature direct ink writing technique without any additional processing steps. The hybrid solid‐state electrolyte consists of solid poly(vinylidene fluoride‐hexafluoropropylene) matrices and a Li + ‐conducting ionic‐liquid electrolyte. The ink is modified by adding nanosized ceramic fillers to achieve the desired rheological properties. The ionic conductivity of the inks is 0.78 × 10 −3 S cm −1 . Interestingly, a continuous, thin, and dense layer is discovered to form between the porous electrolyte layer and the electrode, which effectively reduces the interfacial resistance of the solid‐state battery. Compared to the traditional methods of solid‐state battery assembly, the directly printed electrolyte helps to achieve higher capacities and a better rate performance. The direct fabrication of electrolyte from printable inks at an elevated temperature will shed new light on the design of all‐3D‐printed batteries for next‐generation electronic devices.},
doi = {10.1002/adma.201800615},
journal = {Advanced Materials},
number = 39,
volume = 30,
place = {Germany},
year = {Tue Aug 21 00:00:00 EDT 2018},
month = {Tue Aug 21 00:00:00 EDT 2018}
}
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1002/adma.201800615
https://doi.org/10.1002/adma.201800615
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 125 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Organ printing: computer-aided jet-based 3D tissue engineering
journal, April 2003
- Mironov, Vladimir; Boland, Thomas; Trusk, Thomas
- Trends in Biotechnology, Vol. 21, Issue 4
3D-Printing Electrolytes for Solid-State Batteries
journal, March 2018
- McOwen, Dennis W.; Xu, Shaomao; Gong, Yunhui
- Advanced Materials, Vol. 30, Issue 18
3D-Printed Cathodes of LiMn 1− x Fe x PO 4 Nanocrystals Achieve Both Ultrahigh Rate and High Capacity for Advanced Lithium-Ion Battery
journal, June 2016
- Hu, Jiangtao; Jiang, Yi; Cui, Suihan
- Advanced Energy Materials, Vol. 6, Issue 18
Research on Advanced Materials for Li-ion Batteries
journal, December 2009
- Li, Hong; Wang, Zhaoxiang; Chen, Liquan
- Advanced Materials, Vol. 21, Issue 45, p. 4593-4607
Additive manufacturing of tissues and organs
journal, August 2012
- Melchels, Ferry P. W.; Domingos, Marco A. N.; Klein, Travis J.
- Progress in Polymer Science, Vol. 37, Issue 8
Computer Simulations of Ion Transport in Polymer Electrolyte Membranes
journal, June 2016
- Mogurampelly, Santosh; Borodin, Oleg; Ganesan, Venkat
- Annual Review of Chemical and Biomolecular Engineering, Vol. 7, Issue 1
Evaluation of 3D Printing and Its Potential Impact on Biotechnology and the Chemical Sciences
journal, January 2014
- Gross, Bethany C.; Erkal, Jayda L.; Lockwood, Sarah Y.
- Analytical Chemistry, Vol. 86, Issue 7
Hybrid electrolytes with 3D bicontinuous ordered ceramic and polymer microchannels for all-solid-state batteries
journal, January 2018
- Zekoll, Stefanie; Marriner-Edwards, Cassian; Hekselman, A. K. Ola
- Energy & Environmental Science, Vol. 11, Issue 1
An improved process to prepare high separation performance PA/PVDF hollow fiber composite nanofiltration membranes
journal, December 2007
- Liu, J.; Xu, Z.; Li, X.
- Separation and Purification Technology, Vol. 58, Issue 1
Preparation and electrochemical characterization of electrospun, microporous membrane-based composite polymer electrolytes for lithium batteries
journal, April 2008
- Kim, Jae-Kwang; Cheruvally, Gouri; Li, Xin
- Journal of Power Sources, Vol. 178, Issue 2
A review of the present situation and future developments of micro-batteries for wireless autonomous sensor systems: Micro-batteries for wireless autonomous sensor systems
journal, August 2012
- Oudenhoven, J. F. M.; Vullers, R. J. M.; Schaijk, R.
- International Journal of Energy Research, Vol. 36, Issue 12
Ionic liquid polymer electrolytes
journal, January 2013
- Ye, Yun-Sheng; Rick, John; Hwang, Bing-Joe
- J. Mater. Chem. A, Vol. 1, Issue 8
Direct writing of copper conductive patterns by ink-jet printing
journal, July 2007
- Park, Bong Kyun; Kim, Dongjo; Jeong, Sunho
- Thin Solid Films, Vol. 515, Issue 19
Processing of Iron Oxide-epoxy Vinyl Ester Nanocomposites
journal, March 2003
- Park, S. S.; Bernet, N.; de la Roche, S.
- Journal of Composite Materials, Vol. 37, Issue 5
“Grafting to” route to PVDF-HFP-GMA/BaTiO3 nanocomposites with high dielectric constant and high thermal conductivity for energy storage and thermal management applications
journal, January 2014
- Xie, Liyuan; Huang, Xingyi; Yang, Ke
- Journal of Materials Chemistry A, Vol. 2, Issue 15
Conformal Printing of Electrically Small Antennas on Three-Dimensional Surfaces
journal, January 2011
- Adams, Jacob J.; Duoss, Eric B.; Malkowski, Thomas F.
