Ionic conductive polymers as artificial solid electrolyte interphase films in Li metal batteries – A review

Gao, Shilun; Sun, Feiyuan; Liu, Nian; Yang, Huabin; Cao, Pengfei

doi:10.1016/j.mattod.2020.06.011

Title: Ionic conductive polymers as artificial solid electrolyte interphase films in Li metal batteries – A review

Abstract

Lithium (Li) metal has been considered as the ultimate anode material for next-generation rechargeable batteries due to its ultra-high theoretical specific capacity (3860 mAh g^-1) and the lowest reduction voltage (-3.04 V vs the standard hydrogen electrode). However, the dendritic Li formation, uncontrolled interfacial reactions, and huge volume variations lead to unstable solid electrolyte interphase (SEI) layer, low Coulombic efficiency and hence short cycling lifetime. Designing artificial solid electrolyte interphase (artificial SEI) films on the Li metal electrode exhibits great potential to solve the aforementioned problems and enable Li–metal batteries with prolonged lifetime. Polymer materials with good ionic conductivity, superior processability and high flexibility are considered as ideal artificial SEI film materials. In this review, according to the ionic conductive groups, recent advances in polymeric artificial SEI films are summarized to afford a deep understanding of Li ion plating/stripping behavior and present design principles of high-performance artificial SEI films in achieving stable Li metal electrodes. Perspectives regarding to the future research directions of polymeric artificial SEI films for Li–metal electrode are also discussed. The insights and design principles of polymeric artificial SEI films gained in the current review will be definitely useful in achieving the Li–metal batteries with improved energymore »« less

Authors:

Gao, Shilun ^[1]; Sun, Feiyuan ^[1]; Liu, Nian ^[2]; Yang, Huabin ^[1];

^[3]

Nankai Univ. (China)
Georgia Inst. of Technology, Atlanta, GA (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Publication Date:: Thu Jul 23 00:00:00 EDT 2020

Research Org.:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1649020

Grant/Contract Number:: AC05-00OR22725

Resource Type:: Accepted Manuscript

Journal Name:: Materials Today

Additional Journal Information:: Journal Volume: 40; Journal ID: ISSN 1369-7021

Publisher:: Elsevier

Country of Publication:: United States

Language:: English

Subject:: 25 ENERGY STORAGE

Citation Formats


                    Gao, Shilun, Sun, Feiyuan, Liu, Nian, Yang, Huabin, and Cao, Pengfei. Ionic conductive polymers as artificial solid electrolyte interphase films in Li metal batteries – A review.  United States: N. p., 2020. 
Web.  doi:10.1016/j.mattod.2020.06.011.

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                    Gao, Shilun, Sun, Feiyuan, Liu, Nian, Yang, Huabin, & Cao, Pengfei. Ionic conductive polymers as artificial solid electrolyte interphase films in Li metal batteries – A review.  United States.  https://doi.org/10.1016/j.mattod.2020.06.011

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                    Gao, Shilun, Sun, Feiyuan, Liu, Nian, Yang, Huabin, and Cao, Pengfei. Thu .  
"Ionic conductive polymers as artificial solid electrolyte interphase films in Li metal batteries – A review".  United States.  https://doi.org/10.1016/j.mattod.2020.06.011.  https://www.osti.gov/servlets/purl/1649020.

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@article{osti_1649020,

  title        = {Ionic conductive polymers as artificial solid electrolyte interphase films in Li metal batteries – A review},

  author       = {Gao, Shilun and Sun, Feiyuan and Liu, Nian and Yang, Huabin and Cao, Pengfei},

