skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Directionally assembled MoS 2 with significantly expanded interlayer spacing: a superior anode material for high-rate lithium-ion batteries

Abstract

Interlayer-expanded MoS 2 nanosheets directionally assembled on multi-walled carbon nanotubes represent a new class of anode materials for lithium ion batteries with superior high rate capacity.

Authors:
 [1]; ORCiD logo [2];  [3];  [1]; ORCiD logo [1];  [3]; ORCiD logo [1]
  1. Department of Chemistry, Temple University, Philadelphia, USA
  2. Center for Nanoscale Materials, Argonne National Laboratory, Argonne, USA
  3. Chemical Sciences and Engineering Division, Argonne National Laboratory, Argonne, USA
Publication Date:
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1435988
Grant/Contract Number:  
AC02-06CH11357
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Materials Chemistry Frontiers
Additional Journal Information:
Journal Name: Materials Chemistry Frontiers Journal Volume: 2 Journal Issue: 8; Journal ID: ISSN 2052-1537
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Wei, Qilin, Gao, Min-Rui, Li, Yan, Zhang, Dongtang, Wu, Siyu, Chen, Zonghai, and Sun, Yugang. Directionally assembled MoS 2 with significantly expanded interlayer spacing: a superior anode material for high-rate lithium-ion batteries. United Kingdom: N. p., 2018. Web. doi:10.1039/C8QM00117K.
Wei, Qilin, Gao, Min-Rui, Li, Yan, Zhang, Dongtang, Wu, Siyu, Chen, Zonghai, & Sun, Yugang. Directionally assembled MoS 2 with significantly expanded interlayer spacing: a superior anode material for high-rate lithium-ion batteries. United Kingdom. doi:10.1039/C8QM00117K.
Wei, Qilin, Gao, Min-Rui, Li, Yan, Zhang, Dongtang, Wu, Siyu, Chen, Zonghai, and Sun, Yugang. Mon . "Directionally assembled MoS 2 with significantly expanded interlayer spacing: a superior anode material for high-rate lithium-ion batteries". United Kingdom. doi:10.1039/C8QM00117K.
@article{osti_1435988,
title = {Directionally assembled MoS 2 with significantly expanded interlayer spacing: a superior anode material for high-rate lithium-ion batteries},
author = {Wei, Qilin and Gao, Min-Rui and Li, Yan and Zhang, Dongtang and Wu, Siyu and Chen, Zonghai and Sun, Yugang},
abstractNote = {Interlayer-expanded MoS 2 nanosheets directionally assembled on multi-walled carbon nanotubes represent a new class of anode materials for lithium ion batteries with superior high rate capacity.},
doi = {10.1039/C8QM00117K},
journal = {Materials Chemistry Frontiers},
number = 8,
volume = 2,
place = {United Kingdom},
year = {2018},
month = {1}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1039/C8QM00117K

Citation Metrics:
Cited by: 3 works
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

Self-templated formation of tremella-like MoS2 with expanded spacing of (002) crystal planes for Li-ion batteries
journal, February 2016


Carbon Nanofibers Decorated with Molybdenum Disulfide Nanosheets: Synergistic Lithium Storage and Enhanced Electrochemical Performance
journal, September 2014

  • Zhou, Fei; Xin, Sen; Liang, Hai-Wei
  • Angewandte Chemie International Edition, Vol. 53, Issue 43
  • DOI: 10.1002/anie.201407103

Rhenium dichalcogenides (ReX 2 , X = S or Se): an emerging class of TMDs family
journal, January 2017

  • Hafeez, Muhammad; Gan, Lin; Saleem Bhatti, Arshad
  • Materials Chemistry Frontiers, Vol. 1, Issue 10
  • DOI: 10.1039/C6QM00373G

Atomic Layer Deposited MoS 2 as a Carbon and Binder Free Anode in Li-ion Battery
journal, November 2014


Two-dimensional transition metal dichalcogenide nanomaterials for biosensing applications
journal, January 2017

  • Hu, Yanling; Huang, Ying; Tan, Chaoliang
  • Mater. Chem. Front., Vol. 1, Issue 1
  • DOI: 10.1039/C6QM00195E

Structural destabilization induced by lithium intercalation in MoS 2 and related compounds
journal, January 1983

  • Py, M. A.; Haering, R. R.
  • Canadian Journal of Physics, Vol. 61, Issue 1
  • DOI: 10.1139/p83-013

