Organosulfide-plasticized solid-electrolyte interphase layer enables stable lithium metal anodes for long-cycle lithium-sulfur batteries
Abstract
Lithium metal is a promising anode candidate for the next-generation rechargeable battery due to its highest specific capacity (3860 mA h g-1) and lowest potential, but low Coulombic efficiency and formation of lithium dendrites hinder its practical application. Here, we report a self-formed flexible hybrid solid-electrolyte interphase layer through co-deposition of organosulfides/organopolysulfides and inorganic lithium salts using sulfur-containing polymers as an additive in the electrolyte. The organosulfides/organopolysulfides serve as “plasticizer” in the solid-electrolyte interphase layer to improve its mechanical flexibility and toughness. The as-formed robust solid-electrolyte interphase layers enable dendrite-free lithium deposition and significantly improve Coulombic efficiency (99% over 400 cycles at a current density of 2mAcm-2). A lithium-sulfur battery based on this strategy exhibits long cycling life (1000 cycles) and good capacity retention. This study reveals an avenue to effectively fabricate stable solid-electrolyte interphase layer for solving the issues associated with lithium metal anodes.
- Authors:
-
[1];
[1];
[1]
- Pennsylvania State Univ., University Park, PA (United States). Department of Mechanical and Nuclear Engineering
- Pennsylvania State Univ., University Park, PA (United States). Department of Chemical Engineering
- Publication Date:
- Research Org.:
- Pennsylvania State Univ., University Park, PA (United States). Department of Mechanical and Nuclear Engineering; Pennsylvania State Univ., University Park, PA (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V)
- OSTI Identifier:
- 1430243
- Alternate Identifier(s):
- OSTI ID: 1435961
- Report Number(s):
- DOE-PENN STATE-0007795; DOE-PENNSTATE-0007795
Journal ID: ISSN 2041-1723; PII: 974
- Grant/Contract Number:
- EE0007795
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nature Communications
- Additional Journal Information:
- Journal Volume: 8; Journal Issue: 1; Journal ID: ISSN 2041-1723
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; 36 MATERIALS SCIENCE; 77 NANOSCIENCE AND NANOTECHNOLOGY; 42 ENGINEERING; Organosulfide; Lithium-Sulfur battery; solid-electrolyte interphase; Li metal
Citation Formats
Li, Guoxing, Gao, Yue, He, Xin, Huang, Qingquan, Chen, Shuru, Kim, Seong H., and Wang, Donghai. Organosulfide-plasticized solid-electrolyte interphase layer enables stable lithium metal anodes for long-cycle lithium-sulfur batteries. United States: N. p., 2017.
Web. doi:10.1038/s41467-017-00974-x.
Li, Guoxing, Gao, Yue, He, Xin, Huang, Qingquan, Chen, Shuru, Kim, Seong H., & Wang, Donghai. Organosulfide-plasticized solid-electrolyte interphase layer enables stable lithium metal anodes for long-cycle lithium-sulfur batteries. United States. https://doi.org/10.1038/s41467-017-00974-x
Li, Guoxing, Gao, Yue, He, Xin, Huang, Qingquan, Chen, Shuru, Kim, Seong H., and Wang, Donghai. Wed .
"Organosulfide-plasticized solid-electrolyte interphase layer enables stable lithium metal anodes for long-cycle lithium-sulfur batteries". United States. https://doi.org/10.1038/s41467-017-00974-x. https://www.osti.gov/servlets/purl/1430243.
@article{osti_1430243,
title = {Organosulfide-plasticized solid-electrolyte interphase layer enables stable lithium metal anodes for long-cycle lithium-sulfur batteries},
author = {Li, Guoxing and Gao, Yue and He, Xin and Huang, Qingquan and Chen, Shuru and Kim, Seong H. and Wang, Donghai},
abstractNote = {Lithium metal is a promising anode candidate for the next-generation rechargeable battery due to its highest specific capacity (3860 mA h g-1) and lowest potential, but low Coulombic efficiency and formation of lithium dendrites hinder its practical application. Here, we report a self-formed flexible hybrid solid-electrolyte interphase layer through co-deposition of organosulfides/organopolysulfides and inorganic lithium salts using sulfur-containing polymers as an additive in the electrolyte. The organosulfides/organopolysulfides serve as “plasticizer” in the solid-electrolyte interphase layer to improve its mechanical flexibility and toughness. The as-formed robust solid-electrolyte interphase layers enable dendrite-free lithium deposition and significantly improve Coulombic efficiency (99% over 400 cycles at a current density of 2mAcm-2). A lithium-sulfur battery based on this strategy exhibits long cycling life (1000 cycles) and good capacity retention. This study reveals an avenue to effectively fabricate stable solid-electrolyte interphase layer for solving the issues associated with lithium metal anodes.},
doi = {10.1038/s41467-017-00974-x},
journal = {Nature Communications},
number = 1,
volume = 8,
place = {United States},
year = {Wed Oct 11 00:00:00 EDT 2017},
month = {Wed Oct 11 00:00:00 EDT 2017}
}
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High rate and stable cycling of lithium metal anode
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A new class of Solvent-in-Salt electrolyte for high-energy rechargeable metallic lithium batteries
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The synergetic effect of lithium polysulfide and lithium nitrate to prevent lithium dendrite growth
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Three-dimensional porous carbon composites containing high sulfur nanoparticle content for high-performance lithium–sulfur batteries
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- Nature Communications, Vol. 7, Issue 1
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