DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Microstructures and mechanical properties of a welded CoCrFeMnNi high-entropy alloy

Abstract

The response of the CoCrFeMnNi high-entropy alloy to weld thermal cycles was investigated to determine its applicability as an engineering structural material. Two processes were used: high-energy-density, low-heat-input electron beam (EB) welding and low-energy-density, high-heat-input gas tungsten arc (GTA) welding. Weldability was determined through comprehensive microstructural and mechanical property characterisation of the welds. The welds did not develop solidification cracking or heat-affected zone cracks. The microstructures in weld fusion zones are similar to that in the as-cast materials, consisting of large columnar grains with dendrite. The dendrite arm spacing and the extent of elemental segregation were less in the welds than in the cast ingot, and also were less pronounced in the EB weld than in the GTA weld. Compositional microsegregation between dendritic cores and interdendritic regions of the welds was insignificant. Both welds exhibited slightly higher yield strengths than the base metal. The EB weld possessed comparable tensile strength and ductility to that of the base metal. In comparison, the GTA weld maintained ∼80% of the base metal's tensile strength and 50% of the ductility.

Authors:
 [1];  [1];  [1];  [1]; ORCiD logo [1]
  1. Materials Science and Technology Division, Oak Ridge National Laboratory, Oak Ridge, TN, USA
Publication Date:
Research Org.:
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
2281429
Alternate Identifier(s):
OSTI ID: 1459315
Grant/Contract Number:  
AC05-00OR22725
Resource Type:
Published Article
Journal Name:
Science and Technology of Welding and Joining
Additional Journal Information:
Journal Name: Science and Technology of Welding and Joining Journal Volume: 23 Journal Issue: 7; Journal ID: ISSN 1362-1718
Publisher:
SAGE Publications
Country of Publication:
United Kingdom
Language:
English
Subject:
36 MATERIALS SCIENCE; high-entropy alloy; welding; weldability; mechanical properties; microstructure

Citation Formats

Wu, Z., David, S. A., Leonard, D. N., Feng, Z., and Bei, H. Microstructures and mechanical properties of a welded CoCrFeMnNi high-entropy alloy. United Kingdom: N. p., 2018. Web. doi:10.1080/13621718.2018.1430114.
Wu, Z., David, S. A., Leonard, D. N., Feng, Z., & Bei, H. Microstructures and mechanical properties of a welded CoCrFeMnNi high-entropy alloy. United Kingdom. https://doi.org/10.1080/13621718.2018.1430114
Wu, Z., David, S. A., Leonard, D. N., Feng, Z., and Bei, H. Mon . "Microstructures and mechanical properties of a welded CoCrFeMnNi high-entropy alloy". United Kingdom. https://doi.org/10.1080/13621718.2018.1430114.
@article{osti_2281429,
title = {Microstructures and mechanical properties of a welded CoCrFeMnNi high-entropy alloy},
author = {Wu, Z. and David, S. A. and Leonard, D. N. and Feng, Z. and Bei, H.},
abstractNote = {The response of the CoCrFeMnNi high-entropy alloy to weld thermal cycles was investigated to determine its applicability as an engineering structural material. Two processes were used: high-energy-density, low-heat-input electron beam (EB) welding and low-energy-density, high-heat-input gas tungsten arc (GTA) welding. Weldability was determined through comprehensive microstructural and mechanical property characterisation of the welds. The welds did not develop solidification cracking or heat-affected zone cracks. The microstructures in weld fusion zones are similar to that in the as-cast materials, consisting of large columnar grains with dendrite. The dendrite arm spacing and the extent of elemental segregation were less in the welds than in the cast ingot, and also were less pronounced in the EB weld than in the GTA weld. Compositional microsegregation between dendritic cores and interdendritic regions of the welds was insignificant. Both welds exhibited slightly higher yield strengths than the base metal. The EB weld possessed comparable tensile strength and ductility to that of the base metal. In comparison, the GTA weld maintained ∼80% of the base metal's tensile strength and 50% of the ductility.},
doi = {10.1080/13621718.2018.1430114},
journal = {Science and Technology of Welding and Joining},
number = 7,
volume = 23,
place = {United Kingdom},
year = {Mon Oct 01 00:00:00 EDT 2018},
month = {Mon Oct 01 00:00:00 EDT 2018}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1080/13621718.2018.1430114

