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Title: Quantum-enhanced plasmonic sensing

Abstract

Quantum resources can enhance the sensitivity of a device beyond the classical shot noise limit and, as a result, revolutionize the field of metrology through the development of quantum-enhanced sensors. In particular, plasmonic sensors, which are widely used in biological and chemical sensing applications, offer a unique opportunity to bring such an enhancement to real-life devices. Here, we use bright entangled twin beams to enhance the sensitivity of a plasmonic sensor used to measure local changes in the refractive index. We demonstrate a 56% quantum enhancement in the sensitivity of a state-of-the-art plasmonic sensor when compared with the corresponding classical configuration and a 24% quantum enhancement when compared to an optimal single-beam classical configuration. We measure sensitivities on the order of 10–10 RIU / √Hz, nearly 5 orders of magnitude better than previous proof-of-principle implementations of quantum-enhanced plasmonic sensors. Furthermore, these results promise significant enhancements in ultratrace label-free plasmonic sensing and will find their way into areas ranging from biomedical applications to chemical detection.

Authors:
 [1];  [1]; ORCiD logo [2]; ORCiD logo [2];  [1]
  1. The Univ. of Oklahoma, Norman, OK (United States)
  2. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Publication Date:
Research Org.:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1461064
Grant/Contract Number:  
AC05-00OR22725
Resource Type:
Accepted Manuscript
Journal Name:
Optica
Additional Journal Information:
Journal Volume: 5; Journal Issue: 5; Journal ID: ISSN 2334-2536
Publisher:
Optical Society of America
Country of Publication:
United States
Language:
English
Subject:
47 OTHER INSTRUMENTATION; Quantum optics; Plasmonics; Subwavelength structures; Nanostructures; Optical sensing and sensors

Citation Formats

Dowran, Mohammadjavad, Kumar, Ashok, Lawrie, Benjamin J., Pooser, Raphael C., and Marino, Alberto M. Quantum-enhanced plasmonic sensing. United States: N. p., 2018. Web. doi:10.1364/OPTICA.5.000628.
Dowran, Mohammadjavad, Kumar, Ashok, Lawrie, Benjamin J., Pooser, Raphael C., & Marino, Alberto M. Quantum-enhanced plasmonic sensing. United States. https://doi.org/10.1364/OPTICA.5.000628
Dowran, Mohammadjavad, Kumar, Ashok, Lawrie, Benjamin J., Pooser, Raphael C., and Marino, Alberto M. Wed . "Quantum-enhanced plasmonic sensing". United States. https://doi.org/10.1364/OPTICA.5.000628. https://www.osti.gov/servlets/purl/1461064.
@article{osti_1461064,
title = {Quantum-enhanced plasmonic sensing},
author = {Dowran, Mohammadjavad and Kumar, Ashok and Lawrie, Benjamin J. and Pooser, Raphael C. and Marino, Alberto M.},
abstractNote = {Quantum resources can enhance the sensitivity of a device beyond the classical shot noise limit and, as a result, revolutionize the field of metrology through the development of quantum-enhanced sensors. In particular, plasmonic sensors, which are widely used in biological and chemical sensing applications, offer a unique opportunity to bring such an enhancement to real-life devices. Here, we use bright entangled twin beams to enhance the sensitivity of a plasmonic sensor used to measure local changes in the refractive index. We demonstrate a 56% quantum enhancement in the sensitivity of a state-of-the-art plasmonic sensor when compared with the corresponding classical configuration and a 24% quantum enhancement when compared to an optimal single-beam classical configuration. We measure sensitivities on the order of 10–10 RIU / √Hz, nearly 5 orders of magnitude better than previous proof-of-principle implementations of quantum-enhanced plasmonic sensors. Furthermore, these results promise significant enhancements in ultratrace label-free plasmonic sensing and will find their way into areas ranging from biomedical applications to chemical detection.},
doi = {10.1364/OPTICA.5.000628},
journal = {Optica},
number = 5,
volume = 5,
place = {United States},
year = {Wed May 16 00:00:00 EDT 2018},
month = {Wed May 16 00:00:00 EDT 2018}
}

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Cited by: 65 works
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Works referenced in this record:

Role of the phase-matching condition in nondegenerate four-wave mixing in hot vapors for the generation of squeezed states of light
journal, September 2013