  abstractNote = {Lithium (Li) metal has been considered as the ultimate anode material for next-generation rechargeable batteries due to its ultra-high theoretical specific capacity (3860 mAh g-1) and the lowest reduction voltage (-3.04 V vs the standard hydrogen electrode). However, the dendritic Li formation, uncontrolled interfacial reactions, and huge volume variations lead to unstable solid electrolyte interphase (SEI) layer, low Coulombic efficiency and hence short cycling lifetime. Designing artificial solid electrolyte interphase (artificial SEI) films on the Li metal electrode exhibits great potential to solve the aforementioned problems and enable Li–metal batteries with prolonged lifetime. Polymer materials with good ionic conductivity, superior processability and high flexibility are considered as ideal artificial SEI film materials. In this review, according to the ionic conductive groups, recent advances in polymeric artificial SEI films are summarized to afford a deep understanding of Li ion plating/stripping behavior and present design principles of high-performance artificial SEI films in achieving stable Li metal electrodes. Perspectives regarding to the future research directions of polymeric artificial SEI films for Li–metal electrode are also discussed. The insights and design principles of polymeric artificial SEI films gained in the current review will be definitely useful in achieving the Li–metal batteries with improved energy density, high safety and long cycling lifetime toward next-generation energy storage devices.},

  doi          = {10.1016/j.mattod.2020.06.011},

  journal      = {Materials Today},

  number       = ,

  volume       = 40,

  place        = {United States},

  year         = {Thu Jul 23 00:00:00 EDT 2020},

  month        = {Thu Jul 23 00:00:00 EDT 2020}

}

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Kozen, Alexander C.; Lin, Chuan-Fu; Zhao, Oliver
Chemistry of Materials, Vol. 29, Issue 15
DOI: 10.1021/acs.chemmater.7b01496

Interfacial Chemistry Regulation via a Skin-Grafting Strategy Enables High-Performance Lithium-Metal Batteries
journal, October 2017

Gao, Yue; Zhao, Yuming; Li, Yuguang C.
Journal of the American Chemical Society, Vol. 139, Issue 43
DOI: 10.1021/jacs.7b06437

A Novel Organic “Polyurea” Thin Film for Ultralong-Life Lithium-Metal Anodes via Molecular-Layer Deposition
journal, December 2018

Sun, Yipeng; Zhao, Yang; Wang, Jiwei
Advanced Materials, Vol. 31, Issue 4
DOI: 10.1002/adma.201806541

Simultaneously Regulating Lithium Ion Flux and Surface Activity for Dendrite-Free Lithium Metal Anodes
journal, January 2019

Wang, Xianshu; Pan, Zhenghui; Zhuang, Jingchun
ACS Applied Materials & Interfaces, Vol. 11, Issue 5
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Suppressing Li dendrite by a protective biopolymeric film from tamarind seed polysaccharide for high-performance Li metal anode
journal, March 2019

You, Jin-Hai; Zhang, Shao-Jian; Deng, Li
Electrochimica Acta, Vol. 299
DOI: 10.1016/j.electacta.2019.01.045

Poly(ethyl α-cyanoacrylate)-Based Artificial Solid Electrolyte Interphase Layer for Enhanced Interface Stability of Li Metal Anodes
journal, May 2017

Hu, Zhenglin; Zhang, Shu; Dong, Shanmu
Chemistry of Materials, Vol. 29, Issue 11
DOI: 10.1021/acs.chemmater.7b00091

Surface Coating Layer on Li Metal for Increased Cycle Stability of Li–O ₂ Batteries
journal, January 2014

Jang, Il Chan; Ida, Shintaro; Ishihara, Tatsumi
Journal of The Electrochemical Society, Vol. 161, Issue 5
DOI: 10.1149/2.087405jes

A simple composite protective layer coating that enhances the cycling stability of lithium metal batteries
journal, June 2015

Lee, Hongkyung; Lee, Dong Jin; Kim, Yun-Jung
Journal of Power Sources, Vol. 284
DOI: 10.1016/j.jpowsour.2015.03.004

A Dynamic, Electrolyte-Blocking, and Single-Ion-Conductive Network for Stable Lithium-Metal Anodes
journal, November 2019

Yu, Zhiao; Mackanic, David G.; Michaels, Wesley
Joule, Vol. 3, Issue 11
DOI: 10.1016/j.joule.2019.07.025

Polymeric ionic liquid–ionic plastic crystal all-solid-state electrolytes for wide operating temperature range lithium metal batteries
journal, January 2017