Citation Metrics:
Cited by: 58 works
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

Weldability of a high entropy CrMnFeCoNi alloy
journal, November 2016


In-situ neutron diffraction study of deformation behavior of a multi-component high-entropy alloy
journal, February 2014

  • Wu, Y.; Liu, W. H.; Wang, X. L.
  • Applied Physics Letters, Vol. 104, Issue 5
  • DOI: 10.1063/1.4863748

Tensile properties of high- and medium-entropy alloys
journal, August 2013


Microstructural development in equiatomic multicomponent alloys
journal, July 2004


Cryogenic fracture and adiabatic heating of austenitic stainless steels for superconducting fusion magnets
journal, January 2003


Refractory high-entropy alloys
journal, September 2010


The influences of temperature and microstructure on the tensile properties of a CoCrFeMnNi high-entropy alloy
journal, September 2013


Phenomenological Modeling of Fusion Welding Processes
journal, January 1994


Welding and weldability of candidate ferritic alloys for future advanced ultrasupercritical fossil power plants
journal, November 2013


The influence of stacking fault energy on the mechanical behavior of Cu and Cu-Al alloys: Deformation twinning, work hardening, and dynamic recovery
journal, January 2001

  • Rohatgi, Aashish; Vecchio, Kenneth S.; Gray, George T.
  • Metallurgical and Materials Transactions A, Vol. 32, Issue 1
  • DOI: 10.1007/s11661-001-0109-7

Physical processes in fusion welding
journal, January 1995


Microstructural modification of austenitic stainless steels by rapid solidification
journal, September 1983

  • Vitek, J. M.; Dasgupta, A.; David, S. A.
  • Metallurgical Transactions A, Vol. 14, Issue 9
  • DOI: 10.1007/BF02645553

Thermophysical properties of Ni-containing single-phase concentrated solid solution alloys
journal, March 2017


Strain hardening regimes and microstructural evolution during large strain compression of low stacking fault energy fcc alloys that form deformation twins
journal, September 1997

  • Asgari, Sirous; El-Danaf, Ehab; Kalidindi, Surya R.
  • Metallurgical and Materials Transactions A, Vol. 28, Issue 9
  • DOI: 10.1007/s11661-997-0109-3

Rapid solidification of a droplet-processed stainless steel
journal, May 1984

  • Kelly, Thomas F.; Cohen, Morris; Sande, John B.
  • Metallurgical Transactions A, Vol. 15, Issue 5
  • DOI: 10.1007/BF02644556

Control of Magnesium Loss During Laser Welding of Al-5083 Using a Plasma Suppression Technique
journal, January 1985

  • Blake, A.; Mazumder, J.
  • Journal of Engineering for Industry, Vol. 107, Issue 3
  • DOI: 10.1115/1.3185998

Metal vaporization from weld pools
journal, September 1984

  • Block-Bolten, A.; Eagar, T. W.
  • Metallurgical Transactions B, Vol. 15, Issue 3
  • DOI: 10.1007/BF02657376

Ultrastrong ductile and stable high-entropy alloys at small scales
journal, July 2015

  • Zou, Yu; Ma, Huan; Spolenak, Ralph
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms8748

Metastable high-entropy dual-phase alloys overcome the strength–ductility trade-off
journal, May 2016

  • Li, Zhiming; Pradeep, Konda Gokuldoss; Deng, Yun
  • Nature, Vol. 534, Issue 7606
  • DOI: 10.1038/nature17981

Exceptional damage-tolerance of a medium-entropy alloy CrCoNi at cryogenic temperatures
journal, February 2016

  • Gludovatz, Bernd; Hohenwarter, Anton; Thurston, Keli V. S.
  • Nature Communications, Vol. 7, Issue 1
  • DOI: 10.1038/ncomms10602

Wear resistance and high-temperature compression strength of Fcc CuCoNiCrAl0.5Fe alloy with boron addition
journal, May 2004

