Regulating the spatial distribution of metal nanoparticles within metal-organic frameworks to enhance catalytic efficiency
Abstract
Composites incorporating metal nanoparticles (MNPs) within metal-organic frameworks (MOFs) have broad applications in many fields. However, the controlled spatial distribution of the MNPs within MOFs remains a challenge for addressing key issues in catalysis, for example, the efficiency of catalysts due to the limitation of molecular diffusion within MOF channels. We report a facile strategy that enables MNPs to be encapsulated into MOFs with controllable spatial localization by using metal oxide both as support to load MNPs and as a sacrificial template to grow MOFs. This strategy is versatile to a variety of MNPs and MOF crystals. By localizing the encapsulated MNPs closer to the surface of MOFs, the resultant MNPs@MOF composites not only exhibit effective selectivity derived from MOF cavities, but also enhanced catalytic activity due to the spatial regulation of MNPs as close as possible to the MOF surface.
- Authors:
-
- Beijing Univ. of Chemical Technology (China). State Key Lab. of Chemical Resource Engineering
- Nanjing Univ. of Technology (China). Key Lab. of Flexible Electronics (KLOFE), Inst. of Advanced Materials (IAM) and Jiangsu National Synergetic Innovation Center for Advanced Materials (SICAM)
- Argonne National Lab. (ANL), Argonne, IL (United States). Chemical Sciences and Engineering Division
- Argonne National Lab. (ANL), Argonne, IL (United States). X-Ray Science Division
- Publication Date:
- Research Org.:
- Argonne National Laboratory (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V); National Natural Science Foundation of China (NSFC); Beijing Nova Program; Fundamental Research Funds for the Central Univ. (China); National Basic Research Program of China; Nanjing Tech Univ. (China); Central Committee of the Communist Party of China (CPC)
- OSTI Identifier:
- 1439872
- Grant/Contract Number:
- AC02-06CH11357; 21271019; 21574065; 21504043; 21604038; Z121103002512023; YS1406; IRT1205; 2014CB932104; 2015CB932200; 21625401; BK20140044; BK20160975
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nature Communications
- Additional Journal Information:
- Journal Volume: 8; Journal ID: ISSN 2041-1723
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; 77 NANOSCIENCE AND NANOTECHNOLOGY; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Metal–organic frameworks; Nanoparticles; Organic–inorganic nanostructures
Citation Formats
Yang, Qiu, Liu, Wenxian, Wang, Bingqing, Zhang, Weina, Zeng, Xiaoqiao, Zhang, Cong, Qin, Yongji, Sun, Xiaoming, Wu, Tianpin, Liu, Junfeng, Huo, Fengwei, and Lu, Jun. Regulating the spatial distribution of metal nanoparticles within metal-organic frameworks to enhance catalytic efficiency. United States: N. p., 2017.
Web. doi:10.1038/ncomms14429.
Yang, Qiu, Liu, Wenxian, Wang, Bingqing, Zhang, Weina, Zeng, Xiaoqiao, Zhang, Cong, Qin, Yongji, Sun, Xiaoming, Wu, Tianpin, Liu, Junfeng, Huo, Fengwei, & Lu, Jun. Regulating the spatial distribution of metal nanoparticles within metal-organic frameworks to enhance catalytic efficiency. United States. https://doi.org/10.1038/ncomms14429
Yang, Qiu, Liu, Wenxian, Wang, Bingqing, Zhang, Weina, Zeng, Xiaoqiao, Zhang, Cong, Qin, Yongji, Sun, Xiaoming, Wu, Tianpin, Liu, Junfeng, Huo, Fengwei, and Lu, Jun. Tue .
"Regulating the spatial distribution of metal nanoparticles within metal-organic frameworks to enhance catalytic efficiency". United States. https://doi.org/10.1038/ncomms14429. https://www.osti.gov/servlets/purl/1439872.