Development of MoS 2 -CNT Composite Thin Film from Layered MoS 2 for Lithium Batteries
journal, February 2013

  • Wang, Jia-Zhao; Lu, Lin; Lotya, Mustafa
  • Advanced Energy Materials, Vol. 3, Issue 6
  • DOI: 10.1002/aenm.201201000

Stable Li-ion battery anodes by in-situ polymerization of conducting hydrogel to conformally coat silicon nanoparticles
journal, June 2013

  • Wu, Hui; Yu, Guihua; Pan, Lijia
  • Nature Communications, Vol. 4, Issue 1
  • DOI: 10.1038/ncomms2941

Hierarchical MoS 2 Shells Supported on Carbon Spheres for Highly Reversible Lithium Storage
journal, March 2014

  • Zhang, Lei; Lou, Xiong Wen David
  • Chemistry - A European Journal, Vol. 20, Issue 18
  • DOI: 10.1002/chem.201400128

MoS 2 Nanoflowers with Expanded Interlayers as High-Performance Anodes for Sodium-Ion Batteries
journal, September 2014


Lithium ion battery applications of molybdenum disulfide (MoS 2 ) nanocomposites
journal, January 2014

  • Stephenson, Tyler; Li, Zhi; Olsen, Brian
  • Energy Environ. Sci., Vol. 7, Issue 1
  • DOI: 10.1039/C3EE42591F

MoS 2 Nanoplates Consisting of Disordered Graphene-like Layers for High Rate Lithium Battery Anode Materials
journal, November 2011

  • Hwang, Haesuk; Kim, Hyejung; Cho, Jaephil
  • Nano Letters, Vol. 11, Issue 11
  • DOI: 10.1021/nl202675f

Enabling Colloidal Synthesis of Edge-Oriented MoS 2 with Expanded Interlayer Spacing for Enhanced HER Catalysis
journal, February 2017


Self-assembly of hierarchical MoSx/CNT nanocomposites (2<x<3): towards high performance anode materials for lithium ion batteries
journal, July 2013

  • Shi, Yumeng; Wang, Ye; Wong, Jen It
  • Scientific Reports, Vol. 3, Issue 1
  • DOI: 10.1038/srep02169

Enhanced Li Adsorption and Diffusion on MoS2 Zigzag Nanoribbons by Edge Effects: A Computational Study
journal, August 2012

  • Li, Yafei; Wu, Dihua; Zhou, Zhen
  • The Journal of Physical Chemistry Letters, Vol. 3, Issue 16, p. 2221-2227
  • DOI: 10.1021/jz300792n

Accurate Control of Multishelled Co 3 O 4 Hollow Microspheres as High-Performance Anode Materials in Lithium-Ion Batteries
journal, May 2013

  • Wang, Jiangyan; Yang, Nailiang; Tang, Hongjie
  • Angewandte Chemie International Edition, Vol. 52, Issue 25
  • DOI: 10.1002/anie.201301622

Stacking nature of graphene layers in carbon nanotubes and nanofibres
journal, November 1997


Battery materials for ultrafast charging and discharging
journal, March 2009

  • Kang, Byoungwoo; Ceder, Gerbrand
  • Nature, Vol. 458, Issue 7235, p. 190-193
  • DOI: 10.1038/nature07853

Erratum: Corrigendum: Multi-shelled metal oxides prepared via an anion-adsorption mechanism for lithium-ion batteries
journal, May 2016


Multi-shelled hollow micro-/nanostructures: promising platforms for lithium-ion batteries
journal, January 2017

  • Wang, Jiangyan; Tang, Hongjie; Wang, Huan
  • Materials Chemistry Frontiers, Vol. 1, Issue 3
  • DOI: 10.1039/C6QM00273K

Chemical oxidation of multiwalled carbon nanotubes
journal, May 2008


Interlayer-expanded MoS 2
journal, March 2017


Enhanced Lithium Storage Performances of Hierarchical Hollow MoS 2 Nanoparticles Assembled from Nanosheets
journal, January 2013

  • Wang, Meng; Li, Guangda; Xu, Huayun
  • ACS Applied Materials & Interfaces, Vol. 5, Issue 3
  • DOI: 10.1021/am3026954

Synthesis of molybdenum disulfide (MoS2) for lithium ion battery applications
journal, September 2009