  • Hsu, Chin-You; Yeh, Jien-Wei; Chen, Swe-Kai
  • Metallurgical and Materials Transactions A, Vol. 35, Issue 5
  • DOI: 10.1007/s11661-004-0254-x

A fracture-resistant high-entropy alloy for cryogenic applications
journal, September 2014


Microstructural evolution of a CoCrFeMnNi high-entropy alloy after swaging and annealing
journal, October 2015


Alternating grain orientation and weld solidification cracking
journal, October 1985


High temperature deformation behavior and dynamic recrystallization in CoCrFeNiMn high entropy alloy
journal, June 2015

  • Stepanov, N. D.; Shaysultanov, D. G.; Yurchenko, N. Yu.
  • Materials Science and Engineering: A, Vol. 636
  • DOI: 10.1016/j.msea.2015.03.097

Correlation between solidification parameters and weld microstructures
journal, January 1989


Entropy-stabilized oxides
journal, September 2015

  • Rost, Christina M.; Sachet, Edward; Borman, Trent
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms9485

Current Issues and Problems in Welding Science
journal, July 1992


Alloying element vaporization and weld pool temperature during laser welding of AlSl 202 stainless steel
journal, December 1984

  • Khan, P. A. A.; Debroy, T.
  • Metallurgical Transactions B, Vol. 15, Issue 4
  • DOI: 10.1007/BF02657284

Grain structures in aluminum alloy GTA welds
journal, August 1980

  • Ganaha, T.; Pearce, B. P.; Kerr, H. W.
  • Metallurgical Transactions A, Vol. 11, Issue 8
  • DOI: 10.1007/BF02653489

Influence des conditions de solidification sur le déroulement de la solidification des aciers inoxydables austénitiques
journal, July 1988


On the weldability, composition, and hardness of pulsed and continuous Nd:YAG laser welds in aluminum alloys 6061,5456, and 5086
journal, April 1988

  • Cieslak, M. J.; Fuerschbach, P. W.
  • Metallurgical Transactions B, Vol. 19, Issue 2
  • DOI: 10.1007/BF02654217

The effect of quenching on the solidification structure and transformation behavior of stainless steel welds
journal, July 1982


The effect of heat treatment on microstructure and cryogenic fracture properties in 5Ni and 9Ni steel
journal, August 1980

  • Strife, J. R.; Passoja, D. E.
  • Metallurgical Transactions A, Vol. 11, Issue 8
  • DOI: 10.1007/BF02653488

Nanostructured High-Entropy Alloys with Multiple Principal Elements: Novel Alloy Design Concepts and Outcomes
journal, May 2004

  • Yeh, J.-W.; Chen, S.-K.; Lin, S.-J.
  • Advanced Engineering Materials, Vol. 6, Issue 5, p. 299-303
  • DOI: 10.1002/adem.200300567

Nanoscale origins of the damage tolerance of the high-entropy alloy CrMnFeCoNi
journal, December 2015

  • Zhang, ZiJiao; Mao, M. M.; Wang, Jiangwei
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms10143

Fracture toughness of type 304 and 316 stainless steels and their welds
journal, January 1997


Hybrid fiber laser – Arc welding of thick section high strength low alloy steel
journal, June 2011


Mechanism of alloying element vaporization during laser welding
journal, December 1987

  • Collur, M. M.; Paul, A.; Debroy, T.
  • Metallurgical Transactions B, Vol. 18, Issue 4
  • DOI: 10.1007/BF02672891

Cryogenic fracture toughness of 9Ni steel enhanced through grain refinement
journal, December 1976

  • Syn, Chol K.; Morris, J. W.; Jin, Sungho
  • Metallurgical Transactions A, Vol. 7, Issue 12
  • DOI: 10.1007/BF02659812

Twinning and strain-induced f.c.c. → h.c.p. transformation on the mechanical properties of CoNiCrMo alloys
journal, November 1976


In-situ neutron diffraction studies on high-temperature deformation behavior in a CoCrFeMnNi high entropy alloy
journal, July 2015


Nano-twin mediated plasticity in carbon-containing FeNiCoCrMn high entropy alloys
journal, October 2015