- Advanced Materials, Vol. 23, Issue 11
3D Printing of Interdigitated Li-Ion Microbattery Architectures
journal, June 2013
- Sun, Ke; Wei, Teng-Sing; Ahn, Bok Yeop
- Advanced Materials, Vol. 25, Issue 33, p. 4539-4543
Graphene Oxide-Based Electrode Inks for 3D-Printed Lithium-Ion Batteries
journal, February 2016
- Fu, Kun; Wang, Yibo; Yan, Chaoyi
- Advanced Materials, Vol. 28, Issue 13
Review of gel-type polymer electrolytes for lithium-ion batteries
journal, February 1999
- Song, J. Y.; Wang, Y. Y.; Wan, C. C.
- Journal of Power Sources, Vol. 77, Issue 2, p. 183-197
Nanomaterials for Rechargeable Lithium Batteries
journal, April 2008
- Bruce, Peter G.; Scrosati, Bruno; Tarascon, Jean-Marie
- Angewandte Chemie International Edition, Vol. 47, Issue 16, p. 2930-2946
3D Printing for the Rapid Prototyping of Structural Electronics
journal, December 2014
- Macdonald, Eric; Salas, Rudy; Espalin, David
- IEEE Access, Vol. 2
Design Considerations for Unconventional Electrochemical Energy Storage Architectures
journal, July 2015
- Vlad, Alexandru; Singh, Neelam; Galande, Charudatta
- Advanced Energy Materials, Vol. 5, Issue 19
Linear viscoelasticity and dynamics of suspensions and molten polymers filled with nanoparticles of different aspect ratios
journal, August 2013
- Cassagnau, Philippe
- Polymer, Vol. 54, Issue 18
Review on composite polymer electrolytes for lithium batteries
journal, July 2006
- Manuel Stephan, A.; Nahm, K. S.
- Polymer, Vol. 47, Issue 16
Additive manufacturing and its societal impact: a literature review
journal, October 2012
- Huang, Samuel H.; Liu, Peng; Mokasdar, Abhiram
- The International Journal of Advanced Manufacturing Technology, Vol. 67, Issue 5-8
Composite batteries: a simple yet universal approach to 3D printable lithium-ion battery electrodes
journal, January 2016
- Kohlmeyer, Ryan R.; Blake, Aaron J.; Hardin, James O.
- Journal of Materials Chemistry A, Vol. 4, Issue 43
Dual-phase polymer electrolyte with enhanced phase compatibility based on Poly(MMA-g-PVC)/PMMA
journal, June 2006
- Li, Weili; Yuan, Mingyong; Yang, Mujie
- European Polymer Journal, Vol. 42, Issue 6
Progress in the production and modification of PVDF membranes
journal, June 2011
- Liu, Fu; Hashim, N. Awanis; Liu, Yutie
- Journal of Membrane Science, Vol. 375, Issue 1-2
EIS study on the formation of solid electrolyte interface in Li-ion battery
journal, January 2006
- Zhang, S. S.; Xu, K.; Jow, T. R.
- Electrochimica Acta, Vol. 51, Issue 8-9
Toward garnet electrolyte–based Li metal batteries: An ultrathin, highly effective, artificial solid-state electrolyte/metallic Li interface
journal, April 2017
- Fu, Kun (Kelvin); Gong, Yunhui; Liu, Boyang
- Science Advances, Vol. 3, Issue 4
Dispersibility of nano-TiO2 on performance of composite polymer electrolytes for Li-ion batteries
journal, November 2013
- Cao, Jiang; Wang, Li; Shang, Yuming
- Electrochimica Acta, Vol. 111
Ionic-Liquid-Based Polymer Electrolytes for Battery Applications
journal, November 2015
- Osada, Irene; de Vries, Henrik; Scrosati, Bruno
- Angewandte Chemie International Edition, Vol. 55, Issue 2
3D Printing multifunctionality: structures with electronics
journal, March 2014
- Espalin, David; Muse, Danny W.; MacDonald, Eric
- The International Journal of Advanced Manufacturing Technology, Vol. 72, Issue 5-8
Solid-State Lithium Metal Batteries Promoted by Nanotechnology: Progress and Prospects
journal, May 2017
- Xin, Sen; You, Ya; Wang, Shaofei
- ACS Energy Letters, Vol. 2, Issue 6
Direct writing technology—Advances and developments
journal, January 2008
- Hon, K. K. B.; Li, L.; Hutchings, I. M.
- CIRP Annals, Vol. 57, Issue 2
Reshaping Lithium Plating/Stripping Behavior via Bifunctional Polymer Electrolyte for Room-Temperature Solid Li Metal Batteries
journal, December 2016
- Zeng, Xian-Xiang; Yin, Ya-Xia; Li, Nian-Wu
- Journal of the American Chemical Society, Vol. 138, Issue 49
Direct writing in three dimensions
journal, July 2004
- Lewis, Jennifer A.; Gratson, Gregory M.