Li, Xiaowei; Zhang, Zhengxi; Li, Sijian
J. Mater. Chem. A, Vol. 5, Issue 40
DOI: 10.1039/C7TA04204C

Gel Polymer Electrolyte with High Li ⁺ Transference Number Enhancing the Cycling Stability of Lithium Anodes
journal, January 2019

Wang, Yanan; Fu, Lixin; Shi, Liyi
ACS Applied Materials & Interfaces, Vol. 11, Issue 5
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Ionomer-Liquid Electrolyte Hybrid Ionic Conductor for High Cycling Stability of Lithium Metal Electrodes
journal, September 2015

Song, Jongchan; Lee, Hongkyung; Choo, Min-Ju
Scientific Reports, Vol. 5, Issue 1
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A star-shaped single lithium-ion conducting copolymer by grafting a POSS nanoparticle
journal, August 2017

Cao, Peng-Fei; Wojnarowska, Zaneta; Hong, Tao
Polymer, Vol. 124
DOI: 10.1016/j.polymer.2017.07.052

Effect of Binder Architecture on the Performance of Silicon/Graphite Composite Anodes for Lithium Ion Batteries
journal, January 2018

Cao, Peng-Fei; Naguib, Michael; Du, Zhijia
ACS Applied Materials & Interfaces, Vol. 10, Issue 4
DOI: 10.1021/acsami.7b13205

A Flexible Solid Electrolyte Interphase Layer for Long-Life Lithium Metal Anodes
journal, January 2018

Li, Nian-Wu; Shi, Yang; Yin, Ya-Xia
Angewandte Chemie International Edition, Vol. 57, Issue 6
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Rational design of robust-flexible protective layer for safe lithium metal battery
journal, March 2019

Li, Siyuan; Fan, Lei; Lu, Yingying
Energy Storage Materials, Vol. 18
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Silicon(lithiated)–sulfur full cells with porous silicon anode shielded by Nafion against polysulfides to achieve high capacity and energy density
journal, January 2016

Shen, Chenfei; Ge, Mingyuan; Zhang, Anyi
Nano Energy, Vol. 19
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Rational Integration of Polypropylene/Graphene Oxide/Nafion as Ternary-Layered Separator to Retard the Shuttle of Polysulfides for Lithium-Sulfur Batteries
journal, December 2015

Zhuang, Ting-Zhou; Huang, Jia-Qi; Peng, Hong-Jie
Small, Vol. 12, Issue 3
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Nafion/Titanium Dioxide-Coated Lithium Anode for Stable Lithium-Sulfur Batteries
journal, May 2018

Jiang, Shuang; Lu, Yong; Lu, Yanying
Chemistry - An Asian Journal, Vol. 13, Issue 10
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Fabrication of Hybrid Silicate Coatings by a Simple Vapor Deposition Method for Lithium Metal Anodes
journal, October 2017

Liu, Fang; Xiao, Qiangfeng; Wu, Hao Bin
Advanced Energy Materials, Vol. 8, Issue 6
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An Artificial Solid Electrolyte Interphase Layer for Stable Lithium Metal Anodes
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Li, Nian-Wu; Yin, Ya-Xia; Yang, Chun-Peng
Advanced Materials, Vol. 28, Issue 9
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Green in Situ Growth Solid Electrolyte Interphase Layer with High Rebound Resilience for Long-Life Lithium Metal Anodes
journal, October 2019

Wu, Na; Shi, Ya-Ru; Jia, Ting
ACS Applied Materials & Interfaces, Vol. 11, Issue 46
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Lithium iodide effect on the electrochemical behavior of agarose based polymer electrolyte for dye-sensitized solar cell
journal, August 2011

Wang, Weijia; Guo, Xueyi; Yang, Ying
Electrochimica Acta, Vol. 56, Issue 21
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Dendrite-Free Lithium Anode via a Homogenous Li-Ion Distribution Enabled by a Kimwipe Paper
journal, January 2017