Experimental realization of sub-shot-noise quantum imaging
journal, February 2010


Quantum-Enhanced Measurements: Beating the Standard Quantum Limit
journal, November 2004


Squeezing in the Audio Gravitational-Wave Detection Band
journal, October 2004


Nanostructured Plasmonic Sensors
journal, February 2008

  • Stewart, Matthew E.; Anderton, Christopher R.; Thompson, Lucas B.
  • Chemical Reviews, Vol. 108, Issue 2
  • DOI: 10.1021/cr068126n

Ultrasensitive Non-Resonant Detection of Ultrasound with Plasmonic Metamaterials
journal, March 2013

  • Yakovlev, Vladislav V.; Dickson, Wayne; Murphy, Antony
  • Advanced Materials, Vol. 25, Issue 16
  • DOI: 10.1002/adma.201300314

Quantum Plasmonic Sensing: Beyond the Shot-Noise and Diffraction Limit
journal, April 2016


Plasmonics for extreme light concentration and manipulation
journal, February 2010

  • Schuller, Jon A.; Barnard, Edward S.; Cai, Wenshan
  • Nature Materials, Vol. 9, Issue 3
  • DOI: 10.1038/nmat2630

Thermo-plasmonics: using metallic nanostructures as nano-sources of heat: Thermoplasmonics
journal, April 2012


Extraordinary optical transmission through sub-wavelength hole arrays
journal, February 1998

  • Ebbesen, T. W.; Lezec, H. J.; Ghaemi, H. F.
  • Nature, Vol. 391, Issue 6668, p. 667-669
  • DOI: 10.1038/35570

Plasmonic Trace Sensing below the Photon Shot Noise Limit
journal, December 2015


Squeezed states of light
journal, October 1992


Biosensing with plasmonic nanosensors
journal, June 2008

  • Anker, Jeffrey N.; Hall, W. Paige; Lyandres, Olga
  • Nature Materials, Vol. 7, Issue 6
  • DOI: 10.1038/nmat2162

Surface Plasmon Resonance Sensors for Detection of Chemical and Biological Species
journal, February 2008


Biological measurement beyond the quantum limit
journal, February 2013


Plasmon-assisted transmission of entangled photons
journal, July 2002

  • Altewischer, E.; van Exter, M. P.; Woerdman, J. P.
  • Nature, Vol. 418, Issue 6895
  • DOI: 10.1038/nature00869

A Quantum Laser Pointer
journal, August 2003


Quantum metrology and its application in biology
journal, February 2016


Squeezed states of light
journal, November 1983


Strategies for enhancing the sensitivity of plasmonic nanosensors
journal, April 2015


Coherent Control of Vacuum Squeezing in the Gravitational-Wave Detection Band
journal, July 2006


Plasmonic Films Can Easily Be Better: Rules and Recipes
journal, February 2015

  • McPeak, Kevin M.; Jayanti, Sriharsha V.; Kress, Stephan J. P.
  • ACS Photonics, Vol. 2, Issue 3
  • DOI: 10.1021/ph5004237

A New Generation of Sensors Based on Extraordinary Optical Transmission
journal, August 2008

  • Gordon, Reuven; Sinton, David; Kavanagh, Karen L.
  • Accounts of Chemical Research, Vol. 41, Issue 8
  • DOI: 10.1021/ar800074d

90% Extraordinary optical transmission in the visible range through annular aperture metallic arrays
journal, January 2007

  • Poujet, Yannick; Salvi, Jérôme; Baida, Fadi Issam
  • Optics Letters, Vol. 32, Issue 20
  • DOI: 10.1364/ol.32.002942

Observation of Squeezed States Generated by Four-Wave Mixing in an Optical Cavity
journal, November 1985


Quantum-mechanical noise in an interferometer
journal, April 1981


Precision measurement beyond the shot-noise limit
journal, July 1987


Squeezed-light enhanced polarization interferometer
journal, November 1987


Surface plasmon resonance sensors: review
journal, January 1999

  • Homola, Jiřı́; Yee, Sinclair S.; Gauglitz, Günter
  • Sensors and Actuators B: Chemical, Vol. 54, Issue 1-2, p. 3-15
  • DOI: 10.1016/S0925-4005(98)00321-9