@article{osti_1439872,
title = {Regulating the spatial distribution of metal nanoparticles within metal-organic frameworks to enhance catalytic efficiency},
author = {Yang, Qiu and Liu, Wenxian and Wang, Bingqing and Zhang, Weina and Zeng, Xiaoqiao and Zhang, Cong and Qin, Yongji and Sun, Xiaoming and Wu, Tianpin and Liu, Junfeng and Huo, Fengwei and Lu, Jun},
abstractNote = {Composites incorporating metal nanoparticles (MNPs) within metal-organic frameworks (MOFs) have broad applications in many fields. However, the controlled spatial distribution of the MNPs within MOFs remains a challenge for addressing key issues in catalysis, for example, the efficiency of catalysts due to the limitation of molecular diffusion within MOF channels. We report a facile strategy that enables MNPs to be encapsulated into MOFs with controllable spatial localization by using metal oxide both as support to load MNPs and as a sacrificial template to grow MOFs. This strategy is versatile to a variety of MNPs and MOF crystals. By localizing the encapsulated MNPs closer to the surface of MOFs, the resultant MNPs@MOF composites not only exhibit effective selectivity derived from MOF cavities, but also enhanced catalytic activity due to the spatial regulation of MNPs as close as possible to the MOF surface.},
doi = {10.1038/ncomms14429},
journal = {Nature Communications},
number = ,
volume = 8,
place = {United States},
year = {Tue Feb 14 00:00:00 EST 2017},
month = {Tue Feb 14 00:00:00 EST 2017}
}
Web of Science
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In situ synthesized low-PtCo@porous carbon catalyst for highly efficient hydrogen evolution
journal, January 2019
- Qin, Yudao; Han, Xiaoyu; Gadipelli, Srinivas
- Journal of Materials Chemistry A, Vol. 7, Issue 11
High stability of ultra-small and isolated gold nanoparticles in metal–organic framework materials
journal, January 2019
- Cure, Jérémy; Mattson, Eric; Cocq, Kévin
- Journal of Materials Chemistry A, Vol. 7, Issue 29
Atomic-layer-deposition-formed sacrificial template for the construction of an MIL-53 shell to increase selectivity of hydrogenation reactions
journal, January 2019
- Xu, Tiantian; Sun, Kai; Gao, Daowei
- Chemical Communications, Vol. 55, Issue 53
Regulating the size and spatial distribution of Pd nanoparticles supported by the defect engineered metal–organic framework HKUST-1 and applied in the aerobic oxidation of cinnamyl alcohol
journal, January 2019
- Guo, Penghu; Fu, Qi; Yildiz, Ceylan
- Catalysis Science & Technology, Vol. 9, Issue 14
Core–shell-type ZIF-8@ZIF-67@POM hybrids as efficient electrocatalysts for the oxygen evolution reaction
journal, January 2019
- Wang, Yan; Wang, Yuyin; Zhang, Li
- Inorganic Chemistry Frontiers, Vol. 6, Issue 9
Mechanochemistry-assisted encapsulation of metal nanoparticles in MOF matrices via a sacrificial strategy
journal, January 2019
- Li, Xiaochen; Zhang, Zhihua; Xiao, Weiming
- Journal of Materials Chemistry A, Vol. 7, Issue 24
Zeolitic-imidazolate frameworks derived Pt-free counter electrodes for high-performance quantum dot-sensitized solar cells
journal, May 2018
- Xu, Wenjiao; Sun, Yuxiu; Ding, Bin
- Royal Society Open Science, Vol. 5, Issue 5
Recent Innovation of Metal-Organic Frameworks for Carbon Dioxide Photocatalytic Reduction
journal, December 2019
- Kidanemariam, Alemayehu; Lee, Jiwon; Park, Juhyun
- Polymers, Vol. 11, Issue 12
Engineering channels of metal–organic frameworks to enhance catalytic selectivity
journal, January 2019
- Liu, Ye; Shen, Yu; Zhang, Weina
- Chemical Communications, Vol. 55, Issue 78
Multi-shelled Hollow Metal-Organic Frameworks
journal, March 2017
- Liu, Wenxian; Huang, Jijiang; Yang, Qiu
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Structural Engineering of Low‐Dimensional Metal–Organic Frameworks: Synthesis, Properties, and Applications
journal, April 2019
- Liu, Wenxian; Yin, Ruilian; Xu, Xilian
- Advanced Science, Vol. 6, Issue 12
Zeolitic-imidazolate frameworks derived Pt-free counter electrodes for high-performance quantum dot-sensitized solar cells
journal, May 2018
- Xu, Wenjiao; Sun, Yuxiu; Ding, Bin
- Royal Society Open Science, Vol. 5, Issue 5
Recent Innovation of Metal-Organic Frameworks for Carbon Dioxide Photocatalytic Reduction
journal, December 2019
- Kidanemariam, Alemayehu; Lee, Jiwon; Park, Juhyun
- Polymers, Vol. 11, Issue 12