skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Layered P2-Type K 0.65 Fe 0.5 Mn 0.5 O 2 Microspheres as Superior Cathode for High-Energy Potassium-Ion Batteries

Authors:
 [1];  [1];  [1];  [1];  [1];  [2];  [3];  [3]; ORCiD logo [1]
  1. Department of Chemical and Biomolecular Engineering, University of Maryland, College Park MD 20742 USA
  2. Department of Chemistry and Biochemistry, University of Maryland, College Park MD 20742 USA
  3. School of Materials Science and Engineering, University of Shanghai for Science and Technology, Shanghai 200093 P. R. China
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1439525
Grant/Contract Number:  
DESC0001160
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Advanced Functional Materials
Additional Journal Information:
Journal Name: Advanced Functional Materials Journal Volume: 28 Journal Issue: 28; Journal ID: ISSN 1616-301X
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
Germany
Language:
English

Citation Formats

Deng, Tao, Fan, Xiulin, Chen, Ji, Chen, Long, Luo, Chao, Zhou, Xiuquan, Yang, Junhe, Zheng, Shiyou, and Wang, Chunsheng. Layered P2-Type K 0.65 Fe 0.5 Mn 0.5 O 2 Microspheres as Superior Cathode for High-Energy Potassium-Ion Batteries. Germany: N. p., 2018. Web. doi:10.1002/adfm.201800219.
Deng, Tao, Fan, Xiulin, Chen, Ji, Chen, Long, Luo, Chao, Zhou, Xiuquan, Yang, Junhe, Zheng, Shiyou, & Wang, Chunsheng. Layered P2-Type K 0.65 Fe 0.5 Mn 0.5 O 2 Microspheres as Superior Cathode for High-Energy Potassium-Ion Batteries. Germany. doi:10.1002/adfm.201800219.
Deng, Tao, Fan, Xiulin, Chen, Ji, Chen, Long, Luo, Chao, Zhou, Xiuquan, Yang, Junhe, Zheng, Shiyou, and Wang, Chunsheng. Wed . "Layered P2-Type K 0.65 Fe 0.5 Mn 0.5 O 2 Microspheres as Superior Cathode for High-Energy Potassium-Ion Batteries". Germany. doi:10.1002/adfm.201800219.
@article{osti_1439525,
title = {Layered P2-Type K 0.65 Fe 0.5 Mn 0.5 O 2 Microspheres as Superior Cathode for High-Energy Potassium-Ion Batteries},
author = {Deng, Tao and Fan, Xiulin and Chen, Ji and Chen, Long and Luo, Chao and Zhou, Xiuquan and Yang, Junhe and Zheng, Shiyou and Wang, Chunsheng},
abstractNote = {},
doi = {10.1002/adfm.201800219},
journal = {Advanced Functional Materials},
number = 28,
volume = 28,
place = {Germany},
year = {2018},
month = {5}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1002/adfm.201800219

Citation Metrics:
Cited by: 13 works
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

Layered-to-Rock-Salt Transformation in Desodiated Na x CrO 2 ( x 0.4)
journal, February 2016


Insights into the structural effects of layered cathode materials for high voltage sodium-ion batteries
journal, January 2017

  • Xu, Gui-Liang; Amine, Rachid; Xu, Yue-Feng
  • Energy & Environmental Science, Vol. 10, Issue 7
  • DOI: 10.1039/C7EE00827A

Electrochemical investigation of the P2–NaxCoO2 phase diagram
journal, December 2010

  • Berthelot, R.; Carlier, D.; Delmas, C.
  • Nature Materials, Vol. 10, Issue 1
  • DOI: 10.1038/nmat2920

Investigation of Potassium Storage in Layered P3-Type K 0.5 MnO 2 Cathode
journal, August 2017

  • Kim, Haegyeom; Seo, Dong-Hwa; Kim, Jae Chul
  • Advanced Materials, Vol. 29, Issue 37
  • DOI: 10.1002/adma.201702480

Advances in Structure and Property Optimizations of Battery Electrode Materials
journal, November 2017


Sodium deintercalation from sodium iron oxide
journal, June 1994


Prussian Green: A High Rate Capacity Cathode for Potassium Ion Batteries
journal, June 2015


