DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Li 2 S 6 ‐Integrated PEO‐Based Polymer Electrolytes for All‐Solid‐State Lithium‐Metal Batteries

Authors:
ORCiD logo [1];  [1];  [1];  [2];  [1];  [2];  [1];  [1]; ORCiD logo [1]
  1. Materials Science and Engineering Program and Texas Materials Institute The University of Texas at Austin Austin TX 78712 USA
  2. College of Materials Science and Engineering Zhejiang University of Technology Hangzhou 310014 China
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1804902
Grant/Contract Number:  
SC0005397; EE0007762
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Angewandte Chemie
Additional Journal Information:
Journal Name: Angewandte Chemie Journal Volume: 133 Journal Issue: 32; Journal ID: ISSN 0044-8249
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
Germany
Language:
English

Citation Formats

Fang, Ruyi, Xu, Biyi, Grundish, Nicholas S., Xia, Yang, Li, Yutao, Lu, Chengwei, Liu, Yijie, Wu, Nan, and Goodenough, John B. Li 2 S 6 ‐Integrated PEO‐Based Polymer Electrolytes for All‐Solid‐State Lithium‐Metal Batteries. Germany: N. p., 2021. Web. doi:10.1002/ange.202106039.
Fang, Ruyi, Xu, Biyi, Grundish, Nicholas S., Xia, Yang, Li, Yutao, Lu, Chengwei, Liu, Yijie, Wu, Nan, & Goodenough, John B. Li 2 S 6 ‐Integrated PEO‐Based Polymer Electrolytes for All‐Solid‐State Lithium‐Metal Batteries. Germany. https://doi.org/10.1002/ange.202106039
Fang, Ruyi, Xu, Biyi, Grundish, Nicholas S., Xia, Yang, Li, Yutao, Lu, Chengwei, Liu, Yijie, Wu, Nan, and Goodenough, John B. Wed . "Li 2 S 6 ‐Integrated PEO‐Based Polymer Electrolytes for All‐Solid‐State Lithium‐Metal Batteries". Germany. https://doi.org/10.1002/ange.202106039.
@article{osti_1804902,
title = {Li 2 S 6 ‐Integrated PEO‐Based Polymer Electrolytes for All‐Solid‐State Lithium‐Metal Batteries},
author = {Fang, Ruyi and Xu, Biyi and Grundish, Nicholas S. and Xia, Yang and Li, Yutao and Lu, Chengwei and Liu, Yijie and Wu, Nan and Goodenough, John B.},
abstractNote = {},
doi = {10.1002/ange.202106039},
journal = {Angewandte Chemie},
number = 32,
volume = 133,
place = {Germany},
year = {2021},
month = {6}
}

Works referenced in this record:

Recent Advances in Energy Chemistry between Solid-State Electrolyte and Safe Lithium-Metal Anodes
journal, January 2019


Direct tracking of the polysulfide shuttling and interfacial evolution in all-solid-state lithium–sulfur batteries: a degradation mechanism study
journal, January 2019

  • Song, Yue-Xian; Shi, Yang; Wan, Jing
  • Energy & Environmental Science, Vol. 12, Issue 8
  • DOI: 10.1039/C9EE00578A

An Improved Response of Multi Level Inverter Based PR Controlled SMPS
journal, January 2020


Challenges for Rechargeable Li Batteries
journal, February 2010

  • Goodenough, John B.; Kim, Youngsik
  • Chemistry of Materials, Vol. 22, Issue 3, p. 587-603
  • DOI: 10.1021/cm901452z

In Situ Construction of a LiF‐Enriched Interface for Stable All‐Solid‐State Batteries and its Origin Revealed by Cryo‐TEM
journal, July 2020


Novel composite polymer electrolyte comprising mesoporous structured SiO2 and PEO/Li
journal, January 2003


The synergetic effect of lithium polysulfide and lithium nitrate to prevent lithium dendrite growth
journal, June 2015

  • Li, Weiyang; Yao, Hongbin; Yan, Kai
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms8436

Effects of Al2O3 nanofiller and EC plasticizer on the ionic conductivity enhancement of solid PEO–LiCF3SO3 solid polymer electrolyte
journal, August 2011


Lithium dendrite growth mechanisms in polymer electrolytes and prevention strategies
journal, January 2017

  • Barai, Pallab; Higa, Kenneth; Srinivasan, Venkat
  • Physical Chemistry Chemical Physics, Vol. 19, Issue 31
  • DOI: 10.1039/C7CP03304D

Differentiated Lithium Salt Design for Multilayered PEO Electrolyte Enables a High‐Voltage Solid‐State Lithium Metal Battery
journal, September 2019


In situ polymerized succinonitrile-based solid polymer electrolytes for lithium ion batteries
journal, February 2020


Assessing structure and stability of polymer/lithium-metal interfaces from first-principles calculations
journal, January 2019

  • Ebadi, Mahsa; Marchiori, Cleber; Mindemark, Jonas
  • Journal of Materials Chemistry A, Vol. 7, Issue 14
  • DOI: 10.1039/C8TA12147H

Practical Challenges and Future Perspectives of All-Solid-State Lithium-Metal Batteries
journal, April 2019


Succinonitrile as a Versatile Additive for Polymer Electrolytes
journal, October 2007

  • Fan, L. -Z.; Hu, Y. -S.; Bhattacharyya, A. J.
  • Advanced Functional Materials, Vol. 17, Issue 15
  • DOI: 10.1002/adfm.200601070

