Stable Metal–Organic Frameworks with Group 4 Metals: Current Status and Trends
Abstract
Group 4 metal-based metal–organic frameworks (MIV-MOFs), including Ti-, Zr-, and Hf-based MOFs, are one of the most attractive classes of MOF materials owing to their superior chemical stability and structural tunability. Despite being a relatively new field, MIV-MOFs have attracted significant research attention in the past few years, leading to exciting advances in syntheses and applications. In this outlook, we start with a brief overview of the history and current status of MIV-MOFs, emphasizing the challenges encountered in their syntheses. The unique properties of MIV-MOFs are discussed, including their high chemical stability and strong tolerance toward defects. Particular emphasis is placed on defect engineering in Zr-MOFs which offers additional routes to tailor their functions. Photocatalysis of MIV-MOF is introduced as a representative example of their emerging applications. Finally, we conclude with the perspective of new opportunities in synthesis and defect engineering.
- Authors:
-
[2]
- Department of Chemistry, Texas A&,M University, College Station, Texas 77843-3255, United States
- Department of Chemistry, Texas A&,M University, College Station, Texas 77843-3255, United States, Department of Materials Science and Engineering, Texas A&,M University, College Station, Texas 77843-3003, United States
- Publication Date:
- Research Org.:
- Energy Frontier Research Centers (EFRC) (United States). Center for Gas Separations Relevant to Clean Energy Technologies (CGS); National Energy Technology Laboratory (NETL), Pittsburgh, PA, Morgantown, WV (United States); Texas A & M Univ., College Station, TX (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Fossil Energy (FE)
- OSTI Identifier:
- 1429579
- Alternate Identifier(s):
- OSTI ID: 1498728; OSTI ID: 1508783
- Grant/Contract Number:
- SC0001015; FE0026472
- Resource Type:
- Published Article
- Journal Name:
- ACS Central Science
- Additional Journal Information:
- Journal Name: ACS Central Science Journal Volume: 4 Journal Issue: 4; Journal ID: ISSN 2374-7943
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Yuan, Shuai, Qin, Jun-Sheng, Lollar, Christina T., and Zhou, Hong-Cai. Stable Metal–Organic Frameworks with Group 4 Metals: Current Status and Trends. United States: N. p., 2018.
Web. doi:10.1021/acscentsci.8b00073.
Yuan, Shuai, Qin, Jun-Sheng, Lollar, Christina T., & Zhou, Hong-Cai. Stable Metal–Organic Frameworks with Group 4 Metals: Current Status and Trends. United States. https://doi.org/10.1021/acscentsci.8b00073
Yuan, Shuai, Qin, Jun-Sheng, Lollar, Christina T., and Zhou, Hong-Cai. Fri .
"Stable Metal–Organic Frameworks with Group 4 Metals: Current Status and Trends". United States. https://doi.org/10.1021/acscentsci.8b00073.
@article{osti_1429579,
title = {Stable Metal–Organic Frameworks with Group 4 Metals: Current Status and Trends},
author = {Yuan, Shuai and Qin, Jun-Sheng and Lollar, Christina T. and Zhou, Hong-Cai},
abstractNote = {Group 4 metal-based metal–organic frameworks (MIV-MOFs), including Ti-, Zr-, and Hf-based MOFs, are one of the most attractive classes of MOF materials owing to their superior chemical stability and structural tunability. Despite being a relatively new field, MIV-MOFs have attracted significant research attention in the past few years, leading to exciting advances in syntheses and applications. In this outlook, we start with a brief overview of the history and current status of MIV-MOFs, emphasizing the challenges encountered in their syntheses. The unique properties of MIV-MOFs are discussed, including their high chemical stability and strong tolerance toward defects. Particular emphasis is placed on defect engineering in Zr-MOFs which offers additional routes to tailor their functions. Photocatalysis of MIV-MOF is introduced as a representative example of their emerging applications. Finally, we conclude with the perspective of new opportunities in synthesis and defect engineering.},
doi = {10.1021/acscentsci.8b00073},
journal = {ACS Central Science},
number = 4,
volume = 4,
place = {United States},
year = {Fri Feb 23 00:00:00 EST 2018},
month = {Fri Feb 23 00:00:00 EST 2018}
}
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