A Perovskite Electrolyte That Is Stable in Moist Air for Lithium‐Ion Batteries
Abstract
Abstract Solid‐oxide Li + electrolytes of a rechargeable cell are generally sensitive to moisture in the air as H + exchanges for the mobile Li + of the electrolyte and forms insulating surface phases at the electrolyte interfaces and in the grain boundaries of a polycrystalline membrane. These surface phases dominate the total interfacial resistance of a conventional rechargeable cell with a solid–electrolyte separator. We report a new perovskite Li + solid electrolyte, Li 0.38 Sr 0.44 Ta 0.7 Hf 0.3 O 2.95 F 0.05 , with a lithium‐ion conductivity of σ Li =4.8×10 −4 S cm −1 at 25 °C that does not react with water having 3≤pH≤14. The solid electrolyte with a thin Li + ‐conducting polymer on its surface to prevent reduction of Ta 5+ is wet by metallic lithium and provides low‐impedance dendrite‐free plating/stripping of a lithium anode. It is also stable upon contact with a composite polymer cathode. With this solid electrolyte, we demonstrate excellent cycling performance of an all‐solid‐state Li/LiFePO 4 cell, a Li‐S cell with a polymer‐gel cathode, and a supercapacitor.
- Authors:
-
[1]
- Materials Science and Engineering Program and Texas Materials Institute University of Texas at Austin Austin TX 78712 USA
- Department of Chemistry and Biochemistry Florida State University Tallahassee FL 32310 USA
- Department of Chemistry and Biochemistry Florida State University Tallahassee FL 32310 USA, National High Magnetic Field Laboratory 1800 East Paul Dirac Drive Tallahassee FL 32310 USA
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1441038
- Grant/Contract Number:
- EE0007762; 7223523
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- Angewandte Chemie
- Additional Journal Information:
- Journal Name: Angewandte Chemie Journal Volume: 130 Journal Issue: 28; Journal ID: ISSN 0044-8249
- Publisher:
- Wiley Blackwell (John Wiley & Sons)
- Country of Publication:
- Germany
- Language:
- English
Citation Formats
Li, Yutao, Xu, Henghui, Chien, Po‐Hsiu, Wu, Nan, Xin, Sen, Xue, Leigang, Park, Kyusung, Hu, Yan‐Yan, and Goodenough, John B. A Perovskite Electrolyte That Is Stable in Moist Air for Lithium‐Ion Batteries. Germany: N. p., 2018.
Web. doi:10.1002/ange.201804114.
Li, Yutao, Xu, Henghui, Chien, Po‐Hsiu, Wu, Nan, Xin, Sen, Xue, Leigang, Park, Kyusung, Hu, Yan‐Yan, & Goodenough, John B. A Perovskite Electrolyte That Is Stable in Moist Air for Lithium‐Ion Batteries. Germany. https://doi.org/10.1002/ange.201804114
Li, Yutao, Xu, Henghui, Chien, Po‐Hsiu, Wu, Nan, Xin, Sen, Xue, Leigang, Park, Kyusung, Hu, Yan‐Yan, and Goodenough, John B. Thu .
"A Perovskite Electrolyte That Is Stable in Moist Air for Lithium‐Ion Batteries". Germany. https://doi.org/10.1002/ange.201804114.
@article{osti_1441038,
title = {A Perovskite Electrolyte That Is Stable in Moist Air for Lithium‐Ion Batteries},
author = {Li, Yutao and Xu, Henghui and Chien, Po‐Hsiu and Wu, Nan and Xin, Sen and Xue, Leigang and Park, Kyusung and Hu, Yan‐Yan and Goodenough, John B.},
abstractNote = {Abstract Solid‐oxide Li + electrolytes of a rechargeable cell are generally sensitive to moisture in the air as H + exchanges for the mobile Li + of the electrolyte and forms insulating surface phases at the electrolyte interfaces and in the grain boundaries of a polycrystalline membrane. These surface phases dominate the total interfacial resistance of a conventional rechargeable cell with a solid–electrolyte separator. We report a new perovskite Li + solid electrolyte, Li 0.38 Sr 0.44 Ta 0.7 Hf 0.3 O 2.95 F 0.05 , with a lithium‐ion conductivity of σ Li =4.8×10 −4 S cm −1 at 25 °C that does not react with water having 3≤pH≤14. The solid electrolyte with a thin Li + ‐conducting polymer on its surface to prevent reduction of Ta 5+ is wet by metallic lithium and provides low‐impedance dendrite‐free plating/stripping of a lithium anode. It is also stable upon contact with a composite polymer cathode. With this solid electrolyte, we demonstrate excellent cycling performance of an all‐solid‐state Li/LiFePO 4 cell, a Li‐S cell with a polymer‐gel cathode, and a supercapacitor.},
doi = {10.1002/ange.201804114},
journal = {Angewandte Chemie},
number = 28,
volume = 130,
place = {Germany},
year = {Thu Jun 07 00:00:00 EDT 2018},
month = {Thu Jun 07 00:00:00 EDT 2018}
}
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1002/ange.201804114
https://doi.org/10.1002/ange.201804114
Other availability
Search WorldCat to find libraries that may hold this journal
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
How we made the Li-ion rechargeable battery
journal, March 2018
- Goodenough, John B.