A fundamental parameters approach to X-ray line-profile fitting
journal, April 1992


Tin-based composite anodes for potassium-ion batteries
journal, January 2016

  • Sultana, Irin; Ramireddy, Thrinathreddy; Rahman, Md Mokhlesur
  • Chemical Communications, Vol. 52, Issue 59
  • DOI: 10.1039/C6CC03649J

Superior Stable Self-Healing SnP 3 Anode for Sodium-Ion Batteries
journal, June 2015

  • Fan, Xiulin; Mao, Jianfeng; Zhu, Yujie
  • Advanced Energy Materials, Vol. 5, Issue 18
  • DOI: 10.1002/aenm.201500174

Earth Abundant Fe/Mn-Based Layered Oxide Interconnected Nanowires for Advanced K-Ion Full Batteries
journal, December 2016


Reversible Dendrite-Free Potassium Plating and Stripping Electrochemistry for Potassium Secondary Batteries
journal, July 2017

  • Xiao, Neng; McCulloch, William D.; Wu, Yiying
  • Journal of the American Chemical Society, Vol. 139, Issue 28
  • DOI: 10.1021/jacs.7b04945

High Voltage Mg-Doped Na 0.67 Ni 0.3– x Mg x Mn 0.7 O 2 ( x = 0.05, 0.1) Na-Ion Cathodes with Enhanced Stability and Rate Capability
journal, July 2016


Alternative electrochemical energy storage: potassium-based dual-graphite batteries
journal, January 2017

  • Beltrop, K.; Beuker, S.; Heckmann, A.
  • Energy & Environmental Science, Vol. 10, Issue 10
  • DOI: 10.1039/C7EE01535F

Recent Progress on Spray Pyrolysis for High Performance Electrode Materials in Lithium and Sodium Rechargeable Batteries
journal, December 2016

  • Zhu, Yujie; Choi, Seung Ho; Fan, Xiulin
  • Advanced Energy Materials, Vol. 7, Issue 7
  • DOI: 10.1002/aenm.201601578

Exploration of K 2 Ti 8 O 17 as an anode material for potassium-ion batteries
journal, January 2016

  • Han, Jin; Xu, Maowen; Niu, Yubin
  • Chemical Communications, Vol. 52, Issue 75
  • DOI: 10.1039/C6CC05102B

A New, Safe, High-Rate and High-Energy Polymer Lithium-Ion Battery
journal, August 2009

  • Hassoun, Jusef; Panero, Stefania; Reale, Priscilla
  • Advanced Materials, Vol. 21, Issue 47
  • DOI: 10.1002/adma.200900470

Self-Templated Formation of P2-type K 0.6 CoO 2 Microspheres for High Reversible Potassium-Ion Batteries
journal, January 2018


Potassium secondary cell based on Prussian blue cathode
journal, February 2004


Mg rechargeable batteries: an on-going challenge
journal, January 2013

  • Yoo, Hyun Deog; Shterenberg, Ivgeni; Gofer, Yosef
  • Energy & Environmental Science, Vol. 6, Issue 8, p. 2265-2279
  • DOI: 10.1039/c3ee40871j

P2-type Na0.67Mn0.65Fe0.2Ni0.15O2 Cathode Material with High-capacity for Sodium-ion Battery
journal, January 2014


Update on anode materials for Na-ion batteries
journal, January 2015

  • Kang, Hongyan; Liu, Yongchang; Cao, Kangzhe
  • Journal of Materials Chemistry A, Vol. 3, Issue 35
  • DOI: 10.1039/C5TA03181H

Role of Nitrogen-Doped Graphene for Improved High-Capacity Potassium Ion Battery Anodes
journal, October 2016


A Practical High-Energy Cathode for Sodium-Ion Batteries Based on Uniform P2-Na 0.7 CoO 2 Microspheres
journal, April 2017

  • Fang, Yongjin; Yu, Xin-Yao; Lou, Xiong Wen David
  • Angewandte Chemie International Edition, Vol. 56, Issue 21
  • DOI: 10.1002/anie.201702024

A Novel Potassium-Ion-Based Dual-Ion Battery
journal, March 2017


Porous Fe-Mn-O nanocomposites: Synthesis and supercapacitor electrode application
journal, June 2016