Superior Capacitive Performance Enabled by Edge-Oriented and Interlayer-Expanded MoS 2 Nanosheets Anchored on Reduced Graphene Oxide Sheets
journal, March 2018

  • Ji, Yajun; Wei, Qilin; Sun, Yugang
  • Industrial & Engineering Chemistry Research, Vol. 57, Issue 13
  • DOI: 10.1021/acs.iecr.7b05342

Nanostructured metal chalcogenides: synthesis, modification, and applications in energy conversion and storage devices
journal, January 2013

  • Gao, Min-Rui; Xu, Yun-Fei; Jiang, Jun
  • Chemical Society Reviews, Vol. 42, Issue 7
  • DOI: 10.1039/c2cs35310e

Enhancing sodium-ion battery performance with interlayer-expanded MoS2–PEO nanocomposites
journal, July 2015


Hierarchical MoS 2 microboxes constructed by nanosheets with enhanced electrochemical properties for lithium storage and water splitting
journal, January 2014

  • Zhang, Lei; Wu, Hao Bin; Yan, Ya
  • Energy Environ. Sci., Vol. 7, Issue 10
  • DOI: 10.1039/C4EE01932F

Hierarchical MoS 2 /Polyaniline Nanowires with Excellent Electrochemical Performance for Lithium-Ion Batteries
journal, December 2012


Engineering the surface structure of MoS2 to preferentially expose active edge sites for electrocatalysis
journal, October 2012

  • Kibsgaard, Jakob; Chen, Zhebo; Reinecke, Benjamin N.
  • Nature Materials, Vol. 11, Issue 11, p. 963-969
  • DOI: 10.1038/nmat3439

Interlayer-Expanded Molybdenum Disulfide Nanocomposites for Electrochemical Magnesium Storage
journal, February 2015


Electronics and optoelectronics of two-dimensional transition metal dichalcogenides
journal, November 2012

  • Wang, Qing Hua; Kalantar-Zadeh, Kourosh; Kis, Andras
  • Nature Nanotechnology, Vol. 7, Issue 11, p. 699-712
  • DOI: 10.1038/nnano.2012.193

Two-dimensional layered MoS 2 : rational design, properties and electrochemical applications
journal, January 2016

  • Zhang, Gong; Liu, Huijuan; Qu, Jiuhui
  • Energy & Environmental Science, Vol. 9, Issue 4
  • DOI: 10.1039/C5EE03761A

Tungsten Disulfide Nanotubes for Lithium Storage
journal, January 2004

  • Wang, G. X.; Bewlay, Steve; Yao, Jane
  • Electrochemical and Solid-State Letters, Vol. 7, Issue 10
  • DOI: 10.1149/1.1788591

A graphene-like MoS 2 /graphene nanocomposite as a highperformance anode for lithium ion batteries
journal, January 2014

  • Liu, Yongchang; Zhao, Yanping; Jiao, Lifang
  • J. Mater. Chem. A, Vol. 2, Issue 32
  • DOI: 10.1039/C4TA01644K

MoS 2 /Graphene Composite Paper for Sodium-Ion Battery Electrodes
journal, January 2014

  • David, Lamuel; Bhandavat, Romil; Singh, Gurpreet
  • ACS Nano, Vol. 8, Issue 2
  • DOI: 10.1021/nn406156b

Structural Evolution of Electrochemically Lithiated MoS 2 Nanosheets and the Role of Carbon Additive in Li-Ion Batteries
journal, October 2016


Building better batteries
journal, February 2008

  • Armand, M.; Tarascon, J.-M.
  • Nature, Vol. 451, Issue 7179, p. 652-657
  • DOI: 10.1038/451652a

Electrochemical Tuning of MoS 2 Nanoparticles on Three-Dimensional Substrate for Efficient Hydrogen Evolution
journal, April 2014

  • Wang, Haotian; Lu, Zhiyi; Kong, Desheng
  • ACS Nano, Vol. 8, Issue 5
  • DOI: 10.1021/nn500959v

Vanadium Oxide-Carbon Nanotube Composite Electrodes for Use in Secondary Lithium Batteries
journal, January 2002

  • Sakamoto, J. S.; Dunn, B.
  • Journal of The Electrochemical Society, Vol. 149, Issue 1
  • DOI: 10.1149/1.1425791

Two dimensional atomically thin MoS 2 nanosheets and their sensing applications
journal, January 2015