Chang, Chi-Hao; Chung, Sheng-Heng; Manthiram, Arumugam
Advanced Sustainable Systems, Vol. 1, Issue 1-2
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A dual-functional polymer coating on a lithium anode for suppressing dendrite growth and polysulfide shuttling in Li–S batteries
journal, January 2017

Luo, Jing; Lee, Rung-Chuan; Jin, Jian-Ting
Chemical Communications, Vol. 53, Issue 5
DOI: 10.1039/C6CC09248A

Composite protection layers for dendrite-suppressing non-granular micro-patterned lithium metal anodes
journal, August 2018

Kim, Seokwoo; Park, Jinkyu; Friesen, Alex
Electrochimica Acta, Vol. 282
DOI: 10.1016/j.electacta.2018.05.102

Composite protective layer for Li metal anode in high-performance lithium–oxygen batteries
journal, March 2014

Lee, Dong Jin; Lee, Hongkyung; Song, Jongchan
Electrochemistry Communications, Vol. 40
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Superior Conductive Solid-like Electrolytes: Nanoconfining Liquids within the Hollow Structures
journal, April 2015

Zhang, Jinshui; Bai, Ying; Sun, Xiao-Guang
Nano Letters, Vol. 15, Issue 5
DOI: 10.1021/acs.nanolett.5b00739

Suppression of Lithium Dendrite Growth Using Cross-Linked Polyethylene/Poly(ethylene oxide) Electrolytes: A New Approach for Practical Lithium-Metal Polymer Batteries
journal, May 2014

Khurana, Rachna; Schaefer, Jennifer L.; Archer, Lynden A.
Journal of the American Chemical Society, Vol. 136, Issue 20
DOI: 10.1021/ja502133j

Poly(ethylene oxide)-based electrolytes for lithium-ion batteries
journal, January 2015

Xue, Zhigang; He, Dan; Xie, Xiaolin
Journal of Materials Chemistry A, Vol. 3, Issue 38
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Polar polymer–solvent interaction derived favorable interphase for stable lithium metal batteries
journal, January 2019

Bae, Jiwoong; Qian, Yumin; Li, Yutao
Energy & Environmental Science, Vol. 12, Issue 11
DOI: 10.1039/C9EE02558H

Stabilizing electrodeposition in elastic solid electrolytes containing immobilized anions
journal, July 2016

Tikekar, Mukul D.; Archer, Lynden A.; Koch, Donald L.
Science Advances, Vol. 2, Issue 7
DOI: 10.1126/sciadv.1600320

Hybridization of MOFs and polymers
journal, January 2017

Kitao, Takashi; Zhang, Yuanyuan; Kitagawa, Susumu
Chemical Society Reviews, Vol. 46, Issue 11
DOI: 10.1039/C7CS00041C

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Title: Ionic conductive polymers as artificial solid electrolyte interphase films in Li metal batteries – A review

Abstract

Citation Formats

Anode Interface Engineering and Architecture Design for High‐Performance Lithium–Sulfur Batteries journal, January 2019

Status and challenges in enabling the lithium metal electrode for high-energy and low-cost rechargeable batteries journal, December 2017

Li-ion battery materials: present and future journal, June 2015

Conductive Polymer Binder for High-Tap-Density Nanosilicon Material for Lithium-Ion Battery Negative Electrode Application journal, November 2015

Aluminum fumarate-based metal organic frameworks with tremella-like structure as ultrafast and stable anode for lithium-ion batteries journal, September 2017

Polymer Binders Constructed through Dynamic Noncovalent Bonds for High‐Capacity Silicon‐Based Anodes journal, September 2009

Mechanical rolling formation of interpenetrated lithium metal/lithium tin alloy foil for ultrahigh-rate battery anode journal, February 2020

Toward Safe Lithium Metal Anode in Rechargeable Batteries: A Review journal, July 2017

Li–O2 and Li–S batteries with high energy storage journal, January 2012

A novel maleic acid/graphite composite anode for lithium ion batteries with high energy and power density journal, June 2018

Supremely elastic gel polymer electrolyte enables a reliable electrode structure for silicon-based anodes journal, December 2019

Towards high energy density lithium battery anodes: silicon and lithium journal, January 2019