Shot-noise limited detection for surface plasmon sensing
journal, December 2010

  • Wang, Xi; Jefferson, Michael; Hobbs, Philip C. D.
  • Optics Express, Vol. 19, Issue 1
  • DOI: 10.1364/OE.19.000107

Quantum plasmonic sensing
journal, November 2015


Quantum noise reduction in intensity-sensitive surface-plasmon-resonance sensors
journal, September 2017


Theory of Extraordinary Optical Transmission through Subwavelength Hole Arrays
journal, February 2001

  • Martín-Moreno, L.; García-Vidal, F. J.; Lezec, H. J.
  • Physical Review Letters, Vol. 86, Issue 6, p. 1114-1117
  • DOI: 10.1103/PhysRevLett.86.1114

Energy-Time Entanglement Preservation in Plasmon-Assisted Light Transmission
journal, March 2005


Extraordinary Optical Transmission of Multimode Quantum Correlations via Localized Surface Plasmons
journal, April 2013


Toward quantum plasmonic networks
journal, January 2016


Surface plasmon resonance (SPR) sensors: approaching their limits?
journal, January 2009


Strong low-frequency quantum correlations from a four-wave-mixing amplifier
journal, October 2008


Generation of Spatially Broadband Twin Beams for Quantum Imaging
journal, April 2008


High-contrast, synchronous volumetric imaging with selective volume illumination microscopy
journal, February 2020


Biological measurement beyond the quantum limit
conference, May 2013

  • Taylor, Michael A.; Janousek, Jiri; Daria, Vincent
  • 2013 Conference on Lasers & Electro-Optics Europe & International Quantum Electronics Conference CLEO EUROPE/IQEC
  • DOI: 10.1109/cleoe-iqec.2013.6801628

Observation of Squeezed States Generated by Four-Wave Mixing in an Optical Cavity
journal, February 1986


A quantum laser pointer
conference, January 2003

  • Treps, N.; Grosse, N.; Bowen, W.
  • 2003 European Quantum Electronics Conference. EQEC 2003 (IEEE Cat No.03TH8665)
  • DOI: 10.1109/eqec.2003.1314202

Quantum metrology and its application in biology
preprint, January 2014


Quantum plasmonic sensing: beyond the shot-noise and diffraction limit
text, January 2016


Quantum noise reduction in intensity-sensitive surface plasmon resonance sensors
text, January 2017


Energy-time entanglement preservation in plasmon-assisted light transmission
text, January 2004


Quantum-enhanced measurements: beating the standard quantum limit
text, January 2004


Strong low-frequency quantum correlations from a four-wave mixing amplifier
text, January 2007


Works referencing / citing this record:

Coupling effects in single-mode and multimode resonator-coupled system
journal, January 2019


Ultrasonic Influence on Plasmonic Effects Exhibited by Photoactive Bimetallic Au-Pt Nanoparticles Suspended in Ethanol
journal, June 2019

  • Hurtado-Aviles, Eric Abraham; Torres, Jesús Alejandro; Trejo-Valdez, Martín
  • Materials, Vol. 12, Issue 11
  • DOI: 10.3390/ma12111791

Optimal phase sensitivity by quantum squeezing based on a Mach–Zehnder interferometer
journal, January 2020


Quantum plasmonic sensing using single photons
journal, January 2018

  • Lee, Joong-Sung; Yoon, Seung-Jin; Rah, Hyungju
  • Optics Express, Vol. 26, Issue 22
  • DOI: 10.1364/oe.26.029272

Biosensors for Epilepsy Management: State-of-Art and Future Aspects
journal, March 2019

  • Tiwari, Shivani; Sharma, Varsha; Mujawar, Mubarak
  • Sensors, Vol. 19, Issue 7
  • DOI: 10.3390/s19071525

Twin-beam-enhanced displacement measurement of a membrane in a cavity
journal, December 2019

  • Wei, Xinrui; Sheng, Jiteng; Wu, Yuelong
  • Applied Physics Letters, Vol. 115, Issue 25
  • DOI: 10.1063/1.5129547

Quantum tomography of the photon-plasmon conversion process in a metal hole array
journal, January 2019


Twin-beam-enhanced displacement measurement of a membrane in a cavity
text, January 2019