Electrochemical and interfacial behavior of all solid state batteries using Li10SnP2S12 solid electrolyte
Abstract
Thio-Lithium Superionic Conductor (Thio-LISICON) Li10GeP2S12 equivalent Li10SnP2S12 (LSPS) is comparable in ionic conductivity yet with a lower cost as an electrolyte for all solid-state batteries (ASSBs). In this study, ASSBs with LSPS solid electrolyte (SE), lithium-indium alloy anode, and LiCoO2 (LCO) cathode were successfully fabricated and their electrochemical performance at 60 °C was examined. Atomic layer deposition of Li3NbO4 on LCO was conducted to improve the interfacial stability. The Li3NbO4 coating effectively improves the cycle stability of the ASSB. Electrochemical impedance spectroscopy tests indicate a rapid growth of charge transfer resistance upon cycling for the cell with the uncoated LCO, primarily due to the surface instability and build-up of a space charge layer. However, the ASSBs with Li3NbO4 coated LCO show a more stable interface with a negligible impedance increase upon cycling, attributable to the buffering and passivating roles of the Li3NbO4 coating. Lastly, the interfacial microstructure was analyzed to elucidate at the underlying reasons for the impedance increase and the pivotal role of the Li3NbO4 coating.
- Authors:
-
[3];
- Univ. of Washington, Seattle, WA (United States). Materials Science and Engineering Department
- Pacific Northwest National Lab. (PNNL), Richland, WA (United States). Environmental Molecular Sciences Lab. (EMSL)
- General Motors R&D Center, Warren, MI (United States). Chemical Sciences and Materials Systems Lab
- Publication Date:
- Research Org.:
- Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V); USDOE Office of Science (SC), Biological and Environmental Research (BER); USDOE Office of Energy Efficiency and Renewable Energy (EERE)
- OSTI Identifier:
- 1457752
- Alternate Identifier(s):
- OSTI ID: 1495302
- Report Number(s):
- PNNL-SA-132845
Journal ID: ISSN 0378-7753; PII: S0378775318306347
- Grant/Contract Number:
- AC05-76RL01830; EE0007787; AC02-05CH11231; 18769; 6951379; AC05-76RLO1830
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Power Sources
- Additional Journal Information:
- Journal Volume: 396; Journal ID: ISSN 0378-7753
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; 36 MATERIALS SCIENCE; Li10SnP2S12; All-solid-state battery; Solid electrolyte; Atomic layer deposition; Interfacial stability
Citation Formats
Vinado, Carolina, Wang, Shanyu, He, Yang, Xiao, Xingcheng, Li, Yun, Wang, Chongmin, and Yang, Jihui. Electrochemical and interfacial behavior of all solid state batteries using Li10SnP2S12 solid electrolyte. United States: N. p., 2018.
Web. doi:10.1016/J.JPOWSOUR.2018.06.038.
Vinado, Carolina, Wang, Shanyu, He, Yang, Xiao, Xingcheng, Li, Yun, Wang, Chongmin, & Yang, Jihui. Electrochemical and interfacial behavior of all solid state batteries using Li10SnP2S12 solid electrolyte. United States. https://doi.org/10.1016/J.JPOWSOUR.2018.06.038
Vinado, Carolina, Wang, Shanyu, He, Yang, Xiao, Xingcheng, Li, Yun, Wang, Chongmin, and Yang, Jihui. Tue .
"Electrochemical and interfacial behavior of all solid state batteries using Li10SnP2S12 solid electrolyte". United States. https://doi.org/10.1016/J.JPOWSOUR.2018.06.038. https://www.osti.gov/servlets/purl/1457752.
@article{osti_1457752,
title = {Electrochemical and interfacial behavior of all solid state batteries using Li10SnP2S12 solid electrolyte},
author = {Vinado, Carolina and Wang, Shanyu and He, Yang and Xiao, Xingcheng and Li, Yun and Wang, Chongmin and Yang, Jihui},
abstractNote = {Thio-Lithium Superionic Conductor (Thio-LISICON) Li10GeP2S12 equivalent Li10SnP2S12 (LSPS) is comparable in ionic conductivity yet with a lower cost as an electrolyte for all solid-state batteries (ASSBs). In this study, ASSBs with LSPS solid electrolyte (SE), lithium-indium alloy anode, and LiCoO2 (LCO) cathode were successfully fabricated and their electrochemical performance at 60 °C was examined. Atomic layer deposition of Li3NbO4 on LCO was conducted to improve the interfacial stability. The Li3NbO4 coating effectively improves the cycle stability of the ASSB. Electrochemical impedance spectroscopy tests indicate a rapid growth of charge transfer resistance upon cycling for the cell with the uncoated LCO, primarily due to the surface instability and build-up of a space charge layer. However, the ASSBs with Li3NbO4 coated LCO show a more stable interface with a negligible impedance increase upon cycling, attributable to the buffering and passivating roles of the Li3NbO4 coating. Lastly, the interfacial microstructure was analyzed to elucidate at the underlying reasons for the impedance increase and the pivotal role of the Li3NbO4 coating.},
doi = {10.1016/J.JPOWSOUR.2018.06.038},
journal = {Journal of Power Sources},
number = ,
volume = 396,
place = {United States},
year = {Tue Jun 19 00:00:00 EDT 2018},
month = {Tue Jun 19 00:00:00 EDT 2018}
}
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Figures / Tables:
Fig. 1: (A) Crystal structure of LSPS. [SnS4] (Orange) and [PS4] (Aqua) tetrahedra are shown. (b) Experimental and simulated powder X-ray diffraction (XRD) of LSPS. (c) Nyquist plot of the experimental (Black Square) and fit (Red line) of a LSPS pellet in a C/LSPS/C cell at room temperature. (d) Cyclicmore »
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