Adhesive Polymers as Efficient Binders for High-Capacity Silicon Electrodes journal, March 2020

Advanced Micro/Nanostructures for Lithium Metal Anodes journal, February 2017

Nanoporous Polymer Films with a High Cation Transference Number Stabilize Lithium Metal Anodes in Light-Weight Batteries for Electrified Transportation journal, January 2019

Advances in Interfaces between Li Metal Anode and Electrolyte journal, December 2017

Interconnected hollow carbon nanospheres for stable lithium metal anodes journal, July 2014

Recent progresses in the suppression method based on the growth mechanism of lithium dendrite journal, March 2018

In Situ Volume Change Studies of Lithium Metal Electrode under Different Pressure journal, January 2019

Promoted rate and cycling capability of Li–S batteries enabled by targeted selection of co-solvent for the electrolyte journal, March 2020

Nucleophilic substitution between polysulfides and binders unexpectedly stabilizing lithium sulfur battery journal, August 2017

Gelatin-polyethylenimine composite as a functional binder for highly stable lithium-sulfur batteries journal, August 2018

Issues and challenges facing rechargeable lithium batteries journal, November 2001

Alkali Metal Anodes for Rechargeable Batteries journal, February 2019

Lithium metal anodes for rechargeable batteries journal, January 2014

Suppression of dendritic lithium growth in lithium metal-based batteries journal, January 2018

Towards better Li metal anodes: Challenges and strategies journal, March 2020

High-capacity lithium sulfur battery and beyond: a review of metal anode protection layers and perspective of solid-state electrolytes journal, November 2018

Low-volume-change, dendrite-free lithium metal anodes enabled by lithophilic 3D matrix with LiF-enriched surface journal, January 2019

Poly(dimethylsiloxane) Thin Film as a Stable Interfacial Layer for High-Performance Lithium-Metal Battery Anodes journal, October 2016

A consideration of the morphology of electrochemically deposited lithium in an organic electrolyte journal, August 1998

Behavior of lithium-electrolyte interface during cycling in some ether-carbonate and carbonate mixtures journal, March 1995

Recent advances in understanding dendrite growth on alkali metal anodes journal, July 2019

Understanding and suppression strategies toward stable Li metal anode for safe lithium batteries journal, March 2020

Reviving the lithium metal anode for high-energy batteries journal, March 2017

Recent development in lithium metal anodes of liquid-state rechargeable batteries journal, January 2018

LiXGe containing ion-conductive hybrid skin for high rate lithium metal anode journal, September 2019

Stabilizing Li Metal Anodes through a Novel Self-Healing Strategy journal, July 2018

Two-Dimensional Phosphorene-Derived Protective Layers on a Lithium Metal Anode for Lithium-Oxygen Batteries journal, April 2018

Mechanical Surface Modification of Lithium Metal: Towards Improved Li Metal Anode Performance by Directed Li Plating journal, December 2014

Highly stable lithium metal anode with near-zero volume change enabled by capped 3D lithophilic framework journal, March 2020

Electrochemical Diagram of an Ultrathin Lithium Metal Anode in Pouch Cells journal, July 2019

Temperature-Dependent Nucleation and Growth of Dendrite-Free Lithium Metal Anodes journal, July 2019

Dynamic Lithium Distribution upon Dendrite Growth and Shorting Revealed by Operando Neutron Imaging journal, September 2019

Review—SEI: Past, Present and Future journal, January 2017

3D hollow reduced graphene oxide foam as a stable host for high-capacity lithium metal anodes journal, January 2019

Dendrite-Free, High-Rate, Long-Life Lithium Metal Batteries with a 3D Cross-Linked Network Polymer Electrolyte journal, February 2017

Structural Peculiarities of Ion-Conductive Organic-Inorganic Polymer Composites Based on Aliphatic Epoxy Resin and Salt of Lithium Perchlorate journal, June 2017

A Thermally Conductive Separator for Stable Li Metal Anodes journal, August 2015

Ion-channel aligned gas-blocking membrane for lithium-air batteries journal, September 2017