- Materials Today, Vol. 7, Issue 7-8, p. 32-39
Equilibrium behavior of confined triblock copolymer films
journal, March 1998
- Pickett, Galen T.; Balazs, Anna C.
- Macromolecular Theory and Simulations, Vol. 7, Issue 2
Nanocomposite polymer electrolytes for lithium batteries
journal, July 1998
- Croce, F.; Appetecchi, G. B.; Persi, L.
- Nature, Vol. 394, Issue 6692
Solid-State Li-Ion Batteries Using Fast, Stable, Glassy Nanocomposite Electrolytes for Good Safety and Long Cycle-Life
journal, February 2016
- Tan, Guoqiang; Wu, Feng; Zhan, Chun
- Nano Letters, Vol. 16, Issue 3
Emerging 3D-Printed Electrochemical Energy Storage Devices: A Critical Review
journal, May 2017
- Tian, Xiaocong; Jin, Jun; Yuan, Shangqin
- Advanced Energy Materials, Vol. 7, Issue 17
Observed Surface Energy Effects in Confined Diblock Copolymers
journal, April 1996
- Kellogg, G. J.; Walton, D. G.; Mayes, A. M.
- Physical Review Letters, Vol. 76, Issue 14
Dendrite-Free Li-Metal Battery Enabled by a Thin Asymmetric Solid Electrolyte with Engineered Layers
journal, December 2017
- Duan, Hui; Yin, Ya-Xia; Shi, Yang
- Journal of the American Chemical Society, Vol. 140, Issue 1
3D printing technologies for electrochemical energy storage
journal, October 2017
- Zhang, Feng; Wei, Min; Viswanathan, Vilayanur V.
- Nano Energy, Vol. 40
3D printing based on imaging data: review of medical applications
journal, May 2010
- Rengier, F.; Mehndiratta, A.; von Tengg-Kobligk, H.
- International Journal of Computer Assisted Radiology and Surgery, Vol. 5, Issue 4
A hybrid solid electrolyte for flexible solid-state sodium batteries
journal, January 2015
- Kim, Jae-Kwang; Lim, Young Jun; Kim, Hyojin
- Energy & Environmental Science, Vol. 8, Issue 12
3D Printable Ceramic-Polymer Electrolytes for Flexible High-Performance Li-Ion Batteries with Enhanced Thermal Stability
journal, March 2017
- Blake, Aaron J.; Kohlmeyer, Ryan R.; Hardin, James O.
- Advanced Energy Materials, Vol. 7, Issue 14
Three-dimensional bilayer garnet solid electrolyte based high energy density lithium metal–sulfur batteries
journal, January 2017
- Fu, Kun (Kelvin); Gong, Yunhui; Hitz, Gregory T.
- Energy & Environmental Science, Vol. 10, Issue 7
Building better batteries
journal, February 2008
- Armand, M.; Tarascon, J.-M.
- Nature, Vol. 451, Issue 7179, p. 652-657
Nanostructured materials for advanced energy conversion and storage devices
journal, May 2005
- Aricò, Antonino Salvatore; Bruce, Peter; Scrosati, Bruno
- Nature Materials, Vol. 4, Issue 5, p. 366-377
Lithium batteries: Status, prospects and future
journal, May 2010
- Scrosati, Bruno; Garche, Jürgen
- Journal of Power Sources, Vol. 195, Issue 9
Effects of the porous structure on conductivity of nanocomposite polymer electrolyte for lithium ion batteries
journal, September 2008
- Li, Z. H.; Zhang, H. P.; Zhang, P.
- Journal of Membrane Science, Vol. 322, Issue 2
The influence of large cations on the electrochemical properties of tunnel-structured metal oxides
journal, November 2016
- Yuan, Yifei; Zhan, Chun; He, Kun
- Nature Communications, Vol. 7, Issue 1
Stable Aqueous Based Cu Nanoparticle Ink for Printing Well-Defined Highly Conductive Features on a Plastic Substrate
journal, March 2011
- Jeong, Sunho; Song, Hae Chun; Lee, Won Woo
- Langmuir, Vol. 27, Issue 6
Strong decrease in viscosity of nanoparticle-filled polymer melts through selective adsorption
journal, January 2008
- Jain, Sachin; Goossens, Johannes G. P.; Peters, Gerrit W. M.
- Soft Matter, Vol. 4, Issue 9
Progress in flexible lithium batteries and future prospects
journal, January 2014
- Zhou, Guangmin; Li, Feng; Cheng, Hui-Ming
- Energy Environ. Sci., Vol. 7, Issue 4
Direct Ink Writing of 3D Functional Materials
journal, November 2006
- Lewis, J. A.
- Advanced Functional Materials, Vol. 16, Issue 17
3D Printing of Carbon Nanotubes-Based Microsupercapacitors
journal, January 2017
- Yu, Wei; Zhou, Han; Li, Ben Q.
- ACS Applied Materials & Interfaces, Vol. 9, Issue 5
Superior Ion-Conducting Hybrid Solid Electrolyte for All-Solid-State Batteries
journal, November 2014
- Kim, Jae-Kwang; Scheers, Johan; Park, Tae Joo
- ChemSusChem, Vol. 8, Issue 4