  • Zhu, Guoxing; Yang, Jing; Liu, Yuanjun
  • Progress in Natural Science: Materials International, Vol. 26, Issue 3
  • DOI: 10.1016/j.pnsc.2016.05.016

The Li-Ion Rechargeable Battery: A Perspective
journal, January 2013

  • Goodenough, John B.; Park, Kyu-Sung
  • Journal of the American Chemical Society, Vol. 135, Issue 4
  • DOI: 10.1021/ja3091438

Radially aligned hierarchical columnar structure as a cathode material for high energy density sodium-ion batteries
journal, April 2015

  • Hwang, Jang-Yeon; Oh, Seung-Min; Myung, Seung-Taek
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms7865

Potassium intercalation into graphite to realize high-voltage/high-power potassium-ion batteries and potassium-ion capacitors
journal, November 2015


Potassium-Ion Oxygen Battery Based on a High Capacity Antimony Anode
journal, November 2015

  • McCulloch, William D.; Ren, Xiaodi; Yu, Mingzhe
  • ACS Applied Materials & Interfaces, Vol. 7, Issue 47
  • DOI: 10.1021/acsami.5b08037

A high-voltage solid-state secondary cell based on chromium hexacyanometallates
journal, May 2003


Hard Carbon Microspheres: Potassium-Ion Anode Versus Sodium-Ion Anode
journal, November 2015

  • Jian, Zelang; Xing, Zhenyu; Bommier, Clement
  • Advanced Energy Materials, Vol. 6, Issue 3
  • DOI: 10.1002/aenm.201501874

K-Ion Batteries Based on a P2-Type K 0.6 CoO 2 Cathode
journal, May 2017

  • Kim, Haegyeom; Kim, Jae Chul; Bo, Shou-Hang
  • Advanced Energy Materials, Vol. 7, Issue 17
  • DOI: 10.1002/aenm.201700098

Structure of the high voltage phase of layered P2-Na 2/3−z [Mn 1/2 Fe 1/2 ]O 2 and the positive effect of Ni substitution on its stability
journal, January 2015

  • Talaie, Elahe; Duffort, Victor; Smith, Hillary L.
  • Energy & Environmental Science, Vol. 8, Issue 8
  • DOI: 10.1039/C5EE01365H

Research Development on Sodium-Ion Batteries
journal, October 2014

  • Yabuuchi, Naoaki; Kubota, Kei; Dahbi, Mouad
  • Chemical Reviews, Vol. 114, Issue 23
  • DOI: 10.1021/cr500192f

Electrochemical ammonia compression
journal, January 2017

  • Tao, Ye; Gibbons, William; Hwang, Yunho
  • Chemical Communications, Vol. 53, Issue 41
  • DOI: 10.1039/C7CC02302B

A comprehensive review of sodium layered oxides: powerful cathodes for Na-ion batteries
journal, January 2015

  • Han, Man Huon; Gonzalo, Elena; Singh, Gurpreet
  • Energy & Environmental Science, Vol. 8, Issue 1
  • DOI: 10.1039/C4EE03192J

Non-Aqueous K-Ion Battery Based on Layered K 0.3 MnO 2 and Hard Carbon/Carbon Black
journal, January 2016

  • Vaalma, Christoph; Giffin, Guinevere A.; Buchholz, Daniel
  • Journal of The Electrochemical Society, Vol. 163, Issue 7
  • DOI: 10.1149/2.0921607jes

Suppressing the P2-O2 Phase Transition of Na 0.67 Mn 0.67 Ni 0.33 O 2 by Magnesium Substitution for Improved Sodium-Ion Batteries
journal, May 2016

  • Wang, Peng-Fei; You, Ya; Yin, Ya-Xia
  • Angewandte Chemie International Edition, Vol. 55, Issue 26
  • DOI: 10.1002/anie.201602202

Potassium–Sulfur Batteries: A New Member of Room-Temperature Rechargeable Metal–Sulfur Batteries
journal, August 2014

  • Zhao, Qing; Hu, Yuxiang; Zhang, Kai
  • Inorganic Chemistry, Vol. 53, Issue 17
  • DOI: 10.1021/ic500919e