A Nano‐shield Design for Separators to Resist Dendrite Formation in Lithium‐Metal Batteries journal, February 2020

Three-Dimensional, Solid-State Mixed Electron–Ion Conductive Framework for Lithium Metal Anode journal, May 2018

Low-Weight 3D Al 2 O 3 Network as an Artificial Layer to Stabilize Lithium Deposition journal, August 2018

Anchoring an Artificial Solid-Electrolyte Interphase Layer on a 3D Current Collector for High-Performance Lithium Anodes journal, January 2019

Flower-shaped lithium nitride as a protective layer via facile plasma activation for stable lithium metal anodes journal, March 2019

Porous LiF layer fabricated by a facile chemical method toward dendrite-free lithium metal anode journal, October 2019

Polyethylene oxide film coating enhances lithium cycling efficiency of an anode-free lithium-metal battery journal, January 2018

A dendrite- and oxygen-proof protective layer for lithium metal in lithium–oxygen batteries journal, January 2019

Superstretchable, Self-Healing Polymeric Elastomers with Tunable Properties journal, April 2018

Elastic Single-Ion Conducting Polymer Electrolytes: Toward a Versatile Approach for Intrinsically Stretchable Functional Polymers journal, April 2020

Artificial Interphases for Highly Stable Lithium Metal Anode journal, August 2019

Advances in Artificial Layers for Stable Lithium Metal Anodes journal, April 2020

Interlayers for lithium-based batteries journal, December 2019

Designing polymers for advanced battery chemistries journal, April 2019

Electrochemical characterization of polymer precoated lithium electrodes journal, July 1996

Electrochemical performance of lithium/sulfur batteries with protected Li anodes journal, June 2003

Effects of Polymer Coatings on Electrodeposited Lithium Metal journal, August 2018

Three-Dimensional Conductive Gel Network as an Effective Binder for High-Performance Si Electrodes in Lithium-Ion Batteries journal, July 2015

Double-Layer Polymer Electrolyte for High-Voltage All-Solid-State Rechargeable Batteries journal, December 2018

Poly(ethylene oxide)-based block copolymer electrolytes for lithium metal batteries: PEO-based BCEs for LMBs journal, August 2018

Recent progress in polymer materials for advanced lithium-sulfur batteries journal, March 2019

Review—Solid Electrolytes for Safe and High Energy Density Lithium-Sulfur Batteries: Promises and Challenges journal, June 2017

Improving the cycling stability of silicon nanowire anodes with conducting polymer coatings journal, January 2012

Highly Conductive and Transparent PEDOT:PSS Films with a Fluorosurfactant for Stretchable and Flexible Transparent Electrodes journal, November 2011

Water-Soluble Conductive Composite Binder Containing PEDOT:PSS as Conduction Promoting Agent for Si Anode of Lithium-Ion Batteries journal, August 2014

Ionically cross-linked PEDOT:PSS as a multi-functional conductive binder for high-performance lithium–sulfur batteries journal, January 2018

Ultrafine Sulfur Nanoparticles in Conducting Polymer Shell as Cathode Materials for High Performance Lithium/Sulfur Batteries journal, May 2013

Anode Interface Engineering and Architecture Design for High‐Performance Lithium–Sulfur Batteries
journal, January 2019

Status and challenges in enabling the lithium metal electrode for high-energy and low-cost rechargeable batteries
journal, December 2017

Li-ion battery materials: present and future
journal, June 2015

Conductive Polymer Binder for High-Tap-Density Nanosilicon Material for Lithium-Ion Battery Negative Electrode Application
journal, November 2015

Aluminum fumarate-based metal organic frameworks with tremella-like structure as ultrafast and stable anode for lithium-ion batteries
journal, September 2017

Polymer Binders Constructed through Dynamic Noncovalent Bonds for High‐Capacity Silicon‐Based Anodes
journal, September 2009

Mechanical rolling formation of interpenetrated lithium metal/lithium tin alloy foil for ultrahigh-rate battery anode
journal, February 2020