  • Huang, Yinxi; Guo, Jinhong; Kang, Yuejun
  • Nanoscale, Vol. 7, Issue 46
  • DOI: 10.1039/C5NR06144J

Exfoliated MoS 2 Nanocomposite as an Anode Material for Lithium Ion Batteries
journal, August 2010

  • Xiao, Jie; Choi, Daiwon; Cosimbescu, Lelia
  • Chemistry of Materials, Vol. 22, Issue 16
  • DOI: 10.1021/cm101254j

Three-dimensional bicontinuous ultrafast-charge and -discharge bulk battery electrodes
journal, March 2011

  • Zhang, Huigang; Yu, Xindi; Braun, Paul V.
  • Nature Nanotechnology, Vol. 6, Issue 5, p. 277-281
  • DOI: 10.1038/nnano.2011.38

Electrochemically Induced High Capacity Displacement Reaction of PEO/MoS2/Graphene Nanocomposites with Lithium
journal, May 2011

  • Xiao, Jie; Wang, Xiaojian; Yang, Xiao-Qing
  • Advanced Functional Materials, Vol. 21, Issue 15
  • DOI: 10.1002/adfm.201002752

Ultrasensitive photodetectors based on monolayer MoS2
journal, June 2013

  • Lopez-Sanchez, Oriol; Lembke, Dominik; Kayci, Metin
  • Nature Nanotechnology, Vol. 8, Issue 7
  • DOI: 10.1038/nnano.2013.100

A facile method for the synthesis of a C@MoO 2 hollow yolk–shell structure and its electrochemical properties as a faradaic electrode
journal, January 2017

  • Saha, Arka; Mondal, Aniruddha; Maiti, Sandipan
  • Materials Chemistry Frontiers, Vol. 1, Issue 8
  • DOI: 10.1039/C7QM00006E

Recent progress in conversion reaction metal oxide anodes for Li-ion batteries
journal, January 2017

  • Cao, Kangzhe; Jin, Ting; Yang, Li
  • Materials Chemistry Frontiers, Vol. 1, Issue 11
  • DOI: 10.1039/C7QM00175D

Highly Ordered Mesoporous MoS2 with Expanded Spacing of the (002) Crystal Plane for Ultrafast Lithium Ion Storage
journal, May 2012


The chemistry of two-dimensional layered transition metal dichalcogenide nanosheets
journal, April 2013

  • Chhowalla, Manish; Shin, Hyeon Suk; Eda, Goki
  • Nature Chemistry, Vol. 5, Issue 4, p. 263-275
  • DOI: 10.1038/nchem.1589

First-Principles Study of Zigzag MoS 2 Nanoribbon As a Promising Cathode Material for Rechargeable Mg Batteries
journal, December 2011

  • Yang, Siqi; Li, Daixin; Zhang, Tianran
  • The Journal of Physical Chemistry C, Vol. 116, Issue 1
  • DOI: 10.1021/jp2097026

Investigation of Yttrium and Polyvalent Ion Intercalation into Nanocrystalline Vanadium Oxide
journal, January 2001

  • Amatucci, G. G.; Badway, F.; Singhal, A.
  • Journal of The Electrochemical Society, Vol. 148, Issue 8
  • DOI: 10.1149/1.1383777

Superior stability and high capacity of restacked molybdenum disulfide as anode material for lithium ion batteries
journal, January 2010

  • Du, Guodong; Guo, Zaiping; Wang, Shiquan
  • Chem. Commun., Vol. 46, Issue 7
  • DOI: 10.1039/B920277C

MoS 2 /Graphene Composite Anodes with Enhanced Performance for Sodium-Ion Batteries: The Role of the Two-Dimensional Heterointerface
journal, January 2015

  • Xie, Xiuqiang; Ao, Zhimin; Su, Dawei
  • Advanced Functional Materials, Vol. 25, Issue 9
  • DOI: 10.1002/adfm.201404078

Single-layer MoS2 transistors
journal, January 2011

  • Radisavljevic, B.; Radenovic, A.; Brivio, J.
  • Nature Nanotechnology, Vol. 6, Issue 3, p. 147-150
  • DOI: 10.1038/nnano.2010.279

Edge-terminated molybdenum disulfide with a 9.4-Å interlayer spacing for electrochemical hydrogen production
journal, July 2015

  • Gao, Min-Rui; Chan, Maria K. Y.; Sun, Yugang
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms8493