Potassium Prussian Blue Nanoparticles: A Low-Cost Cathode Material for Potassium-Ion Batteries
journal, December 2016

  • Zhang, Chenglin; Xu, Yang; Zhou, Min
  • Advanced Functional Materials, Vol. 27, Issue 4
  • DOI: 10.1002/adfm.201604307

Potassium Secondary Batteries
journal, October 2016

  • Eftekhari, Ali; Jian, Zelang; Ji, Xiulei
  • ACS Applied Materials & Interfaces, Vol. 9, Issue 5
  • DOI: 10.1021/acsami.6b07989

First-Principles Study of Alkali and Alkaline Earth Ion Intercalation in Iron Hexacyanoferrate: The Important Role of Ionic Radius
journal, October 2013

  • Ling, Chen; Chen, Jiajun; Mizuno, Fuminori
  • The Journal of Physical Chemistry C, Vol. 117, Issue 41
  • DOI: 10.1021/jp4078689

Low-Cost High-Energy Potassium Cathode
journal, January 2017

  • Xue, Leigang; Li, Yutao; Gao, Hongcai
  • Journal of the American Chemical Society, Vol. 139, Issue 6
  • DOI: 10.1021/jacs.6b12598

Energy and Capacity Projections for Practical Dual-Graphite Cells
journal, January 2000

  • Dahn, J. R.; Seel, J. A.
  • Journal of The Electrochemical Society, Vol. 147, Issue 3
  • DOI: 10.1149/1.1393289

Lithium-ion batteries. A look into the future
journal, January 2011

  • Scrosati, Bruno; Hassoun, Jusef; Sun, Yang-Kook
  • Energy & Environmental Science, Vol. 4, Issue 9
  • DOI: 10.1039/c1ee01388b

Hard-Soft Composite Carbon as a Long-Cycling and High-Rate Anode for Potassium-Ion Batteries
journal, May 2017

  • Jian, Zelang; Hwang, Sooyeon; Li, Zhifei
  • Advanced Functional Materials, Vol. 27, Issue 26
  • DOI: 10.1002/adfm.201700324

P2-type Nax[Fe1/2Mn1/2]O2 made from earth-abundant elements for rechargeable Na batteries
journal, April 2012

  • Yabuuchi, Naoaki; Kajiyama, Masataka; Iwatate, Junichi
  • Nature Materials, Vol. 11, Issue 6
  • DOI: 10.1038/nmat3309

Pomegranate-Structured Conversion-Reaction Cathode with a Built-in Li Source for High-Energy Li-Ion Batteries
journal, May 2016


Carbon Electrodes for K-Ion Batteries
journal, September 2015

  • Jian, Zelang; Luo, Wei; Ji, Xiulei
  • Journal of the American Chemical Society, Vol. 137, Issue 36
  • DOI: 10.1021/jacs.5b06809

Short-Range Order in Mesoporous Carbon Boosts Potassium-Ion Battery Performance
journal, October 2017

  • Wang, Wei; Zhou, Jinhui; Wang, Zhuopeng
  • Advanced Energy Materials, Vol. 8, Issue 5
  • DOI: 10.1002/aenm.201701648

Layered P2-Na 0.66 Fe 0.5 Mn 0.5 O 2 Cathode Material for Rechargeable Sodium-Ion Batteries
journal, August 2013


Scalable synthesis of Na 3 V 2 (PO 4 ) 3 /C porous hollow spheres as a cathode for Na-ion batteries
journal, January 2015

  • Mao, Jianfeng; Luo, Chao; Gao, Tao
  • Journal of Materials Chemistry A, Vol. 3, Issue 19
  • DOI: 10.1039/C5TA01007A

High-Performance Olivine NaFePO 4 Microsphere Cathode Synthesized by Aqueous Electrochemical Displacement Method for Sodium Ion Batteries
journal, August 2015

  • Fang, Yongjin; Liu, Qi; Xiao, Lifen
  • ACS Applied Materials & Interfaces, Vol. 7, Issue 32
  • DOI: 10.1021/acsami.5b04691

Activated carbon from the graphite with increased rate capability for the potassium ion battery
journal, October 2017


Potassium Ion Batteries with Graphitic Materials
journal, October 2015