- Nature Electronics, Vol. 1, Issue 3
Negating interfacial impedance in garnet-based solid-state Li metal batteries
journal, December 2016
- Han, Xiaogang; Gong, Yunhui; Fu, Kun (Kelvin)
- Nature Materials, Vol. 16, Issue 5
Li-Ion Conduction and Stability of Perovskite Li 3/8 Sr 7/16 Hf 1/4 Ta 3/4 O 3
journal, June 2016
- Huang, Bing; Xu, Biyi; Li, Yutao
- ACS Applied Materials & Interfaces, Vol. 8, Issue 23
Fluorine-Doped Antiperovskite Electrolyte for All-Solid-State Lithium-Ion Batteries
journal, June 2016
- Li, Yutao; Zhou, Weidong; Xin, Sen
- Angewandte Chemie International Edition, Vol. 55, Issue 34
Challenges for Rechargeable Li Batteries
journal, February 2010
- Goodenough, John B.; Kim, Youngsik
- Chemistry of Materials, Vol. 22, Issue 3, p. 587-603
High-power all-solid-state batteries using sulfide superionic conductors
journal, March 2016
- Kato, Yuki; Hori, Satoshi; Saito, Toshiya
- Nature Energy, Vol. 1, Issue 4
Hybrid Polymer/Garnet Electrolyte with a Small Interfacial Resistance for Lithium-Ion Batteries
journal, December 2016
- Li, Yutao; Xu, Biyi; Xu, Henghui
- Angewandte Chemie International Edition, Vol. 56, Issue 3
Transition from Superlithiophobicity to Superlithiophilicity of Garnet Solid-State Electrolyte
journal, September 2016
- Luo, Wei; Gong, Yunhui; Zhu, Yizhou
- Journal of the American Chemical Society, Vol. 138, Issue 37
Hybrid Polymer/Garnet Electrolyte with a Small Interfacial Resistance for Lithium-Ion Batteries
journal, December 2016
- Li, Yutao; Xu, Biyi; Xu, Henghui
- Angewandte Chemie, Vol. 129, Issue 3
Fluorine-Doped Antiperovskite Electrolyte for All-Solid-State Lithium-Ion Batteries
journal, June 2016
- Li, Yutao; Zhou, Weidong; Xin, Sen
- Angewandte Chemie, Vol. 128, Issue 34
The origin of high electrolyte–electrode interfacial resistances in lithium cells containing garnet type solid electrolytes
journal, January 2014
- Cheng, Lei; Crumlin, Ethan J.; Chen, Wei
- Phys. Chem. Chem. Phys., Vol. 16, Issue 34
A chemistry and material perspective on lithium redox flow batteries towards high-density electrical energy storage
journal, January 2015
- Zhao, Yu; Ding, Yu; Li, Yutao
- Chemical Society Reviews, Vol. 44, Issue 22
Surface Chemistry Mechanism of Ultra-Low Interfacial Resistance in the Solid-State Electrolyte Li 7 La 3 Zr 2 O 12
journal, September 2017
- Sharafi, Asma; Kazyak, Eric; Davis, Andrew L.
- Chemistry of Materials, Vol. 29, Issue 18
An In Vivo Formed Solid Electrolyte Surface Layer Enables Stable Plating of Li Metal
journal, December 2017
- Pang, Quan; Liang, Xiao; Shyamsunder, Abhinandan
- Joule, Vol. 1, Issue 4
Synergistic Coupling between Li 6.75 La 3 Zr 1.75 Ta 0.25 O 12 and Poly(vinylidene fluoride) Induces High Ionic Conductivity, Mechanical Strength, and Thermal Stability of Solid Composite Electrolytes
journal, September 2017
- Zhang, Xue; Liu, Ting; Zhang, Shuofeng
- Journal of the American Chemical Society, Vol. 139, Issue 39
Polysulfide-Shuttle Control in Lithium-Sulfur Batteries with a Chemically/Electrochemically Compatible NaSICON-Type Solid Electrolyte
journal, August 2016
- Yu, Xingwen; Bi, Zhonghe; Zhao, Feng
- Advanced Energy Materials, Vol. 6, Issue 24
Stability of NaSICON-type Li1.3Al0.3Ti1.7P3O12 in aqueous solutions
journal, May 2013
- Jackman, Spencer D.; Cutler, Raymond A.
- Journal of Power Sources, Vol. 230
Facile proton conduction in H+/Li+ ion-exchanged garnet-type fast Li-ion conducting Li5La3Nb2O12
journal, January 2013
- Truong, Lina; Howard, Matthew; Clemens, Oliver
- Journal of Materials Chemistry A, Vol. 1, Issue 43
Mastering the interface for advanced all-solid-state lithium rechargeable batteries
journal, November 2016
- Li, Yutao; Zhou, Weidong; Chen, Xi
- Proceedings of the National Academy of Sciences, Vol. 113, Issue 47
Dendrite-Free Li-Metal Battery Enabled by a Thin Asymmetric Solid Electrolyte with Engineered Layers
journal, December 2017
- Duan, Hui; Yin, Ya-Xia; Shi, Yang
- Journal of the American Chemical Society, Vol. 140, Issue 1
Lithium battery chemistries enabled by solid-state electrolytes
journal, February 2017
- Manthiram, Arumugam; Yu, Xingwen; Wang, Shaofei
- Nature Reviews Materials, Vol. 2, Issue 4
Toward garnet electrolyte–based Li metal batteries: An ultrathin, highly effective, artificial solid-state electrolyte/metallic Li interface
journal, April 2017
- Fu, Kun (Kelvin); Gong, Yunhui; Liu, Boyang
- Science Advances, Vol. 3, Issue 4
Plating a Dendrite-Free Lithium Anode with a Polymer/Ceramic/Polymer Sandwich Electrolyte
journal, July 2016
- Zhou, Weidong; Wang, Shaofei; Li, Yutao
- Journal of the American Chemical Society, Vol. 138, Issue 30
Stability of the solid electrolyte Li3OBr to common battery solvents
journal, January 2014
- Schroeder, D. J.; Hubaud, A. A.; Vaughey, J. T.
- Materials Research Bulletin, Vol. 49