Toward Safe Lithium Metal Anode in Rechargeable Batteries: A Review
journal, July 2017

Li–O₂ and Li–S batteries with high energy storage
journal, January 2012

A novel maleic acid/graphite composite anode for lithium ion batteries with high energy and power density
journal, June 2018

Supremely elastic gel polymer electrolyte enables a reliable electrode structure for silicon-based anodes
journal, December 2019

Towards high energy density lithium battery anodes: silicon and lithium
journal, January 2019

Adhesive Polymers as Efficient Binders for High-Capacity Silicon Electrodes
journal, March 2020

Advanced Micro/Nanostructures for Lithium Metal Anodes
journal, February 2017

Nanoporous Polymer Films with a High Cation Transference Number Stabilize Lithium Metal Anodes in Light-Weight Batteries for Electrified Transportation
journal, January 2019

Advances in Interfaces between Li Metal Anode and Electrolyte
journal, December 2017

Interconnected hollow carbon nanospheres for stable lithium metal anodes
journal, July 2014

Recent progresses in the suppression method based on the growth mechanism of lithium dendrite
journal, March 2018

In Situ Volume Change Studies of Lithium Metal Electrode under Different Pressure
journal, January 2019

Promoted rate and cycling capability of Li–S batteries enabled by targeted selection of co-solvent for the electrolyte
journal, March 2020

Nucleophilic substitution between polysulfides and binders unexpectedly stabilizing lithium sulfur battery
journal, August 2017

Gelatin-polyethylenimine composite as a functional binder for highly stable lithium-sulfur batteries
journal, August 2018

Issues and challenges facing rechargeable lithium batteries
journal, November 2001

Alkali Metal Anodes for Rechargeable Batteries
journal, February 2019

Lithium metal anodes for rechargeable batteries
journal, January 2014

Suppression of dendritic lithium growth in lithium metal-based batteries
journal, January 2018

Towards better Li metal anodes: Challenges and strategies
journal, March 2020

High-capacity lithium sulfur battery and beyond: a review of metal anode protection layers and perspective of solid-state electrolytes
journal, November 2018

Low-volume-change, dendrite-free lithium metal anodes enabled by lithophilic 3D matrix with LiF-enriched surface
journal, January 2019

Poly(dimethylsiloxane) Thin Film as a Stable Interfacial Layer for High-Performance Lithium-Metal Battery Anodes
journal, October 2016

A consideration of the morphology of electrochemically deposited lithium in an organic electrolyte
journal, August 1998

Behavior of lithium-electrolyte interface during cycling in some ether-carbonate and carbonate mixtures
journal, March 1995

Recent advances in understanding dendrite growth on alkali metal anodes
journal, July 2019

Understanding and suppression strategies toward stable Li metal anode for safe lithium batteries
journal, March 2020

Reviving the lithium metal anode for high-energy batteries
journal, March 2017

Recent development in lithium metal anodes of liquid-state rechargeable batteries
journal, January 2018

LiXGe containing ion-conductive hybrid skin for high rate lithium metal anode
journal, September 2019

Stabilizing Li Metal Anodes through a Novel Self-Healing Strategy
journal, July 2018

Two-Dimensional Phosphorene-Derived Protective Layers on a Lithium Metal Anode for Lithium-Oxygen Batteries
journal, April 2018

Mechanical Surface Modification of Lithium Metal: Towards Improved Li Metal Anode Performance by Directed Li Plating
journal, December 2014

Highly stable lithium metal anode with near-zero volume change enabled by capped 3D lithophilic framework
journal, March 2020

Electrochemical Diagram of an Ultrathin Lithium Metal Anode in Pouch Cells
journal, July 2019

Temperature-Dependent Nucleation and Growth of Dendrite-Free Lithium Metal Anodes
journal, July 2019

Dynamic Lithium Distribution upon Dendrite Growth and Shorting Revealed by Operando Neutron Imaging
journal, September 2019

Review—SEI: Past, Present and Future
journal, January 2017

3D hollow reduced graphene oxide foam as a stable host for high-capacity lithium metal anodes
journal, January 2019