Reviving the lithium metal anode for high-energy batteries
journal, March 2017

  • Lin, Dingchang; Liu, Yayuan; Cui, Yi
  • Nature Nanotechnology, Vol. 12, Issue 3
  • DOI: 10.1038/nnano.2017.16

Interfacial Chemistry Enables Stable Cycling of All-Solid-State Li Metal Batteries at High Current Densities
journal, April 2021

  • Xu, Biyi; Li, Xinyu; Yang, Chao
  • Journal of the American Chemical Society, Vol. 143, Issue 17
  • DOI: 10.1021/jacs.1c00752

Low-Cost Hollow Mesoporous Polymer Spheres and All-Solid-State Lithium, Sodium Batteries
journal, October 2015

  • Zhou, Weidong; Gao, Hongcai; Goodenough, John B.
  • Advanced Energy Materials, Vol. 6, Issue 1
  • DOI: 10.1002/aenm.201501802

In Situ Formation of Li 3 P Layer Enables Fast Li + Conduction across Li/Solid Polymer Electrolyte Interface
journal, April 2020

  • Wu, Nan; Li, Yutao; Dolocan, Andrei
  • Advanced Functional Materials, Vol. 30, Issue 22
  • DOI: 10.1002/adfm.202000831

A review of composite solid-state electrolytes for lithium batteries: fundamentals, key materials and advanced structures
journal, January 2020

  • Zheng, Yun; Yao, Yuze; Ou, Jiahua
  • Chemical Society Reviews, Vol. 49, Issue 23
  • DOI: 10.1039/D0CS00305K

Enhanced Surface Interactions Enable Fast Li + Conduction in Oxide/Polymer Composite Electrolyte
journal, January 2020

  • Wu, Nan; Chien, Po‐Hsiu; Qian, Yumin
  • Angewandte Chemie International Edition, Vol. 59, Issue 10
  • DOI: 10.1002/anie.201914478

Effect of plasticizer on structure—property relationship in composite polymer electrolytes
journal, January 2005


Fast Li + Conduction Mechanism and Interfacial Chemistry of a NASICON/Polymer Composite Electrolyte
journal, January 2020

  • Wu, Nan; Chien, Po-Hsiu; Li, Yutao
  • Journal of the American Chemical Society, Vol. 142, Issue 5
  • DOI: 10.1021/jacs.9b12233

Intermolecular Chemistry in Solid Polymer Electrolytes for High‐Energy‐Density Lithium Batteries
journal, July 2019


Toward High‐Energy‐Density Lithium Metal Batteries: Opportunities and Challenges for Solid Organic Electrolytes
journal, January 2020

  • Wang, Xiaoen; Kerr, Robert; Chen, Fangfang
  • Advanced Materials, Vol. 32, Issue 18
  • DOI: 10.1002/adma.201905219

Initial Steps in PEO Decomposition on a Li Metal Electrode
journal, August 2019

  • Mirsakiyeva, Amina; Ebadi, Mahsa; Araujo, C. Moyses
  • The Journal of Physical Chemistry C, Vol. 123, Issue 37
  • DOI: 10.1021/acs.jpcc.9b07712

Ultrathin, flexible, solid polymer composite electrolyte enabled with aligned nanoporous host for lithium batteries
journal, May 2019


Conformational, thermal, and ionic conductivity behavior of PEO in PEO/PMMA miscible blend: Investigating the effect of lithium salt
journal, December 2012

  • Ghelichi, Mahdi; Qazvini, Nader Taheri; Jafari, Seyed Hassan
  • Journal of Applied Polymer Science, Vol. 129, Issue 4
  • DOI: 10.1002/app.38897

Effect of plasticizers (EC or PC) on the ionic conductivity and thermal properties of the (PEO)9LiTf: Al2O3 nanocomposite polymer electrolyte system
journal, January 2008

  • Pitawala, H. M. J. C.; Dissanayake, M. A. K. L.; Seneviratne, V. A.
  • Journal of Solid State Electrochemistry, Vol. 12, Issue 7-8
  • DOI: 10.1007/s10008-008-0505-7

Recent Progress of the Solid-State Electrolytes for High-Energy Metal-Based Batteries
journal, January 2018


High-performance all-solid-state batteries enabled by salt bonding to perovskite in poly(ethylene oxide)
journal, August 2019

  • Xu, Henghui; Chien, Po-Hsiu; Shi, Jianjian
  • Proceedings of the National Academy of Sciences, Vol. 116, Issue 38
  • DOI: 10.1073/pnas.1907507116

Enhanced Surface Interactions Enable Fast Li + Conduction in Oxide/Polymer Composite Electrolyte
journal, January 2020


Nanocomposite solid polymer electrolytes based on poly(ethylene oxide)/POSS-PEG (n=13.3) hybrid nanoparticles for lithium ion batteries
journal, November 2015


Reaction Mechanism Optimization of Solid‐State Li–S Batteries with a PEO‐Based Electrolyte
journal, May 2020

  • Fang, Ruyi; Xu, Henghui; Xu, Biyi
  • Advanced Functional Materials, Vol. 31, Issue 2
  • DOI: 10.1002/adfm.202001812

Beyond PEO—Alternative host materials for Li + -conducting solid polymer electrolytes
journal, June 2018


Revisiting Scientific Issues for Industrial Applications of Lithium-Sulfur Batteries
journal, December 2018

  • Liu, Bo; Fang, Ruyi; Xie, Dong
  • Energy & Environmental Materials, Vol. 1, Issue 4
  • DOI: 10.1002/eem2.12021