Dendrite-Free, High-Rate, Long-Life Lithium Metal Batteries with a 3D Cross-Linked Network Polymer Electrolyte
journal, February 2017

Structural Peculiarities of Ion-Conductive Organic-Inorganic Polymer Composites Based on Aliphatic Epoxy Resin and Salt of Lithium Perchlorate
journal, June 2017

A Thermally Conductive Separator for Stable Li Metal Anodes
journal, August 2015

Ion-channel aligned gas-blocking membrane for lithium-air batteries
journal, September 2017

A Nano‐shield Design for Separators to Resist Dendrite Formation in Lithium‐Metal Batteries
journal, February 2020

Three-Dimensional, Solid-State Mixed Electron–Ion Conductive Framework for Lithium Metal Anode
journal, May 2018

Low-Weight 3D Al ₂ O ₃ Network as an Artificial Layer to Stabilize Lithium Deposition
journal, August 2018

Anchoring an Artificial Solid-Electrolyte Interphase Layer on a 3D Current Collector for High-Performance Lithium Anodes
journal, January 2019

Flower-shaped lithium nitride as a protective layer via facile plasma activation for stable lithium metal anodes
journal, March 2019

Porous LiF layer fabricated by a facile chemical method toward dendrite-free lithium metal anode
journal, October 2019

Polyethylene oxide film coating enhances lithium cycling efficiency of an anode-free lithium-metal battery
journal, January 2018

A dendrite- and oxygen-proof protective layer for lithium metal in lithium–oxygen batteries
journal, January 2019

Superstretchable, Self-Healing Polymeric Elastomers with Tunable Properties
journal, April 2018

Elastic Single-Ion Conducting Polymer Electrolytes: Toward a Versatile Approach for Intrinsically Stretchable Functional Polymers
journal, April 2020

Artificial Interphases for Highly Stable Lithium Metal Anode
journal, August 2019

Advances in Artificial Layers for Stable Lithium Metal Anodes
journal, April 2020

Interlayers for lithium-based batteries
journal, December 2019

Designing polymers for advanced battery chemistries
journal, April 2019

Electrochemical characterization of polymer precoated lithium electrodes
journal, July 1996

Electrochemical performance of lithium/sulfur batteries with protected Li anodes
journal, June 2003

Effects of Polymer Coatings on Electrodeposited Lithium Metal
journal, August 2018

Three-Dimensional Conductive Gel Network as an Effective Binder for High-Performance Si Electrodes in Lithium-Ion Batteries
journal, July 2015

Double-Layer Polymer Electrolyte for High-Voltage All-Solid-State Rechargeable Batteries
journal, December 2018

Poly(ethylene oxide)-based block copolymer electrolytes for lithium metal batteries: PEO-based BCEs for LMBs
journal, August 2018

Recent progress in polymer materials for advanced lithium-sulfur batteries
journal, March 2019

Review—Solid Electrolytes for Safe and High Energy Density Lithium-Sulfur Batteries: Promises and Challenges
journal, June 2017

Improving the cycling stability of silicon nanowire anodes with conducting polymer coatings
journal, January 2012

Highly Conductive and Transparent PEDOT:PSS Films with a Fluorosurfactant for Stretchable and Flexible Transparent Electrodes
journal, November 2011

Water-Soluble Conductive Composite Binder Containing PEDOT:PSS as Conduction Promoting Agent for Si Anode of Lithium-Ion Batteries
journal, August 2014

Ionically cross-linked PEDOT:PSS as a multi-functional conductive binder for high-performance lithium–sulfur batteries
journal, January 2018

Ultrafine Sulfur Nanoparticles in Conducting Polymer Shell as Cathode Materials for High Performance Lithium/Sulfur Batteries
journal, May 2013

Improved Cycling Stability of Lithium Electrodes in Rechargeable Lithium Batteries
journal, October 2013

Enhanced cycle performance of a Li–S battery based on a protected lithium anode
journal, January 2014

An air-stable and waterproof lithium metal anode enabled by wax composite packaging
journal, July 2019